• 제목/요약/키워드: solid target

검색결과 347건 처리시간 0.03초

Determination of nickel and cadmium in fish, canned tuna, black tea, and human urine samples after extraction by a novel quinoline thioacetamide functionalized magnetite/graphene oxide nanocomposite

  • Naghibzadeh, Leila;Manoochehri, Mahboobeh
    • Carbon letters
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    • 제26권
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    • pp.43-50
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    • 2018
  • In this research, a novel and efficient quinoline thioacetamide functionalized magnetic graphene oxide composite ($GO@Fe_3O_4@QTA$) was synthesized and utilized for dispersive magnetic solid phase preconcentration of Cd(II) and Ni(II) ions in urine and various food samples. A number of diverse methods were employed for characterization of the new nanosorbent. The design of experiments approach and response surface methodology were applied to monitor and find the parameters that affect the extraction performance. After sorption and elution steps, the concentrations of target analytes were measured by employing FAAS. The highest extraction performance was achieved under the following experimental conditions: pH, 5.8; sorption time, 6.0 min; $GO@Fe_3O_4@QTA$ amount, 17 mg; 2.4 mL $1.1mol\;L^{-l}$ $HNO_3$ solution as the eluent and elution time, 13.0 min. The detection limit is 0.02 and $0.2ng\;mL^{-1}$ for Cd(II), and Ni(II) ions, respectively. The accuracy of the new method was investigated by analyzing two certified reference materials (sea food mix, Seronorm LOT NO 2525 urine powder). The interfering study revealed that there are no interferences from commonly occurring ions on the extractability of target ions. Finally, the new method was satisfactorily employed for rapid extraction and determination of target ions in urine and various food samples.

저온 분사 공정을 통하여 형성된 Al/Ni 복합소재 코팅의 특성 평가 (Property Evaluation of Kinetic Sprayed Al-Ni Composite Coatings)

  • 변경준;김재익;이창희;김시조;이성
    • Journal of Welding and Joining
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    • 제32권5호
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    • pp.72-79
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    • 2014
  • Shaped charge(SC) ammunition is a weapon that penetrates directly the target by made jet from metal liner on impacting at a target. In SC, the liner occupies significantly important role causing an explosion and penetration of the target. The Al-Ni composite coating was deposited on copper liner in a solid state via kinetic spraying to improve the explosive force. The mechanical properties, reactivity and microstructure were investigated to confirm the possibility of kinetic sprayed Al/Ni composite coating as a reactive liner material. Reactive liner using Al/Ni composite exhibited much enhanced reactivity than pure copper liner due to Self-propagating High-temperature Synthesis (SHS) reaction with significantly improved adhesive bond strength. Especially, among the Al/Ni composite coatings, AN11 (the Al versus Ni atomic percent ratio is 1:1) showed the greatest reactivity due to its widest reaction area between deposited Al and Ni.

두경부암의 최신 표적치료 (What's New in Molecular Targeted Therapies for Head and Neck Cancer?)

  • 이서영;김혜련
    • 대한두경부종양학회지
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    • 제37권2호
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    • pp.11-17
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    • 2021
  • Head and neck cancer is the 6th most frequently diagnosed solid tumor in the world. Alcohol consumption, smoking, and HPV infection are associated with the incidence of head and neck squamous cell carcinoma (HNSCC). Although a multidisciplinary approach is a key strategy for the treatment of locally advanced HNSCC, systemic therapy is the mainstream of recurrent or metastatic HNSCC treatment. Stage IV HNSCC has a relatively poor prognosis with median overall survival of around one year. There have been many clinical trials to investigate the efficacy of target agents in the treatment of HNSCC. In the HPV-negative HNSCC, TP53 and CDKN2A are the most commonly mutated genes. In the HPV-positive HNSCC, the PI3K pathway is frequently altered. EGFR, PI3K, cell cycle pathway, MET, HRAS, and IL6/JAK/STAT pathway are explored targets in HNSCC. In this study, we review the target pathways and agents under research. We also introduce here umbrella trials of recurrent or metastatic HNSCC conducted by the Korea Cancer Study Group. The combination of target agents with immune checkpoint inhibitors or cytotoxic chemotherapies would be a future step in the precision medicine of HNSCC treatment.

