• 제목/요약/키워드: slow phase

검색결과 372건 처리시간 0.025초

Mo-25.0at%Si 혼합분말의 기계적 합금화에 미치는 밀링매체 재료의 영향 (Effect of Milling Medium Materials on Mechanical Alloying of Mo-25.0at%Si Powder Mixture)

  • 박상보
    • 한국분말재료학회지
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    • 제5권1호
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    • pp.64-70
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    • 1998
  • Milling media of steel and partially stabilized zirconia(PSZ) were used to produce $Mo_3$Si by mechanical alloying(MA) of Mo-25.0at%Si elemental powder mixture. The effect of milling medium materials on MA of the powder mixture have been investigated by XRD and DTA. The reaction rate and the end-product noticeably depended upon the milling medium material. The formation of $Mo_3$Si and $Mo_5Si_3$phases by PSZ ball-milling took place after 15 hr of MA and was characterized by a slow reaction rate as Mo, Si, $Mo_5Si_3$ and $Mo_3$Si coexisted for a long period of milling time. The formation of a new phase by steel ball-milling, however, did not take Place even after 96 hr of MA. DTA and annealing results showed that $Mo_5Si_3$ and $Mo_3$Si were formed after heating the ball-milled powder specimens to different temperatures. At low temperatures, Mo and Si were transformed into $Mo_5Si_3$. At high temperatures, the formation of $Mo_3$Si can be partially attributed to the reaction, 7Mo+Si+$Mo_5Si_3$-.4$Mo_3$Si . The formation of $Mo_3$Si and Mo5Si3 phases by mechanical alloying of the powder mixture and the relevant reaction rate appeared to depend upon the milling medium material as well as the thermodynamic properties of the end-products.

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중심 편석층이 있는 극후판 박스-칼럼의 대입열 코너이음 용접시 그루브 형상의 영향 (Effect of the Groove Shape of Ultra Thick Box-Column with Center Segregation under High Heat Input for Corner Welding)

  • 최원규;이종봉;권영두;구남서
    • 한국해양공학회지
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    • 제16권2호
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    • pp.72-79
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    • 2002
  • In this study, time-dependent distributions of temperature and stresses, in the box-column welded from ultra thick plates with center segregation, has been analyzed by the commercial finite element package SYSWELD+, for several types and angles of groove. The major points of investigation are the optimum type and angle of groove that minimize weld stress specially at the center segregation, as well as temperature distribution, residual stresses and changes in the mechanical properties. The results can be summarized as follows; 1) Generally the thermal cycle at the root of groove exhibits relatively rapid cooling pattern, however, most of the other part weldment have a slow cooling pattern in all groove types. 2) Most of the micro-structures of weldment are composed of ferrite and pearlite, meanwhile we could find martensite and bainite locally a the root of the groove. 3) Optimum groove type for high heat input welding of box-column corner is a double groove type, and the optimum angle for the groove is 30~$45^{\circ}$ that minimize deformation and weld stress at the center segregation.

Interface formation between $MgF_2$ and Si(111) studied by LEED, AES, and TPD

  • Y.S. Chung;J.Y. Maeng;Kim, Sehun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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    • pp.183-183
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    • 1999
  • The phases and interface formation of MgF2 on Si(111) were studied by using LEED, AES, and TPD. When thick MgF2 film was deposited on the Si(111) surface at RT뭉 annealed at higher temperatures, a sequence of LEED patterns (no LEED pattern $\longrightarrow$1$\times$1$\longrightarrow$3$\times$1$\longrightarrow$7$\times$7) was observed. On the 1$\times$1 model in which Mg adsorbs on T4 site and F on H3 site could explain the simultaneous desorption of SiF2 and Mg. When thin MgF2 film was deposited, and initial $\alpha$-$\times$1 phase transforms to 3$\times$3 and $\beta$-1$\times$1 by thermal annealing with a slow evaporation of F and diffusion of Mg into the surface. the 3$\times$3 surface changes to ${\gamma}$-1$\times$1 by the selective desorptioon of F under e-beam irradiation and subsesquently to a Mg-induced {{{{ SQRT { 3} }}}} structure by annealing at $600^{\circ}C$.

