• Journal of the Korean Ceramic Society
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• v.39 no.7
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• pp.675-679
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• 2002

To produce a strengthened glass, single ion exchange properties such as three-point bend strength and residual stress were investigated in soda-lime-silicate substrate glass for display use. The present work showed that the maximum value of strength was 62.5${\times}$10$\sub$6/ kg/㎡ after, the two-step single ion exchange process at 470$^{\circ}C$ for 1 h and 450$^{\circ}C$ for 24 h. As the result of the fracture analysis after bending test, the residual stress on the fractured surface of the strengthened glass increased the flexibility by means of absorbing the elastic deformation energy in the glass. Also, the effects of absorbing the elastic deformation energy were analysed by curvature change, number of multiple crack branches and brittleness.

• Journal of the Korean Wood Science and Technology
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• v.31 no.6
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• pp.31-39
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• 2003

The enzymatic isolation of residual lignins obtained from spruce and beech pulps (obtained by sulfite, kraft, ASAM and soda/AQ/MeOH pulping processes) and their characterization was described in previous publications. Here, the residual lignins have been submitted to potassium permanganate oxidation (KMnO₄ degradation), and 9 aromatic carboxylic acids (3 of them are dimeric) were identified after methylation with diazomethane by GC/MS. The analytical challenge during qantification by the internal standard methods was the partly high protein content of the samples, which resulted in elevated anisic acid yields in the degradation mixture of sulfite residual lignins. The results are compared with the KMnO₄ degradation of the corresponding MWLs and discussed in terms of S/G ratios and degrees of condensation. The latter was calculated as a quotient between the aromatic carboxylic acids derived from condensed and non-condensed lignin structures. Typical degradation patterns for the various processes have been observed. Among other parameter, the relative compositions between iso-hemipinic acid (which is for condensation in pos. 5 of the aromatic ring) and meta-hemipinic acid and 3,4,5-trimethoxyphthalic acid (both are for condensation in pos. 6 of the aromatic ring) was found to be process specific. Kraft and soda/AQ/MeOH residual lignins yielded higher amounts of iso-hemipinic acid. In contrast, the relative yields of meta-hemipinic acid and 3,4,5-trimethoxyphthalic acid (the latter in beech lignins) are higher in sulfite and particularly in ASAM residual lignin. In case of beech residual lignins the amount of acids originated from non-condensed syringyl type lignin units was surprisingly high. The condensation degree of residual lignins was shown to be generally higher than that of MWLs. This was especially true for the G units. ASAM residual lignin exhibited very high S/G ratios and degrees of polymerization. Causality between condensation degree and total yield of degradation products was demonstrated.

• Journal of the Optical Society of Korea
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• v.7 no.3
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• pp.160-164
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• 2003

Materials processing by ultrashort pulsed laser is actively being applied to micromachining technology due to its advantages with regard to non-thermal machining. In this study, materials processing with ultrashort pulses was studied by using the high repetition rate of a 800 nm Ti:sapphire regenerative amplifier. This revealed that the highly precise micromachining of metallic thin film and bulk glass with a minimal heat affected zone (HAZ) could be obtained by using near damage threshold energy. Grooves with diffraction limited sub-micrometer width were obtained with widths of 620 nm on Cr thin film and 800 nm on a soda-lime glass substrate. The machined patterns were investigated through SEM images. We also phenomenologically examined the influence of variations of parameters and proposed the optimal process conditions for microfabrication.

• Journal of the Korean Ceramic Society
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• v.25 no.3
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• pp.237-242
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• 1988

Ion exchange behavior of glasses was investigated in this study. The used glasses were Soda-limesilica glasses that was produced by float process. In order to analyse effects of ion exchange, some properties were measured; $K^+$ ion penetration depth, compressive stress, compression layer thickness, amount of $K^+$ ion exchange and density, in case of 43$0^{\circ}C$-8h and 45$0^{\circ}C$-6h, and activation energy is 17.0kcal/mole. Further it can be seen that excessive heat treatment brings about stress relaxation.

