• Title/Summary/Keyword: solution phase reduction

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Predictive Current Control for Multilevel Cascaded H-Bridge Inverters Based on a Deadbeat Solution

  • Qi, Chen;Tu, Pengfei;Wang, Peng;Zagrodnik, Michael
    • Journal of Power Electronics
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    • v.17 no.1
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    • pp.76-87
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    • 2017
  • Finite-set predictive current control (FS-PCC) is advantageous for power converters due to its high dynamic performance and has received increasing interest in multilevel inverters. Among multilevel inverter topologies, the cascaded H-bridge (CHB) inverter is popular and mature in the industry. However, a main drawback of FS-PCC is its large computational burden, especially for the application of CHB inverters. In this paper, an FS-PCC method based on a deadbeat solution for three-phase zero-common-mode-voltage CHB inverters is proposed. In the proposed method, an inverse model of the load is utilized to calculate the reference voltage based on the reference current. In addition, a cost function is directly expressed in the terms of the voltage errors. An optimal control actuation is selected by minimizing the cost function. In the proposed method, only three instead of all of the control actuations are used for the calculations in one sampling period. This leads to a significant reduction in computations. The proposed method is tested on a three-phase 5-level CHB inverter. Simulation and experimental results show a very similar and comparable control performance from the proposed method compared with the traditional FS-PCC method which evaluates the cost function for all of the control actuations.

Effect of pH in 3.5% NaCl aqueous solution and ferrite grain size on corrosion fatigue fracture of dual phase steel (複合組織鋼의 부식피로파괴에 미치는 3.5% NaCl水溶液의 pH와 母相粒徑의 效果)

  • 오세욱;강호민
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.6
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    • pp.867-876
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    • 1987
  • Corrosion fatigue fracture with change in the grain size of M.E.F. dual phase steel is investigated in 3.5% NaCI aqueous solution at pH 2, 4, 6, 9, and 11. Generally speaking, decrease in corrosion fatigue life is strongly dependent on decrease in pH and slightly on the grain size. For the B material with the big grain size, the fatigue life is small due to its large reduction ratio of corrosion fatigue life. The influence of grain size on the reduction ratio of corrosion fatigue life is large at pH 11-6. Whi9le at pH 4-2 the reduction ratio of corrosion fatigue life only depends on the corrosion effect. The larger grain size and the lass pH result in the greater influence on corrosion fatigue crack propagation rate. As pH decreases, the plateau portion in the crack propagation rate curves of the B material are distinct. Crack propagation rate curves become slow down at high .DELTA.K range because crack closure effect by minute corrosion products inside crack causes the oxidation corrosion action less effective for a certain period of time. In A material with small grain size, fatigue life is increased in proportion with increase of martensite intergranular which brings forth restraining the crack propagation decreases crack propagation rate. Corrosion pit which is created in the surface of specimen is found at pH 6,4 and 2 which is noticeable and the unevenness of the surface of the specimen becomes severe as pH decreases. The unevenness of corrosion fatigue fracture surface is severe as the effect of pH increases i.e. as pH decreases. In proportion with increase in the grain size and decrease in pH, the aspect of brittle fracture becomes evident.

Effects of phase changes on mechanical properties of Ti-Nb alloys (Ti-Nb계 합금의 상변화가 기계적 성질에 미치는 영향)

  • Park, Hyo-Byeong
    • Journal of Technologic Dentistry
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    • v.27 no.1
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    • pp.9-17
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    • 2005
  • The use of titanium alloys as biomaterials is increasing due to their superior biocompatibility and enhanced corrosion resistance compared to conventional stainless steels and cobalt-based alloys. Ti-6Al-4V ($\alpha+\beta$type) alloy instead of pure titanium ($\alpha$type) is being widely used as biomaterials has some characteristics such as high fatigue strength, tensile strength and corrosion resistance. But it has been reported recently that the vanadium element expresses cytotoxicity and the aluminium element is related with dementia of Alzheimer type and neurotoxicity. In order to overcome their detrimental effects, $\beta$-phase stabilizer Nb was chosen in the present study. This paper was described the influence of phase changes of Ti-Nb alloys on mechanical properties. Ti-3wt.%Nb($\alpha$type),Ti-20wt.%Nb($\alpha+\beta$type) and Ti-40wt.%Nb($\beta$type) alloys were melted by vacuum arc furnace. The specimens were homogenized at 1050$^{\circ}C$ for 24hr and were then hot rolled to 50% reduction. Each alloys were solution heat treated at $\beta$ zone and $\alpha+\beta$ zone after homogenization and then were aged. The mechanical properties of Ti alloys were analysed by hardness test, tensile test, elongation test and SEM test. The results can be summarized as follows: 1) The higher hardness value of $\alpha+\beta$type alloy was obtained compared to the, $\alpha,\beta$type alloys. 2) The aged treated showed better hardness compared to the solution heat treated, homogenized. 3) In the case of solution and aging treatment at $\beta$region, the $\alpha+\beta$type alloy showed the most highest tensile strength and $\beta$type alloy showed the best elongation.

