• Title/Summary/Keyword: soluble sulfur

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A Study on the Leaf Acidity, Bark Acidity and Water Soluble Sulfur Contents of Pinus Koraiensis in Chuncheon and Cheongpyoung (강원대 학술림과 경춘가도(청평)변 잣나무 잎과 수피의 pH및 수용성 황함량에 관한 연구)

  • Lee Sang Deok;Kim Hong Ryul;Joo Yeoung Teuk
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.6 no.3
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    • pp.190-195
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    • 2004
  • This study investigated effects of water content in leaf, leaf acidity, bark acidity and water soluble sulfur contents by vehicle. The results were as follows: The average water content in Pinus Koraiensis leaves at Cheongpyoung and Chuncheon were 49% and 51 % respectively. The average leaf acidity and bark acidity at Cheongpyoung and Chuncheon were respectively pH 4.8 and pH 4.9 in leaf, pH 5.3 and 5.4 bark. The average water soluble sulfur content in leaves showed a significant difference between Cheongpyoung and Chuncheon of 0.133% and 0.053% respectively.

Reducing Phytotoxic by Adjusted pH and Control effect of Loess-Sulfur Complex as Organic Farming Material against Powdery Mildew in Tomato (유기농자재인 황토유황합제의 약해 경감 및 흰가루병 방제효과)

  • Shim, Chang-Ki;Kim, Min-Jeong;Kim, Yong-Ki;Hong, Sung-Jun;Kim, Suk-Chul
    • The Korean Journal of Pesticide Science
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    • v.18 no.4
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    • pp.376-382
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    • 2014
  • The soluble loess-sulfur mixture allowed standing to remove insoluble component materials for five weeks after manufacturing. We decreased the pH level of soluble loess-sulfur mixture at pH 1.0 modified with decreasing 25% sodium hydroxide than original content. The pH ranges of soluble loess-sulfur mixture solutions were adjusted to pH 5.0-pH 11.0 (pH 1 unit) with brown rice vinegar (pH 2.8). The pH of original loess-sulfur mixture was about pH 13 and damaged the foliar parts and young leaves of tomato after twice application. These stock solutions can be diluted 500:1 with tap water to make a 0.05% working solution and were sprayed two times with 7 days interval to the leaf and stem of tomato, which were spontaneously infected with E. cichoracearum. Control efficacy of powdery mildew ranged from 85% to 90% at 7 days after first application. After second application, each loess-sulfur mixture solutions adjusted pH level significantly suppressed the powdery mildew disease in tomato. Consequently, loess-sulfur complex adjusted pH level with brown rice vinegar was suggested to be low in acute toxicity at all different pH values and suggested to use an agent for control of tomato powdery mildew in organic farming.

The Effect of Sulfur Dioxide by Burn out on Enzyme Activity and Lipid Content in Rats (소환시 발생되는 아황산 가스가 흰쥐 혈청 중의 효소 활성도 및 지질 함량에 미치는 영향)

  • Kim, Hae-Dong;Kim, Byung-Hak;Ha, Hun;Cho, Soo-Yeul;Yoon, Soo-Hong
    • Environmental Analysis Health and Toxicology
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    • v.12 no.3_4
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    • pp.61-66
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    • 1997
  • Recently, incidences of pulmonary-related diseases are increasing and natural ecosystem is destroyed year by year owing to air pollutions by industrial noxious gases such as sulfur dioxide and carbon dioxide, etc. Sulfur dioxide produced by oxidation of sulfur compounds is water soluble and causes several kinds of pulmonary diseases, damaging on plants and animals. This study was undertaken to investigate effects of acute exposure of rats to sulfur dioxide using biochemical parameters. The sAST (aspartate transaminase) activity was not significantly affected but sALT (alanine transaminase), sLDH (lactate dehydrogenase) and sALP (alkaline phosphatase) activities were significantly increased by acute sulfur dioxide gas exposure. Also sulfur dioxide gas treatment significantly diminished serum cholinesterase activity. The total lipid, triglyceride, total-, HDL- and LDL-cholesterol contents were significantly increased by sulfur dioxide gas exposures. But the body and liver weight were generally diminished in comparison with control group. Our results' showed increased enzyme activities and lipid contents, but body and liver weight were all diminished by sulfur dioxide gas treatment.

