• Title/Summary/Keyword: soil and rock condition

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Mg/Al Impregnated Biochar for the Removal and Recovery of Phosphates and Nitrate

  • Kim, Dong-Jin
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2019.10a
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    • pp.134-134
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    • 2019
  • Utilization of organic waste as a renewable energy source is promising for sustainability and mitigation of climate change. Pyrolysis converts organic waste to gas, oil, and biochar by incomplete biomass combustion. Biochar is widely used as a soil conditioner and adsorbent. Biochar adsorbs/desorbs metals and ions depending on the soil environment and condition to act as a nutrient buffer in soils. Biochar is also regarded as a carbon storage by fixation of organic carbon. Phosphorus (P) and nitrogen (N) are strictly controlled in many wastewater treatment plants because it causes eutrophication in water bodies. P and N is removed by biological and chemical methods in wastewater treatment plants and transferred to sludge for disposal. On the other hand, P is an irreplaceable essential element for all living organisms and its resource (phosphate rock) is estimated about 100 years of economical mining. Therefore, P and N recovery from waste and wastewater is a critical issue for sustainable human society. For the purpose, intensive researches have been carried out to remove and recover P and N from waste and wastewater. Previous studies have shown that biochars can adsorb and desorbed phosphates implying that biochars could be a complementary fertilizer. However, most of the conventional biochar have limited capacity to adsorb phosphates and nitrate. Recent studies have focused on biochar impregnated with metal salts to improve phosphates and nitrate adsorption by synthesizing biochars with novel structures and surface properties. Metal salts and metal oxides have been used for the surface modification of biochars. If P removal is the only concern, P adsorption kinetics and capacity are the only important factors. If both of P and N removal and the application of recovery are concerned, however, P and N desorption characteristics and bioavailability are also critical factors to be considered. Most of the researches on impregnated biochars have focused on P removal efficiency and kinetics. In this study, coffee waste is thermally treated to produce biochar and it was impregnated with Mg/Al to enhance phosphates and nitrate adsorption/desorption and P bioavailability to increase its value as a fertilizer. Kinetics of phosphates and nitrate adsorption/desorption and bioavailability analysis were carried out to estimate its potential as a P and N removal adsorbent in wasewater and a fertilizer in soil.

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Suppression of Pyrite Oxidation by Formation of Iron Hydroxide and Fe(III)-silicate Complex under Highly Oxidizing Condition

  • Lee, Jin-Soo;Chon, Chul-Min;Kim, Jae-Gon
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.2
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    • pp.297-302
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    • 2011
  • Acid drainage generated by pyrite oxidation has caused the acidification of soil and surface water, the heavy metal contamination and the corrosion of structures in abandoned mine and construction sites. The applicability of Na-acetate (Na-OAc) buffer and/or Na-silicate solution was tested for suppressing pyrite oxidation by reacting pyrite containing rock and treating solution and by analyzing solution chemistry after the reaction. A finely ground Mesozoic andesite containing 10.99% of pyrite and four types of reacting solutions were used in the applicability test: 1) $H_2O_2$, 2) $H_2O_2$ and Na-silicate, 3) $H_2O_2$ and 0.01M Na-OAc buffer at pH 6.0, and 4) $H_2O_2$, Na-silicate and 0.01M Na-OAc buffer at pH 6.0. The pH in the solution after the reaction with the andesite sample and the solutions was decreased with increasing the initial $H_2O_2$ concentration but the concentrations of Fe and $SO_4^{2-}$ were increased 10 - 20 times. However, the pH of the solution after the reaction increased and the concentrations of Fe and $SO_4^{2-}$ decreased in the presence of Na-acetate buffer and with increasing Na-silicate concentration at the same $H_2O_2$ concentration. The solution chemistry indicates that Na-OAc buffer and Na-silicate suppress the oxidation of pyrite due to the formation of Fe-hydroxide and Fe-silicate complex and their coating on the pyrite surface. The effect of Na-OAc buffer and Na-silicate on reduction of pyrite oxidation was also confirmed with the surface examination of pyrite using scanning electron microscopy (SEM). The result of this study implies that the treatment of pyrite containing material with the Na-OAc buffer and Na-silicate solution reduces the generation of acid drainage.

