• 제목/요약/키워드: sodium hydroxide solution

검색결과 303건 처리시간 0.025초

Some Thiosemicarbazide Derivatives as Corrosion Inhibitors for Aluminium in Sodium Hydroxide Solution

  • Moussa, M.N.;Fouda, A.S.;Taha, F.I.;Elnenaa, A.
    • Bulletin of the Korean Chemical Society
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    • 제9권4호
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    • pp.191-195
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    • 1988
  • The effect of some thiosemicarbazide derivatives on corrosion of aluminium in 2M sodium hydroxide has been studied using thermometric, weight loss and hydrogen evolution techniques. The rate of the corrosion depends on the nature of the inhibitor and its concentration, heated of hydrogenation, mode of interaction with the metal surface and formation of metallic complexes. The compounds are weakly adsorbed on the surface of aluminium and form a monolayer of the adsorbate. Values of the Arrhenius activation energies indicate agreement with those obtained for an activation controlled process.

Properties of recycled steel fibre reinforced expanded perlite based geopolymer mortars

  • Celikten, Serhat
    • Advances in concrete construction
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    • 제13권1호
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    • pp.25-34
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    • 2022
  • The production of geopolymer is considered as a cleaner process due to much lower CO2 emission than that from the production of Portland cement. This paper presents a study of the potential use of recycled steel fibre (RSF) coming from the recycling process of the old tires in geopolymer mortars. Ground expanded perlite (EP) is used as a source of alumino-silicate and sodium hydroxide (NaOH=5, 10, 15, and 20M) is used as alkaline medium for geopolymer synthesis. RSFs were added to the mortar mixtures in four different volume fractions (0, 0.5, 1.0, and 1.5% of the total volume of mortar). The unit weight, ultrasound pulse velocity, flexural and compressive strength of expanded perlite based geopolymer mortar (EPGM) mixtures were determined. The microstructures of selected EPGMs were examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) analyses. The optimum molarity of sodium hydroxide solution was found to be 15M for geopolymer synthesis by EP. The test results revealed that RSFs can be successfully used for fibre-reinforced geopolymer production.

NaOH 및 $H_2SO_4$ 처리가 인삼 종자의 배생장에 미치는 영향 (Effects of Sodium Hydroxide and Sulfuric Acid on the Embryo Growth of Ginseng Seed (Panax ginseng C. A. Meyer))

  • 이종철;변정수;박훈
    • 한국작물학회지
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    • 제29권1호
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    • pp.98-101
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    • 1984
  • 인삼종자의 내과지는 배생장을 현저히 억제시켰다. 이 억제작용은 내과지에 의한 수분흡수 때문이 아니라 기계적인 것으로 추측되어졌다. 수산화나트리움 2.5% 용액에 인참종자를 10분 내지 30분 침적시키므로써 배생장을 촉진시킬 수 있었으나 황산처리는 인삼종자의 배생장에 영향을 주지 못했다.

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楮皮를 포함하는 絹紙의 特性 (Properties of the Handsheet Paper made from Silk Fibers and Paper Mulberry)

  • 강경돈;이기훈;정병희;류운영;남중희
    • 한국잠사곤충학회지
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    • 제41권3호
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    • pp.201-204
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    • 1999
  • The silk/paper mulberry paper was prepared by recycling of the hard twisted silk waste and its mechanical properties was investigated. The silk waste was pretreated with sodium hydroxide(0.5%) and sodium carbonate(4%) to make it easy for beating and fibrillation. The silk/paper mulberry hand sheet paper has better mechanical properties of tearing strength and air permeability compared with the traditional and modified traditional paper. Treating with alkaline solution, the hard twisted silk waste could be used for an novel composite material.

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The Commercial Use of Ultrafiltration Membranes in the Resolution of Aqueous Problems

  • Layton, R.B.
    • 한국막학회:학술대회논문집
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    • 한국막학회 1997년도 제5회 하계 Workshop (97 한,카 국제공동 Workshop, 고도 수처리를 위한 막분리 공정)
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    • pp.175-181
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    • 1997
  • This paper describes the commercial application of custom ultrafiltration (UF) membranes in the resolution of two aqueous-based problems: the recovery and recycling of laundry wash water and the fmal polishing of sodium hydroxide sterilization solution in the dairy and brewing industries. Both applications are currently in the pilot Stage and employ custom-made UF membranes developed by Liumar Technologies Corporation of Ottawa, Canada.

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알루미늄 자연발색에 관한 연구 (Integral coloring of aluminum)

  • 이구종;박광자
    • 한국표면공학회지
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    • 제17권4호
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    • pp.99-105
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    • 1984
  • Integral coloring of aluminum and its alloy with the elecrolytic solution of sulfosallicylic acid and sodium hydroxide was investigated in this study. Addition of hydrogen peroxide and potassium permanganate accelerated the anodizing speed and deepened the color of anodized film. Electron microscopic study was also performed on the surface and cross section.

