• Journal of the Korean Society for Marine Environment & Energy
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• v.10 no.4
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• pp.201-210
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• 2007

Pollution by chemical substances such as POPs, EDCs and PBTs in the ecosystem has become more complex and varied, increasing the possibility of irreversible damage to human health or the ecosystem. It is necessary to have a exposure assessment in a multi-media environment for various chemical substances is required for efficient management. This study applied MUSEM(Multi-media Simplebox-systems Environmental Model), a multimedia environmental model that can simultaneously evaluate the possibility of exposure of hundreds of chemical substances in order to efficiently manage chemical substances that can have negative impact on human health or ecological environment through environmental contamination. MUSEM executed the modeling for Japan by setting all 47 prefectures of japan as the regional area for 62 chemical substances and the rest of the territory of japan, excluding regional area, as the continental area and made the estimation of concentration among environment media in each administrative area and made the sensitivity analysis on Tokyo area. The results of simulation for chemical distribution showed that most of the target chemicals located in water region. The result of sensitivity analysis for octanol-water partition rate showed that the concentration change of soil in urban/industrial area and sediment in freshwater was high. In the case of sensitivity analysis for degradation rate showed that the concentration change of freshwater, soil in urban/industrial area, and sediment in freshwater was high.

• Journal of Soil and Groundwater Environment
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• v.9 no.4
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• pp.15-23
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• 2004

Deicer operations provide traffic safety during winter driving conditions in urban areas. Using large quantities of de-icing chemicals (i.e., $CaCl_2$ and NaCl) can cause serious environmental problems and may change behaviors of heavy metals in roadside sediments, resulting in an increase in mobilization of heavy metals due to complexation of heavy metals with chloride ions. To examine effect of de-icing salt concentration on the leaching behaviors and mobility of heavy metals (cadmium, zinc, copper, lead, arsenic, nickel, chromium, cobalt, manganese, and iron), leaching experiments were conducted on roadside sediments collected from Seoul city using de-icing salt solutions having various concentrations (0.01-5.0M). Results indicate that zinc, copper, and manganese in roadside sediments were easily mobilized, whereas chromium and cobalt remain strongly fixed. The zinc, copper and manganese concentrations measured in the leaching experiments were relatively high. De-icing salts can cause a decrease in partitioning between adsorbed (or precipitated) and dissolved metals, resulting in an increase in concentrations of dissolved metals in salt laden snowmelt. As a result, run-off water quality can be degraded. The de-icing salt applied on the road surface also lead to infiltration and contamination of heavy metal to groundwater.

• Journal of Korea Soil Environment Society
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• v.3 no.1
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• pp.31-44
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• 1998

The geochemical experiments were carried out to investigate a removal effect of heavy metals in abdndoned metallic mine wastes, and to conceive a treatment techniques of them. In order to prevent contamination, experiment appature was made of acrylic acid resin and polyethylene which resist to acid and alkali. Experiment models are devided into four groups based on the system environments, distribution patterns and a kind of filling materials. The first group is background model(model I ) which is filled with waste only and opened to air. The second one is four layer group which is subdivided into two models, opened and closed systems, and the third mix group which is subdivided into three models based on mixing ratio of filling materials and system environment like a layered group. The forth is composed of two layer model, lower one composed of waste and upper one limestone chips. Solution drained from Model Ishows a high contents of heavy metals on the all terms of experiments. Among the models, however, the closed mix model V and Ⅶ show the most effective removal of heavy metals liberated from wastes. Models having different mixing ratios of filling materials on closed systems does not affect in heavy metal removal effect. But, the distribution patterns of filling materials affect very much on removal effect of heavy metals. The closed models with same constitution ratios and distribution patterns of filling materials show more and less effective removal to the open models.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.3
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• pp.38-45
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• 1998

