• Economic and Environmental Geology
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• v.38 no.1
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• pp.23-31
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• 2005

This study was performed to investigate the effect of humic acid on the adsorption of arsenic onto hematite and its binding mechanism through the chemical speciation modeling in the binary system and the adsorption modeling in the ternary system. The complexation modeling of arsenic and humic acid was suitable for the binding model with the basis of the electrostatic repulsion and the effect of bridging metal. In comparison with the experimental adsorption data in the ternary system, the competitive adsorption model from the binary intrinsic equilibrium constants was consistent with the amount of arsenic adsorption. However, the additive rule showed the deviation of model in the opposite way of cationic heavy metals, because the reduced organic complexation of arsenic and the enhanced oxyanionic competition diminished the adsorption of arsenic. In terms of the reaction mechanism, the organic complex of arsenic, neutral As(III) and oxyanionic As(V) species were transported and adsorbed competitively to the hematite surface forming the inner-sphere complex in the presence of humic acid.

• Economic and Environmental Geology
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• v.55 no.4
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• pp.339-352
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• 2022

As environmental criteria items are increased or strengthened, cases of heavy metal contamination by geogenic origin are increasing, and the need to distinguish between natural and anthropogenic origins in soil or groundwater exceeding the standard is increasing. In this study, geochemical occurrences of geogenic heavy metals were identified through statistical processing of the national geochemical map data and evaluation of geochemical characteristics of regions with high geoaccumulation indices. Cobalt, Cr, Cu, Ni, Pb, V, and Zn were targeted for which the national geochemical maps were prepared, and Co, Cr, Ni, and V derived from ultrabasic or ultramafic rocks were classified as factor 1. Copper, Pb and Zn of non-ferrous sulfide origin were classified as factor 2. In particular, enrichment of heavy metals by factor 1 occurs mainly in the serpentine distribution areas of the Chungcheong region, and there is a risk of contamination in neighboring areas. In the case of factor 2, geogenic occurrence is concerned not only in non-ferrous metal mineralization areas such as Taebacksan and Gyeongnam mineralization zones, but also in Au-Ag mineralization areas distributed nationwide.

• Ecology and Resilient Infrastructure
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• v.3 no.3
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• pp.207-211
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• 2016

This study focuses on the categorization of the phenomenon of vegetative recruitment on riparian channels, so called, the phenomenon from "white river" to "green river", and proposes for the corresponding research direction. According to the literature review and research outputs obtained from the authors' previous research performed in Korea within a limited scope, the necessary and sufficient conditions for the recruitment and retrogression of riparian vegetation may be the mechanical disturbance (riverbed tractive stress), soil moisture (groundwater level, topography, composition of riverbed material, precipitation etc.), period of submergence, extreme weather, and nutrient inflow. In this study, two categories, one for the reduction in spring flood due to the change in spring precipitation pattern in unregulated rivers and the other for the increase in nutrient inflow into streams, both of which were partially proved, have been added in the categorization of the vegetative recruitment and retrogression on the riparian channels. In order to scientifically investigate further the phenomenon of the riparian vegetative recruitment and retrogression and develop the working riparian vegetative models, it is necessary to conduct a systematic nationwide survey on the "white to green" rivers, establishment of the categorization of the vegetation recruitment and retrogression based on the proof of those hypotheses and detailed categorization, development of the working mathematical models for the dynamic riparian vegetative recruitment and retrogression, and adaptive management for the river changes.

• Journal of Wetlands Research
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• v.18 no.4
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• pp.481-487
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• 2016

In this research, a pilot scale hybrid rain garden system was developed in order to investigate the efficiency in the different components of the hybrid rain garden system and at the same time evaluate the initial efficiency of the system in treating urban stormwater runoff prior to its actual use in the field. Experimental runs were conducted using synthetic runoff having target concentrations similar to that of the typical runoff characteristics found in different countries and in Korea. With the employment of the hybrid rain garden system, hydrologic improvement was observed as the system demonstrates an approximately 95% reduction in the influent runoff volume with 80% retained in the system, and 15% recharged to groundwater. The reduction was contributed by the retention capabilities of ST and infiltration capabilities in PB and IT. With the combined mechanisms such as filtration-infiltration, biological uptake from plants and soil and phytoremediation that are incorporated in PB and IT, the system effectively reduces the amount of pollutant concentration wherein the initial mean removal efficiency for TSS is 87%, while an approximate mean removal efficiency of 76%, 46% and 56% was observed in terms of organics, nutrients and heavy metal, respectively. With these findings, the research helps in the further improvement, innovation and optimization of rain garden systems and other facilities as well.

