• 제목/요약/키워드: solution resistance

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SiO2 polysilicate 및 Melamine 조성에 따른 유/무기하이브리드 용액에 의한 자동차용 냉연강판의 내식성 (Corrosion Resistance of Cold Rolled Steel by Organic/Inorganic Hybrid Solution according to Composition of SiO2 polysilicate and Melamine)

  • 남기우;정희록;안병건;이광호
    • 동력기계공학회지
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    • 제20권5호
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    • pp.20-28
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    • 2016
  • This study has developed an organic/inorganic hybrid solution by addition of $SiO_2$ polysilicate and Melamine to the urethane. The three types of cold rolled steel were evaluated a corrosion resistance properties by using these solutions. The urethane solution(U) and the urethane solution with $SiO_2$ polysilicate($US_7$) were generate a lot of corrosion. The urethane solution with $SiO_2$ polysilicate and melamine($US_7M_3$) was excellent in corrosion resistance, regardless of the steel type. In addition, corrosion resistance has been shown to depend on the tensile strength. The appearance of coating by U and $US_7$ solution is bumpy surface, and were a lot of fine defects. $US_7M_3$ solution is made a sophisticated molecular cross-linking structure inside the coating, it was a slick surface. Other characteristics are exhibited the excellent property for all solutions.

Cr-free Si 변성 유/무기하이브리드 코팅액에 의한 열화된 STS310S 및 STS347H의 내식성 (Corrosion Resistance of Degraded STS310S and STS347H by Cr-free Modified Si Organic/Inorganic Hybrid Coating Solution)

  • 이소영;김영수;정희록;김귀식;남기우
    • 동력기계공학회지
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    • 제19권6호
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    • pp.12-18
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    • 2015
  • Austenitic stainless steels generally experience the occurrence of chromium-depleted zones at the boundaries, known as sensitization, caused by the carbide precipitation that takes place due to a welding process or heat treatment. Normally, the depleted zones become the focus of the intense corrosion. In this study, the Cr-free organic/inorganic hybrid solution was developed, and the artificially degraded STS316S and STS347H with the solution-coating investigated the corrosion resistance by salt spray test. Both the OIBD-1 and OIBD-2 solutions improved the corrosion resistance of STS310S and STS347H. The corrosion resistance with the OIBD-1 solution was better than that of OIBD-2 solution. Additionally, Both solutions have been proven excellence in adhesion ability, boiling water resistance and flexibility. However, a problem of rubbing after the boiling was found out to be overcome.

열화한 STS316L에 대한 Cr-free 코팅액의 내식특성 (Corrosion Resistance Characteristics of Cr-free Coating Solution for Degraded STS316L)

  • 이소영;김영수;정희록;안석환;남기우
    • 한국해양공학회지
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    • 제29권6호
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    • pp.475-480
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    • 2015
  • In this study, we developed a Cr-free organic/inorganic hybrid solution and investigated its coating properties on degraded STS316L. Both the OIBD-1 solution and OIBD-2 solution had excellent corrosion resistance and adhesion ability. However, the solution had some problems in a boiling water environment. In addition, the flexibility was excellent, and the scratch resistance was relatively good.

Preparation and Characterization of Coating Solution Based on Waterborne Polyurethane Dispersion containing Fluorine for Primer on Electro Galvanized Steel Sheet

  • Jin, Chung Keun;Lim, Sung Hyung
    • Corrosion Science and Technology
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    • 제14권5호
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    • pp.207-212
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    • 2015
  • The purpose of this research was to synthesize fluorine modified waterborne polyurethane dispersion (F-WPU) by soap-free (internal emulsifier) emulsion polymerization techniques, to prepare coating solution based on fluorine modified waterborne polyurethane dispersion (F-WPU) and to compare the chemical and thermo-mechanical properties on the electrogalvanized steel sheet. Environmentally friendly F-WPU was prepared with a fluorinated polyol containing 60 wt% of fluorine. There are various ways of combining a wide variety of fluorinated polyols and diisocyanate to exhibit novel properties of waterborne polyurethane dispersion. Components of coating solution were largely divided into 4 kinds i.e., F-WPU, acrylic emulsion, silane coupling agent, and colloidal silicate. F-WPU coating solution on the electro-galvanized steel sheet showed excellent properties of corrosion resistance, alkali resistance and heat resistance, as compared to other coating solutions using a general waterborne resin. The F-WPU coating solution's reliable effects are possibly due to the fluorine atoms incorporated even in a small amount of F-WPU.

전기화학적 부동태화에 의한 동관의 내식성 개선 연구 (Improvement of Corrosion Resistance for Copper Tube by Electrochemical Passivation)

  • 민성기;김경태;황운석
    • Corrosion Science and Technology
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    • 제10권4호
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    • pp.125-130
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    • 2011
  • This study was performed to improve the corrosion resistance and the stability of passive film on copper tube by potentiostatic polarization method in synthetic tap water. Formation of passive film was carried out by anodic potentiostatic polarization at various passivation potentials and passivation times in 0.1 M NaOH solution. Stability of passive film and corrosion resistance was evaluated by self-activation time, ${\tau}_0$ from passive state to active state on open-circuit state in 0.1 M NaOH solution. Addition of polyphosphate in NaOH solution prolonged the self-activation time and improved the corrosion resistance, and the addition of 5 ppm polyphosphate was most effective. It was also observed that better corrosion resistance was obtained by potentiostatic polarization at 1.0 V (vs. SCE) than at any other passivation potentials. Passivated copper tube showed perfect corrosion resistance for the immersion test in synthetic tap water showing that the anodic potentiostatic polarization treatment in 0.1 M NaOH with 5 ppm polyphosphate solution would be effective in improving the corrosion resistance and preventing the blue water problem.

