• 제목/요약/키워드: soil gas monitoring

검색결과 59건 처리시간 0.022초

Fluorescence Characteristic Spectra of Domestic Fuel Products through Laser Induced Fluorescence Detection

  • Wu, Ting-Nien;Chang, Shui-Ping;Tsai, Wen-Hsien;Lin, Cian-Yi
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제19권5호
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    • pp.18-25
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    • 2014
  • Traditional investigation procedures of soil and groundwater contamination are followed by soil gas sampling, soil sampling, groundwater sampling, establishment of monitoring wells, and groundwater monitoring. It often takes several weeks to obtain the analysis reports, and sometimes, it needs supplemental sampling and analysis to delineate the polluted area. Laser induced fluorescence (LIF) system is designed for the detection of free-phase petroleum pollutants, and it is suitable for on-site real-time site investigation when coupling with a direct push testing tool. Petroleum products always contain polycyclic aromatic hydrocarbon (PAH) compounds possessing fluorescence characteristics that make them detectable through LIF detection. In this study, LIF spectroscopy of 5 major fuel products was conducted to establish the databank of LIF fluorescence characteristic spectra, including gasoline, diesel, jet fuel, marine fuel and low-sulfur fuel. Multivariate statistical tools were also applied to distinguish LIF fluorescence characteristic spectra among the mixtures of selected fuel products. This study successfully demonstrated the feasibility of identifying fuel species based on LIF characteristic fluorescence spectra, also LIF seemed to be uncovered its powerful ability of tracing underground petroleum leakages.

THE CONCENTRATION OF PCDD/FS IN FLUE GAS AND SOIL COLLECTED IN THE VICINITY OF VARIOUS INCINERATORS, KOREA

  • Kim, Kyoung-Soo;Kim, Kyeo-Keun;Kim, Jong-Guk
    • Environmental Engineering Research
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    • 제12권2호
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    • pp.55-63
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    • 2007
  • PCDD/Fs monitoring was carried out to estimate the contamination level in soil samples taken in the vicinity of the various incinerators throughout South Korea from July 2003 to December 2004. The levels ranged from N.D. to 130.39 pg I-TEQ/g (d.w.) with an average concentration of 11.38 pg I-TEQ/g (d.w.). The level of PCDD/Fs in this study is similar to that of other countries. Overall, the highest mean concentration in the soil was found at 250 m from the stack. In addition, the flue gases were analyzed in order to obtain the congener profiles of the PCDD/Fs emitted from the incinerators. The concentration of I-TEQ in the flue gas ranged from 0.33 to 21.5 ng TEQ/$Sm^3$. These levels were much lower than the concentration stipulated in the Korean emission criterion(40 ng TEQ/$Sm^3$ until 2005). The comparison of the congener patterns using cluster analysis showed that the incinerators and PCP are sources of PCDD/Fs in the soil samples according to the sampling point, but the possibility of unidentified combustion sources and vehicles exists in the case of complex industrial regions.

다공성 세라믹(${\alpha}-Al_{2}O_{3}$)를 이용한 지중 매설형 기준전극 (The Development of Buried Type Reference Electrode Using Porous Ceramic(${\alpha}-Al_{2}O_{3}$))

  • 배정효;하윤철;하태현;이현구;김대경
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.145-147
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    • 2005
  • In present, most of metallic structures(gas pipeline, oil pipeline, water pipeline, etc) are running parallel with subway and power line in seoul. Moreover subway system and power line make a stray current due to electrical corrosion on metallic structures. The owner of metallic structures has a burden of responsibility for the protection of corrosion and the prevention against big accident such as gas explosion or soil pollution and so on. So, they have to measure and analyze the data about P/S(Pipe to Soil) potential due to stray current of subway system. So, we have developed the Real-time Wireless Remote Monitoring System for Stray Current of Subway System. In this system, the permanent buried type reference electrode is necessary. In this paper, results of development of buried type reference electrode using porous ceramic$({\alpha}-Al_{2}O_{3})$ are presented.

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Suggestions for the Estimation of the Methane Emission from a Landfill Site

  • Lee, Kyungho;Jeon, Eunjeong;Lee, Youngmin;Park, Junghyun
    • 도시과학
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    • 제9권1호
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    • pp.69-73
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    • 2020
  • Sudokwon landfill("Sudokwon" means regions of Seoul, Kyunggi and Incheon metropolitan cities in Korea), the world's largest sanitary landfill, has been systematically managing statistics on the incoming and dumping wastes and satisfactorily controlling pollutants including leachate and LFG. According to our long time experience of LFG field monitoring, the emission of GHG from landfill estimated by the IPCC Guideline showed much difference with our results. C&D waste has high concentration of sulfate compared to other wastes. Increased C&D waste of dumping waste had changed the COD/sulfate ratio in the landfill, which caused the increase of H2S gas and the decrease of CH4 gas. But the IPCC estimation method does not consider the effects of sulfate. In addition to that, the oxidation factor of the cover soil is set to the default values of 0.1 but the measured values by the field monitoring, are showing much higher than that, especially in the closed landfill.