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Experimental Results of Ship's Maneuvering Test Using GPS

  • Yoo, Yun-Ja;Hou, Dai-Jin;Hamada, Masaaki;Nakama, Yoshiyasu;Kouguchi, Nobuyoshi
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2006년도 Asia Navigation Conference
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    • pp.49-55
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    • 2006
  • Kinematic GPS provides quite good accuracy of position in cm level. Though K-GPS assures high precision measurement in cm level on the basis of an appreciable distance between a station and an observational point, but it has measurable distance restriction within 20 km from a reference station on land. So it is necessary to make out a simple and low-cost method to obtain accurate positioning information without distance restriction. In this paper, the velocity integration method to get the precise velocity information of ship is explained. Next two experimental results (Zig-zag maneuvering test and Williamson turn) as the ship's maneuvering test and also the experimental results of leaving and entering port as slow speed ship's movement were shown. In these experimental results, ship's course, speed and position are compared with those obtained by kinematic-GPS, velocity integration method and dead reckoning position using Gyro-compass and Doppler-log.

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3-level인버터를 이용한 과변조영역에서의 간접벡터 유도전동기 구동 (Driving the induction motor of indirect vector control using the 3-level inverter in the overmodulation region)

  • 이재문;정헌선;노세진;이은규;염상구;최재호
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2007년도 하계학술대회 논문집
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    • pp.403-405
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    • 2007
  • This paper presents the over-modulation strategy and indirect vector control drive of NPC type PWM inverter. NPC inverter has three level phase voltage output.It can perform in high voltage through assembling switching components. It has less harmonics and surge voltage stress at motor terminals than the 2 level inverter in same switching frequency through 3 level voltage. The conventional railway vehicle has used the vector control to MI=0.907 and the slip-frequency control from MI=0.907 to six-step mode. The slip-frequency control has bad motive power and slow torque control response. But vector control has good motive power and can instant torque control. In this paper, output voltage is controlled linearly from linear region to six-step mode by using over-modulation strategy. And NPC inverter is used.

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Stop-and-Go 플래그를 가지는 새로운 블라인드 등화 알고리즘 (A New Blind Equalization Algorithm with A Stop-and-Go Flag)

  • 정영화
    • 정보학연구
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    • 제8권3호
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    • pp.105-115
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    • 2005
  • The CMA and MMA blind equalization algorithm has the inevitable large residual error caused by mismatching between the symbol constellation at a steady state after convergence. Stop-and-Go algorithm has a very superior residual error characteristics at a steady state but a relatively slow convergence characteristics. In this paper, we propose a SAG-Flagged MMA as a new adaptive blind equalization algorithm with a Stop-and-Go flag which follows a flagged MMA in update scheme of tap weights as appling the flag obtaining from Stop-and-Go algorithm to MMA. Using computer simulation, it is confirmed that the proposed algorithm has an enhancing performance from the viewpoint of residual ISI, residual error and convergence speed in comparison with MMA and Stop-and-Go algorithm. Algorithm has a new error function using the decided original constellation instead of the reduced constellation. By computer simulation, it is confirmed that the proposed algorithm has the performance superiority in terms of residual ISI and convergence speed compared with the adaptive blind equalization algorithm of CMA family, Constant Modulus Algorithm with Carrier Phase Recovery and Modified CMA(MCMA).

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Determination of the Copper Valency and the Oxygen Deficiency in the High Tc Superconductor, $YBa_2Cu_3O_{7-\delta}$

  • Choy, Jin-Ho;Choi, Suk-Yong;Byeon, Song-Ho;Chun, Sung-Ho;Hong, Seung-Tae;Jung, Duk-Young;Choe, Won-Young;Park, Yung-Woo
    • Bulletin of the Korean Chemical Society
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    • 제9권5호
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    • pp.289-291
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    • 1988
  • The ratio of trivalent to divalent copper has been determined by the redox titration for two superconducting phases of $YBa_2Cu^{3+}_{2x}Cu^{2+}_{3-2x}O_{6.5+x}$ with the onset temp. of 60K (x = 0.23 ${\pm}$ 0.01) and 90K (x = 0.35 ${\pm}$ 0.02), and for the insulating one (x ${\cong}$ 0) which was kept in an ambient atmosphere for 72 hrs. It is found that $T_c$, and the ratio of $Cu^{3+}/Cu^{2+}$ depend strongly on the annealing temperature and time. A typical orthorhombic phase can easily be obtained by a slow cooling or stepwise cooling at $PO_2$ = 1 atm, and shows a high Tc (ca. 90K) superconductivity.