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인산나트륨과 염화암모늄의 혼입 비율에 따른 순환골재의 pH 변화특성 (Changing Features of pH at the Cyclic Aggregate According to Mixing Ratio of Sodium Phosphate and Ammonium Chloride)

  • 高山;이건철;이건영;최중구;고동근
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 추계 학술논문 발표대회
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    • pp.47-48
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    • 2015
  • Recycled aggregate used in a site is strong alkali due to calcium hydroxide attached on its surface. Accordingly, many environmental problems arise. Therefore, as basic research to reduce pH of recycled aggregate, this study tries to reduce the strong alkalinity of recycled aggregate by using mixture solution based on sodium phosphate and ammonium chloride. As a result, original aggregate has the strong alkalinity of pH 11.23, whereas pH of recycled aggregate immersed in mixture solution decreased as more mixture rate increased, and mostly pH 9.8 or less was found.

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열수 및 알칼리 용액을 이용한 국산 목재 칩으로부터 헤미셀룰로오스의 선추출 및 특성 구명 (Pre-extraction of Hemicelluloses from Korean Mixed Hardwood Chips Using Hot Water and Alkali Solution and its Characteristics)

  • 조휘;신희내;심규정;윤혜정;이학래
    • 펄프종이기술
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    • 제43권1호
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    • pp.83-91
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    • 2011
  • Hemicelluloses are useful materials for papermaking and other biotechnological applications. To recover and further utilize the hemicelluloses, this study carried out the pre-extraction of the hemicelluloses from Korean mixed hardwoods chips using hot water and sodium hydroxide solution at various temperature and time conditions. Through the hot water pre-extraction, the wood components of 22% was extracted and the 35% of the hemicelluloses which were contained in the original wood chips were dissolved into the pre-extractives. The yield of the pre-extractives was more significantly influenced by the pre-extraction temperature than the time. The pre-extractives with the yield of 30% could be obtained by alkali pre-extraction and alkali concentration was the most important factor. It had lower hemicellulose content but high molecular weight, compared with the hot water pre-extractives.

시멘트 수용액에서 흡수 지연을 위한 Crosslinked Poly(sodium acrylate)의 표면 가교 (Synthesis of Surface Crosslinked Poly(sodium acrylate) for Delayed Absorption in Cement Solution)

  • 황기섭;장석수;정용욱;이승한;하기룡
    • 폴리머
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    • 제35권4호
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    • pp.363-369
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    • 2011
  • 콘크리트 제조 시 사용되는 잉여수를 지연 흡수시키기 위하여 역유화중합법으로 중합된 가교 poly(sodium acrvlate) (cPSA)를 ethylene glycol dimethacrylate(EGDMA)로 표면 가교시켰다. cPSA의 제조에서 연속상은 paraffin liquid, 단량제는 8 M 농도의 NaOH 수용액으로 90% 중화된 acrylic acid(AA), 가교제는 N,N-methylene bisacrylamide(MBA), redox 개시제는 ammonium persulfate(APS)와 sodium metabisulfite(SMBS)를 사용하여 역유화중합법으로 제조하였다. 제조된 cPSA는 EGDMA플 사용하여 표면 가교 반응을 수행하였다. 시멘트 수용액에서 $Ca^{2+}$ 이온과 cPSA의 상호 작용을 관찰하기 위하여 FTIR spectroscopy 분석법을 사용하였다. 제조된 흡수제들을 탈이온수 $Ca(OH)_2$ 수용액(pH 12) 및 시멘트 포화 수용액에서의 팽윤비를 측정하였으며, cPSA는 2시간만에 팽윤이 완료되었지만, 표면이 가교된 cPSA-EGDMA는 3시간 후 팽윤이 거의 완료되는 것을 관찰하였다. 또한 합성한 cPSA-EGDMA를 첨가함으로써 시멘트의 응결시간과 모르타르의 압축강도 증가를 관찰하였다.

우라늄 오염 동전기 침출액의 재이용을 위한 침전-여과 방법 (Precipitation-Filtering Method for Reuse of Uranium Electrokinetic Leachate)

  • 김계남;손동빈;박혜민;김기홍;이기원;문제권
    • 방사성폐기물학회지
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    • 제9권2호
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    • pp.63-71
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    • 2011
  • 우라늄 오염토양을 동전기제염 시 많은 양의 동전기 침출액이 발생한다. 발생된 우라늄 침출액을 재이용하기 위한 처리기술이 개발되었다. 동전기제염 시 발생된 우라늄침출액 내의 우라늄농도는 180 ppm이었고, Mg(II), K(I), Fe(II), Al(III) 농도는 20 ppm~1,210 ppm이었다. 우라늄침출액의 최적 처리공정은 혼합, 응집, 침전, 농축, 그리고 여과로 구성된다. 침전액의 pH를 11로 맞추기 위해, calcium hydroxide는 3.0g/100ml 그리고 sodium hydroxide는 2.7g/100ml이 필요했다. 여러 침전실험 결과 NaOH+0.2g alum+0.15g magnetite가 여과를 위한 최적 침전혼합제로 선정되었다. NaOH+0.2g alum+0.15g magnetite 투입 시 침전입자의 평균크기는 $600\;{\mu}m$이었다. pH=9에서 침전 후 상등액에 총 금속농도가 가장 낮았기 때문에, 최적 침전을 위하여 먼저 0.2g/100ml alum와 0.15g/100ml magnetite 투입한 후 pH=9일 때까지 sodium hydroxide을 투입하여야 한다.