• Title/Summary/Keyword: smog

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Crystallization of Hydrazinium Nitroformate(HNF) as Eco-friendly Oxidizer (친환경 산화제 HNF 결정화 연구)

  • Kim, Jina;Kim, Min Jun;Min, Byoung Sun
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.6
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    • pp.76-82
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    • 2016
  • Recently, environmental sustainability of the transitional explosives and propellants is an issue of growing importance in energetic materials. For examples, ammonium perchlorate(AP) as an solid propellants oxidizer could create a poisonous gas and atmospheric pollutions, such as HCl. Among the several oxidizers, hydrazinium nitroformate(HNF) is an effective candidate substance for eco-friendly oxidizer, which has high density, pressure index, and less smog generating property during combustion for the thrust control system. This study was controlled the size distribution and shapes through various conditions. Length and diameter ratio(L/D) of crystals has below 1 : 3, and the particle size was two types of $200{\mu}m$ and $50{\mu}m$.

Characteristics of VOCs Adsorption of Brick Prepared by MSWI Fly Ash (소각재로 제조한 건축외장재의 VOCs 흡착 특성 평가)

  • Ban, Hyo-Jin;Jeong, Jae-A;Lee, Woo-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.9
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    • pp.857-861
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    • 2010
  • Recently photochemical smog has become a serious urban air pollution. And VOC is the major pollutant for it. With the advance of industrialization and urbanization, MSWI fly ash and sewage sludge and melting slag were generated. It is necessary to de-toxificate ashes, because they contain many toxic constituents and probably lead to contaminate the environment. The objective of this research was to prepare multi-functional brick which is able to remove VOCs in ambient air. The bricks were made of MSWI fly ash, sewage sludge and slag. The benzene adsorption experiment by brick was acted to evaluate its adsorptivity. And also photocatalyst material was coated to enhance its adsorptivity and the endurance on the brick. According to the result, the benzene showed 74~96%. The removal efficiency was increased and the breakpoint time was lengthened by coating a brick.

Characteristics of Source and Concentration of VOCs in Daegu (대구지역 대기 중 VOCs 농도 및 발생원 특성)

  • Gu Min-Jung;Choi Sung-Woo
    • Journal of Environmental Science International
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    • v.14 no.6
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    • pp.543-553
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    • 2005
  • In recent days, photochemical smog due to the rapid industry development and vehicle increasement has become a critical pollutant in the metropolitan area and the number of ozone alarm signal has increased every year. This research was performed to evaluate VOCs emission source characteristics and concentration of VOCs in Daegu. The site average concentration was observed in the following order: industrial area > commercial area > residential area. Most of the VOCs species except toluene showed variations with higher concentration during nighttime, and lower concentration during the daytime. The major VOCs of stationary emission source were BTEX(benzene, toluene, ethylbenzene. xylene) and methylene chloride, trichloroethene and styrene. Also, those of automobile exhaust were toluene and benzene. Also, the major VOCs concentration emited by the vehicle fuel was observed in the following order: gasoline > light oil > liquefied petroleum gas (L.P.G). Correlation coefficients values were estimated between major VOCs such as toluene, ethylbenzene, m,p-xylene, o-xylene. Results showed that correlation coefficient values were significant magnitude above 0.76. Also, there showed highly significant correlations among ethyl benzene, m,p-xylene, and o-xylene concentration(Pearson correlation coefficients, r=0.868-0.982). Calculated correlation coefficients among commercial area,industrial area and residential area were 0.934-0.981, they showed high correlation. There showed highly correlation between stationary emission source and industrial area, compared with commercial area and residential area. Also, calculated correlation coefficients among commercial area, industrial area, residential area and automobile exhaust were 0.732, 0.725, 0.777, respectively.

A Study on Long Range Image Monitoring and Tracking System Using Laser Range-Gate Method in Inclement Weather Conditions (악천후 상황에서 Laser Range-Gate 방식을 이용한 원거리 영상 감시 및 추적 시스템에 대한 연구)

  • Oh, Sung-Kwun;Yoo, Sung-Hoon;Ku, Kyong-Wan;Kim, Su-Chan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.2
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    • pp.257-263
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    • 2013
  • In case of image observation equipments, CCTV for short distance visual field is usually installed and operated mostly as the means of crime-prevention. However, the extensive demand for monitoring problems in case of the increase in intelligent crimes and disasters has led to the necessity of the development of long-distance observation equipments embedded with Night View functions. In case of the Night View equipments, the relevant market is set up to be focused mostly on Thermal Observation Device(hereinafter, TOD), but some shortcomings such as the limitation of image visibility and excessive maintenance cost, etc. have actually caused the necessity of new long distance Night View equipment. Moreover there might follow lots of difficulties in long-distance visualization in the event that irregular reflection is generated by minute particles in the atmosphere such as fog, smog, and dust, etc. These factors are motivate the work presented in this study. Our study is aimed at the realization of Pulsed Laser Illuminator and newly proposed Range-Gated image acquisition technology. And also the implementation of Tracker for continuous trace of the objects of interest from the obtained sequence images.

