• 제목/요약/키워드: soluble sulfur

검색결과 97건 처리시간 0.026초

대기오염에 대한 가로수의 내연성 연구 (Studies on the Air Pollution Tolerance of the Urban Trees)

  • 배정오;김정규;김재봉;박재규
    • 환경위생공학
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    • 제1권1호
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    • pp.97-107
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    • 1986
  • This study was performed to investigate the air pollution tolerance of urban trees; Gingko biloba, Platanus occidentalis, Salix pseudolagiogyne and Purunus serrulata growing in Seoul, Taegu, Chungju area. Vitality of trees and water soluble sulfur content in the leaves were determined at 24 points in those cities. The ratio of the each number of Platanus occidentalis, Gingko biloba, Salix psuedolagiogyne and Prunus serrulata to the total number of urban tree in Seoul area was $49.38\%,\; 17.36\%,\; 13.42\%,\;2.43\%$, respectively. Its ratio in Taegu area was $36.76\%,\;14.25\%,\;13.36\%,\;3.32\%$ and in the Chungju area was $59.06\%,\;17.35\%,\;11.09\%,\;8.33\%$, respectively. The species deversity was 0.7017, 09067, 0.5297 in Seoul, Taegu, Chungju, respectively. The significant correlation between the S02 concentration and the tree vitality highly found on Platanus occidentalis, Gingko biloba, Salix pseudolagiogyne and Prunus serrulata. Positive correlation coefficient between $SO_2$ concentration and water soluble sulfur content were shown on Platanus occidentalis, Salix pseudolagiogyne and Prunus serrulata and that between tree vitality and water soluble sulfur content were shown on Platanus occidentalis and Gingko biloba. The tolerant to the S02 gas was high in order of Salix pseudolagiogyne, Gingko biloba, Prunus serrulata and Platanus occidentalis. Also the absorption activity to the $SO_2$ gas was high in order of Salix psuedolagiogyne, Gingko biloba, Platanus occidentalis and Prunus serrulata.

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나노 흡착제가 Li/S 이차전지용 유황양극의 전기화학적 특성에 미치는 영향 (The Effects of the Nano-sized Adsorbing Material on the Electrochemical Properties of Sulfur Cathode for Lithium/Sulfur Secondary Battery)

  • 송민상;한상철;김현석;안효준;이재영
    • 한국수소및신에너지학회논문집
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    • 제13권4호
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    • pp.259-269
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    • 2002
  • A battery based on the lithium/elemental sulfur redox couple has the advantage of high theoretical specific capacity of 1,675 mAh/g-sulfur. However, Li/S battery has bad cyclic durability at room temperature due to sulfur active material loss resulting from lithium polysulfide dissolution. To improve the cycle life of Li/S battery, PEGDME (Poly(ethylene glycol) dimethyl ether) 500 containing 1M LiTFSI salt which has high viscosity was used as electrolyte to retard the polysulfide dissolution and nano-sized $Mg_{0.6}Ni_{0.4}O$ was added to sulfur cathode as additive to adsorb soluble polysulfide within sulfur cathode. From experimental results, the improvement of the capacity and cycle life of Li/S battery was observed( maximum discharge capacity : 1,185 mAh/g-sulfur, C50/C1 = 85 % ). Through the charge-discharge test, we knew that PEGDME 500 played a role of preventing incomplete charge-discharge $behavior^{1,2)$. And then, in sulfur dissolution analysis and rate capability test, we first confirmed that nano-sized $Mg_{0.6}Ni_{0.4}O$ had polysulfide adsorbing effect and catalytic effect of promoting the Li/S redox reaction. In addition, from BET surface area analysis, we also verified that it played the part of increasing the porosity of sulfur cathode.

