• Journal of Korea Foundry Society
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• v.43 no.2
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• pp.55-63
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• 2023

Due to the importance of the surface on the final slab quality, it is essential to maintain a smooth segment roll surface that is in touch with the thin solid shell during solidification. In this paper, the surface of the used continuous casting guide roll was analyzed to realize the mechanism of its surface deterioration. Surface analysis has revealed severe corrosion at two distinct areas leading to deep roughness occurring on the guide roll. Firstly, the severe corrosion follows prior austenite grain boundary due to exposure with acidic environment. Also, in heat affected zone (HAZ) where two cladding beads overlap, more severe corrosion takes place. The overheat input results in local ferritization without full melting which increases retained δ-ferrite content almost 10 times higher than surrounding area. Corrosion was observed to happen at the δ-γ interface where Cr depletion takes place.

• Composites Research
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• v.20 no.6
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• pp.15-20
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• 2007

In this work, the structural response of thin-walled, composite beams with built-in twist angles is analyzed using a mixed beam approach. The analytical model includes the effects of elastic couplings, shell wall thickness, and torsion warping. Reissner's semi-complimentary energy functional is used to describe the beam theory and also to deal with the mixed-nature in the beam kinematics. The bending and torsion related warpings introduced by the non-zero pretwist angles are derived in closed-form through the proposed beam formulation. The theory is validated with available literature and detailed finite element analysis results for rectangular solid section beams with elastic couplings. Very good correlation has been obtained for the cases considered.

• Computers and Concrete
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• v.33 no.6
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• pp.643-658
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• 2024

To date, shell-solid and fibre element model analysis are the most commonly used methods to investigate the seismic performance of concrete-filled steel tube (CFST) bridge piers. However, most existing research does not consider the loss of bearing capacity caused by the fracture of the outer steel tube. To fill this knowledge gap, a refined finite element (FE) model considering the ductile damage of steel tubes and the behaviour of infilled concrete with cracks is established and verified against experimental results of unidirectional, bidirectional cyclic loading tests and pseudo-dynamic loading tests. In addition, a parametric study is conducted to investigate the seismic performance of CFST bridge piers with different concrete strength, steel strength, axial compression ratio, slenderness ratio and infilled concrete height using the proposed model. The validation shows that the proposed refined FE model can effectively simulate the residual displacement of CFST bridge piers subjected to highintensity earthquakes. The parametric analysis indicates that CFST piers hold sufficient strength reserves and sound deformation capacity and, thus, possess excellent application prospects for bridge construction in high-intensity areas.

• Food Science and Preservation
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• v.24 no.2
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• pp.215-220
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• 2017

Cut Kimchi cabbages ($3{\times}3cm$) were dipped in the egg shell solution (0.5% egg shell calcium/0.5% citric acid solution) and stored in the low-density polyethylene (LDPE) film bag at $4^{\circ}C$ for 2 weeks. Using this cut Kimchi cabbage, kimchi was prepared and their physicochemical qualities were investigated. Moreover, their sensory qualities were compared with Kimchi prepared with normal Kimchi cabbages. Egg shell calcium pretreatment (ET) showed the lower weight loss of cabbages than non-treatment (NT), and soluble solid compounds were decreased in all samples. Titratable acidity showed no statistical difference. After making a kimchi using cut Kimchi cabbages stored for 2 weeks no statistical differences in soluble solids and titratable acidities of kimchi stored for 7 days were shown. As a result of sensory test, preference of color was decreased and salted condition of control was the most significantly decreased. Pickled seafood odor of kimchi showed statistical difference, compared with the control. Crispness decreased in all samples. On the other hand, salty flavor and pickled seafood flavor were increased, fresh cabbage flavor, bitter flavor and carbonic flavor were decreased. Overall sensory quality of cut Kimchi cabbage (ETK) didn't show significant difference compare with kimchi prepared with normal cabbage (CON). It is possible to make kimchi with approvable sensory quality using cut Kimchi cabbage treated with egg shell calcium.

