• Title/Summary/Keyword: solvent system

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Fabrication of waveguide using UV Ar-ion laser direct writing (Laser Direct Writing 방법을 이용한 광도파로 제작)

  • Kang H. S.;Suh J.;Lee J. H.;Kim J. O.
    • Laser Solutions
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    • v.8 no.1
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    • pp.9-18
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    • 2005
  • The laser direct writing method using a UV Argon-ion laser is studied for fabrication of waveguide. The laser direct writing system is constructed with a vision camera, a xy-stage, a motion controller and the delivery components of a laser beam. The UV Argon-ion laser has wavelength range of $333.6\~363.8$ nm. A photo-active UV curable polymer for a planar light-wave circuit(PLC) of single mode is used. This polymer is irradiated by Argon-ion laser and developed by a solvent after a post-baking. The optimum laser direct writing condition is obtained experimentally by changing various process parameters such as laser power, writing speed and focal length. The propagation and coupling loss of a optical waveguide was measured as 1dB/cm and 0.6dB/cm, respectively. Also, the minimum width of waveguide of $100{\mu}m$(ZPLW-207) is obtained. Finally, the waveguides of line, bend and branch type are successfully fabricated.

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A study on the Change of Hand of Chitosan Crosslinked Cotton Fabrics - Effect of Concentration of Epichlorohydrin and Chitosan - (키토산 가교처리된 면직물의 태 변화에 관한 연구 - 에피클로로히드린과 키토산 농도의 영향-)

  • Kim, Min-Ji;Park, Jung-Woo;Lee, Shin-Hee
    • Fashion & Textile Research Journal
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    • v.6 no.5
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    • pp.660-666
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    • 2004
  • This article describes the change of hand value of chitosan crosslinked cotton fabrics. The chitosan crosslinked cotton fabrics were manufactured by mercerizing process using epichlorohydrin(ECH) as crosslinkins agent, 2% aqueous acetic acid as a solvent of chitosan and ECH, and 20% aqueous sodium hydroxide as a mercerizing agent and crosslinking catalyst. Cotton fabrics were dipped in the mixed solution of chitosan and ECH, picked up by mangle, mercerized and crosslinked in NaOH solution, and finally wash and dry. Mechanical and physical properties of the chitosan crosslinked fabric were investigated using Kawabata Evaluation System(KES) and other instruments. Tensile energy and tensile strain were decreased with the increase of the concentration of chitosan. Tensile resilience, compression resilience bending rigidity, bending hysteresis, shear stiffness, shear hysteresis, coefficient of friction, geometrical roughness, compression linearity, compressional energy, and thickness were increased with the increase of the concentration of chitosan. On the other hand, bending rigidity, bending hysteresis, coefficient of friction, geometrical roughness, compressional resilience, and thickness were increased with the increase of the concentration of crosslinking agent(epichlorohydrin).

Characterization of Methanol-Water and Acetonitrile-Water Mixtures Using Iterative Target Transform Factor Analysis on Near Infrared Absorption Spectra (근적외선흡광스픽트럼에 대한 반복목표변환인자분석에 의한 메탄올-물 혼합액 및 아세토니트릴 -물 혼합액의 특성 확인)

  • 박영주;조정환
    • YAKHAK HOEJI
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    • v.48 no.1
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    • pp.6-12
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    • 2004
  • Near-infrared spectra of methanol-water mixtures and acetonitrile-water mixtures were acquired to find interactions between solvents widely used for reverse-phase liquid chromatography. Mixtures were prepared to give a series of increasing mole fractions of methanol or acetonitrile in water. Data matrices of acquired spectra were analyzed to determine the proper number of principal components of each mixture system using Malinowski's factor indicator function. Initial guess of score matrix and loading matrix were calculated by nonlinear iterative partial least squares (NIPALS) algorithm for faster computation. Iterative target transform factor analysis (ITTFA) was applied to convert the initial estimation of score matrix to true concentration profile and loading matrix to pure spectra of pure components of the mixtures. In case of methanol-water the number of principal components was found to be 4 and those initial guess of factors were converted to the pure spectra of water methanol and two kinds of complexes. In case of acetonitrile-water the number of pure components of the mixtures was found to be 3 and the pure spectrum of acetonitrile-water complex was found. The nonlinear characteristics of concentration profiles of complexes in the solvent mixtures may give a good criteria in understanding their elution characteristics in reverse-phase liquid chromatogrsphy.