Development and Application of Customized Shielded Cask Transport System

  • Lee, Jong Kwang;Jeon, Min Ku;Jung, Yunmock;Park, Wooshin;Hong, Sun Seok;Choi, Eun-Young
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2018년도 추계학술논문요약집
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    • pp.157-158
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    • 2018
  • In this work, we developed a customized shielded cask transport system which is equipped with a railguided travelling unit and a position adjustment unit for the cask without any crane service. The designed solid model was verified to have sufficient safety margin by using structural analysis. The developed system was introduced to a hot-cell and successfully tested and verified to have required target performance.

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Conceptual design study on Plutonium-238 production in a multi-purpose high flux reactor

  • Jian Li;Jing Zhao;Zhihong Liu;Ding She;Heng Xie;Lei Shi
    • Nuclear Engineering and Technology
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    • 제56권1호
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    • pp.147-159
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    • 2024
  • Plutonium-238 has always been considered as the one of the promising radioisotopes for space nuclear power supply, which has long half-life, low radiation protection level, high power density, and stable fuel form at high temperatures. The industrial-scale production of 238Pu mainly depends on irradiating solid 237NpO2 target in high flux reactors, however the production process faces problems such as large fission loss and high requirements for product quality control. In this paper, a conceptual design study of producing 238Pu in a multi-purpose high flux reactor was evaluated and analyzed, which includes a sensitivity analysis on 238Pu production and a further study on the irradiation scheme. It demonstrated that the target structure and its location in the reactor, as well as the operation scheme has an impact on 238Pu amount and product quality. Furthermore, the production efficiency could be improved by optimizing target material concentration, target locations in the core and reflector. This work provides technical support for irradiation production of 238Pu in high flux reactors.

전고상 리튬 박막 전지 구현을 위해 펄스 레이저 증착법으로 LiCoO2 정극위에 성장시킨 비정질 (Li, La)TiO3고체 전해질의 특성 (Amorphous Lithium Lanthanum Titanate Solid Electrolyte Grown on LiCoO2 Cathode by Pulsed Laser Deposition for All-Solid-State Lithium Thin Film Microbattery)

  • 안준구;윤순길
    • 한국세라믹학회지
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    • 제41권8호
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    • pp.593-598
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    • 2004
  • 1 $\mu$m이하의 전고상 리튬 박막전지의 구현을 위해 펄스 레이저 증착법을 이용하여 Pt/TiO$_2$/SiO$_2$/Si 기판위에 LiCoO$_2$정극을 증착온도와 Li/Co 간의 몰 비율을 변화시켜가며 성장시켰다. 특히, Li/Co=1.2의 조성을 갖는 LiCoO$_2$를 50$0^{\circ}C$의 증착온도에서 성장시킬 경우 53 $\mu$Ah/$cm^2$-$\mu$m의 높은 초기 용량값을 가지며 100 싸이클 후에도 67.6%의 용량값을 유지하였다. LiCoO$_2$/Pt/TiO$_2$/SiO$_2$/Si위에 고체 전해질인 (Li, La)TiO$_3$를 비정질상으로 하여 PLD방법으로 낮은 온도대역에서 증착온도를 다양하게 하여 증착하였다. 10$0^{\circ}C$의 증착온도에서 LiCoO$_2$Pt/TiO$_2$/SiO$_2$/Si위에 성장시킨 (Li, La)TiO를 가지고 LiClO$_4$ in PC 안에서 Li anode와 충$.$방전 측정 결과 약 51$\mu$Ah/$cm^2$-$\mu$m의 초기 용량값을 나타내었으며 100싸이클 후에도 90%의 훌륭한 방전용량의 보존력을 나타내었다. 비정질상의 (Li, La)TiO$_3$ 고체 전해질은 전고상 박막전지로의 구현이 가능하다.