• Journal of Environmental Health Sciences
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• v.28 no.2
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• pp.117-129
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• 2002

Concentration of welding fumes and their components is known to be hazardous to welder and adjacent worker. To determine the generation rates of metals in fumes, $CO_2$ flux cored arc welding on stainless steel was performed in well designed fume collection chamber. Variables were different products of flux cored wire(2 domestic products and 4 foreign products) and input energy(low-, optimal- , high input energy). Mass of welding fumes was determined by gravimetric method(NIOSH 0500 method), and 17 metals were analysed by inductively coupled plasm-atomic emission spectroscopy(NIOSH 7300 method). Flux cored wire tube and flux were analysed by scanning electron microscopy to determine their metal composition. 17 metals were classified by their generation rates. Generation rates of iron, manganese, potassium and sodium were all above 50mg/min at optimal input energy level. Generation rates of chromium and amorphous silica were 25~50mg/min. At 1~25mg/min level, nickel, titanium, molybdenum, and aluminum were included. Copper, zinc, calcium, lead, magnesium, lithium, and cobalt were generated below 1 mg/min. Generation rates of metal components in fumes were influenced by input energy, types of flux cored wire. Flux cored wire was consisted of outer shell tube and inner flux. Iron, chromium, and nickel were the major components of outer tube. Flux contained iron, chromium, nickel, potassium, sodium, silica, and manganese. The use of flux cored wire can increase the hazards by increasing the amounts of fumes formed relative to that of solid wire. The reason might be the direct transfer of elements from the flux, since the flux is fine power. Ratio of metals to the fume of flux cored wire was lower than that of solid wire because non-metal components of flux were transferred. Total metal content of fumes in flux cored arc welding was 47.4(24.3~57.2) percent that is much lower than that of solid wire, 75.9 percent. We found that generation rates of iron, manganese, chromium and nickel, all well known to cause work related disease to welder, increased more rapidly with increasing input energy than those of fumes. To reduce worker exposure to fumes and hazardous component at source, further research is needed to develop new welding filler materials that decrease both the amount of fumes and hazardous components.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.289-289
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• 2013

While there are plenty of studies on synthesizing semiconducting germanium nanowires (Ge NWs) by vapor-liquid-solid (VLS) process, it is difficult to inject dopants into them with uniform dopants distribution due to vapor-solid (VS) deposition. In particular, as precursors and dopants such as germane ($GeH_4$), phosphine ($PH_3$) or diborane ($B_2H_6$) incorporate through sidewall of nanowire, it is hard to obtain the structural and electrical uniformity of Ge NWs. Moreover, the drastic tapered structure of Ge NWs is observed when it is synthesized at high temperature over $400^{\circ}C$ because of excessive VS deposition. In 2006, Emanuel Tutuc et al. demonstrated Ge NW pn junction using p-type shell as depleted layer. However, it could not be prevented from undesirable VS deposition and it still kept the tapered structures of Ge NWs as a result. Herein, we adopt $C_2H_2$ gas in order to passivate Ge NWs with carbon sheath, which makes the entire Ge NWs uniform at even higher temperature over $450^{\circ}C$. We can also synthesize non-tapered and uniformly doped Ge NWs, restricting incorporation of excess germanium on the surface. The Ge NWs with carbon sheath are grown via VLS process on a $Si/SiO_2$ substrate coated 2 nm Au film. Thin Au film is thermally evaporated on a $Si/SiO_2$ substrate. The NW is grown flowing $GeH_4$, HCl, $C_2H_2$ and PH3 for n-type, $B_2H_6$ for p-type at a total pressure of 15 Torr and temperatures of $480{\sim}500^{\circ}C$. Scanning electron microscopy (SEM) reveals clear surface of the Ge NWs synthesized at $500^{\circ}C$. Raman spectroscopy peaked at about ~300 $cm^{-1}$ indicates it is comprised of single crystalline germanium in the core of Ge NWs and it is proved to be covered by thin amorphous carbon by two peaks of 1330 $cm^{-1}$ (D-band) and 1590 $cm^{-1}$ (G-band). Furthermore, the electrical performances of Ge NWs doped with boron and phosphorus are measured by field effect transistor (FET) and they shows typical curves of p-type and n-type FET. It is expected to have general potentials for development of logic devices and solar cells using p-type and n-type Ge NWs with carbon sheath.

