• 제목/요약/키워드: slope ratio

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A Study on the Elution Mechanism of Ni(II)-Isonitrosoethylacetoacetate Imine Chelates by Reversed Phase High Performance Liquid Chromatography (역상 액체 크로마토그래피에 의한 Ni(II)-Isonitrosoethylacetoacetate Imine 유도체 킬레이트의 용리 메카니즘에 관한 연구)

  • Kim In-Whan;Choi Gang-Yeol;Lee Man-Ho;Kang Chang-Hee;Lee, Won
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.697-708
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    • 1992
  • Liquid Chromatographic behavior of Ni(II) in Isonitrosoethylacetoacetate Imine(IEAA-NR), Ni(IEAA-NH)(IEAA-NR)(R = H, CH_3, C-2H_5, n-C_4H_9, C_6H_5-CH_2) chelates were investigated by reversed-phase HPLC on Micropak MCH-5 column using methanol/water as mobile phase. The optimum conditions for the separation of Ni(IEAA-NH)(IEAA-NR) chelates were examined with respect to the effect of the flow rate, sample solvent, mobile phase strength and column temperature. It was fo$und that metal chelates were properly eluted in an acceptable range of capacity factor value(0{\le}logk'{\le}1). The dependence of the logarithm of capacity factor (k') on the volume fraction of water in the binary mobile phase as well as on the liquid-liquid extraction distribution ratio (Dc) in methanol-water/n-alkane extraction system showed the good linearties, and the dependence of the logarithm of capacity factor (k') on the column temperature and on the enthalpy exhibited the good linearties, and the compensation temperature ({\beta}) from the slope was 773.47{\circ}K. It was suggested that the retention of metal chelates was largely affected by the hydrophobic effect.

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Andic Properties of Major Soils in Cheju Island II. Electric Charge Characteristics (제주도(濟州島) 대표토양(代表土壤)의 Andic 특성(特性)에 관한 연구 II.전하특성(電荷特性))

  • Song, Kwan-Cheol;Yoo, Sun-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.24 no.4
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    • pp.241-247
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    • 1991
  • Electric charge characteristics of volcanic ash soils in Cheju Island were investigated. For this study, soils of toposequence distributed along the sourthern slope of Mt. Halla, and the major soil groups such as dark brown soils, very dark brown soils, black soils, and brown forest soils were collected and analyzed for extratable acidity, KCl ext. Al, CEC, base saturation, permanent charge and variable charge, etc.. Weolpyeong and Yongheung soils developed on the lower elevations have high $NH_4OAc$ ext. bases, permanent charge and base saturation, and relatively low ext. acidity, CEC and variable charge. For other soils, whose colloidal fractions are dominated by allophane or Al-humus complexes, ext. acidity, CEC, variable charge, and variable charge ratio were very high, and $NH_4OAc$ ext. bases, permanent charge, and base saturation were very low. These trends were especially prominant in the surface. horizons of black soils and brown forest soils dominated by Al-humus complexes. Ext. acidity, CEC($NH_4OAc$), CEC(sum of cations), and variable charge strongly correlated with pyrophosphate ext. carbon. Very dark brown soils and cinder cone soils dominated by allophane showed low KCl ext. Al and relatively high pH, despite their very low base saturation.

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Design of an Offset Interdigital Filter Based on Multi-Port EM Simulated Y-Parameters (EM 시뮬레이션 기반 다중 포트 Y-파라미터를 이용한 변위된 인터디지털 여파기 설계)

  • Lee, Seok-Jeong;Oh, Hyun-Seok;Jeong, Hae-Chang;Yeom, Kyung-Whan
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.7
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    • pp.694-704
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    • 2011
  • In this paper, we present a design of a 5th order Chebyshev interdigital band-pass filter using inverter and susceptance slope parameter values obtained from EM simulated multi-port Y-parameters. The shifted length of the resonator is determined when the frequency of the transmission zero is separated far away from the center frequency. For the initial dimensions of the interdigital filter, the filter is decomposed into the individual resonators, and the dimensions are obtained using EM Simulation of the decomposed resonators. However, the interdigital filter with the dimensions determined from the EM simulation of the decomposed resonators shows slightly distorted response from the desired frequency response due to the coupling between non-adjacent resonators. To obtain a EM simulation dataset, EM simulation for this filter is carried out by parameter sweep with constant ratio for the initial values. In this dataset, it is determined the final values for the filter by optimization. The fabricated filter by PCB shows an upper-shift of center frequency of about 70 MHz, which was caused by permittivity changed and tolerance of fabrication.