Simple Forecasting of Surface Ozone through a Statistical Approach

  • Ma, Chang-Jin;Kang, Gong-Unn
    • Journal of Environmental Health Sciences
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    • v.44 no.6
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    • pp.539-547
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    • 2018
  • Objectives: Ozone ($O_3$) advisories are issued by provincial/prefectural and city governments in Korea and Japan when oxidant concentrations exceed the criteria of the related country. Advisories issued only after exposure to high $O_3$ concentrations cannot be considered ideal measures. Forecasts of $O_3$ would be more beneficial to citizens' health and daily life than real-time advisories. The present study was undertaken to present a simplified forecasting model that can predict surface $O_3$ concentrations for the afternoon of the day of the forecast. Methods: For the construction of a simple and practical model, a multivariate regression model was applied. The monitored data on gases and climate variables from Japan's air quality networks that were recorded over nearly one year starting from April 2016 were applied as the subject for our model. Results: A well-known inverse correlation between $NO_2$ and $O_3$ was confirmed by the monitored data for Iksan, Korea and Fukuoka, Japan. Typical time fluctuations for $O_3$ and $NO_x$ were also found. Our model suggests that insolation is the most influential factor in determining the concentration of $O_3$. $CH_4$ also plays a major role in our model. It was possible to visually check for the fit of a theoretical distribution to the observed data by examining the probability-probability (P-P) scatter plot. The goodness of fit of the model in this study was also successfully validated through a comparison (r=0.8, p<0.05) of the measured and predicted $O_3$ concentrations. Conclusions: The advantage of our model is that it is capable of immediate forecasting of surface $O_3$ for the afternoon of the day from the routinely measured values of the precursor and meteorological parameters. Although a comparison to other approaches for $O_3$ forecasting was not carried out, the model suggested in this study would be very helpful for the citizens of Korea and Japan, especially during the $O_3$ season from May to June.

A Study on the BTEX Ratio and Correlation of C2-benzenes in Vehicle Exhaust (자동차 배출가스 중 BTEX의 비율과 C2-benzenes의 상관성 연구)

  • Mun, Sunhee;Chung, Taekho;Jung, Sungwoon;Kim, Sunmoon;Seo, Seokjun;Lee, Seounghwan;Kim, Jounghwa;Hong, Youdeog;Hong, Heekyoung
    • Journal of ILASS-Korea
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    • v.23 no.4
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    • pp.185-191
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    • 2018
  • Benzene, toluene, ethylbenzene and xylene (BTEX) were well known as ozone precursors from photochemical reactions and contribute to the formation of photochemical smog which pose health hazards. Also, some of these compounds directly affect the human health due to their toxicity such as benzene. In this study, BTEX ratios and correlation of $C_2$-benzenes (xylenes, ethylbenzene) in vehicle exhaust from recreational vehicle (RV) and multi-purpose vehicle (MPV) were characterized using a chassis dynamometer. VOCs were collected by tedlar bag and a GC/MS system was used for their quantification. Among all of the BTEX, toluene has the highest concentration(more than 30% in composition of BTEX). The average ratio of toluene to benzene emissions (T/B ratio=2.2) was found in vehicle exhaust. The average m,p-xylene/ethylbenzene and m,p-xylene/o-xylene ratios were 1.0 and 3.0 respectively. As a result, it showed a good correlation between the $C_2$-benzenes ($R^2=0.98{\sim}0.99$). In the future, it can be used as a marker for effect evaluation to atmospheric environment by vehicle exhaust.

An Enhanced Cloud Cover Reading Algorithm Against Aerosol (연무에 강한 구름 판독 알고리즘)

  • Yun, Han-Kyung
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.12 no.1
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    • pp.7-12
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    • 2019
  • Clouds in the atmosphere are important variables that affect the temperature change by reflecting the radiant energy of the earth surface as well as changing the amount of sunshine by reflecting the sun's radiation energy. Especially, the amount of sunshine on the surface is very important It is essential information. Therefore, eye-observations of the sky on the surface of the earth have been enhanced by satellite photographs or relatively narrowed observation equipments. Therefore, cloud automatic observing systems have been developed in order to replace the human observers, but depending on the seasons, the reliability of observations is not high enough to be applied in the field due to pollutants or fog in the atmosphere. Therefore, we have developed a cloud observation algorithm that is robust against smog and fog. It is based on the calculation of the degree of aerosol from the all-sky image, and is added to the developed cloud reader to develop season- and climate-insensitive algorithms to improve reliability. The result compared to existing cloud readers and the result of cloud cover is improved.