• Journal of the Korean Society for Precision Engineering
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• v.18 no.11
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• pp.93-100
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• 2001

Brittle materials are very weak for impact because of typical characteristics which happen to be easily fractured with low fracture toughness and crack sensitivity. When brittle materials are subjected to impact due to small spheres, high contact pressure is occurred to impact surface and then local damage on specimen is developed, since there are little plastic deformations due to contact pressure compared to metals. This local damage is a dangerous factor which gives rise to final fracture of structures. In this research, the crack propagation process of soda lime glass by impact of small sphere is explained and the effects of the constraint conditions of impact spheres and materials for the material damage were studied by using soda-lime glass. that is the effects for the materials and sizes of impact ball, thickness of specimen and residual strength. Especially, this research has focused on the damage behavior of ring crack, cone crack and several kinds of cracks.

• Applied Chemistry for Engineering
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• v.16 no.4
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• pp.519-526
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• 2005

Hydrolysis of soda-lime waste glass was investigated to test the feasibility for use of waste glass as feed material in the production of foamed glass. The soda-lime glass, such as plate glass and various bottle glasses, was effectively hydrolyzed by steam and water under high pressure. The proper condition for the hydrolysis was found to be reaction temperature of $250^{\circ}C$ and reaction time of 2 h. Under this condition, the water content of hydrated glass through hydrolysis was 7.85~10.04%, allowing successful foaming process for production of foamed glass. Using Na as the modifying agent of glass was effective in the hydrolysis by water. The highest water content of hydrated glass was obtained when weight ratio of NaOH to the glass was 0.04.

• Proceedings of the KIEE Conference
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• 2000.07c
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• pp.1625-1627
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• 2000

Cu(InGa)$Se_2$(CIGS) thin film absorbers with various Cu/(In+Ga) atomic ratios were prepared by a three-stage process using a co-evaporation appartus. The effect of Na on the structural and electrical properties of CIGS films were studied and their effects on the CIGS/Mo thin film solar cells were investigated. Soda-lime glass and Corning glass were used as substrates to compare the effect of Na diffusion into CIGS film. The resistivity of CIGS films was not changed in the Cu-poor lesion due to diffusion of Na from soda-lime glass but was mainly determined by the surface resistivity controlled by excess Na.

• Resources Recycling
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• v.4 no.3
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• pp.19-25
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• 1995

A Study on the recovery of the valuable metals(Vanadium Molybdenium) was carried out using spent catalysts originated from desulfurizing process of oil refinery. Experiments consisted of pre-roasting for Sulfur and Carbon removal, soda roasting and leaching for the extraction of valuable metals, and selective precipitation of Vanadium and Molybdenium. Effects of temperature and time in roasting for Sulfur removal, of $Na_2CO_3$ concentrations in soda roasting, and of pulp density, temperature and time in leaching were investigated for the recovery of Vanadium and Molybdenium. A optimum condition having over 85% in yield of Vanadium and Molybdenium was found. In the selective precipitation, more than 98% of Vanadium and Molybdenium were obtained by the variation of pH and concentration of additives.

• Proceedings of the KSME Conference
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• 2007.05a
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• pp.1754-1759
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• 2007

Propagation of a mixed-mode crack in Soda-Lime silica glass using Movable Cellular Automata (MCA) method is demonstrated in this study. In MCA method, special fracture criterion is used to describe the process of crack initiation and propagation. Comparison between MCA and other crack initiation criteria results are made. The crack resistance curves and bifurcation angles under different loading angles are found. In comparisons with results of maximum circumferential tensile stress criterion, MCA result showed the sufficient agreement.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.93.2-93.2
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• 2010

Recently, printing and coating technologies application fields have been expanded to the energy field such as solar cell. One of the main reasons, why many researchers have been interested in printing technology as a manufacturing method, is the reduction of manufacturing cost. In this paper, We fabricated CIGS solar cell thin film layer by doctor blade methods using synthesis of CIS precursor nanoparticles ink on molybdenum (Mo) coated soda-lime glass substrate. Synthesis CIS precursor nanoparticles ink fabrication was mixed Cu, In, Se powder and Ethylenediamine, using microwave and centrifuging. Using multi coating process as we could easily fabrication a fine flatness CIS thin-film layer ($0.7{\sim}1.35{\mu}m$), and reduce a manufacture cost and process steps. Also if we use printing and coating method and solution process in each layer of CIGS solar cell (electrode, buffer), it is possible to fabricate all printed thin-film solar cell.