Solid Phase Microextraction 및 Purge & Trap을 이용한 생물시료 중 휘발성 유기화합물의 GC/MS 분석비교 (Comparison Solid Phase Microextraction with Purge & Trap on the GC/MS Analysis of Volatile Organic Compounds in Biota Samples)

  • 안윤경;서종복;홍종기
    • 분석과학
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    • 제14권5호
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    • pp.392-399
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    • 2001
  • 생물시료에 존재하는 휘발성 유기화합물 중 n-butylbenzene과 1,2-dibromo-3-chloropropane (DBCP)를 기체크로마토그래피/질량분석기-선택이온검색법에 의해 수행하였다. 시료 중 휘발성 유기화합물은 $100{\mu}m$ polydimethyl siloxane (PDMS) fiber를 사용하여 headspace solid phase microextractio (SPME) 및 purge & trap 방법에 의해 추출 및 비교하였다. SPME에 의한 회수율은 n-butylbenzene의 경우 85.8%, DBCP의 경우 92.4%로 나타났고 검출한계는 각각 $0.15{\mu}g/kg$, $0.05{\mu}g/kg$로 나타났다. 반면, purge & trap의 경우 회수율은 n-butylbenzene의 경우 115.2%, DBCP의 경우는 80.9%로 나타났고 검출한계는 각각 $0.04{\mu}g/kg$$0.70{\mu}g/kg$로 나타나 두 방법에 있어 국내에서 규제하는 검출한계측면에서 큰 차이는 없었다.

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Design for a Low-Pressure Hydrocyclone with Application for Fecal Solid Removal Using Polystyrene Particles

  • Lee, Jin-Hwan;Jo, Jae-Yoon
    • 한국양식학회지
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    • 제18권3호
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    • pp.180-188
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    • 2005
  • The separation performances for thirty different dimensions of a low-pressure hydrocyclone (LPH) were tested in order to obtain an optimum dimension scale for fecal solid removal from an aquaculture system. The geometric variables were considered on two inlet diameters (Di: 30 and 50 mm), five overflow diameters (Do: 30, 50, 60, 70 and 100 mm), and three cylinder lengths (Lc: 250, 345 and 442 mm), while the cylinder diameter (Dc) of 335 mm, underflow diameter (Du) of 50 mm and cone angle (${\theta}$) of $68^{\circ}$ were kept constant. A small size for carp feces was regarded as the target for the removal of solids. Spherical polystyrene particles (1.1-1.3 mm dia., ${\rho}_s=1.05g/cm^3$), which demonstrate a similar settling velocity and specific gravity to the carp feces, were used as feed. The separation performance was tested in the range of 330 to 1200 ml/s of the inflow rate. Experimental results using ANCOVA and the Tukey test (${\alpha}=0.05$) demonstrated that the separation performances of LPH were significantly affected (P<0.05) by fi, Di and Do. In contrast, there was no significant Lc effect (P>0.05) on the separation performances. The maximum separation performance was detected at dimension combinations of 30 mm of inflow diameter (Di), 50, 60 and 70 mm of overflow diameter (Do), 345 mm of cylinder length (Lc). The dimension proportions were 0.09, 1.03, 0.15-0.21 and 0.15 (or Di/Dc, Lc/Dc, Do/Dc and Du/Dc, respectively.

접촉계면 반사 초음파의 음향 비선형 특성 (Acoustic Nonlinear Characteristics of Ultrasonic Wave Reflected at Contact Interfaces)

  • 박병준;이태훈;김정석;장경영
    • 비파괴검사학회지
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    • 제31권1호
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    • pp.40-46
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    • 2011
  • 닫힘균열과 같은 고체-고체의 접촉계면에서 접촉 음향 비선형성을 평가하기 위해 벌크 투과파를 이용하는 기존의 전통적인 음향 비선형 기술의 경우 현장 적용하는데 있어서 송수신 탐촉자를 장착하기 위해 구조물 내부로 접근하는 것은 접근한계성의 어려움이 있다. 본 연구에서, 고체-고체의 접촉계면에서 음향 비선형성을 측정하기 위해 새로운 반사기법을 제안하였고 이는 대상재료의 동일한 면에서 송신과 수신을 하여 현장 적용성에 매우 편리한 기법이다. 이를 위해, 접촉압력에 대한 멱함수 모델를 통한 선형 그리고 비선형 강성을 추정하고 이를 기반으로 계면에서 반사된 초음파의 비선형 파라미터를 이론적으로 계산하였다. A16061-T6 시편에 대한 접촉압력에 따른 접촉계면 실험 결과들은 이론적인 예측과 매우 잘 일치하였으며 따라서 본 연구에서 제안된 반사모드 기술의 유효성을 검증하였다.