• 제목/요약/키워드: sodium ion absorption

검색결과 35건 처리시간 0.02초

이온교환에 의한 칼슘알지네이트 섬유의 제조 (Preparation of Calcium Alginate Fiber by Ion Exchange)

  • 손태원;이민경;한송정
    • 한국염색가공학회지
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    • 제23권1호
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    • pp.51-59
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    • 2011
  • Calcium alginate fiber were prepared by wet spinning of various conditions, including different concentrations of sodium alginate solution and $CaCl_2$ concentrations for coagulating the fiber through an absorption of calcium ion. The absorption of calcium ion during the coagulating step lead to solidify the fibers by the replacement of sodium ion with calcium ion to produce some crosslinking. The concentration of calcium ion in the calcium alginate fiber seems to be well related to the mechanical and physical property of the fiber, such as fiber strength moisture regain, and degree of swelling. The tensile strength of calcium alginate fiber was increased along with the increasing amount of sodium alginate solution. According to EDS analysis, 7 wt% $CaCl_2$ coagulation bath resulted in more calcium ion in the fiber compared to 3 wt% $CaCl_2$ coagulation bath. The decomposition temperature of calcium alginate fiber was $199^{\circ}C$, which $14^{\circ}C$ higher than that of sodium alginate.

이온크로마토그래피를 이용한 Sodium bisulfite 수용액 중의 미량 요오드 정량 (Determination of Trace Iodide in Sodium Bisulfite Aqueous Solution by Ion Chromatography with UV Detection)

  • 박양순;김도양;최광순;박순달;한선호
    • 분석과학
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    • 제13권3호
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    • pp.304-308
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    • 2000
  • 모의사용후핵연료로부터 sodium bisulfite 수층에 회수된 요오드($I^-$)를 이온크로마토그래피법을 이용해 정량할 때, 0.1 M sodium bisulfite와 1 mM 질산의 영향 없이 미량 오오드(1ppm)를 정량하기 위한 방법을 검토하였다. AS4A-SC(DIONEX) 컬럼과 자외선검출기를 사용하였고 sodium bisulfite, 질산 및 요오드의 자외선 흡광도를 측정하여 요오드 정량에 적합한 흡수파장으로 230nm를 선택하였고 용리액 농도는 0.1 M NaCl이 효율적이었다. 이 조건에서 0-1,000ppb 범위의 검정곡선을 작성하였다. 이때 선형상환계수는 0.99993 이었으며 검출한계는 5 ppb였다. 상대표준편차는 1.26% 이었다.

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Aerosol Flame Deposition법을 이용한 Er-doped Sodium Borosilicate 유리박막 제작에 관한 연구 (Fabrication of Er-doped Sodium Borosilicate Glass Films Using Aerosol Flame Deposition Method)

  • 문종하;정형곤;이정우;박강희;박현수;김병훈
    • 한국세라믹학회지
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    • 제37권2호
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    • pp.117-121
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    • 2000
  • Er-doped sodiumborosilicate glass films for waveguides amplifier were fabricated by Aerosol Flame Deposition(AFD) method. Al2O3 was added to sodium borosilicate glass films to suppress the formation of crystalline phase and control the refractive index. the formation of crystalline phase was suppressed above Al2O3 of 6 wt%. As the amount of Al2O3 increased from 2 to 12 wt% the refractive index of glass films increased lineary from 1.4595 up to 1.4710. After the core of 77SiO2-15B2O3-8Na2O+6 wt%Al2O3+8wt%Er2O3 was coated on the buffer layer of 77SiO2-15B2O3-8Na2O+6 wt%Al2O3, the core was etched by reactive ion etching. The absorption spectrum of 3 cm waveguide amplifier showed two peaks of 1530 and 1550 nm.