Structural Characteristics of Berchemia berchemiaefolia Stands at Mt. Gunja (군자산 자생 망개나무 임분의 구조적 특성)

  • Lee, Kyung-Su;Jung, Tae-Young;Park, Chull-Ha;Han, Ju-Hwan;Lee, Gui-Yong;Koo, Chang-Duck
    • Journal of Korean Society of Forest Science
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    • v.101 no.4
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    • pp.579-591
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    • 2012
  • Berchemia berchemiaefolia is a rare and endangered species and important as a honey resource. The purposes of this study were to investigate physical environmental factors and the population and community structure of Berchemia berchemiaefolia stands at Mt. Gunja in Sogrisan National Park in Chungcheongbuk-do. The B. berchemiaefolia stands belonged to deciduous forests in mid-temperate zone and were $5{\sim}25^{\circ}$ in slope, 30~90% in rock ratio, and 6.37 in soil pH. They had 656 trees within the area of 36 ha and their average density was 18.2 trees per ha. The trees within the stands were 11.8 m in tree height, 22.6 cm in DBH and 56 years old. The number of branched stems was the maximum 8 and 32.9% of the trees were branched. B. berchemiaefolia trees over 12 cm diameter occupied 89.9%, but young B. berchemiaefolia did only 11%. The structure of B. berchemiaefolia stands were classified into three groups as Acer pseudo-sieboldianum & A. mono community group, A. pseudo-sieboldianum & Quercus aliena community group, and B. berchemiaefolia & Quercus serata community group. The mean importance value of B. berchemiaefolia was 10.9%, while species diversity of the community ranged 0.77~1.31 and interspecific competition ranged 0.78~0.94. The dominance of the community ranged of 0.07~0.29 and the evenness ranged 0.71~0.93. Although B. berchemiaefolia was dominant in the habitat, but the species was already in natural successional stage to Cornus controversa or Ulmus davidiana var. japonica.

The proposal on the new method for accurate to measure the plastic limits (정확한 소성한계 측정을 위한 새로운 실험법 제안)

  • Ko, Jae-Min;Lee, Byung-Suk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.68-79
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    • 2018
  • An examination of the characteristics of the ground material in is very important in a ground investigation. Casagrande classified soil using the material properties of soils. The liquid-plastic limit test is useful for obtaining basic information of soil, and is an effective method for classifying silt and clay, as well as the material properties, such as shear strength, shrinkage, and expansion. Unlike the liquid limit test, the plasticity limit test is due to the ambiguity of the test procedure. Many geotechnical engineers and scholars have questioned the test results. In this study, a new plasticity limit method was used to compare with the thread rolling method with kaolinite, ilite and bentonite at a certain ratio, and samples were collected from the west coast of Korea. As a result of the comparison, the test value of the new test method showed high reproducibility because the error range of the test value of the conventional thread rolling test was only 10% but the error range of the new test values decreased to 2%. The difference in the slope of the existing plasticity test values was 0.1519 ~ 0.1925, and the results of the test were similar or coincided with each other. Aone - point method was proposed to make it easier to apply the new test method.

The Value of Isotope Nephrography in Carcinoma of Cervix - Follow up Studies of Pre and Post Irradiation (자궁경부암(子宮頸部癌) 방사선치료(放射線治療) 전후(前後) Renogram의 의의(意義))

  • Yoo, H.S.;Suh, J.H.;Park, C.Y.;Choi, B.S.;Jung, S.O.;Kwak, H.M.
    • The Korean Journal of Nuclear Medicine
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    • v.9 no.1
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    • pp.51-58
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    • 1975
  • It is a great value to find an early detection of involvement of ureteric obstruction in the carcinoma of cervix. Little or no knowledge of the condition of the kidneys or the lower urinary tract are able to elucidate by the biochemical studies such as blood nitrogen or urine creatinine in carcinoma of cervix. Findings of urography delineates the condition of urinary tract stasis in the renal pelvis and ureters, however, slight stasis maybe difficult to demonstrate. On the other hand isotope nephrography is accepted as a sensitive method to observe renal function especially in regarding to the excretory function of kidney. It was attempted to analysis the findings of urography conjunction with isotope nephrography in 50 cases of unselected patients with invasive carcinoma of cervix through pre and post irradiation follow up studies. Urography was done as a routine procedure and.analysed emphasising changes of collecting systems and ureter condition. Isotope nephrography was carried out by means of $15{\mu}ci\;I^{131}$-Hippuran injected intravenously and the curves were analysed as follows. Parameter were; time of maximum amplitude ($T_{max}$), half time of maximum amplitude ($T\frac{1}{2}$), Kac and Kex value calculated from these two parameters in Tobe's method. The excretion index by Aurell defines the ratio between the maximum activity and the activity measured on the slope of the third phase ten minites after it has reached its maximum. Results: 1. 28.8% had an abnormal IVP suggestive of ureteric involvement before irradiation therapy and the patient of stage III and IV were the great part. 2. 21.7% had abnormal findings of per-irradiation renogram whom showed normal IVP. The other group showed normal IVP which group also showed normal renogram prior irradiation. 3. The more severe the ureteric involvement, the change of excretion index was greater. 4. Even in stage I and II patient, abnormal renogram was revealed in 12 cases (39.4%) among 31 cases. 5. All cases of TAH showed abnormal findings of IVP and renogram. 6. No. definite change of renogram was obtained just after the irradiation therapy (point $A:8000{\sim}9000rads,\;B:5000{\sim}6000rads,\;Co:11000{\sim}13000rads$). Each 3 month follow up study was performed and comparing with preirradiation study which showed significant changes of excretion index of renogram were 42.8% in $6{\sim}9$ month follow-up and 75% in $9{\sim}12$ month, respectively. 7. It seems to be important to observe the parameter Kex and excretion index of renogram to determine early abnormality of kidney excretory function by means of post-irradiation follow up study.