Soil and water contamination caused by the abundant use of agricultural chemicals including herbicides and fertilizers draws public concerns since these chemicals may pollute the agricultural lands as well as the food products grown on these lands. As a method to reduce the use of agricultural chemicals mulching with thin plastic film has been commonly practised for many years. Although use of the plastic film for mulching is very effective in preventing the growth of weed, it is almost impossible to remove all of the plastic film from the agricultural land and the remaining film eventually contaminates the soils. Therefore, it is very imperative to develop a mulching material that decomposes completely to prevent soil pollution problems and to enhance the competitive edge of domestic agriculture. Mulch papers are believed to have many positive characteristics in preventing problems caused by the plastic mulch film since it decomposes completely after use. However, the basis weight of mulch papers needs to be reduced to improve its handling properties and to reduce the raw material costs of pulps. In this paper the possibilities of using domestic old corrugated containers in producing mulch papers were examined. Also use of unbleached softwood kraft pulps and dry strength additives were exploited along with two-layered sheet forming technology in decreasing the basis weight of the mulch paper. Results showed that reduction of 20g/$m^2$ of basis weight of mulch paper was possible by the appropriate raw material selection and application of strength resin. To use the mulch papers in paddy fields, however, further research to improve its durability should be pursued.

• Korean Journal of Soil Science and Fertilizer
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• v.32 no.4
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• pp.375-382
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• 1999

In order to investigate the contamination characteristics of the heavy metals in the mine tailings of abandoned gold mine and its surrounding agricultural soils, a sequential extraction procedure of increasing reactivity in the dissolution processes of the heavy metals(Cd, Cu, and Pb) which were associated with solid and/or solution phase in soils was attempted to partition into six particulate fractions : exchangeable, bound to carbonate, bound to Fe-Mn oxides, bound to organic matter, residual, and soluble. Among indigenous heavy metals in the mine tailings, Pb was the most abundant and Cu and Cd were followed by. Fractionation result of Pb obtained from the triplicate samples of the mine tailings were in the order of Fe-Mn oxide> Carbonate> Residual> Organic> Exchangeable> Soluble, while Wolgok series were Exchangeable > Fe-Mn oxide > Carbonate> Organic> Residual> Soluable. However the other heavy metals studied were not followed this trend. The fractionation results of mine tailing and agricultural soils demonstrated that different geochemical fractions were operationally defined by an extraction sequence that generally followed the order of decreasing solubility. Therefore potential mobility and bioavailability of heavy metals as toxic pollution sources can be evaluated when studying the pollution levels of heavy metals in soils.

• Journal of Applied Biological Chemistry
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• v.61 no.4
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• pp.391-395
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• 2018

There is an increasing concern over arsenic (As) contamination of paddy soil and rice with regard to food safety. This study was conducted to investigate total and inorganic As concentration in one hundred husked and polished rice samples collected at the non-contaminated paddy soil in Korea. Arsenic species in rice samples were extracted using 1% nitric acid ($HNO_3$) with a microwave oven and were measured using high performance liquid chromatography coupled with inductively coupled plasma-mass spectrometry. Mean concentrations of total As in husked rice and polished rice were 0.18 and $0.11mg\;kg^{-1}$, respectively. Also, average inorganic As concentrations in husked rice and polished rice were 0.11 and $0.07mg\;kg^{-1}$, respectively. These levels are lower than the standard guideline value 0.35 and $0.2mg\;kg^{-1}$ for inorganic As in husked and polished rice recommended by Codex Committee on Contaminants in Foods and Ministry of Food and Drug Safety, respectively. The mean of the inorganic As ratio for the total amount of As was 0.65 and 0.67 for husked rice and polished rice, respectively, and the range was from 0.08 to 1.0. For health risk assessment, the average value of cancer risk probability was $9.24{\times}10^{-5}$ and ranged from $2.30{\times}10^{-5}$ to $1.90{\times}10^{-5}$. Therefore, human exposure to As through dietary intake of surveyed rice samples might considered to be a low health risk.

• Korean Journal of Heritage: History & Science
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• v.48 no.4
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• pp.62-73
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• 2015

The Tae-Jo Geonwolleung is the tomb of the first king Tae-Jo of the Joseon Dynasty in the complex of the Royal Tombs of the Joseon Dynasty which is listed in World Heritage, and it contains various types of stone properties. The material of the stone properties consist of a single type of medium-grained biotite granite, however, each properties have different intensity and types in deterioration phenomena according to their locations and purposes. The major deterioration types of the stones are analyzed as physical decomposition and biodeterioration. The exfoliation, breaking-out and granular decomposition are widespread types of the deterioration throughout the entire burial mound stone properties and surrounding stone properties. On the other hands, the colonization of mosses and plants, and contamination by foreign materials are found more frequent in the burial mound stone properties as these stones are in contact with the soil of the tomb mound and moisture in the soil helped biodeterioration. It is suggested that anti-biology treatment and physical reinforcement are applied to the deteriorated stones to prevent further damage on the stone components of the tomb.