Development of Temperature Control Algorithm for Supercooling Storage of Pork Loin and Its Feasibility for Improving Freshness and Extending Shelf Life

  • Lee, SangYoon;Park, Dong Hyeon;Kim, Eun Jeong;Kim, Honggyun;Lee, YunJung;Choi, Mi-Jung
    • 한국축산식품학회지
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    • 제42권3호
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    • pp.467-485
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    • 2022
  • Supercooling storage refers to lowering the product temperature below its freezing point without phase transition and has the potential to extend shelf life. Nevertheless, supercooled objects are in a thermodynamically unstable state, and nucleation can occur spontaneously. To achieve supercooling storage, slow cooling and insulation are essential. Hence, a stepwise algorithm for the supercooling storage of pork loins was designed and validated in this study. Pork loins were stored at 3℃, -18℃, and -3℃ (freezing), and supercooled for 16 days. All samples remained in a supercooled state and were unfrozen at the end of storage. Supercooled pork loins were superior in terms of drip loss, cooking loss, and water-holding capacity compared to frozen samples. Additionally, supercooling treatment prevented discoloration, increase of volatile basic nitrogen, and microbial growth. Thus, supercooling of pork loin was achieved using a stepwise program and was effective to maintain meat quality.

Analyses of hydrogen risk in containment filtered venting system using MELCOR

  • Choi, Gi Hyeon;Jerng, Dong-Wook;Kim, Tae Woon
    • Nuclear Engineering and Technology
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    • 제54권1호
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    • pp.177-185
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    • 2022
  • Hydrogen risk in the containment filtered venting system (CFVS) vessel was analyzed, considering operation pressure and modes with the effect of PAR and accident scenarios. The CFVS is to depressurize the containment by venting the containment atmosphere through the filtering system. The CFVS could be subject to hydrogen risk due to the change of atmospheric conditions while the containment atmosphere passes through the CFVS. It was found that hydrogen risk increased as the CFVS opening pressure was set higher because more combustible gases generated by Molten Core Concrete Interaction flowed into the CFVS. Hydrogen risk was independent of operation modes and found only at the early phase of venting both for continuous and cyclic operation modes. With PAR, hydrogen risk appeared only at the 0.9 MPa opening pressure for Station Black-Out accidents. Without PAR, however, hydrogen risk appeared even with the CFVS opening set-point of 0.5 MPa. In a slow accident like SBO, hydrogen risk was more threatening than a fast accident like Large Break Loss-of-Coolant Accident. Through this study, it is recommended to set the CFVS opening pressure lower than 0.9 MPa and to operate it in the cyclic mode to keep the CFVS available as long as possible.

Impedance Spectroscopy of (Pb0.92La0.08)(Zr0.95Ti0.05)O3 Ceramics above Room Temperatures

  • Jong-Ho Park
    • 한국재료학회지
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    • 제34권5호
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    • pp.242-246
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    • 2024
  • La modified lead zirconate titanate ceramics (Pb0.92La0.08)(Zr0.95Ti0.05)O3 = PLZT-8/95/5 were prepared using the conventional solid state reaction method in order to investigate the complex impedance characteristics of the PLZT-8/95/5 ceramic according to temperature. The complex impedance in the PLZT-8/95/5 ceramic was measured over a temperature range of 30~550 ℃ at several frequencies. The complex dielectric constant anomaly of the phase transition was observed near TU1 = 179 ℃ and TU2 = 230 ℃. A remarkable diffuse dielectric constant anomalous behaviour of the complex dielectric constant was found between 100 ℃ and 550 ℃. The complex impedance spectra below and above TU1 and TU2 were fitted by the superposition of two Cole-Cole types of impedance relaxations. The fast component in the higher frequency region may be due to ion migration in the bulk, and the slow component in the lower frequency region is interpreted to be the formation and migration of ions at the grain boundary or electrode/crystal interfacial polarization.