Exploiting Natural Diatom Shells as an Affordable Polar Host for Sulfur in Li-S Batteries

  • Hyean-Yeol Park;Sun Hyu Kim;Jeong-Hoon Yu;Ji Eun Kwon;Ji Yang Lim;Si Won Choi;Jong-Sung Yu;Yongju Jung
    • Journal of Electrochemical Science and Technology
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    • 제15권1호
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    • pp.198-206
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    • 2024
  • Given the high theoretical capacity (1,675 mAh g-1) and the inherent affordability and ubiquity of elemental sulfur, it stands out as a prominent cathode material for advanced lithium metal batteries. Traditionally, sulfur was sequestered within conductive porous carbons, rooted in the understanding that their inherent conductivity could offset sulfur's non-conductive nature. This study, however, pivots toward a transformative approach by utilizing diatom shell (DS, diatomite)-a naturally abundant and economically viable siliceous mineral-as a sulfur host. This approach enabled the development of a sulfurlayered diatomite/S composite (DS/S) for cathodic applications. Even in the face of the insulating nature of both diatomite and sulfur, the DS/S composite displayed vigorous participation in the electrochemical conversion process. Furthermore, this composite substantially curbed the loss of soluble polysulfides and minimized structural wear during cycling. As a testament to its efficacy, our Li-S battery, integrating this composite, exhibited an excellent cycling performance: a specific capacity of 732 mAh g-1 after 100 cycles and a robust 77% capacity retention. These findings challenge the erstwhile conviction of requiring a conductive host for sulfur. Owing to diatomite's hierarchical porous architecture, eco-friendliness, and accessibility, the DS/S electrode boasts optimal sulfur utilization, elevated specific capacity, enhanced rate capabilities at intensified C rates, and steadfast cycling stability that underscore its vast commercial promise.

디젤기관의 산화촉매에서 Pt 로딩량에 따른 배출가스 저감에 관한 실험적 연구 (A Experimental Study on Exhaust Gas Reduction by Pt Loading in Oxidation Catalyst of Diesel Engine)

  • 오용석
    • 한국생산제조학회지
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    • 제8권4호
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    • pp.13-18
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    • 1999
  • Recently among after-treatment devices which have high possibility of utility diesel oxidation catalyst(DOC) is concerned over the world. DOC oxidizes pollutants by means of activate-reaction during by-passing in the catalyst in doing so conversion efficiency of PM, CO and HC is high and this device does not have an effect on engine performance because back pressure is not nearly increased, But as a small amount of sulfur content in fuel is oxidized it makes sulfate which is absorbed on the surface of catalyst. So in this study the experiment is carried out by means of using ordinary fuel(0.1wt%) and low sulfur fuel(0.05wt%) with DOC and the emission gas of diesel engine is measured.

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유황토분 처리가 사과 부란병에 미치는 영향 (Effect of Soil Sulfur treatment on Apple Valsa Canker)

  • 전익조;박승민
    • 한국유기농업학회지
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    • 제25권1호
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    • pp.125-134
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    • 2017
  • 본 연구는 친환경 유기과원의 부란병 방제를 위한 유황토분의 효과를 검증코자 2년간 수행되었다. 제조된 유황토분의 사과 부란병 치유효과를 검증하기 위해 유기과원에는 석회유황합제의 처리와 비교하였으며, 관행과원에서는 석회유황합제, 유황토분 및 네오아소진을 처리하였다. 유기과원의 유황토분의 부란병 치유율은 대조구에 비해 뚜렷하게 유의성이 인정되었으나, 2013년 봉현 과원을 제외하고는 석회유황합제와는 큰 차이가 없었다. 유기과원의 과실품질조사 결과, 과피의 붉은 색은 대조구에 비해 석회유황합제 처리구에서 다소 높게 나타냈으며, 과실의 경도에서는 유황토분 처리구가 대조구에 비해 유의적으로 높게 나타났다. 관행과원에서의 유황토분, 석회유황합제 및 네오아소진 처리는 대조구에 비해 통계적 유의적으로 높게 조사되었다. 유황토분의 부란병 치유율은 유기사과과원 및 관행사과과원에서 87.5~97.5%인 것으로 조사되었다. 관행과원에서의 유황토분 처리는 신초생육에 있어 네오아소진에 비해 통계적 유의성이 있게 증가하였다. 과실품질의 경우 유황토분처리는 과실의 붉은 색의 증가를 보였으나, 다른 과실품질인 무게, 경도, 당도 및 적정산도에서 통계적 유의성을 나타내지 않았다.