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An Experimental Study on Emission Reduction by Low Sulfur Diesel Fuel in Diesel Oxidation Catalyst of Heavy Duty Diesel Engine (대형디젤기관의 디젤산화촉매장치에서 저유황 경유에 의한 배출가스 저감에 관한 실험적 연구)

  • 요용석;강호인;한영출
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.3
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    • pp.138-142
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    • 1998
  • Among aftertreatment devices which reduce exhaust gas of diesel engine, diesel oxidation catalyst(DOC) with high reduction efficiency for gaseous matter and particulate matter is now being studied actively. In this study, an experiment was conducted to analyze the effects of low sulfur diesel fuel in heavy duty diesel engine equipped with DOC. We tested to estimate change of engine performance for the low and high sulfur diesel fuels in a 11,000cc diesel engine equipped with DOC. We conducted test to estimate the reduction efficiency of exhaust gas in D-13 mode of heavy duty diesel regulation mode and in smoke opacity mode for two samples of high sulfur content (0.2%) and low sulfur content(0.05%)

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The Effect of Biodiesel and Ultra Low Sulfur Diesel Fuels on Emissions in 11,000 cc Heavy-Duty Diesel Engine

  • Baik, Doo-Sung;Han, Young-Chool
    • Journal of Mechanical Science and Technology
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    • v.19 no.3
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    • pp.870-876
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    • 2005
  • It seems very difficult to comply with upcoming stringent emission standards in vehicles. To develop low emission engines, better quality of automotive fuels must be achieved. Since sulfur contents in diesel fuels are transformed to sulfate-laden particulate matters as a catalyst is applied, it is necessary to provide low sulfur fuels before any Pt-based oxidation catalysts are applied. In general, flash point, distillation $90\%$ and cetane index are improved but viscosity can be worse in the process of desulfurization of diesel fuel. Excessive reduction of sulfur may cause to degrade viscosity of fuels and engine performance in fuel injection systems. This research focused on the performance of an 11,000 cc diesel engine and emission characteristics by the introduction of ULSD, bio-diesel and a diesel oxidation catalyst, where the bio-diesel was used to improve viscosity of fuels in fuel injection systems as fuel additives or alternative fuels.

EMISSION CHARACTERISTICS IN ULTRA LOW SULFUR DIESEL

  • Oh, S.-K.;Baik, D.-S.;Han, Y.C.
    • International Journal of Automotive Technology
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    • v.4 no.2
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    • pp.95-100
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    • 2003
  • Automobile industry has been developed rapidly as a key manufacturing industry in Korea. Meanwhile, air pollution is getting worse noticeably than ever. In the diesel emission, PM (Particulate Matter) and NOx (Nitrogen Oxides) have been exhausted with a great amount and the corresponding emission regulations are getting stringent. In order to develop low emission engines, it is necessary to research on better qualified fuels. Sulfur contained in fuel is transformed to sulfur compound by DOC (Diesel Oxidation Catalyst) and then it causes to the increase of sulfate-laden PM on the surface of catalyst. In this research, ULSD (Ultra Low Sulfur Diesel) is used as a fuel and some experimental results are investigated. ULSD can reduce not only PM but also gas materials because cetane value, flash point, distillation 90%, pour point and viscosity are improved in the process of desulfurization. However, excessively reduced sulfur may cause to decease lubricity of fuel and engine performance in fuel injection system. Therefore, it requires only modest adjusted amount of sulfur can improve engine performance and DOC, as well as decrease of emission.

Contents of Sulfur, Fluorine, Wax and Chlorophyll in Needle Tissue and Needle Growth of Pinus thunbergii as Bioindicators of Air Pollution (대기오염(大氣汚染) 지역의 해송엽내(海松葉內) 수용성(水溶性) 황(黃), 불소(弗素), WAX, 엽록소(葉綠素) 함량(含量) 및 엽(葉) 생장(生長)의 변화와 생물지표성(生物指標性))

  • Kim, Joon Sun;Kim, Yong Hwan;Lee, Han Yol
    • Journal of Korean Society of Forest Science
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    • v.82 no.4
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    • pp.347-353
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    • 1993
  • Accumulation of air pollutants such as $SO_2$ and HF, chlorophyll contents, wax concentrations in needle tissue and needle growth of Pinus thunbergii were studied to verify possibilities of bioindicators of air pollution in Yochon Industrial Complex from July to October, 1991. The concentrations of water-soluble sulfur and fluorine increased nearer to the pollution sources regardless of sampling time, but water-soluble sulfur varied little during investigation and fluorine accumulated more with the passage of time. Total chlorophyll contents decreased a little in the slightly polluted site but sharply in the heavily polluted site. The higher the pollution level was, the more decreased chloroform-extractable wax. Air pollution exposure inhibited needle growth of Pinus tbunbergii during the latter part of growth period. Water soluble sulfur, fluorine and wax concentrations in needle of Pinus thunbergii were rather wood sensitive indicators of susceptibility to ambient air pollution from early July to early October. Chlorophyll contents seemed to be able to be used as a bioindicator of air pollution in early stage of needle development and in the severely polluted area. In the meanwhile needle length must be used as a bioindicator in latter part of growing season.