Studies on the Effect of Aloe spp. on Ethanol Methabolism (I). -Effect of Aloe vera on Serum Ethanol Level and Hepatic ADH Activity- (Aloe속 식물이 알콜대사에 미치는 작용에 관한 연구(1) -Aloe vera가 알콜 및 알콜대사효소에 미치는 효과-)

  • Shin, Kuk-Hyun;Woo, Won-Sick;Song, Young-Jin;Chung, Ha-Sook;Lee, Jung-Mi;Shm, Chang-Sub
    • Korean Journal of Pharmacognosy
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    • v.26 no.2
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    • pp.148-153
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    • 1995
  • As an initial step for evaluating hepatoprotective components against alcohol-induced toxicity, the effect of various fractions from Aloe vera on alcohol metabolism in rats were examined and the results were as follows: Water soluble fraction, after a single oral administration to rats, was found to cause a significant decrease in the serum ethanol concentration as well as enhancement of liver cytosolic ADH activity. On the other hand, the fractions soluble in organic solvent was found to cause an increase in the blood ethanol concentration and inhibit ADH activity. Further fractionation of the water soluble fraction by ultrafiltration system gave four subfractions corresponding to molecular weight and treatment of them in rats demonstrated that subfraction of M.W. > 30,000 exhibited the most potent enhancing activity of ethanol methabolism.

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Induction of Methanol Tolerance in Rhizopus nigricans Ehrenberg (Rhizopus nigricans Ehrenberg의 Methanol 내성 유도)

  • 김명희;성혜윤;김말남
    • Korean Journal of Microbiology
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    • v.31 no.4
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    • pp.306-311
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    • 1993
  • The effects of methanol. used as a solvent for the hydrophobic substrate progesterone. on the morphology of Rhizopus nigricans and 11$\alpha$-hydroxylation of progesterone was investigated. The methanol tolerance of the 11$\alpha$-hydroxylase system in polyacrylamide immobilized R. nigricans mycelia as well as in free mycelia has been induced by adding various unsaturated fatty acids. biotin and ions into the cultivation medium. Immobilization of the cell seemed to protect the cells from denaturation by methanol. It gave higher reaction rate of progesterone than the free mycelia in the presence of methanol.500 $\mu$g/l of biotin was found to be the most effective induction agent for the methanol tolerance among tested chemicals. R. nixricans cells sustained its enzymatic activity at higher methanol concentrations as a result of accumulation of unsaturated fatty acids. especially oleic acid. in the membrane phospholipid.

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Detergency of PET Film Having Various Surface Free Energy: Part I. Surface Tension of MAA Grafted PET Film (Polyethylene terephthalate 필름의 표면에너지 변화에 따른 세척성(제일보) Methacrylic acid 그라프트 PET 필름의 표면장력)

  • Chung Hae-Won;Kim Sung-Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.12 no.2 s.27
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    • pp.217-223
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    • 1988
  • This study is to examine the cleaningproof by dry cleaning runs and parts(shoulder, belly, butt) of garment leathers tanned chrome. This study is composed of three methods of test; color difference test, surface view by scanning electron micrographs, mechanical properties measurement by KES-FB system. The results obtained were as follows: 1. In stiffening of parts of sample, the belly is the best degree in smoothness, fullness, softness. But that of the butt have been found to be the worst degree and to be thick. 2. In fading of parts, the shoulder is an extreme case, but the belly is the best among three parts. 3. In dry cleaning runs, the view after 3 runs has been found to be the best result. 4. The stiffening after dry cleaning 1 run have been low grade, for the sample absorb much solvent of dry cleaning. And, the fading and the decoloration are to be worse after 5 runs. Because the leather surface is affected by dry cleaning runs.