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Parameter Regionalization of Semi-Distributed Runoff Model Using Multivariate Statistical Analysis (다변량 통계분석을 이용한 준분포형 유출모형 매개변수 지역화)

  • Lee, Byong-Ju;Jung, Il-Won;Bae, Deg-Hyo
    • Journal of Korea Water Resources Association
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    • v.42 no.2
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    • pp.149-160
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    • 2009
  • The objective of this study is to suggest parameter regionalization scheme which is integrated two multivariate statistical methods: principal components analysis(PCA) and hierarchical cluster analysis(HCA). This technique is to apply semi-distributed rainfall-runoff model on ungauged catchments. 7 catchment characteristics (area, mean altitude, mean slope, ratio of forest, water content at saturation, field capacity and wilting point) are estimated for 109 mid-sized sub-basins. The first two components from PCA results account for 82.11% of the total variance in the dataset. Component 1 is related to the location of the catchments relevant to the altitude and Component 2 is connected with the area of these. 103 ungauged catchments are clustered using HCA as the following 6 groups: Goesan 23, Andong 6, Imha 5, Hapcheon 21, Yongdam 4, Seomjin 44. SWAT model is used to simulate runoff and the parameters of the model on the 6 gauged basins are estimated. The model parameters were regionalized for Soyang, Chungju and Daecheong dam basins which are assumed as ungauged ones. The model efficiency coefficients of the simulated inflows for these three dams were at least 0.8. These results also mean that goodness of fit is high to the observed inflows. This research will contribute to estimate and analyze hydrologic components on the ungauged catchments.

Monitoring on the Soils and Plant Growth in Modular Sloped Rooftop Greening System (모듈형 경사지붕 녹화시스템의 토양과 식물생육 모니터링)

  • Ryu, Nam-Hyong;Lee, Chun-Seok
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.14 no.5
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    • pp.53-67
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    • 2011
  • The major objective of this study was to quantify the effects of substrate depth and substrate composition on the development of sedum etc., in a sloped rooftop (6 : 12 pitch) environment during a 4-year period. The experiment was conducted from 2006 October to 2010 December under several conditions without soil erosion control : two substrate depth (5cm, 10cm), four substrate composition (A5N3C2, A3N3C4, A6C4, G5L3C2: A: artificial lightweight soil, N : natural soil, G : granite decomposed soil, C : leave composite, L : loess), four sloped roof direction ($E40^{\circ}W$, $W40^{\circ}N$, $S40^{\circ}W$, $N40^{\circ}E$). In this experiment 4 sedum etc., were used: Sedum sarmentosum, Sedum kamtschaticum, Sedum rupestre, Sedum telephium, flowering herbs (mixed seed : Taraxacum platycarpum, Lotus corniculatus, Aster yomena, Aster koraiensis), western grasses (mixed seed : Tall fescue, Creeping redfescue, Bermuda grass, Perennial ryegrass). The establishment factor had two levels : succulent shoot establishment (sedum), seeding (flowering herbs, western grasses). 1. Enkamat, as it bring about top soil exfoliation, was unsuitable material for soil erosion control. 2. Sedum species exhibited greater growth at a substrate depth of 10cm relative to 5cm. All flowering herbs and western grasses established only at a substrate depth of 5cm were died. A substrate depth of 5cm was not suited in sloped rooftop greening without maintenance. If additional soil erosion control will be supplemented, a substrate depth of 10cm in sloped rooftop greening without maintenance was considered suitable. 3. For all substrate depth and composition, the most abundant species was Sedum kamtschaticum. The percentage of surviving Sedum kamtschaticum was 73.4% at a substrate depth of 10cm in autumn 2007 one year after the roof vegetation had been established. But the percentage of surviving other sedum were 33.3%~51.9%, therefor mulching for soil erosion control was essential after rooftop establishment in extensive sloped roof greening was proved. To raise the ratio of plant survival, complete establishment of plant root at substrate was considered essential before rooftop establishment. 4. There was a significant interaction between biomass and substrate moisture content. There were also a significant difference of substrate moisture and erosion among substrate composition. The moisture content of A6C4 was highest, the resistance to erosion of A5N3C2 was highest among substrate composition. The biomass of plants were not significantly higher in A5N3C2 and A6C4 relative to A3N3C4 and G5L3C2, For substrate moisture and erosion resistance, A5N3C2 and A6C4 were considered suitable in sloped rooftop greening without maintenance. 5. There were significant difference among roof slope direction on the substrate moisture. Especially, the substrate moisture content of $S40^{\circ}W$ was lower relative to that of $N40^{\circ}E$, that guessed by solar radiation and erosion.