마늘 신품종 홍산과 한산의 식물화학적 구성 및 생리활성 비교 (Comparison of phytochemical composition and physiological activity of 'Hongsan' and 'Hansan', a new variety of garlic)

  • 김주성;라종환
    • 한국식품과학회지
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    • 제51권2호
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    • pp.147-151
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    • 2019
  • 본 연구는 2016년 품종보호권이 등록된 홍산마늘과 한산마늘의 생리활성을 측정하기 위하여 실시되었다. 나트륨과 황 성분을 제외한 미네랄 성분들은 한산마늘에서 높게 측정되었으며 함유 황화합물 역시 한산마늘에서 높았다. 또한 고형물함량과 환원당 및 알파글루코시다아제 저해활성 역시 한산마늘이 높았다. 그러나 산도, pH, 총페놀 및 플라보노이드 함량은 홍산마늘에서 높게 나타났다. 두 품종에서 항미생물활성은 그람음성균보다 그람양성균에 대한 저해활성이 높았으며 한산마늘보다 홍산마늘이 조금 높은 항미생물활성을 나타내었다. 이러한 연구결과는 향후 위 품종을 재배하는 농가에 유용한 정보를 제공해 줄 것으로 기대된다.

경유 중 황이 산화촉매 장착 디젤엔진의 입자상 물질에 미치는 영향 (The Effect of Fuel Sulfer on Particulate Matter of Diesel Engine Equipped with Oxidation Catalyst)

  • 조강래;신영조;류정호;김희강
    • 한국대기환경학회지
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    • 제13권6호
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    • pp.487-495
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    • 1997
  • The most desirable diesel oxidation catalyst (DOC) should have the properties of oxidizing CO, HC and SOF effectively at low exhaust gas temperature while minimizing the formation of sulfate at high exhaust gas temperature. Precious metals such as platinum and palladium have been known to be sufficiently active for oxidizing SOF and also to have high activity for the oxidation of sulfur dioxide $(SO_2)$ to sulfur trioxide $(SO_3)$. There is a need to develop a highly selective catalyst which can promote the oxidation SOF efficiently, on the other hand, suppress the oxidation of $SO_2$. In this study, a Pt-V catalyst was prepared by impregnating platinum and vanadium onto a Ti-Si wash coated ceramic monolith substrate. A prepared Pt-V catalytic converter was installed on a heavy duty diesel engine and the effect of fuel sulfur on particulate matter (PM) of heavy duty diesel engine was measured. The effect of fuel sulfur on PM of Pt-V was also compared with that of a commercialized Pt catalyst currently being used in some of the heavy duty diesel engines in advanced countries. Only 1 $\sim$ 3% of sulfur in the diesel fuel was converted to sulfate in PM for the engine without catalyst, but almost 100% of sulfur conversion was achieved for the engine with Pt catalyst at maximum loading condition. In the case of Pt-V catalyst, there was no big difference in conversion with the base engine even at maximum loading condition. The reason of SOF increase according to the increase of suflate emission was identified as the washing off effect of bound water in sulfate.

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석회유황합제의 다중처리에 따른 '후지' 및 '홍로' 사과의 적과 효과 (Multiple Applications of Lime Sulfur for Fruit Thinning of 'Fuji' and 'Hongro' Apple Trees)

  • 전익조;정위위;최철;송양익;강인규;피터 허스트
    • 생물환경조절학회지
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    • 제21권4호
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    • pp.445-451
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    • 2012
  • 본 연구는 2년간 '홍로'/M.9 및 '후지'/M.9 품종의 적과를 위한 석회유황합제 및 어유와의 혼합처리 효과를 조사하기 위해 진행하였다. '후지' 1년 차에 있어, 만개 시 석회유황합제 1% 또는 2% 처리는 대조구에 비해 정과 및 액과의 유과수를 감소시켰다. 하지만 2차년도에는 석회유황합제 1% 또는 2% 단용처리에서는 정과 유과수의 차이를 나타내지 않았다. 다만 석회유황합제 1%의 3회 처리에서는 1차년도와 2차년도 모두 유의적인 적과효과를 나타내었다. 석회유황합제 1%의 다중처리는 '홍로'에서 가장 효율적인 적과효과를 나타내었다. 1차년도의 경우, 석회유황합제 1%의 2회 또는 3회 살포가 효과적인 적과효과를 보였으며, 2차년도에서는 석회유황합제 1% 1회처리를 제외하고는 모두 유의적인 적과효과를 나타내었다. 첨가된 어유의 경우 대부분의 경우 석회유황합제의 적과효과를 강화하지 않았다. 본 시험에 사용된 모든 처리구는 과실의 동녹 형성에 악영향을 미치지 않았으며, 또한 '후지' 및 '홍로'의 과실 중량, 경도, 가용성고형물 및 적정산도와 같은 과실품질에 영향을 미치지 않았다.

