• Title/Summary/Keyword: solidus condition

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The use of fluid inclusions to constrain P-T-X conditions of formation of Eonyang amethyst (언양 자수정 형성 환경의 압력-온도-성분에 대한 유체포유물의 이용)

  • K. H. Yang
    • The Journal of the Petrological Society of Korea
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    • v.5 no.1
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    • pp.1-9
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    • 1996
  • Eonyang amethyst deposits are thought to be spatially and temporally associated with the biotite granite of the Kyeongsang Basin. The examined euhedral quartz crystals in cavities in the aplite intruded biotite granite are colored-zoned from white at the base to amethystine at the tops. Three types of primary Inclusions were observed and three is representing each types are constructed to constrain the trapping conditions and fluid evolution involved during the formation of the amethyst. The intersection of the isochore representing the early fluid inclusions with solidus temperature of the host granite indicates initial quartz formation at about $600^{\circ}C$ and 1.0-1.5 kbars . Intermediate quartz formation, associated with the high-salinity inclusions, occurred at somewhat lower temperatures ($400^{circ}c$) and pressures of about 1 kbar. The amethystine quartz formed from $H_2O$-$CO_2$-NaCl fluids at temperatures between 280-$400^{circ}c$ and pressures of about 1 kbar. Early quartz is interpreted to have formed from fluids that either exsolved from or were in equilibrium with the granite at near solidus conditions, whereas the amethystine quartz apparently grew from fluids of at least partial sedimentary origin.

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Measurement of Melting Temperatures of $UO_2,\;(U,Gd)O_2\;and\;(U,Er)O_2$ Fuels

  • Kang Ki Won;Yang Jae Ho;Kim Keon Sik;Kim Jong Hun;Lee Young Woo;Song Kun Woo
    • Nuclear Engineering and Technology
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    • v.36 no.1
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    • pp.104-111
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    • 2004
  • The melting temperatures of $UO_2,\;UO_2-6wt\%Gd_{2}O_3,\;UO_2-12wt\%Gd_{2}O_3,\;UO_2-2wt\%Er_{2}O_3,\;and\;UO_2-4wt\%Er_{2}O_3$ fuels were measured. Fuel materials were loaded in a tungsten capsule of which shape met the black body condition. The melting temperature was measured by the thermal arrest method during heating of the capsule in an induction furnace. The measured melting temperature of $UO_2$ fuel was $2815{\pm}20^{\circ}C$. The solidus and liquidus temperatures of $UO_2-Gd_{2}O_3\;and\;UO_2-Er_{2}O_3$ had also been measured, and it was observed that the solidus temperatures of them were lower than the liquidus temperature by $15{\sim}25^{\circ}C$. Measured melting temperatures of $UO_2,\;UO_2-Gd_{2}O_3\;and\;UO_2-Er_{2}O_3$ fuels were as follows:

Thixoforging Process and the Problems of Hollow Type Metal Matrix Composite Part (중공형 금속 복합 재료 부품의 Thixoforging 공정과 문제점)

  • 이승후;허재찬;강충길
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.808-811
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    • 1997
  • MMC has excellent mechanical properties in many ways in automotive industrial, and get into the spotlight as a light materials substituted for iron and steel. But the know-how about MMC research lack, MMC is expensive and difficult to apply the sound parts. Especially it is difficult to produce the hollow type parts composed with MMC. Therefore, hollow type parts of metal composites by using thixoforming process which as co-existing solidus-liquidus phase, it is very important to obtain forming condition. In this study, MMC billet producted by electro-magnetic stirring and mechanical stirring process is formed to hollow type parts of thixoforming process and inspected of suitability for application. It is optimized production condition, and applied to experiment. After variable materials were produced for thixoforming process, it were inspected of suitability for application by comparsion with mechanical properties. In this study, used materials were A357, A380 10%vol, and 20%vol SiCp, and the size of particultes were 14$\mu\textrm{m}$ and 5.5$\mu\textrm{m}$.