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Suppressive Effect of Organic Farming Materials on the Development of Tomato Gray Mold (토마토 잿빛곰팡이병에 대한 유기농업자재의 억제효과)

  • Hong, Sung-Jun;Kim, Yong-Ki;Shim, Chang-Ki;Kim, Min-Jeong;Park, Jong-Ho;Han, Eun-Jung;Jee, Hyeong-Jin;Kim, Suk-Chul
    • Korean Journal of Organic Agriculture
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    • v.23 no.3
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    • pp.567-582
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    • 2015
  • Botrytis cinerea infects stems, leaves and fruits of greenhouse tomato and can cause serious economic losses. This study was conducted to develop organic farming control method against tomato gray mold. Twenty two organic farming materials including mineral and plant extracts were screened for the suppressive activity against Botrytis cinerea, in vitro and in vivo. Among the organic farming materials, sulfur, copper, Chinese twinleaf extract and rhubarb extract decreased by 51.7-90% of the spore germination of Botrytis cinerea. Also, gray mold incidence was reduced more than 90% on tomato stems by treating sulfur, seaweed extracts, rhubarb root extracts and Chinese twinleaf extract. After the selected four organic farming materials were applied on tomato cultivated in greenhouse, their control effects against the tomato gray mold were tested. When the water soluble sulfur was foliar-sprayed on the tomato leaves infected by artificial inoculation with spore suspension of Botrytis cinerea, it showed 87.9% of control value. Also, control activity of the water soluble sulfur was paralleled with chemical fungicide, diethofencarb+carbendazim. The above mentioned results indicate the sulfur formulation can be used as chemical fungicide alternatives for controlling tomato gray mold in the greenhouse.

Thermal Generation and Antimicrobial Activity of Unusual Heterocyclic Sulfur Compounds in Garlic

  • Chung, In-Shick;Chae, Kyung-Yun;Kyung, Kyu-Hang
    • Food Science and Biotechnology
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    • v.17 no.5
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    • pp.1032-1037
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    • 2008
  • Lowly volatile heterocyclic sulfur compounds generated in autoclaved garlic extract were isolated and identified, and their antimicrobial activity was determined. Two kinds of unusual volatile sulfur compounds were separated from heated garlic by preparative recycling high performance liquid chromatography (HPLC), and identified by gas chromatography (GC)-mass spectrometry (MS) and $^1H$-nuclear magnetic resonance (NMR). They had heterocyclic structures with 4 to 5 sulfur atoms in the molecules. 4-Methyl-1,2,3-trithiolane (MTTT) is highly volatile and was not able to be concentrated, and was identified by GCMS only. MTTT and 6-methyl-1,2,3,4,5-pentathiepane (MPTP) are lowly volatile and were obtained in pure states to be positively identified for the first time. All 3 heterocyclic sulfur compounds began to appear by the time when the early-formed diallyl sulfides started to disappear. The minimum inhibitory concentration range of MTTT and MPTP was determined to be between 1 and 6 ppm against all yeasts tested. MTTT and MPTP were lowly volatile and sparingly soluble in water.

COMBINED EFFECTS OF BD20, LOW SULFUR DIESEL FUEL AND DIESEL OXIDATION CATALYST IN A HD DIESEL ENGINE

  • Baik, D.S.
    • International Journal of Automotive Technology
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    • v.7 no.6
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    • pp.653-658
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    • 2006
  • The enormous increase in the use of fossil energy sources throughout the world has caused severe air pollution and a depletion of energy. Besides, it seems very difficult to comply with the upcoming stringent emission standards in vehicles. In order to develop low emission engines, research on better qualified fuels as alternative fuels to secure high engine performance becomes a more important issue than ever. Since sulfur contained in diesel fuel is transformed in sulfate-laden particulate matters when a catalyst is applied, it is necessary to provide low sulfur fuels before any Pt-based oxidation catalysts are applied. But the excessive reduction of sulfur levels may cause the lubricity of fuel and engine performance to degrade. In this aspect, biodiesel fuel derived from rice bran is applied to compensate viscosity lost in the desulfurization treatment. This research is focused on the performance of an 11,000cc diesel engine and the emission characteristics by the introduction of ULSD(Ultra Low Sulfur Diesel), BD20(Diesel 80%+Biodiesel 20%) and a diesel oxidation catalyst, where BD20 is used to improve the lubricity of fuel in fuel injection systems as fuel additives or alternative fuels.