Radon distribution in geochemical environment and controlling factors in Radon concentration(Case study) (지구화학환경에서의 라돈농도분포와 라돈농도의 지배요인(사례연구))

  • 전효택
    • The Journal of Engineering Geology
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    • v.10 no.2
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    • pp.189-214
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    • 2000
  • Three study areas of Kwanak campus(Seoul National University), Gapyung and Boeun were selected and classified according to bedrock types in order to investigate soil-gas radon concentrations. Several soil-gas samples showed relatively high radon concentrations in the residual soils which derived from granite bedrock. It also showed that water content of soil and the degree of radioactivity disequilibrium was a secondary factor governing radon emanation and distribution of radon radioactivity. The results of radon concentrations and working levels for forty rooms in Kwanak campus, Seoul National University, showed that indoor basement rooms under poor ventilation condition can be classified as high radon risk zone having more than EPA guideline(4 pCi/L). Some results of section analysis which was surveyed in the fault zone of Kyungju and Gapyung area confirmed the existence of fault-associated radon anomalies with a meaning of radon risk zone.

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Cyclic Hardening and Degradation Effects on Site Response during an Earthquake (지진시 지반의 반복경화/연화 현상에 의한 부지응답 특성 영향 연구)

  • Lee, Jin-Sun
    • Journal of the Earthquake Engineering Society of Korea
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    • v.12 no.6
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    • pp.65-71
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    • 2008
  • A one-dimensional site response analysis program (KODSAP) was developed using cyclic soil behavior model by using the modified parallel IWAN model. The model is able to predict the cyclic hardening and degradation of soil through the adjustment of the internal slip stresses of its elements beyond the cyclic threshold, and satisfies Bauschinger's effect and the Masing rule in terms of its own behavior characteristics. The program (KODSAP) used the direct integration method in the time domain. The elasticity of the base rock was considered as a viscous damper boundary condition. The effects of cyclic hardening or degradation of soil on site response analysis were evaluated through parametric studies. Three types of analyses were performed to compare the effect of analysis and cyclic parameter on site response. The first type was equivalent linear analysis, the second was nonlinear analysis, and a third was nonlinear analysis using the cyclic hardening or degradation model.

Effects of Soil Hardness on the Root Distribution of Pinus rigida Mill. Planted in Association with Sodding Works on the Denuded Land (사방시공지(砂防施工地)에 있어서 리기다소나무의 수근(樹根)의 분포(分布)에 미치는 토양견밀도(土壤堅密度)의 영향(影響))

  • Cho, Hi Doo
    • Journal of Korean Society of Forest Science
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    • v.56 no.1
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    • pp.66-76
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    • 1982
  • Soil harness represents such physical properties as porosity, amount of water, bulk density and soil texture. It is very important to know the mechanical properties of soil as well as the chemical in order to research the fundamental phenomena in the growth and the distribution of tree roots. The writer intended to grip soil hardness by soil layer and also to grasp the root distribution and the correlation between soil hardness and the root distribution of Pinus riguda Mill. planted on the denuded hillside with sooding works by soil layer on soil profile. The site investigated is situated at Peongchang-ri 13, Kocksung county, Chon-nam Province. The area is consisted of 3.63 ha having on elevation of 167.5-207.5 m. Soil texture is sandy loam and parant rock in granite. Average slope of the area is $17^{\circ}-30^{\circ}$. Soil moisture condition is dry. Main exposure of the area is NW or SW. The total number of plots investigated was 24 plots. It divided into two groups by direction each 12 plots in NW and SW and divided into three groups by the position of mountain plots in foot of mountain, in hillside, and in summit of mountain, respectively. Each sampling tree was selected as specimen by purposive sampling and soil profile was made at the downward distance of 50cm form the sampling tree at each plot. Soil hardness, soil layer surveying, root distribution of the tree and vegetation were measured and investigated at the each plot. The soil hardness measured by the Yamanaka Soil Hardness Tester in mm unit. the results are as follows: 1) Soil hardness increases gradually in conformity with the increment of soil depth. The average soil indicator hardness by soil layer are as follows: 14.6mm in I - soil layer (0-10cm in depth from soil surface), 16.2mm in II - soil layer (10-20cm), 17.2 in III - soil layer (20-30cm), 18.3mm in IV - soil layer(30-40cm), 19.8mm in V - soil layer (4.50mm). 2) The tree roots (less than 20mm in diameter) distribute more in the surface layer than in the subsoil layer and decrease gradually according to the increment of soil depth. The ratio of the root distribution can be illustrated by comparing with each of five soil layers from surface to subsoil layer as follows: I - soil layer; 31%, II - soil layer; 26%, III - soil layer; 18%, IV - soil layer; 12%, V - soil layer; 13%, 3) Soil hardness and tree root distribution (less than 20mm in diameter) of Pinus rigida Mill. correlate negatively each other; the more soil hardness increases, the most root distribution decreases. The correlation coefficients between soil hardness and distribution of tree roots by soil layer are as follows: I - soil layer; -0.3675 (at the 10% significance level), II - soil layer; -0.5299 (at the 1% significance level), III - soil layer; -0.5573 (at the 2% significance level), IV - soil layer; -0.6922 (at the 5% significance level), V - soil layer; -0.7325 (at the 2% significance level). 4) the most suitable range of soil hardness for the growth of Pinus rigida Mill is the range of 12-14.9mm in soil indicator hardness. In this range of soil indicator hardness, the root distribution of this tree amounts to 41.8% in spite of 33% in soil harness and under the 20.9mm of soil indicator hardness, the distribution amounts to 93.2% in spite of 82% in soil hardness. Judging from above facts, the roots of Pinus rigida can easily grow within the soil condition of 20.9mm in soil indicator hardness. 5) The soil layers are classified by their depths from the surface soil.