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The Effects of Natural Convection on Macrosegregation during Alloy Solidification (합금 응고과정에서 자연대류가 거시편석에 미치는 영향)

  • Lee, Kyun-Ho;Mok, Jin-Ho;Lee, Jin-Ho
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.37-44
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    • 2000
  • Numerical investigation is made to study the effects of natural convection on the formation of macrosegregation of a Pb-Sn alloy solidification process in a 2-D confined rectangle mold. The governing equations are calculated using previous continuum models with SIMPLE algorithm doring the solidification process. In addition. to track the solid-liquid interface with time variations. the moving boundary condition Is adopted and irregular interface shapes are treated with Boundary-Fitted Coordinate system. As the temperature reduce from the liquidus to the solidus, the liquid concentration of Sn. the lighter constituent, increases. Then the buoyancy-driven flow due to temperature and liquid composition gradients, called thermosolutal convection or double diffusion, occurs in the mushy region and forms the complicated macrosegregation maps. Related to this phnomena, effects on the macrosegregation formation depending on the cooling condition and gravity values are described.

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The Effects of Thermosolutal Convection on Macrosegregation during Alloy Solidification (합금응고과정에서 이중확산대류가 거시편석에 미치는 영향)

  • Lee, Gyun-Ho;Mok, Jin-Ho;Lee, Jin-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.10
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    • pp.1337-1345
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    • 2001
  • Numerical investigation is made to study the effects of thermosolutal convection on the formation of macrosegregation in a Pb-Sn alloy solidification process in a two dimensional confined rectangluar mold. The basic equations are sovled using the Contrinum Model theory with the SIMPE algorithm during the solidification process. In addition, to track the liquid-solid interface with time variations, the moving boundary condition was adopted and moving irregular interface shapes were treated with the time-dependent, boundary-fitted coordinate system. As the temperature reduces from the liquidus to the solidus, the liquid concentration of Sn, the lighter constituent, increases. Then the buoyancy-driven flow due to temperature and liquid composition gradients occurs in the mushy region and forms the complicated macrosegregation maps. belated to this phenomena, effects on the macrosegregation formation depending on the cooling condition and gravity values are examined.

Fluid Inclusion Study of the Samcheonpo Amethyst Deposit of Kyongsangnamdo, Korea (경상남도 삼천포 광산의 자수정에 대한 유체포유물 특성)

  • Bae, Yun-Sue;Yang, Kyoung-Hee
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.3 s.49
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    • pp.153-162
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    • 2006
  • Fluid inclusions in amethyst from the Samcheonpo amethyst deposit of the Waryongsan area, Kyongnam generally grouped into four different types: Type I (liquid-rich and $10{\sim}23wt%$ NaCl, $Th=289{\sim}359^{\circ}C$), Type II (vapor-rich and $2{\sim}10wt%$ NaCl, $Th=304{\sim}365^{\circ}C;$), Type III (halite-bearing, $31{\sim}54wt%$ NaCl, $Th=259{\sim}510^{\circ}C;$), and Type IV ($CO_{2}-bearing\;9{\sim}13wt%\;NaCl,\;126{\sim}277^{\circ}$). Type I, II, and III inclusions are confined in the lower part of the amethyst and Type IV in the upper, which indicates significant hydrothermal activity during the earliest stage of the amethyst growth or the solidus condition of granitic rocks. The earliest fluid exsolved from the crystallizing granitic magma formed Type IIIa which is spatially associated with silicate melt inclusions. The homogenization behavior of Type IIIa inclusions by dissolution of the halite crystal after the bubble disappearance indicates that Type IIIa inclusions were trapped at some relatively elevated pressure. Exsolution of Type IIIb, I, II forming fluids with gradual decrease in their salinity was followed. The last fluid was $CO_{2}-bearing$ fluid (Type IV), which is assumed to be derived by decarbonization reactions with the surrounding sedimentary rocks. It suggests that the fine-grained granitic rocks containing the Samcheonpo amethyst crystallized at the sub-solvus condition saturated with water and exsolved abundant water.