Effective Single Image Haze Removal using Edge-Preserving Transmission Estimation and Guided Image Filtering (에지 보존 전달량 추정 및 Guided Image Filtering을 이용한 효과적인 단일 영상 안개 제거)

  • Kim, Jong-Ho
    • The Journal of the Korea institute of electronic communication sciences
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    • v.16 no.6
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    • pp.1303-1310
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    • 2021
  • We propose an edge-preserving transmission estimation by comparing the patch-based dark channel and the pixel-based dark channel near the edge, in order to improve the quality of outdoor images deteriorated by conditions such as fog and smog. Moreover, we propose a refinement that applies the Guided Image Filtering (GIF), a kind of edge-preserving smoothing filtering methods, to edges using Laplacian operation for natural restoration of image objects and backgrounds, so that we can dehaze a single image and improve the visibility effectively. Experimental results carried out on various outdoor hazy images that show the proposed method has less computational complexity than the conventional methods, while reducing distortion such as halo effect, and showing excellent dehazing performance. In It can be confirmed that the proposed method can be applied to various fields including devices requiring real-time performance.

Computational Study on the Application of Porous Media to Fluid Flow in Exhaust Gas Scrubbers (배기가스 세정장치내 유체 유동에 대한 다공성 매질 적용 기반의 전산해석적 연구)

  • Hong, Jin-pyo;Yoon, Sang-hwan;Yoon, Hyeon-kyu;Kim, Lae-sung;An, Jun-tae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.2
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    • pp.1-10
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    • 2022
  • Exhaust gases emitted from internal combustion engines contain nitrogen oxides (NOx) and sulfur oxides (SOx), which are major air pollutants causing acid rain, respiratory diseases, and photochemical smog. As a countermeasure, scrubber systems are being studied extensively. In this study, the pressure drop characteristics were analyzed by changing the exhaust gas inflow velocity using a scrubber for a 700 kW engine as a model. In addition, the fluid flow inside the scrubber and the behavioral characteristics of the droplets were studied using CFD, and the design compatibility of the cleaning device was verified. Flow analysis was performed using inertial and viscous resistances by applying porous media to the complex shape of the scrubber. The speed of the exhaust passing through the outlet nozzle from the inlet was determined through the droplet behavior analysis by spraying, and the flow characteristics for the pressure drop were studied. In addition, it was confirmed through computational analysis whether there was a stagnation section in the exhaust gas flow in the scrubber or the sprayed droplets were in good contact with the exhaust gas.

Causes of High PM2.5 Concentrations in Cheongju Owing to Non-Asian Dust Events (비황사 사례에 기인한 청주시 PM2.5 고농도 원인)

  • Kim, Da-Bin;Moon, Yun-Seob
    • Journal of the Korean earth science society
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    • v.41 no.6
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    • pp.557-574
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    • 2020
  • The purpose of this study is to analyze the cause of high PM2.5 mass concentrations in Cheongju for the period of non-Asian dust days using the weather chart, the stream lines at 850 hPa, the backward trajectory, and the weather and air quality model. As a result of analyzing the time series of PM2.5 concentrations and weather charts for the episodic days in Cheongju, the weather patterns were shown in related to long-range transport of PM2.5 from China or surrounding areas. In fact, in the PM2.5 time series, 60-80 ㎍ m-3, which is more than 2-3 times higher than the concentration attributed to Cheongju activities, was observed as a background concentration related to long-range transport. The distribution of high PM2.5 concentration was typically dependent on the locations of the high and low pressures above the ground while the upper jet stream passed through the Korean Peninsula. Consequently, the high PM2.5 concentration in Cheongju is due to massive air pollutants in the form of smog originated from industrial, household and energy combustion sources of Beijing and other nearby regions of China. These air pollutants move along a fast zonal wind caused by the atmospheric pressure arrangement. high concentration of PM2.5 in Cheongju City is because the mass of air pollutants in the form of smog generated from industrial, household and energy combustion origins in Beijing or other nearby regions of China move along a fast wind speed zone according to the atmospheric pressure arrangement of long-distance transportation. Air pollutants including PM2.5 show an M-shaped pattern that passes through the topography of the Cheongju basin from north to south as a belt or band-shaped pollutant. The ground high pressure according to the above-ground high pressure expansion area and cut-off low or low pressure arrangement, or the bands in the form of river stems appear in a gradual incremental pattern that changes into a U-shape under the influence of the wind.