Impacts of Unsystematic Solid Waste Dumping on Soil Properties and Climate Change

  • Benish ZAHRA;Farida BEGUM;Woo-Taeg KWON;Seung-Jun WOO;Min-Jae JUNG
    • 웰빙융합연구
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    • 제7권3호
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    • pp.31-42
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    • 2024
  • Purpose: Open-air dumping is a significant problem in Gilgit City, with limited research analyzing waste generation and its physicochemical impact on the soil. This study aimed to evaluate the effects of open dumping on soil properties and compare them with a controlled site. Research Design, data, and Methodology: Using ANOVA, the study found significant differences in electrical conductivity (EC), soil organic matter (SOM), soil organic carbon (SOC), sand, silt, and clay between the two sites, except for pH. Pearson correlation revealed that pH negatively correlated with EC, sand, and silt, but positively with SOM, SOC, and clay. The control site's mean EC was 6.06 mS/m, whereas the dumping site recorded 8.5 mS/m. EC is inversely related to SOM, SOC, silt, and clay, but directly to sand. SOC and SOM values varied significantly, with notable differences in soil texture components like clay and silt. Results: The research highlights the detrimental effects of unsystematic waste dumping on soil health and its contribution to greenhouse gas emissions, particularly methane, which exacerbates climate change. Conclusion: The study concluded that waste deposition and decomposition significantly impact EC, SOM, SOC, and soil texture, though pH remains unchanged. The unsystematic dumping of solid waste contributes to climate change through methane production, a potent greenhouse gas. To mitigate these impacts, the study recommends regular monitoring, waste prevention, recycling strategies, and continuous training for stakeholders to achieve sustainable development.

Analysis of Polycyclic Aromatic Hydrocarbons in Agricultural Soils by Gas Chromatography-Ion Trap Tandem Mass Spectrometry

  • Nam, Jae-Jak;Lee, Sang-Hak
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2003년도 International Symposium on Clean Environment
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    • pp.113-118
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    • 2003
  • An investigation has been carried out on collision-induced dissociation (CID) in the development of an analytical protocol for the determination of polycyclic aromatic hydrocarbons (PARs) by ion trap tandem mass spectrometry. Two different considerations were used to choose the optimal CID conditions for complex matrix environmental samples, namely, to determine the highest signal-to-noise (SIN) ratio and the other to eliminate the background interferences originated from complex matrix samples. The PAR content of agricultural soil was measured to estimate overall distribution of PAR in throughout the country, we collected and analyzed 226 soil samples from paddy and upland soil. The average content of total PAR in all samples was 236 ${\mu}g$ $kg^{-1}$, and the range was from 23.3 to 2, 834 ${\mu}g$ $kg^{-1}$. The overall distribution of PAR was found to be closely related to the pollution sources, the size of city and the type of industry.

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고체기준전극 및 원격전위측정 시스템 개발에 관한 연구 (A Study on the Development of Solid Reference Electrode and Remote Protection Potential Measuring System)

  • 류영돈;김진준;김동균
    • 한국가스학회지
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    • 제19권3호
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    • pp.38-43
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    • 2015
  • 지하에 매설된 도시가스 배관은 부식으로부터 보호하기 위하여 전기방식조치를 하도록 하고 있으며, 전기방식시설의 효과적인 유지관리를 위해 1년마다 배관의 전위를 측정 하도록 하고 있다. 방식전위의 측정은 테스트박스(T/B)에서 실시하게 되는데, 도심에 설치된 T/B의 경우 대부분 도로상에 설치되어 있어 전위를 측정할 때 어려움이 있다. 즉, 교통량이 많은 도로에서 전위를 측정하기 위해서는 차량을 통제하거나, 교통량이 적은 심야에 실시해야 하는 등 어려움이 있다. 본 연구에서는 이러한 방식전위 측정의 문제점을 해결하기 위해 고체기준전극 및 무선통신기술을 이용한 원격전위 측정시스템 개발에 관한 연구를 수행하였다. 고체기준 전극을 개발하여 실험실에서 성능테스트를 실시하고, 도시가스 배관이 설치된 현장에 직접 매설하여 전위 값의 변화를 관찰하였다. 또한, 무선통신을 이용하여 측정된 전위값을 서버로 전송하고, 사무실에서 전위값의 변화를 확인하였다. 고체기준전극을 이용한 전위값은 국내에서 사용되고 있는 타사 제품과 큰 차이가 없는 것으로 확인되었으며, 현장에서 측정한 전위 값과 웹서버로 보내진 전위값의 차이는 없었다. 개발된 고체기준전극은 향후 도심에 설치된 테스트 박스의 전위를 차량을 이용하여 측정하는데 사용할 계획이다.