Mechanical Properties for Hollow Shape Part of Metal Matrix Composites by Thixoforging (Thixoforging에 의한 중공형 금속복합재료 부품의 기계적 특성)

  • Heo J. C.;Lee S. H.;Kang C. G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.10a
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    • pp.281-284
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    • 2001
  • MMC was developed that had distinguished mechanical properties and light weighted. MMC has excellent mechanical properties in many ways in automotive industrial, and get into the spotlight as a light materials substituted for iron and steel. But the know-how about MMC research lack, MMC is expensive and difficult to apply the sound parts. Especially it is difficult to produce the hollow type parts composed with MMC. Therefore, hollow type parts of metal matrix composites by thixoforging process which as co-existing solidus-liquidus phase, it is very important to obtain forming condition. In this study, used materials were A357, A380, A380 $10\%$vol, and $20\%$vol SiCp, and the size of particulates were $14{\mu}m$ and $5.5{\mu}m$

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Multi-Step Reheating Process of Metal Matrix Composites for Thixoforming (Thixoforming을 위한 금속 복합재료의 다단 재가열 공정)

  • 허재찬;강충길
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.180-183
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    • 1997
  • The forming process of metal matrix composites by the die casting and squeeze casting process are limited in size and dimension in term of final parts without machining. The thixoforming process for metal matrix composites has numerous advantages compared to die casting, squeeze casting and compocasting. The characteristics of thixoforming process can decrease the liquid segregation because of he improvement in fluidity in a globular microstructure state and utilizes flow without air entrapment. Therefore, in order to obtain the sound parts of metal matrix composites by using thixoforming process which as co-existing solidus-liquidus pahse, it si very important to obtain reheating condition. However, for he thixoforming process, the billet with the desired volume fraction must be heated to obtain a uniform temperature distribution over the entire cross-sectional areas. To obtain the reheating conditions of composites, the particulate reinforced metal matrix composites for thixoforming were fabricated by combined stirring process which is simultaneously performed with electro-magnetic stirring process which is simultaneously performed with electro-magnetic stirring and mechanical stirring process.

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Reheating Process and FEM Analysis of Inductive Heating (재가열 공정과 유도 가열의 FEM 해석)

  • 손영익
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03b
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    • pp.195-198
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    • 1999
  • For the thixoforming process beside an existing solidus-liquidus interval, the reheating conditions to obtain the globular microstructure are very important. It relies on the control of globular microstructure of semi-solid alloys that contain non-dendritic particles. To obtain the globular microstructure in cross section of billet, the optimal design of the induction coil is necessary. Therefore, in this paper the optimal coil design to minimize electromagnetic end effect will be proposed. The results of coil design were also applied to the reheating process to obtain a fine globular microstructure. Finally, reheating data base of aluminum alloys for thixoforming and FEM model for induction heating based on the optimal coil design have been proposed.

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용탕유동과 응고를 고려한 주조공정의 유한요소해석

  • 윤석일;김용환
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1995.04a
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    • pp.620-625
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    • 1995
  • Finite element analysis tool was developed to analyze the casting process. Generally, casting processes consists of mold filling and solifification. In order to investigate the effects of process variables and to predict the defects, both filling and solidiffication process were simulated simultaneously. At filling process, especiallywe consider thermal coupling to investigate thermal history of material during the filling stage. And thermal condition at the final stage of filling is used as the initial conditions in a solidification process for the exact simulation of the actual casting processes. At mold filling process, Lagrangian-type finite element method with automatic remashing scheme was used to find the material flow. To avoid numerical instability in low viscous fluid, a perturbation method with artificial viscosity is adopted. At solififfication process, enthalpy-based finite element method was used to solve the heat transfer problem with phase change. And elastic stress analysis has been performed to predict the thermal residual stress. Through the FE analysis, solidiffication time, position of solidus line, liquidus line and thermal residual stress are studied. Finite element tools developed in this study will be used process design of casting process and maybe basic structure for total CAE system of castigs which will be constructed afterward.