• Journal of Apiculture
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• v.32 no.3
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• pp.163-170
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• 2017

Small hive beetle (SHB, Aethina tumida Murray (Coleoptera: Nitidulidae) is a honeybee pest infesting combs and stores inside the hive. Contamination of the SHB on Apis mellifera colonies were firstly noticed on September 23, 2016, in Miryang City, Gyeongnam Province in Korea. After that, on October 5, 2016, we investigated the spatial distribution of SHB inside the hive and outside soil within the apiary. Total of 169 beehives were observed. We found all stages of SHB inside or outside of hives. 61% of hives infested with the adult SHB still had live honeybees whereas hives containing larval SHB did not have bees, implying colony destruction In hives with live bees, infestation density was higher as bee population became higher. Coefficient of dispersions (CD) showed significant clumped distribution of infestation among hives. CDs were much higher inside hive than outside soil. Our results indicates SHB could result in honeybee colony collapse it not managed properly. Also even during October, there are new infestation into honeybee colonies and every stage of SHB could still be able to develop. Further detailed analysis of this insect' adaptation in Koran environment could help guide the management strategies of the invaded new pest of honeybee.

• Journal of the Korean GEO-environmental Society
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• v.23 no.9
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• pp.17-23
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• 2022

Using cement as a road subbase is economical, easily modified and supplemented and has excellent road pavement quality control. In addition, cement adheres well to sandy soils without adhesion, and it plays a role of permanently preserving adhesion in viscous soils with adhesion, so it can be widely applied as stable treatment with the advantages of increased strength, reduced compressibility. and improved durability. However, while cement is excellent in terms of strength for a road subbase, the material properties mean that it is difficult to maintain and reinforce when cracks or fractures occur due to dry shrinkage, and the pH increases in the ground due to hexavalent chromium eluting from cement. which can cause environmental problems such as groundwater contamination. Therefore, this study evaluates the usability of alternatives in the road base layer such as environmentally cementitious stabilizer and on-site soil generated from the site. We intend to reduce the environmental damage and evaluate the durability. To evaluate the applicability of the site, Environmental stability test and freeze-thaw test and wetting-drying test was conducted to evaluate the strength characteristics of alternative materials on the road through the limited performance evaluation of environmentally cementitious stabilizer. The test ranges were set at mixing ratios of 10%, 20%, and 30% and ages of three days, and 28 days old to evaluate the early strength and reference strength according to the mixing ratio of the environmentally cementitious stabilizer.

• Journal of Environmental Impact Assessment
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• v.25 no.6
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• pp.414-431
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• 2016

There are numerous closed and abandoned mines in Korea, from which diverse heavy metals (e.g., As, Cd, Cu, Pb, Zn) are released into the surrounding soil, groundwater, surface water, and crops, potentially resulting in detrimental effects on the health of nearby residents. Therefore, we performed human risk assessments of two abandoned metal mines, Yanggok (YG) and Samsanjeil (SJ). The exposure parameters used in this assessment were specific to residents near mines and the included exposure pathways were relevant to areas around metal mines. The computed total excess carcinogenic risks for both areas exceeded the acceptable carcinogenic risk ($1{\times}10^{-6}$), indicating that these areas are likely unsafe due to a carcinogenic hazard. In contrast, the non-carcinogenic risks of the two areas differed among the studied receptors. The hazard indices were higher than the unit risk (=1.0) for male and female adults in YG and male adults in SJ, suggesting that there are non-carcinogenic risks for these groups in the study areas. However, the hazard indices for children in YG and female adults and children in SJ were lower than the unit risk. Consumption of groundwater and crops grown in the area were identified as major exposure pathways for carcinogenic and non-carcinogenic hazards in both areas. Finally, the dominant metals contributing to carcinogenic and non-carcinogenic risks were As and As, Cu, and Pb, respectively. In addition, the carcinogenic and non-carcinogenic risks of YG were evaluated to be 10 and 4 times higher than those of SJ, respectively, resulted from the relatively higher exposure concentration of As in groundwater within SJ area. Because of lacking of several exposure parameters, some of average daily dose (ADD) could not be computed in this study. Furthermore, it is likely that the ADDs of crop-intake pathway included some errors because they were calculated using soil exposure concentrations and bioconcentration factor (BCF) rather than using crop exposure concentrations.