• Journal of the Korean Society of Groundwater Environment
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• v.1 no.1
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• pp.23-32
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• 1994

To determine the apparent equilibrium constants, K$_{ad,app}$, for the adsorption reactions of trace metals on amorphous iron oxyhydroxide (AIO) in the Taebag coal mine area, time-adsorption and pH-adsorption experiments were performed for a selected bottom sediment mainly comprised of AIO from the study area. The results from the adsorption experiments indicate that most of the trace metals, except Pb, achieve equilibrium states with AIO and thus, the calculated K$_{ad,app}$ may represent the true apparent equilibrium constants. K$_{ad,app}$ and the stoichiometric coefficients of proton, x, of the adsorption reactions between the trace metals and AIO were respectively calculated from the intercepts and slopes of the regression lines of log($\Gamma$/ ［M］$_{aq}$)against pH provided by pH-adsorption experiments. The calculated K$_{ad,app}$ this study has the values of the range from 10$^{－4.5}$ to 10$^{2.75}$ , which is much different from the reported values by other investigators for simple experimental systems. K$_{ad,app}$ of this study is more or less close but not exactly pertinent to the estimated values for the other natural systems. It indicates that K$_{ad,app}$ for the adsorption reactions in the aquatic system in the study area is unique and thus should be determined befor the adsorption modelling. The calculated x of this study has the values of the range from -0.3 to 0.7, which is also much different from what most geochemists generally accept. The discrepancy in x may be due to the competition among different kinds of ionic species on the adsorption site or simulataneous occurrence of different kinds of adsorption reactions. The results from this study should help construct an appropriate adsorption model for the aquatic systems polluted by the coal mine drainage in the Taebag area. With the constructed model, one can describe the concentration variations of trace metals due to the adsorption in the system, which is an essential part of the investigation on the water quality affected by coal mine drainage in the Taebag coal field.

• Journal of Integrative Natural Science
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• v.4 no.2
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• pp.103-112
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• 2011

This study was carried out on 4 batch reactors to determine the specific ammonium oxidizing rate (SAOR), specific nitrate forming rate (SNFR) and inhibitory degree of nitrifying activities with saline concentrations. Under salt free condition ammonia was consumed during the reaction period within 200 min. When the salt level increased to 10, 20 and 30 g $NaClL^{-1}$ in reactor, ammonia depletion took 250, 300 and above 350 min, respectively. During concentration above 10 g $NaClL^{-1}$, there was nitrite accumulation. Also, at 30 g $NaClL^{-1}$ ammonia did not depleted and $NO_2{^-}$-N accumulated until the final reaction. Nitrate formation rates decreased with increasing salt concentration. SAOR and SNFR showed a decreasing trend as salinity concentrations were increased. The SAOR was reduced from 0.2 to 0.08 mg $NH_4{^+}$-N $g^{-1}VSS\;day^{-1}$ as the salt concentration increased from 0 to 30 g $NaClL^{-1}$. Similarly, the SNFR decreased from 0.26 kg $NO_3{^-}$-N $kg^{-1}VSS\;day^{-1}$ at saline free to 0.1 kg $NO_3{^-}$-N $kg^{-1}VSS\;day^{-1}$ at saline 30 g L-1. A severe inhibition of nitrifiers activity was observed at increased salt concentrations. The inhibition ratio of specific ammonium oxidation rates were 17, 47 and 60% on the reactor of 10, 20 and 30 g $NaClL^{-1}$ added, respectively. The inhibition ratio of specific nitrate forming rates also were inhibited 30, 53 and 62% on the reactor of 10, 20 and 30 g $NaClL^{-1}$ added, respectively. As the salinity concentrations increased from 0 to 30 mg $NaClL^{-1}$, the average MLSS concentration increased from 1,245 to 1,735 $mgL^{-1}$. The SS concentration of supernatant in reactor which settled about 30 minutes was not severely difference between concentration of salt free reactor and one of those high salt contained reactors.

