• 제목/요약/키워드: sodium hydroxide concentration

검색결과 201건 처리시간 0.022초

실험실 폐수중 Aflatoxin 감소를 위한 화학적 처리에 관한 연구 (Chemical Treatment for the Destruction of Aflatoxins in Laboratory Waste Water)

  • 김종규
    • 한국환경보건학회지
    • /
    • 제18권2호
    • /
    • pp.52-56
    • /
    • 1992
  • The ability of chemicals, 10% sodium hypochlorite, 28% ammonium hydroxide, 5% sodium hydroxide, 5% sodium bicarbonate, 0.1% hydrochloric acid, 5% hydrogen peroxide, and 5% acetone, to destroy aflatoxins in laboratory waste water containing 3.26 ppb of B$_{1}$ 7.64 ppb of B$_{6}$3 ppb of G$_{1}$, and 11.39 ppb of G$_{2}$ with the total of 29.11 ppb was investigated. High performance liquid chromatograph (HPLC) was used for the separation and quantitation of aflatoxins. Treatment for 2 hours by the chemicals affected the destruction of aflatoxins and the most effective chemical was 10% sodium hypochlorite (p<0.05). Sodium hypochlorite concentrations more than 1% significantly reduced aflatoxin B$_{2}$, G$_{1}$, G$_{2}$ and total aflatoxins and more than 3% reduced B$_{1}$ (p<0.05). No further significant decreases were observed above the concentration of 5% for all 4 aflatoxins. Complete destruction of aflatoxins B$_{2}$, G_{1}$, and G$_{2}$ was achieved by 5% sodium hypochlorite at 48 hours and B$_{1}$ at 72 hours.

  • PDF

알칼리 처리에 따른 폐골목 및 굴참나무의 효소당화 특성 비교 (Comparison of enzymatic hydrolysis characteristics of mushroom culutured waste (MCW) and Cork oak by alkali treatment)

  • 윤수영;성현아;신수정
    • 펄프종이기술
    • /
    • 제46권3호
    • /
    • pp.44-49
    • /
    • 2014
  • The mushroom cultured waste(MCW) from cork oak was evaluated as the raw material for bioethanol production. For enzymatic hydrolysis, cellulase cocktails (Celluclast 1.5L and Novozym 188) was used for polysaccharides to monosaccharides conversion. Compared with sound cork oak woodmeal, woodmeal from MCW showed higher cellulose to glucose conversion. To improve polysaccharides to monosaccharides conversion, pretreatment by sodium hydroxide was applied. Even though more xylan and lignin were removed in woodmeal of MCW than that of cork oak, concentration of glucose was higher from sodium hydroxide treated cork oak woodmeal (51.3 g/L) than treated MCW woodmeal (41.6 g/L).

과망간산칼륨 용액에서 화학적으로 형성된 AZ31B 마그네슘 합금의 피막 특성평가 (Characteristics of Films Formed on AZ31B Magnesium Alloy by Chemical Oxidation Process in Potassium Permanganate Solution)

  • 김민정;김형찬;윤석영;정우창
    • 한국표면공학회지
    • /
    • 제44권2호
    • /
    • pp.44-49
    • /
    • 2011
  • The films formed on AZ31B magnesium alloy were prepared from alkaline solution composed of potassium permanganate and sodium hydroxide. The immersion tests were carried out at the different concentration of sodium hydroxide and pre-treatment method in 5 minute. The morphology and the phase composition of the film were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The corrosion behavior of the film in 5.0% NaCl solution was evaluated using potentiodyanmic polarization. Open circuit potential in developing film was examined with time. The thin and transparent film was mainly composed of MgO and $Mg(OH)_2$. The film with the best corrosion resistance was obtained at $70^{\circ}C$ bath temperature, 1.6 M concentration of sodium hydroxide and chemical pre-treatment.