Ecological Characteristics of Viola websteri Hemsley Habitats (왕제비꽃 자생지의 생태특성)

  • Jang, Su-Kil;Cheon, Kyeong-Sik;Kim, Kyung-Ah;Jang, Jin-Hwan;Yoo, Ki-Oug
    • Korean Journal of Plant Resources
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    • v.23 no.4
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    • pp.261-273
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    • 2010
  • This study intended to investigate the environmental factors including soil and vegetation in order to understand the environmental and ecological characteristics of seven different habitats of Viola websteri. These habitats, according to investigations, are mostly located on the slope of mountains facing north at an altitude of 343 m to 991 m above sea level with angle of inclination from 1 degree to 33 degrees. The type of soil is mostly sandy loam and the average field capacity of soil is 28.97%. Their average organic matter is 16.63%, soil pH 5.62, and available phosphorus is 14.75%. A total of 133 vascular plants are identified in 18 quadrates of seven habitats. Dominant species of woody plants in seven habitats are represented as Acer pictum subsp. mono and Quercus mongolica in tree layer, and Acer pictum subsp. mono in subtree layer. Importance value of Viola websteri is 9.66%, as regards the herbaceous layer, and five highly ranked species such as Meehania urticifolia(8.53%), Pseudostellaria heterophylla(6.51%), Hylomecon vernalis(5.15%), Oxalis obtriangulata (4.52%), and Pseudostellaria davidii(4.15%) are considered to be an affinity with Viola websteri in their habitats. The degree of their average species diversity is 1.32, and that of dominance and evenness are 0.08 and 0.89, respectively. Correlation coefficients analysis based on environmental factors, vegetation and soil analysis shows that the coverage of Viola websteri is correlated with silt and sand ratio, and coverage of tree layers are correlated with species richness and altitude. Cluster analysis based on vegetation structure of each habitats are forms a three groups.

Detection of Water Cloud Microphysical Properties Using Multi-scattering Polarization Lidar

  • Xie, Jiaming;Huang, Xingyou;Bu, Lingbing;Zhang, Hengheng;Mustafa, Farhan;Chu, Chenxi
    • Current Optics and Photonics
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    • v.4 no.3
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    • pp.174-185
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    • 2020
  • Multiscattering occurs when a laser transmits into dense atmosphere targets (e.g. fogs, smoke or clouds), which can cause depolarization effects even though the scattering particles are spherical. In addition, multiscattering effects have additional information about microphysical properties of scatterers. Thus, multiscattering can be utilized to study the microphysical properties of the liquid water cloud. In this paper, a Monte Carlo method was used to simulate multi-scattering transmission properties of Lidar signals in the cloud. The results showed the slope of the degree of linear polarization (SLDLP) can be used to invert the extinction coefficient, and then the cloud effective size (CES) and the liquid water content (LWC) may be easily obtained by using the extinction coefficient and saturation of the degree of linear polarization (SADLP). Based on calculation results, a microphysical properties inversion method for a liquid cloud was presented. An innovative multiscattering polarization Lidar (MSPL) system was constructed to measure the LWC and CES of the liquid cloud, and a new method based on the polarization splitting ratio of the Polarization Beam Splitter (PBS) was developed to calibrate the polarization channels of MSPL. By analyzing the typical observation data of MSPL observation in the northern suburbs of Nanjing, China, the LWC and CES of the liquid water cloud were obtained. Comparisons between the results from the MSPL, MODIS and the Microwave radar data showed that, the microphysical properties of liquid cloud could be retrieved by combining our MSPL and the inversion method.