• Title/Summary/Keyword: solution synthesis

Search Result 1,784, Processing Time 0.026 seconds

Synthesis and Characterization of Borosilicate Catalyst (보로실리케이트 촉매의 합성 및 물성에 관한 연구)

  • Kaesoo Lee;Minsoo Cho;Chongsoo Han;Myeongseon Kim;Gon Seo
    • Journal of the Korean Chemical Society
    • /
    • v.33 no.4
    • /
    • pp.379-387
    • /
    • 1989
  • The synthesis of borosilicate consisted of boron and silicon was stadied. The composition, acidity and adsorption characteristics of synthesized borosilicate were examined. The synthesis rate increased with temperature and concentration of $Na_2O$, but the enhansing effects were different according to the reaction conditons. The synthesis process could be simulated by solution transfer mechanism assuming that crystals grow on the surface of crystal or nuclei with dissolved reactant. Adsorption characteristics of synthesized borosilicate was discussed with temperature programmed desorption patterns of ammonia and propylene and adsorption isotherms of propylene and propane.

  • PDF

A Study on Glycoside Synthesis Using Alginate-enclosed Microspheres (Alginate-enclosed Microspheres를 이용한 배당체 합성에 관한 연구)

  • 김해성;김우식
    • KSBB Journal
    • /
    • v.8 no.4
    • /
    • pp.320-327
    • /
    • 1993
  • Latex microspheres of styrene/acryl copolymer with acrylamide functional group were used for the stable covalent immobilization of an enzyme applicable for enzymatic synthesis of glycoside. The latex microspheres were coated with polyethyleneimine to establish structural and functional properties relevant to the covalent Immobilization with a high retention of activity. Polythyleneimine-coated microspheres satisfactorily immobilized the invertase for methyl fructoside synthesis, and model reaction were formed into alginate-enclosed microspheres biocatalyst. Using the alginate-enclosed microspheres biocatalyst, the yield of model glycoside was obtained as high as 52.2% at concentration of aqueous 30%(v/v) methanol and 0.291mo1/1 sucrose solution with 2U/ml of activity. The present study showed that the latex microspheres were successfully applied to enzymatic synthesis of glycoside.

  • PDF

Preparation of Oligonucleotide Arrays with High-Density DNA Deposition and High Hybridization Efficiency

  • Park, Jeong-Won;Jung, Yong-Won;Jung, Young-Hwan;Seo, Jeong-Sun;Lee, Young-Hoon
    • Bulletin of the Korean Chemical Society
    • /
    • v.25 no.11
    • /
    • pp.1667-1670
    • /
    • 2004
  • In DNA microarray produced by DNA-deposition technology, DNA-immobilization and -hybridization yields on a solid support are most important factors for its accuracy and sensitivity. We have developed a dendrimeric support using silylated aldehyde slides and polyamidoamine (PAMAM) dendrimers. An oligonucleotide array was prepared through a crosslinking between the dendrimeric support and an oligonucleotide. Both DNAimmobilization and -hybridization yields on the solid support increased by the modification with the dendrimers. The increase of the immobilization and hybridization efficiency seems to result from a threedimensional arrangement of the attached oligonucleotide. Therefore, our dendrimeric support may provide a simple and efficient solution to the preparation of DNA microarrays with high-density DNA-deposition and high hybridization efficiency.

INTERACTIVE SYSTEM DESIGN USING THE COMPLEMENTARITY OF AXIOMATIC DESIGN AND FAULT TREE ANALYSIS

  • Heo, Gyun-Young;Lee, Tae-Sik;Do, Sung-Hee
    • Nuclear Engineering and Technology
    • /
    • v.39 no.1
    • /
    • pp.51-62
    • /
    • 2007
  • To efficiently design safety-critical systems such as nuclear power plants, with the requirement of high reliability, methodologies allowing for rigorous interactions between the synthesis and analysis processes have been proposed. This paper attempts to develop a reliability-centered design framework through an interactive process between Axiomatic Design (AD) and Fault Tree Analysis (FTA). Integrating AD and FTA into a single framework appears to be a viable solution, as they compliment each other with their unique advantages. AD provides a systematic synthesis tool while FTA is commonly used as a safety analysis tool. These methodologies build a design process that is less subjective, and they enable designers to develop insights that lead to solutions with improved reliability. Due to the nature of the two methodologies, the information involved in each process is complementary: a success tree versus a fault tree. Thus, at each step a system using AD is synthesized, and its reliability is then quantified using the FT derived from the AD synthesis process. The converted FT provides an opportunity to examine the completeness of the outcome from the synthesis process. This study presents an example of the design of a Containment Heat Removal System (CHRS). A case study illustrates the process of designing the CHRS with an interactive design framework focusing on the conversion of the AD process to FTA.

On the Possibility of Bulk Large Diamond Single Crystal Synthesis with Hydrothermal Process

  • Andrzej M. Szymanski
    • Journal of the Mineralogical Society of Korea
    • /
    • v.10 no.1
    • /
    • pp.18-32
    • /
    • 1997
  • Analysis of geological data, relating to occurrence and formation of diamonds as well as host rocks, inclined author to have different outlook on the diamond genesis and to establish a proposition on their formation at pneumatolytic-hydrothermal conditions near superficial Earth zones. Based on that theoretical foundations and experimental works, the first low-pressure and low-temperature hydrothermal diamond synthesis from water solution in pressure autoclave was executed. As a result, the natural diamond seed crystal grew bigger ad coupling of the synthetic diamond single-crystalline grains were obtained. SEM documentation proofs that parallely paragenetic crystallization of quartz and diamond, and nucleation of new octahedral diamond crystals brush take place on the seed crystal surface. Forecast of none times growth of diamond industrial application at 2000 and seventeen times at 2010 with reference to 1995, needs technology of large and pure single-crystals diamond synthesis. Growth of the stable and destressed diamond single-crystals in the pseudo-metastable diamond plot, may be realized with processes going through the long time and with participation of free radicals catalysts admixtures only. Sol-gel colloidal processes are an example of environment which form stable crystals in thermodynamically unstable conditions through a long time. Paper critically discusses a whole way of studies on the diamond synthesis, from high-pressure and high-temperature processes through chemical vapour deposition up to hydrothermal experiments.

  • PDF