알칼리 처리에 의한 Zeolite 광물의 물리화학적 특성 (Physicochemical Characteristics of Zeolite Mineral by Alkali Solution Treatment)

  • 임굉
    • 자연과학논문집
    • /
    • 제8권2호
    • /
    • pp.119-127
    • /
    • 1996
  • Zeolite인 mordenite 광물을 수산화나트륨용액으로 화학처리한 효과에 대해서 화학분석, X-선 분말회절, 열분석, 이산화탄소의 흡착측정 및 GC를 통하여 조사하였다. 출발원료로 mordenite 광물을 3시간동안 water bath 중 약 $95^{\circ}C$에서 NaOH 0.1-5N의 농도범위로 화학 처리한 결과, 시료중 함유된 모든 화학성분은 NaOH 0.5N 이하의 농도에서는 불용이고 mordenite 구조는 변화하지 않았으며 1N 이상의 농도에서는 실리카, 알루미나 등과 같이 성분들이 용해되었고 시료중 실리카의 용해비율이 알루미나의 용해보다 높으며 실리카와 알루미나의 비가 2-3N 농도 범위에서는 급격히 감소하였다.Mordenite 의 (202)면의 X-선 회절피크 강도와 $CO_2$ 흡착량은 1N 이상의 NaOH 농도가 증가함에 따라 감소하며 이로 인하여 mordenite 구조의 붕괴가 나타났다.산소, 질소 및 일산화탄소의 GC분리공정에서는 NaOH 용액 처리에 의한 영향을 받지 않으나 메탄과 크립톤의 용출피크가 넓어지는 경향이 나타나며 retention time 은 단축되었고 이 두 기체모두 용리피크는 산소 또는 질소와 중복되기 쉬운 경향을 보여주었다.

  • PDF

황산용액과 수산화나트륨용액의 침출에 의한 국내산 흑연 정광으로부터 불순물 제거 (The Removal of Impurities from Domestic Graphite Concentrate by H2SO4 Solution and NaOH Solution Leaching)

  • 이준섭;유경근;박현규
    • 자원리싸이클링
    • /
    • 제32권3호
    • /
    • pp.38-44
    • /
    • 2023
  • 국내산 흑연정광으로부터 불순물을 제거하기 위해 황산용액 및 수산화나트륨용액을 이용하여 침출실험을 진행하였다. 황산용액과 수산화나트륨용액을 각각 사용하여 침출실험을 진행한 결과, 수산화나트륨과 황산의 농도가 2 mol/L 이상에서 제거효과의 차이가 미미하고, 황산용액침출에서 온도가 증가함에 따라 고정탄소함량이 증가하는 것에 비해 수산화나트륨용액에서는 150℃ 이상에서 큰 차이가 나타나지 않았다. 수산화나트륨용액침출은 2 mol/L NaOH, 200℃, 1시간의 조건으로 선정하고, 황산용액침출은 2 mol/L H2SO4, 100℃, 1 시간의 조건으로 선정하여 5회까지 반복하여 침출을 진행하였다. 황산용액침출 후 수산화나트륨용액침출을 5회 반복했을 때 고정탄소는 99.95 %까지 증가하였고, 회분은 0.048 %까지 감소하였다. 수산화나트륨용액침출 후 황산용액침출을 5회 반복한 결과, 고정탄소는 99.98 %, 회분은 0.018까지 감소하여 수산화나트륨용액 침출 후 황산용액침출을 수행한 결과가 다소 높게 나타났다.

천연인디고를 이용한 견직물 염색의 표준화 연구 (Optimization of Silk Dyeing with Natural Indigo)

  • 손경희;신윤숙;류동일
    • 한국염색가공학회:학술대회논문집
    • /
    • 한국염색가공학회 2008년도 제38차 학술발표대회
    • /
    • pp.102-104
    • /
    • 2008
  • Natural indigo dye was prepared by extracting from Polygonum tintorium, precipitating with calcium hydroxide, and dried. Dyeing was carried out using sodium hydrosulfite as a reducing agent for the prepared natural indigo powder. K/S value, color property, and colorfastness of dyed fabrics were investigated. Optimum dyeing conditions obtained were 60$^{\circ}C$, 20min. Regardless of indigo dye and sodium hydrosulfite concentration, Munsell hue of dyed fabrics was PB color. Compared to the dyed fabric with both sodium hydroxide and sodium hydrosulfite, those with sodium hydrosulfite only showed higher color strength(K/S value). Colorfastness of dyed fabrics showed high rating except of wash/dry cleaning fastness of silk fabrics dyed low color strength.