지중 금속구조물 부식감시를 위한 영구매설용 기준전극 개발 (Development of Permanent Reference Electrode for Corrosion Monitoring of Underground Metallic Structures)

  • 하윤철;배정효;하태현;이현구;이재덕;김대경
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 학술대회 논문집 정보 및 제어부문
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    • pp.532-534
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    • 2004
  • The advancement of electronics and telecommunication technologies has forced the risk management system for underground metallic structures to evolve into the remote monitoring and control system. Especially, facilities such as gas pipelines, oil pipelines and water distribution lines might make hazardous effect on human safety without continuous monitoring and control. As a result, pipeline engineers have applied cathodic protection system to prevent the degradation of their facilities by corrosion and carried out a periodic monitoring of the pipe-to-soil (P/S) potentials at numberous test boxes along their pipelines. The latter action on a road in downtowns, however, is so much dangerous that the inspectors should be ready to suffer the threatening of their lives and maintenance. In order to minimize these social costs and hazards, a stand-alone type corrosion monitoring equipment which can be installed in test box, store the P/S data for given Belied and send the data by wired/wireless telecommunications is under development. In order to obtain the exact P/S data, however, a reference electrode should be located as close to the pipeline as possible. Actually, the measured potential by a conventional portable reference electrode contain inevitably an IR drop portion caused by the current flow from the cathodic protection rectifier or the subway railroad. To minimize this error, it is recommended that the reference electrode should be buried within 10 cm from the pipeline. In this paper, we describe the design parameters for fabricating the permanent type reference electrode and the characteristics of the developed reference electrode.

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지중 금속구조물 부식감시를 위한 측정단자함 인입형 소형 계측 장치개발에 관한 연구(II) (development of small size corrosion monitoring system for under ground metal structures)

  • 이재덕;배정효;하태현;이현구;하윤철;김대경
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 학술대회 논문집 정보 및 제어부문
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    • pp.104-106
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    • 2004
  • There are many under grounds facilities like oil pipes, gas pipes, water pipes, oil tanks, etc. and severe corrosion of these facilities made big problems. Fire, wide area water and soil pollution, massive and hazardous explosion, etc. can make big problems and cause big economical loss. So, various technologies were developed to keep these undergrouns facilities safely, and cathodic protection is one of it. For cathodic protection, one must detect potential of pipes, and there are so many test box to check pipes potentials. In this thesis, we describe on the development of small size corrosion monitoring system that measure pipes potentials easily and economically.

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기체크로마토그래피/동위원소 희석 질량분석법을 이용한 토양 중 폴리브롬화 디페닐에테르의 분석법 (Determination of Polybrominated Diphenyl Ethers(PBDEs) in Soil using Gas Chromatography/Isotope Dilution Mass Spectrometry)

  • 나윤철;장윤석;김해동;홍종기
    • 분석과학
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    • 제17권1호
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    • pp.29-36
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    • 2004
  • 본 연구에서는 토양중에 존재하는 폴리브롬화 디페닐에테르 (polybrominated diphenyl ethers, PBDEs)를 동위원소희석법을 이용한 기체크로마토그래피/질량분석기-선택이온검색법에 의해 검출하는 분석방법을 소개하였다. 토양 중 PBDEs는 속실렛 장치로 추출하고 실리카와 플로리실 흡착제를 이용한 고체상 추출법을 비교하였다. 정제 후 추출물은 기체크로마토그래피/질량분석기-선택이온검색방법으로 분석하였으며, 동위원소로 치환된 4종의 PBDEs를 내부표준물질로 이용한 동위원소 희석법으로 8종의 PBDEs를 정량하였다. 속실렛추출 후 플로리실과 실리카 카트리지를 통한 회수율은 각각 30.8~110.8%, 44.4~110.7%이었다. 이 분석법의 검출한계는 0.04~0.3 ng/g로 나타났다.