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포토폴리머와 희토류이온이 첨가된 유리에서의 이광자흡수를 이용한 광정보저장 (Optical memory in photopolymers and rare-earth ion-doped glasses using two-photon absorption)

  • 이명규;김은경;;임기수
    • 한국광학회지
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    • 제17권1호
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    • pp.75-80
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    • 2006
  • 펨토초 레이저 펄스에 의한 포토폴리머의 투과율 변화와 Eu 이온과 Sm 이온이 첨가된 sodium borate 유리의 형광파장의 변화를 이용하여 3차원 광메모리 가능성을 연구하였다. 780 nm의 모드잠금 타이사파이어 레이저를 이용하여 이광자흡수에 의해 DuPont 포토폴리머에서는 투과율을 변화시켰으며 이로 인해 $0.6{\mu}m$ 크기의 비트를 형성하였다. Sm 이온이 첨가된 재료에서는 이광자흡수로 인한 Sm 이온의 광환원을 이용하여 $4{\mu}m$ 크기의 형광 비트를 얻을 수 있었고 다층구조에서의 비트 형성을 시도하였다.

이온 전송 및 고주파 유전 흡수 (Ion Transport and High Frequency Dielectric Absorption)

  • 윤주호;최용성;황종선;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.379-380
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    • 2008
  • Molecular Dynamics (MD) simulations have been used to model the dynamics of the charge-compensating sodium ions in the non-stoichiometric hollandite Nax$(Ti_{8-x}Cr_x)O_{16}$. These interstitial ions reside in 'tunnels' in the crystal structure and move under the forces of both the ions making up the cage structure and the many body interactions of the other sodium ions in the tunnel. The Velocity Autocorrelation Function (VAF) of the sodium ions is calculated for a range of temperature from 250K to 1000K and converted into the linear ac-conductivity and ac-susceptibility response via Fourier transformation. A peak is found in the conductivity around $6\times10^{12}$ Hz that has some of the character of a Poley absorption. Here it is shown to be due to an harmonically coupled site vibrations of the sodium atoms, which extend only over a limited range. At frequencies below the peak the conductivity tends towards a constant i.e. dc value corresponding to a constant flow of ions through the simulation cell. At high temperatures the conductivity due to this ion transport process behaves like a metal with an insulator to metal transition occurring around a specific temperature.

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직물의 표백과 세척이 유연제 (DSDMAC) 흡착에 미치는 영향(제1보) (The Effects of Bleaching or Washing on the Absorption of Softener (DSDMAC) (part 1))

  • 박선경;유효선
    • 한국의류학회지
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    • 제20권2호
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    • pp.270-281
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    • 1996
  • This study was carried to figure out the effect of bleaching on the cationic surfactant (DSDMAC) absorption by cotton fabrics. And physico-chemical change, static electricity, and fabric stiffness of bleached cotton fabrics were measured. Cotton fabrics bleached with sodium hypochlorite soluton and with sodium percarbonate solution were used to analyze the DADMAC absorption. The results were as follows: 1. As the number of bleaching cycles were increased, the degree of oxidation on cotton fabrics was increased. So their carboxyl content was increased and their tensile strength was decreased. 2. DSDMAC absorption by cotton fabrics was increased by bleaching and was in propor- tion to carboxyl content. Therefore, it was groved that DSDMAC absorption by cotton fabrics was motivated by ion exchange mechanism. 3. The static electricity of cotton fabrics almost no change when bleached and unbleached absorption had no effect on the static electricity of cotton fabrics. 4. DSDMAC which was absorbed by cotton fabrics acted as a lubricant. DSDMAC absorption reduced the friction coefficient of yarn, so stiffness of cotton fabric was decreased.

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Hollandite Nax$(Ti_{8-x}Cr_x)O_{16}$의 이온 전송과 고유전율 특성 (Ion Transport and High Frequency Dielectric of the Hollandite Nax$(Ti_{8-x}Cr_x)O_{16}$)

  • 윤주호;이영;최용성;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.241-242
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    • 2008
  • The Velocity Autocorrelation Function (VAF) of the sodium ions is calculated for a range of temperature from 250K to 1000K and converted into the linear ac-conductivity and ac-susceptibility response via Fourier transformation. A peak is found in the conductivity around $6\times10^{12}$ Hz that has some of the character of a Poley absorption. Here it is shown to be due to an harmonically coupled site vibrations of the sodium atoms, which extend only over a limited range. At frequencies below the peak the conductivity tends towards a constant i.e. dc value corresponding to a constant flow of ions through the simulation cell. At high temperatures the conductivity due to this ion transport process behaves like a metal with an insulator to metal transition occurring around a specific temperature.