Effect of Dietary Processed Sulfur Supplementation on Texture Quality, Color and Mineral Status of Dry-cured Ham

  • Kim, Ji-Han;Ju, Min-Gu;Yeon, Su-Jung;Hong, Go-Eun;Park, WooJoon;Lee, Chi-Ho
    • 한국축산식품학회지
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    • 제35권5호
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    • pp.660-668
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    • 2015
  • This study was performed to investigate the chemical composition, mineral status, oxidative stability, and texture attributes of dry-cured ham from pigs fed processed sulfur (S, 1 g/kg feed), and from those fed a basal diet (CON), during the period from weaning to slaughter (174 d). Total collagen content and soluble collagen of the S group was significantly higher than that of the control group (p<0.05). The pH of the S group was significantly higher than that of the control group, whereas the S group had a lower expressible drip compared to the control group. The S group also showed the lower lightness compared to the control group (p<0.05). In regard to the mineral status, the S group had significantly lower Fe2+ and Ca2+ content than the control group (p<0.05), whereas the proteolysis index of the S group was significantly increased compared to the control group (p<0.05). The feeding of processed sulfur to pigs led to increased oxidative stability, related to lipids and pigments, in the dry-cured ham (p<0.05). Compared to the dry-cured ham from the control group, that from the S group exhibited lower springiness and gumminess; these results suggest that feeding processed sulfur to pigs can improve the quality of the texture and enhance the oxidative stability of dry-cured ham.

특이산성토양(特異酸性土壤)에서 담수시(湛水時) 석회처리(石灰處理) 및 온도조절(溫度調節)이 토양(土壤)의 유효성분(有效成分) 변화(變化)에 미치는 영향(影響) (Effect of Lime and Temperature on the Changes of Available Soil Nutrients in Acid Sulfate Soil under Submergence)

  • 강위금;하호성
    • 한국토양비료학회지
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    • 제18권3호
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    • pp.282-288
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    • 1985
  • 산성황산염토양(酸性黃酸鹽土壤)에서 담수시(湛水時) 석회(石灰) 처리량(處理量)과 온도(溫度) 조건(條件)에 따른 유효인산(有效燐酸)과 규산(珪酸)의 변화양상(變化樣相)과 함께 토양산도(土壤酸度)와 여러가지 화학성분(化學成分)과의 상관관계(相關關係)를 구명(究明)한 결과(結果)를 요약(要約)하면 다음과 같다. 1. 담수조건(湛水條件)은 토양(土壤)의 pH, 유효인산(有效燐酸) 유효규산(有效珪酸), 암모니아태(態) 질소(窒素), 제일철(第一鐵)의 증가(增加)와 알루미늄, 유효(有效)망간, 수용성(水溶性) 유황(硫黃)의 감소(減少)를 보였다. 2. 석회처리(石灰處理)는 토양(土壤)의 pH, 유효인산(有效燐酸), 유효규산(有效珪酸), 암모니아태(態) 질소(窒素), 수용성(水溶性) 유황(硫黃)의 증가(增加)와 알루미늄, 제일철(第一鐵), 유효(有效)망간의 감소(減少)를 보였다. 3. 석회(石灰) 12me/100gr 처리(處理)에서 pH 6.5 내외(內外)를 유지(維持)하였을 뿐만아니라 유효인산(有效燐酸), 암모니아태(態) 질소(窒素)의 증가(增加)와 알루미늄, 제일철(第一鐵)의 감소(減少)에도 효과(效果)가 컸다. 4. 온도간(溫度間)에는 $25^{\circ}C$보다 $35^{\circ}C$항온구(恒溫區)에서 유효인산(有效燐酸), 암모니아태(態) 질소(窒素), 그리고 환원태(還元態)인 제일철(第一鐵)의 생성(生成)이 많았다. 5. 담수기간(湛水期間) pH는 유효규산(有效珪酸)과 고도(高度)의 정상관(正相關)이 있었으며, 알루미늄, 제일철(第一鐵), 유효(有效)망간과는 부(負)의 상관관계(相關關係)를 보였다.

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