  • PDF

알칼리 전처리가 굴참나무의 효소 당화에 미치는 영향 (Impact of Alkali Pretreatment to Enzymatic Hydrolysis of Cork Oak (Quercus Variabilis))

  • 윤수영;신수정
    • 펄프종이기술
    • /
    • 제46권6호
    • /
    • pp.1-7
    • /
    • 2014
  • Dissolving part of xylan and lignin in lignocellulosic biomass by base can be used as pretreatment technique. Cork oak was pretreated with sodium hydroxide solution and the pretreatment effects were evaluated with two critical factors - NaOH concentration and pretreatment temperature. Some of xylan and lignin were removed by base pretreatment. At $90^{\circ}C$ and 13% NaOH pretreatment, 22.0% of lignin and 78.8% of xylan removed by base treatment. Enzymatic hydrolysis of cork oak which was pretreated at higher temperature or concentration was further improved. After pretreatment of cork oak with 13% NaOH at $90^{\circ}C$, the conversion rate of cellulose to fermentable sugars were reached up to 91.3%. At ethanol fermentation with enzymatic hydrolysate from different pretreatment conditions, all enzymatic saccharification liquids were well fermented by Saccharomyces cerevisiae.

습식 스크러버를 이용한 NOx 제거에 관한 연구 (The Simultaneous removal of NOx using Wet Scrubber)

  • 김재강;이주열;박병현;최진식
    • 한국응용과학기술학회지
    • /
    • 제32권2호
    • /
    • pp.296-301
    • /
    • 2015
  • The experiment was performed for in order to remove NOx which is generated in the Ship's engine. it was performed test in order to remove NOx which is generated in the Ship's engine. It was used as the oxidizing agent sodium chlorite. Use the oxidizer is nitrogen monoxide was oxidized to nitrogen dioxide. and was tested pH adjustment to increase the efficiency of oxidizing. An aqueous solution of sodium hydroxide was used for the nitrogen dioxide absorbent. Low concentration of the solution, it showed a high efficiency. improves the absorption efficiency by add additives.

유기산을 이용한 납 오염토양의 복원에 관한 연구 (A Study on the Pb-contaminated Soil Remediation by Organic Acid Washing)

  • 정의덕
    • 한국환경과학회지
    • /
    • 제9권5호
    • /
    • pp.437-441
    • /
    • 2000
  • A study on the removal of Pb ion from Pb-contaminated soil was carried out using ex-site extraction process. Tartaric acid (TA) and iminodiacetic acid sodium salt(IDA) as a washing agent were evaluated as a function of concentration reaction time mixing ratio of washing agent and recycling of washing agent. TA showed a better extraction performance than IDA. The optimum washing condition of TA and IDA were in the ratio of 1:15 and 1:20 between soil and acid solution during 1 hr reaction. The total concentrations of Pb ion by TA and IDA at three repeated extraction were 368.8 ppm and 267.5 ppm respectively. The recovery of Pb ion from washing solution was achieved by adding calcium hydroxide and sodium sulfide form the precipitation of lead hydroxide and lead sulfide and optimum amounts of sodium sulfide and calcium hydroxide were 7 g/$\ell$ for the TA washing solution and 4 g/$\ell$, 5g/$\ell$ for the IDA washing solution respectively. The efficiency of recycle for TA and IDA washing solution were 78.8% , 95.1%, and 89.2%, 96.6% at third extractions under $Na_2S$ and $Ca(OH)_2$, respectively.

  • PDF

A study on Nickel Hydroxide Crystallization for Plating waste Treatment

  • Lee, Chang-Hwan;Lee, Choul-Ho
    • 대한전자공학회:학술대회논문집
    • /
    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
    • /
    • pp.292-295
    • /
    • 2001
  • A Study on the precipitation characteristics of nickel hydroxide as well as carbonate and sulfide is carried out to determine the proper treatment condition of the wastewater induced from nickel-plating industry. The nickel concentrations in the effluent could be kept lower than 5ppm when the value of pH was maintained higher than 10. The precipitation of nickel salts by alkaline addition to the nickel containing model wastewater was conducted by using proper amount of sodium hydroxide, sodium carbonate, sodium bicarbonate and sodium sulfide. In case of the sulfide treatment, the residual nickel concentration in the clear water after precipitates removed showed the lowest value. The influences of the precipitation condition upon the particle size of the crystals precipitated were also investigated. In spite of the various precipitation conditions were adopted, the particle size of the precipitated crystals showed no great differences. The sedimentation rates of the precipitated particle bed were observed and the free sedimentation period was terminated within 20 minutes. Although the hindered sedimentation as well as bed compaction progressed subsequently, the bed heights were maintained almost the same level after two hours of sedimentation.

  • PDF