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X-ray Absorption Spectroscopy of a Poly Sodium 4-Styrensulfonate Intercalated Graphite Oxide Electrode

  • 정혜경;박병규;김재영;노한진
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.393-393
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    • 2011
  • We investigated the electronic structures of a poly sodium 4-styrensulfonate intercalated graphite oxide (PSSGO) electrode and a precursor graphite oxide (GO) electrode using X-ray absorption spectroscopy (XAS). Both electrodes were obtained from electrochemical cells. We found that in the C K-edge XAS spectra the ${\pi}^*$ state intensity originating from the sp2 hybridization of graphite decreases predominantly in the graphite oxide and PSSGO electrodes. This indicates that the negatively charged electrolyte ion (BF4-) is absorbed onto the electrodes and is transferred to the ${\pi}^*$ state of the both electrodes. The analysis of their F K-edge spectra reveals that more BF4- ions were found in the PSSGO electrode than in the graphite oxide electrode. This indicates that more electrolyte ions are absorbed in the PSSGO than in the graphite oxide electrode. We argue that this is the main reason why PSSGO cells have higher capacitance, higher energy density, and higher power density when compared to the graphite oxide cells. We also found that BF4- is the primary working ion that can be inserted into the interlayers of the PSSGO electrode.

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이온성 고분자를 이용한 나트륨 섭취 감소 효과 (Effect of Ionic Polymers on Sodium Intake Reduction)

  • 박세현;이영주;이종휘
    • 폴리머
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    • 제37권4호
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    • pp.533-538
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    • 2013
  • 염화나트륨은 우리 몸의 체액에 존재하며, 혈액 속에 약 0.9 wt%의 농도로 존재하여 삼투압을 유지하는 중요한 역할을 하고 있다. 그러나 사람들이 섭취하는 소금의 양은 증가하는 추세이며, 과량 섭취로 인해 고혈압 등의 원인이 되기도 한다. 본 연구에서는 생체적합성 이온성 고분자들의 특정 반대이온을 칼슘과 칼륨으로 치환시켜 나트륨 이온과의 이온교환을 통해 고분자에 나트륨이 흡착되어 대변으로 배출시킬 수 있는지를 in vitro 실험과 in vivo 실험을 통해 연구하였다. 조사된 고분자들 중 칼슘과 칼륨의 폴리스티렌설폰산, 칼슘 치환된 카라기난과 타마린드가 우수한 나트륨 치환 능력을 보유하고 있음을 확인하였고, 체온과 인공위액 및 인공장액의 조건에서도 나트륨 치환능을 유지하는 것을 확인하였다. 이러한 고분자들의 난용성 특징을 통해 구강 내에서는 맛의 변화를 주지 않으면서 나트륨을 흡착해 배설하는 메카니즘을 나트륨 과다 섭취에 따른 문제 해결을 위해 활용할 수 있을 것으로 사료된다.

Hollandite $Nax(Ti_8-_xCr_x)O_{16}$의 이온 전송과 고유전율 (Ion Transport and High Frequency Dielectric of the Hollandite $Nax(Ti_8-_xCr_x)O_{16}$)

  • 신현만;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 추계학술대회 논문집 전기설비전문위원
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    • pp.243-244
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    • 2008
  • The Velocity Autocorrelation Function (VAF) of the sodium ions is calculated for a range of temperature from 250K to 1000K and converted into the linear ac-conductivity and ac-susceptibility response via Fourier transformation. A peak is found in the conductivity around $6{\times}10^{12}Hz$ that has some of the character of a Poley absorption. Here it is shown to be due to an harmonically coupled site vibrations of the sodium atoms, which extend only over a limited range. At frequencies below the peak the conductivity tends towards a constant i.e. dc value corresponding to a constant flow of ions through the simulation cell. At high temperatures the conductivity due to this ion transport process behaves like a metal with an insulator to metal transition occurring around a specific temperature.

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