• Korean Chemical Engineering Research
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• v.52 no.5
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• pp.592-602
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• 2014

In the Integrated Gasification Combined Cycle (IGCC), the stability of the gasifier has strong influences on the rest of the plant as it supplies the feed to the rest of the power generation system. In order to ensure a safe and stable operation of the entrained-flow gasifier and for protection of the gasifier wall from the high internal temperature, the solid slag layer thickness should be regulated tightly but its control is hampered by the lack of on-line measurement for it. In this study, a previously published dynamic simulation model of a Shell-type gasifier is reproduced and two different linear model predictive control strategies are simulated and compared for multivariable control of the entrained-flow gasifier. The first approach is to control a measured secondary variable as a surrogate to the unmeasured slag thickness. The control results of this approach depended strongly on the unmeasured disturbance type. In other words, the slag thickness could not be controlled tightly for a certain type of unmeasured disturbance. The second approach is to estimate the unmeasured slag thickness through the Kalman filter and to use the estimate to predict and control the slag thickness directly. Using the second approach, the slag thickness could be controlled well regardless of the type of unmeasured disturbances.

• International Journal of Highway Engineering
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• v.5 no.4 s.18
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• pp.1-11
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• 2003

Recently, the new pavement design method considering Korean environment and the specification for improving performance of pavement are being developed in Korea. The Jointed Concrete Pavement Program Applying Load Discretization Algorithm (called HEART-JCP) is one of the results of Korea Pavement Research Project in Korea. HEART-JCP program is developed to analyze various loading condition using the load discretization algorithm without mesh refinement. In addition, it can be modified easily into multi-purpose concrete pavement nidyses program because of the modularized structure characteristic of HEART-JCP. The program consists of basic program part and load discretization part. In basic program part, the displacement and stress are computed in the concrete slab, sub-layer, and dowel bar, which are modeled with plate/shell element, spring element and beam element. In load discretization program part, load discretization algorithm that was used for the continuum solid element is modified to analyze the model with plate and shell element. The program can analyze the distributed load, concentrated load, thermal load and body load using load discretization algorithm. From the result of verification and sensitivity study, it was known that the loading position, the magnitude of load, and the thickness of slab were the major factors of concrete pavement behavior as expected. Since the result of the model developed is similar to the results of Westergaard solution and ILLISLAB, the program can be used to estimate the behavior of jointed concrete pavement reasonably.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.443-454
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• 2013

Various metal ions (transition and base metals) incorporated MCM-41 catalysts can be synthesized using colloidal and soluble silica with non-sodium involved process. Transition metal ion-typically $V^{5+}$, $Co^{2+}$, and $Ni^{2+}$-incorporated MCM-41 catalysts were synthesized by isomorphous substitution of Si ions in the framework. Each incorporated metal ion created a single species in the silica framework, single-site solid catalyst, showing a substantial stability in reduction and catalytic activity. Radius of pore curvature effect was investigated with Co-MCM-41 by temperature programmed reduction (TPR). The size of metallic Co clusters, sub-nanometer, could be controlled by a proper reduction treatment of Co-MCM-41 having different pore size and the initial pH adjustment of the Co-MCM-41 synthesis solution. These small metallic clusters showed a high stability under a harsh reaction condition without serious migration, resulting from a direct anchoring of small metallic clusters to the partially or unreduced metal ions on the surface. After a complete reduction, partial occlusion of the metallic cluster surface by amorphous silica stabilized the particles against aggregations. As a probe reaction of particle size sensitivity, carbon single wall nanotubes (SWNT) were synthesized using Co-MCM-41. A metallic cluster stability test was performed by CO methanation using Co- and Ni-MCM-41. Methanol and methane partial oxidations were carried out with V-MCM-41, and the radius of pore curvature effect on the catalytic activity was investigated.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.31 no.5
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• pp.215-226
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• 2018

In this paper, to estimate the dynamic behavior of a submerged floating tunnel(SFT) by underwater explosion(UE), the SFT is modeled and analyzed by the explicit structural analysis package LS-DYNA. The section of SFT near to explosion point is modeled to shell and solid elements using elasto-plasticity material model for concrete tubular section and steel lining. And the other parts of the SFT are modeled to elastic beam elements. Also, mooring lines are modeled as tension-only cable elements. Total mass of SFT is including an added mass by hydrodynamic effect. The buoyancy on the SFT is considered in its initial condition using a dynamic relaxation method. The accuracy and the feasibility of the analysis model aree verified by the results of series of free field analysis for UE. And buoyancy ratio(B/W) of SFT, the distance between SFT and an explosion point and the arrangement of mooring line aree considered as main parameters of the explosion analysis. As results of the explosion analysis, the dynamic responses such as the dent deformation by the shock pressure are responded less as more distance between SFT and an explosion point. However, the mooring angle of the diagonal mooring system can not affect the responses such as the horizontal displacement of SFT by the shock pressure.