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A Study on the Distribution Characteristics of Buxus koreana in Kwanaksan Ecological and Scenery Conservation Area (관악산 생태경관보전지역 내 회양목 분포 특성 연구)

  • Lee, Ho-Young;Oh, Choong-Hyeon;Lee, Sang-Jin
    • Korean Journal of Environment and Ecology
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    • v.26 no.1
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    • pp.91-99
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    • 2012
  • The purpose of this study was to find out the vegetation community structure and the distribution characteristics of Buxus koreana through analysis of the topography and soil characteristics in Kwanaksan Ecological and Scenery Conservation Area. To do this twenty two plots as $100m^2$ each were set up and investigated. As a result, the vegetation communities were classified in four groups; Pinus rigida community (I), P. rigida - B. koreana community(II), Quercus mongolica community(III), Quercus acutissima - Quercus serrata community(IV). The distribution characteristics in topography appeared that B. koreana distributed more in valley where soil water and nutrition conditions are good. The drainage condition also influenced the distribution, because the ratio of clay was low in the result of soil texture analysis. B. koreana was distributed in high-pitched slope and the high rock ratio area. According to the soil analysis, the mean soil pH of B. koreana distributed groups(pH 4.79) was higher than that of non-B. koreana distributed groups(pH 4.41). It appeared that B. koreana had tolerance to the barren soil, so the value of exchangeable cations such as $Ca^{2+}$ and $Mg^{2+}$were showed lower than that of the average of Korean forest soil.

Analysis of Characteristics of Horizontal Response Spectrum of Ground Motions from 19 Earthquakes (국내 관측자료를 이용한 수평 응답스펙트럼 특성 분석)

  • Kim, Jun-Kyoung
    • Tunnel and Underground Space
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    • v.20 no.6
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    • pp.399-407
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    • 2010
  • The horizontal response spectra using the observed ground motions from the recent more than 19 macro earthquakes were analysed and then were compared to both the seismic design response spectra (Reg Guide 1.60), applied to the domestic nuclear power plants, and the Korean Standard Design Response Spectrum for general structures and buildings (1997). 130 horizontal ground motions, without considering soil types, were used for normalization with respect to the peak acceleration value of each ground motion. The results showed that response spectrum have strong dependency on epicentral distance. The results also showed that the horizontal response spectra revealed much higher values for frequency bands above 5 Hz than Reg. Guide (1.60). The results were also compared to the Korean Standard Response Spectrum for the 3 different soil types and showed that the vertical response spectra revealed much higher values for the frequency bands below 0.3 second than the Korean Standard Response Spectrum (SD soil condition). These spectral values dependent on frequency could be related to characteristics of the domestic crustal attenuation and the effect of each site amplification. However, through the qualitative improvements and quantitative enhancement of the observed ground motions, the conservation of horizontal seismic design response spectrum should be considered more significantly for the frequency bands above 5 Hz.