• Korean Journal of Environmental Agriculture
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• v.41 no.3
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• pp.191-198
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• 2022

BACKGROUND: Plants can be grown using a culture medium without soil using a hydroponic system. Crop production by the hydroponic system is likely to increase as a means of solving various problems in the agricultural sector such as aging of rural population and climate change. Different water sources can be used to prepare the culture medium used in the hydroponic system. Therefore, it is necessary to study the effect of different water sources on crop production by the hydroponic system in order to explore the applicability of various water resources. METHODS AND RESULTS: Lettuce was cultivated by the hydroponic system and three different water sources [tap water (TW), bottled water (BW), and groundwater (GW)] were used to compare the effect of water sources on lettuce growth. The three kinds of waters with a nutrient solution (TW-M, BW-M, GW-M) were also used as the media. After the six-week growth period, the lettuce length and weight, the number of leaves, and the contents of chlorophylls and polyphenols were compared among the different media used. The lettuces did not grow in the waters without the nutrient solution. In the media, the lettuce growth and the contents of chlorophylls were affected by the different water sources used to prepare the media, while the contents of polyphenols were not affected. The absorbed amounts of ions by lettuces, especially Ca and Zn ions, and the dry weight of the harvested lettuces showed a strong positive correlation. CONCLUSION(S): Overall, this study shows that different water sources used for growing lettuce in a hydroponic system can affect lettuce growth. Further studies on the enhancement of crop qualities using different water sources may be required in future studies.

• Economic and Environmental Geology
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• v.56 no.4
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• pp.409-419
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• 2023

Acid mine drainage(AMD) treatment is classified as both passive and active treatment. During the treatment, about 5,000 tons of neutralization sludge is generated as a by-product per year in Korea. This study was conducted to evaluate the characteristics of sludge generated from physico·chemical treatment processes as an active treatment from 5 different sources (D, H, S, T, Y) and the possibility of the sludges being recycled. The sludges have a pH range of 5.86 ~ pH 7.89, and a water content range of 51% ~ 82%. Most of particle sizes were less than 25 ㎛. In analysis of inorganic elements, the concentration of Al, Fe, and Mn were between 1,189 mg/kg ~ 129,344 mg/kg, 106,132 mg/kg ~ 338,011 mg/kg, and 3,472 mg/kg ~ 11,743 mg/kg, respectively. The concentration of As and Zn in sludge-T, Cd in sludge-D, Ni in sludge-H, Zn in sludge-S, and Cd in sludge-Y exceeded the soil contamination standards of Korea. The results from 2 separate kinds of leaching test, the Korea Standard Leaching Test(KSLT) and Toxicity Characteristic Leaching Procedure(TCLP), showed that all the sludges met the Korea groundwater standards. From the XRD and SEM-EDS analysis, the peaks of calcite and quartz were found in the sludges. The sludge also had a high proportion of Fe and O, and the majority of the composition was amorphous iron hydroxide.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.2
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• pp.507-519
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• 2013

This study is to evaluate agricultural water supply capacity in Geum river basin (9,865 $km^2$), one of the 5 big river basin of South Korea using MODSIM-DSS (MODified SIMyld-Decision Support System) model. The model is a generalized river basin decision support system and network flow model developed at Colorado State University designed specifically to meet the growing demands and pressures on river basin management. The model was established by dividing the basin into 14 subbasins and the irrigation facilities viz. agricultural reservoirs, pumping stations, diversions, culverts and groundwater wells were grouped and networked within each subbasin and networked between subbasins including municipal and industrial water supplies. To prepare the inflows to agricultural reservoirs and multipurpose dams, the Soil and Water Assessment Tool (SWAT) was calibrated using 6 years (2005-2010) observed dam inflow and storage data. By MODSIM run for 8 years from 2004 to 2011, the agricultural water shortage had occurred during the drought years of 2006, 2008, and 2009. The agricultural water shortage could be calculated as 282 $10^6m^3$, 286 $10^6m^3$, and 329 $10^6m^3$ respectively.

• Journal of the Korean GEO-environmental Society
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• v.12 no.7
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• pp.49-56
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• 2011

Recently, the ground injection method using water glass as one of the components of the main resources and the products of the construction has some basic problems for permanent reinforcement of foundation and stopping leakage of water because it has some serious problems such as durability reduction, compression strength reduction and eluviation. This study was to evaluate the environmental impact and durability of the developed friendliness of Natural and Durable Stabilizer(NDS) of inorganic injection and Space Grouting Roket(SGR) with typical water glass type material. Two materials, NDS and SGR, were compared with each other by unconfined compressive strength test, fish poison test, durability test and triaxial permeability test. The results of the durability test indicated that the 28-day strength of the NDS was 1.5 times higher than that of the SGR. The fish poison test proved that the survival rate in the SGR and NDS is 50~70%, and 100%, respectively. Therefore, the NDS has higher survival rate than that of the existing SGR. The NDS will be considered by an environmentally friendly product and moreover it has a few problems for soil and groundwater pollution.