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A Study on Cleaningproof of Tanned Chrome Garment Leathers -On the Fading and Stiffening by Dry Cleaning- (의류용 크롬유혁의 내클리닝성에 관한 연구 -드라이클리닝에 의한 변색과 경화를 중심으로-)

  • Cho Seung-Shick;Sim Mi-Sook;Kim Un-Bae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.12 no.2 s.27
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    • pp.207-216
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    • 1988
  • This study is to examine the cleaningproof by dry cleaning runs and parts(shoulder, belly, butt) of garment leathers tanned chrome. This study is composed of three methods of test; color difference test, surface view by scanning electron micrographs, mechanical properties measurement by KES-FB system. The results obtained were as follows: 1. In stiffening of parts of sample, the belly is the best degree in smoothness, fullness, softness. But that of the butt have been found to be the worst degree and to be thick. 2. In fading of parts, the shoulder is an extreme case, but the belly is the best among three parts. 3. In dry cleaning runs, the view after 3 runs has been found to be the best result. 4. The stiffening after dry cleaning 1 run have been low grade, for the sample absorb much solvent of dry cleaning. And, the fading and the decoloration are to be worse after 5 runs. Because the leather surface is affected by dry cleaning runs.

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Preparation and Characterization of Chitosan/Cellulose Acetate Blend Film (키토산/셀룰로오스 아세테이트 복합필름의 제조와 특성)

  • Jung, Young-Jin;An, Byung-Jae;Choi, Hae-Wook;Kim, Hong-Sung;Lee, Young-Hee
    • Textile Coloration and Finishing
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    • v.19 no.4
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    • pp.10-17
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    • 2007
  • Chitosan(CS) and cellulose acetate(CA) composite films were prepared using formic acid as a cosolvent by casting, solvent evaporating and neutralization method. This study examines if the blending method, which uses formic acid as a cosolvent is efficient in improving the mechanical properties of CS film, especially wet strength and elongation. Formic acid is an effective cosolvent for the blend of CS and CA. Under wet condition, tensile strength and elongation of the composite films were obviously higher than those of the films made from pure CS. FTIR, DSC, and X-ray diffraction showed that the composite films exhibit a high level of compatibility and that strong interaction between the CS and CA was caused by intermolecular hydrogen bonding. The affinity series of composite film to transition metal ions are Cu(II) > Cd(II) > Cr(III). The adsorption of Cu((II) ion was shown to be highly pH sensitive.

Free Radical Scavenging and Antioxidative Activities by Ethanol Extract from Capsella bursa-pastoris (냉이(Capsella bursa-pastoris) 에탄올 추출물의 유리라디칼 소거 및 항산화 활성)

  • Hong, Jeong-Il;Na, Gyeong-Su;Yang, Han-Cheol
    • The Korean Journal of Food And Nutrition
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    • v.7 no.3
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    • pp.169-176
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    • 1994
  • Screening was performed on edible natural sources to examine superoxide radical scavenging activities by using the method of superoxide dismutase assay. Among 47 kinds of samples, the extract of Capsella bursa-pastoris showed a potent superoxide radical scavenging activity of 11.6 unit / mg solid and was selected for further studies. In order to select optimal extraction solvent system, Cappella bursa-pastoris was extracted with various solvents and the electron donating abilities and inhibitory effects on lipid peroxidation of linoleic acid were measured. Among them, the ethanol extract of Capsella bursa-pastoris possessed the highest level of activities. The ethanol extract of Cappella bursa-pastoris was found to have an inhibitory effect on autoxidation of soybean oil at 5$0^{\circ}C$ from peroxide value, conjugated diene value and refractive index. In the soybean oil containing 0.2% of ethanol extract, induction period was increased 2 times in comparison with control.

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Manufacture of ZPP Granule Using the LabRAM Mixer (LabRAM Mixer를 이용한 ZPP 입자 제조)

  • Jeong, Hyeheun;Kim, Junhyung;Ko, Seungwon;Ryu, Byungtae
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.4
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    • pp.63-70
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    • 2017
  • ZPP (Zirconium-Potassium Perchlorate) is type of primary charge initiators for PMD (Pyrotechnic Mechanical Device) system. The binder component dissolved in the solvent is precipitated to suspended particles in the granules. The LabRAM Mixer uses resonance phenomenon to transfer energy, unlike blade equipment that utilizes mechanical contact. In this study, the properties of the particles prepared by the LabRAM Mixer were evaluated with the changes of the conditions.