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Analysis of a Two-Phases System of Mass Transfer and Electro-Reduction of Uranium(VI) in Nitric Acid-Hydrazine Media (질산-하이드라이진 매질에서 우라늄(VI)의 물질전달과 전기적 환원을 갖는 이 상계의 해석)

  • Kim, K.W.;Yoo, J.H.;Park, H.S.;Kim, J.D.;Aoyagi, H.;Yoshida, Z.
    • Nuclear Engineering and Technology
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    • v.27 no.2
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    • pp.216-225
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    • 1995
  • Simulation for a dynamic analysis of the electrolytic preparation of U(IV) in two-phases system, which consisted of mass transfer of U(VI) from TBP phase into HNO$_3$ solution and electrolytic re-duction of U(VI) to U(IV) at a cathode in aqueous phase, was carried out in order to establish the most suitable operating condition and best electrode area as basic design data for the system. It was found that maintaining an appropriate mass transfer rate was more significant rather than enlarging the surface area of the cathode for more effective production yield of U(IV). The electrode area and the operation time affected deeply the production composition of U(IV) in the resulting aqueous phase. And optimal electrode areas ore evaluated to meet production criteria of U(IV) of resulting solution in several system conditions. Though about 0.37M HNO$_3$ was preferable to prepare the solution of U(IV), nitric acid concentration should be higher than 0.5M to prevent a hydrolysis of U(IV) in the aqueous phase.

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Effects of Natural Organic Matter (NOM) on Cr(Ⅵ) reduction by Fe(II) (Fe(II)을 이용한 Cr(Ⅵ) 환원시 천연유기물의 영향)

  • 한인섭
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1999.10a
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    • pp.81-84
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    • 1999
  • The aqueous geochemical characteristics of Cr(III) and Cr(Ⅵ) in environmental systems are very different from one another: Cr(Ⅵ) is highly soluble, mobile and toxic relative to Cr(III) Reduction of Cr(Ⅵ) to Cr(III) are beneficial in aquatic systems because of the transformation of a highly mobile and toxic species to one having a low solubility in water, thus simultaneously decreasing chromium mobility and toxicity. Fe(II) species are excellent reductants for transforming Cr(Ⅵ) to Cr(III), and in addition, keeping Cr(III) concentrations below the drinking water standard of 52 ppb at pH values between 5 and 11. Investigations of the effects of NOM on Cr(Ⅵ) reduction are for examining the feasibility of using ferrous iron to reduce hexavalent chromium in subsurface environments. Experiments in the presence of soils, however, showed that the solid phase consumes some of the reducing capacity of Fe(II) and makes the overall reduction kinetics slower. The soil components bring about consumption of the ferrous iron reductant. Particular attention is devoted to the complexation of Fe(II) by NOM and the subsequent effect on Cr(Ⅵ) reduction. Cr(Ⅵ) reduction rate by Fe(II) was affected by the presence of NOM (humic acid), The effects of humic acid was different from the solution pH values and the concentration of humic acid. It was probably due to the reactions between humic acid and Cr(Ⅵ), humic acid and Fe(II), and between Cr(Ⅵ) and Fe(II), at each pH.

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Microstructure and Magnetic Properties of Nanostructured Fe-Co Alloy Powders Produced by Chemical Solution Mixing and Hydrogen Reduction Methods (화학용액혼합과 수소환원법으로 제조된 나노 구조 Fe-Co 합금분말의 미세구조 및 자성 특성)

  • 박현우;이백희;이규환;김영도
    • Journal of Powder Materials
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    • v.10 no.5
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    • pp.333-336
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    • 2003
  • The purpose of this study is the fabrication of nano-sized Fe-Co alloy powders with soft magnetic properties by the slurry mixing and hydrogen reduction (SMHR) process. $FeCl_2$0 and $CoCl_2$ powders with 99.9% purities were used for synthesizing nanostructured Fe-Co alloy powder. Nano-sized Fe-Co alloy powders were successfully fabricated using SMHR, which was performed at 50$0^{\circ}C$ for 1 h in H$_2$ atmosphere. The fabricated Fe-Co alloy powders showed $\alpha$' phase (ordered body centered cubic) with the average particle size of 45 nm. The SMHR powder exhibited low coercivity force of 32.5 Oe and saturation magnetization of 214 emu/g.

Coating of Cobalt Over Tungsten Carbide Powder by Wet Chemical Reduction Method

  • Hong, Hyun-Seon;Yoon, Jin-Ho
    • Journal of Powder Materials
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    • v.21 no.2
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    • pp.93-96
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    • 2014
  • Cobalt coated tungsten carbide-cobalt composite powder has been prepared through wet chemical reduction method. The cobalt sulfate solution was converted to the cobalt chloride then the cobalt hydroxide. The tungsten carbide powders were added in to the cobalt hydroxide, the cobalt hydroxide was reduced and coated over tungsten carbide powder using hypo-phosphorous acid. Both the cobalt and the tungsten carbide phase peaks were evident in the tungsten carbide-cobalt composite powder by X-ray diffraction. The average particle size measured via scanning electron microscope, particle size analysis was around 380 nm and the thickness of coated cobalt was determined to be 30~40 nm by transmission electron microscopy.

Compensation of Cross Talk Error for Optical Voltage Sensors

  • Cho, Jae-Kyong
    • Journal of the Optical Society of Korea
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    • v.11 no.4
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    • pp.177-182
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    • 2007
  • This paper discusses the errors associated with electric field cross talk for optical voltage sensors in a three-phase electric system and provides a solution to compensate the errors. For many practical conductor configurations, the electric field cross talk may cause errors unacceptable for the accuracy requirements of the sensors. We devised a real time compensation method for the cross talk and built an electronic circuits based on it. The mechanism of the compensation and the corresponding error reduction were discussed.

Oxidation-free Cu material for printed electronics

  • Kim, Sang-Ho
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.16.2-16.2
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    • 2009
  • Developing a low cost printing material that can replace silver for the formation of a conducting pattern is an important issue in printed electronics. We report a novel approach using a non-oxidized copper material during the printing and sintering process under ambient conditions, which was previously considered unachievable. An attempt was made to understand the conversion process of cuprous oxide nanoparticle aggregates on metallic copper crystals through chemical reduction in the solution phase. The detailed mechanism for this conversion, including the role of the surfactant and crystal growth, was examined.

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