Development of Site Classification System and Modification of Site Coefficients in Korea Based on Mean Shear Wave Velocity of Soil and Depth to Bedrock (기반암 깊이와 토층 평균 전단파속도를 이용한 국내 지반분류 방법 및 지반 증폭계수 개선)

  • Kim, Dong-Soo;Lee, Sei-Hyun;Yoon, Jong-Ku
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.1C
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    • pp.63-74
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    • 2008
  • Site response analyses were performed based on equivalent linear technique using the local geologic and dynamic site characteristics, which include soil profiles, shear wave velocity profiles and depth to bedrock for 125 sites collected in Korean Peninsula. From the results of site response analyses, 2-parameters site classification system based on the combination of mean shear wave velocity of soil and depth to bedrock was newly recommended for regions of shallow bedrock depth in Korea. First, as the borders of bedrock depth (H) for site classification were determined as 10m and 20m, the soil sites were divided into 3 classes as $H_1$, $H_2$ and $H_3$ sites. And then, the 3 site classes were subdivided into 7 classes based on the mean shear wave velocity of soil ($V_{s,soil}$). The feasibility of new site classification system was verified and the representative site coefficients ($F_a$ and $F_v$) and design response spectrum were suggested by analyzing uniform trend and dispersion of site coefficients for each site class. The suggested site coefficients and the regression curves present the nonlinear characteristics of soils according to the change of rock outcrop acceleration with uniform trend effectively. From the comparison between the mean values of response spectrum which was acquired from the site response analysis and the suggested design response spectrum, there was a little difference in some of site classes and it was verified to adjust the integration interval to make it more suitable for the site condition in Korea.

The Stability Analysis Method with the Failure Shape in Cutting Slopes (절취사면에서의 파괴형태에 따른 안정해석방법)

  • Kang, Yea Mook;Chee, In Taeg;Kim, Yong Seong;Kim, Ji Hoon
    • Korean Journal of Agricultural Science
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    • v.25 no.1
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    • pp.97-106
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    • 1998
  • This study was carried out to investigate the problem of analysis method of circular sliding, which uses a high rate to work out a countermeasure for landslides. The results of this study were summarized as follows : 1. As a result of the analysis of sliding surface along the soil layers in forty model slopes, the boundary layer in weathered soil and weathered rock indicated a very high possibility of sliding than in other places. 2. Because most landslides in Korea occur along the discontinuity face at the boundary of soil layers, below 2m. from land surface, it is a good method for safe design to work the countermeasure for these kinds of landslides in cutting slopes. 3. When the inclination of slopes is fixed and the length of slopes is changed, the cercular sliding slopes were more safe as the soil layers are more shallow and the length of slopes are shorter, but the safety ratio of infinite sliding slopes was same as the other even though their length of slopes was different. 4. As a result of the analysis by cercular sliding analysis method and infinite sliding analysis method with some condition that the inclination of slopes was $30^{\circ}$ degree, because most landslides in Korea occur at this condition, these methods indicated different results to each other as well as cercular sliding analysis method showed too much safety ratio than infinite sliding analysis method.

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Influence of geometric factors on pull-out resistance of gravity-type anchorage for suspension bridge

  • Hyunsung, Lim;Seunghwan, Seo;Junyoung, Ko;Moonkyung, Chung
    • Geomechanics and Engineering
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    • v.31 no.6
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    • pp.573-582
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    • 2022
  • The geometry of the gravity-type anchorage changes depends on various factors such as the installation location, ground type, and relationship with the upper structure. In particular, the anchorage geometry embedded in the ground is an important design factor because it affects the pull-out resistance of the anchorage. This study examined the effect of four parameters, related to anchorage geometry and embedded ground conditions, on the pull-out resistance in the gravity-type anchorage through two-dimensional finite element analysis, and presented a guide for major design variables. The four parameters include the 1) flight length of the stepped anchorage (m), 2) flight height of the stepped anchorage (n), 3) the anchorage heel height (b), and 4) the thickness of the soil (e). It was found that as the values of m increased and the values of n decreased, the pull-out resistance of the gravity-type anchorage increased. This trend is related to the size of the contact surface between the anchorage and the rock, and it was confirmed that the value of n, which has the largest change rate of the contact surface between the anchorage and the rock, has the greatest effect on the pull-out resistance of the anchorage. Additionally, the most effective design was achieved when the ratio of the step to the bottom of the anchorage (m) was greater than 0.7, and m was found to be an important factor in the pull-out resistance behavior of the anchorage.