Ni-SiC 복합도금층의 내마모성에 관한 연구 (A study on the wear resistance of Ni-SiC composite plating)

  • 김성호;한혜원;장현구
    • 한국표면공학회지
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    • 제29권1호
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    • pp.26-35
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    • 1996
  • The Ni-SiC composite plating was performed in a Watt nickel solution and the wear resistance of the composite layer was studied on a pin-on-flat type wear tester. The volume losses and friction coefficients were measured. It was found that the quantity of SiC powder in the composite layers was affected by SiC concentration, pH, temperature, and agitation speed in the Watt nickel solution. The hardness and wear resistance of the coatings increased with SiC content. The quantity of SiC powder in the coating from a nickel sulfamate solution is larger than that of the Watt nickel solution, because the amount of nickel ions absorbed on the SiC powder in the nickel sulfamate solution is greater than that in the Watt's solution.

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미끄럼시험에서 비눗물을 대체하기 위한 SDS 수용액의 적정 혼합비율 도출 (Extraction of Proper Mixture Ratio of SDS Solution as the Substitute of Soapy Water in a Slip Test)

  • 김대규;신윤호;최수경
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2016년도 춘계 학술논문 발표대회
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    • pp.83-84
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    • 2016
  • For the slip resistance test of shower room floor, the "O-Y Pull Slip Meter method (O-Y·PSM)" regulated under KS M 3510. This test method uses cooking oil as a substitute of soapy water, and thus it does not reflect the real condition. In this study, on 10 types of floor material samples, the Coefficient of Slip Resistance Bath (CSR·B) on bare foot between 10 types of body wash solution and 6 types of SDS solution was compared. The body wash solution is a mixture of soap and water in 1:20 ratio. As a result, SDS 0.1% solution was the most suitable for a substitute of soapy water in shower.

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전기화학적 노이즈 저항 측정에서의 불확도 평가 (Uncertainty evaluation in electrochemical noise resistance measurement)

  • 김종집;강수연
    • Corrosion Science and Technology
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    • 제12권5호
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    • pp.220-226
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    • 2013
  • The uncertainty in statistical noise resistance measurement was evaluated for a type 316 stainless steel in NaCl solutions at room temperature. Sensitivity coefficients were determined for measurands or variables such as NaCl concentration, pH, solution temperature, surface roughness, inert gas flow rate and bias potential amplitude. The coefficients were larger for the variables such as NaCl concentration, pH, inert gas flow rate and solution temperature, and they were the major factors increasing the combined standard uncertainty of noise resistance. However, the contribution to the uncertainty in noise resistance measurement from the above variables was remarkably low compared to that from repeated measurements of noise resistance, and thus, it is difficult to lower the uncertainty in noise resistance measurement significantly by lowering the uncertainties related with NaCl concentration, pH, inert gas flow rate and solution temperature. In addition, the uncertainty in noise resistance measurement was high amounting to 17.3 % of the mean, indicating that the reliability in measurement of noise resistance is low.

AFM 기반 액중 Tribo nanolithography 에서의 마스크 층 내식각성에 관한 연구 (Etch Resistance of Mask Layer modified by AFM-based Tribo-Nanolithography in Aqueous Solution)

  • 박정우;이득우
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 추계학술대회 논문집
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    • pp.268-271
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    • 2005
  • Etch resistance of mask layer on silicon substrate modified by AFM-based Tribo-Nanolithography (TNL) in Aqueous Solution in an aqueous solution was demonstrated. n consists or sequential processes, nano-scratching and wet chemical etching. The simple scratching can form a mask layer on the silicon substrate, which acting as an etching mask. For TNL, a specially designed cantilever with diamond tip, allowing the formation of mask layer on silicon substrate easily by a simple scratching process, has been applied instead of conventional silicon cantilever fur scanning. This study demonstrates how the TNL parameters can affect the etch resistance of mask layer, hence introducing a new process of AFM-based maskless nanolithography in aqueous solution.

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셀 몰드 주조한 SSC13 엘보우 피팅 주강의 고용화율에 따른 델타 페라이트 분율 변화와 내부식특성 (Effect of Austenitizing Ratio on the Delta Ferrite Volume Fraction and Corrosion Resistance of Shell Mold Cast SSC13 Elbow Fitting)

  • 김국진;임수근;주형규;박성준
    • 한국주조공학회지
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    • 제35권5호
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    • pp.109-113
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    • 2015
  • In this study, the measurement of FN (ferrite volume fraction) and the solution annealing ratio at a temperature of $1130^{\circ}C$ were determined with 15A elbow fittings of shell cast SSC13, and the corrosion resistance with and without austenitizing solution annealing were investigated in comparison with AISI304. The delta ferrite phase was observed in the material due to the slow cooling effect of the shell mold casting. However, the delta ferrite phase decreased gradually with the solution annealing at a temperature of $1130^{\circ}C$. The hardness generally decreased with a heat treatment; however, its corrosion resistance was improved with the heat treatment. In addition, when a passivation treatment was applied, its corrosion ratio showed the lowest value. The pattern of general corrosion decreased due to the decrease in the delta ferrite phase with the solution annealing treatment. Consequently, it is suggested that the corrosion resistance of SSC13 elbow fittings can be improved by increasing the ratio of any solution annealing treatment used and by decreasing the ferrite phase. The relationship between the ratio of solution annealing and delta ferrite is expressed as follows: SA (solution annealing ratio,%) = 98 - FN (ferrite volume fraction, %).