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Resistance of Cementitious Binders to Chloride Induced Corrosion of Embedded Steel by Electrochemical and Microstructural Studies

  • Song, Ha-Won;Ann, Ki-Yong;Kim, Tae-Sang
    • Corrosion Science and Technology
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    • v.8 no.2
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    • pp.74-80
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    • 2009
  • The high alkaline property in the concrete pore solution protects the embedded steel in concrete from corrosion due to aggressive ions attack. However, a continuous supply of those ions, in particular, chlorides altogether with a pH fall in electrochemical reaction on the steel surface eventually depassivate the steel to corrode. To mitigate chloride-induced corrosion in concrete structures, finely grained mineral admixtures, for example, pulverized fuel ash (PFA), ground granulated blast furnace slag (GGBS) and silica fume (SF) have been often advised to replace ordinary Portland cement (OPC) partially as binder. A consistent assessment of those partial replacements has been rarely performed with respect to the resistance of each binder to corrosion, although the studies for each binder were extensively looked into in a way of measuring the corrosion rate, influence of microstructure or chemistry of chlorides ions with cement hydrations. The paper studies the behavior of steel corrosion, chloride transport, pore structure and buffering capacity of those cementitious binders. The corrosion rate of steel in mortars of OPC, 30% PFA, 60% GGBS and 10% SF respectively, with chloride in cast ranging from 0.0 to 3.0% by weight of binder was measured at 7, 28 and 150 days to determine the chloride threshold level and the rate of corrosion propagation, using the anodic polarization technique. Mercury intrusion porosimetry was also applied to cement pastes of each binder at 7 and 28 days to ensure the development of pore structure. Finally, the release rate of bound chlorides (i.e. buffering capacity) was measured at 150 days. The chloride threshold level was determined assuming that the corrosion rate is beyond 1-2 mA/$m^3$ at corrosion and the order of the level was OPC > 10% SF > 60% GGBS > 30% PFA. Mercury intrusion porosimetry showed that 10% SF paste produced the most dense pore structure, followed by 60% GGBS, 30% PFA and OPC pastes, respectively. It was found that OPC itself is beneficial in resisting to corrosion initiation, but use of pozzolanic materials as binders shows more resistance to chloride transport into concrete, thus delay the onset of corrosion.

Mechanical Properties of High Strength Concrete with High Volume Mineral Admixture (다량의 혼화재를 사용한 고강도 콘크리트의 역학적 특성)

  • Baek, Chul-Woo;Park, Cho-Bum;Choi, Sung-Woo;Jo, Hyun-Tae;Ryu, Deuk-Hyun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.3
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    • pp.180-187
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    • 2014
  • The purpose of this study is to evaluate on the mechanical properties of High Volume Mineral Admixture(HVMA) high strength concrete to reduce the amount use of Ordinary Potland Cement, to discover the optimized HVMA binder and to test HVMA concrete based on the change of W/B and curing temperature. The results were shown as follows: The HVMA binder using the mixture of combined heat power plant fly ash and anhydrous gypsum known as inorganic activators with the mixture of blast furnace slag and fly ash was optimized. The mixture of HVMA high strength concrete at 26% of W/B ratio had a good result on flow characteristic and mechanical properties. High strength HVMA concrete over 50MPa is possibly manufactured over curing temperature $20^{\circ}C$.

Fundamental Study on Pervious Concrete Materials for Airport Pavement Cement Treated Base Course (공항포장 시멘트안정처리기층에 적용하기 위한 투수콘크리트 개발에 관한 기초연구)

  • Kim, Seung Won;Oh, Ji Hyeon;Jang, Bong Jin;Ju, Min Kwan;Kim, In Tai;Park, Cheol Woo
    • International Journal of Highway Engineering
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    • v.15 no.4
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    • pp.65-73
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    • 2013
  • PURPOSES : As a research to develop a cement treated base course for an airport pavement which can enhance its drainage, this paper investigated the strength, infiltration performance and durability of the pervious concrete with respect to maximum coarse aggregate sizes and compaction methods. METHODS : This study measured compressive strength, infiltration rate, continuous porosity and freeze-thaw resistance of pervious concrete specimens, which were fabricated with five different compaction methods and different maximum aggregate sizes. In addition, in order to reduce the usage of Portland cement content and to enhance environment-friendliness, a portion of the cement was replaced with Ground Granulated Blast Furnace Slag (GGBS). RESULTS: Compressive strength requirement, 5 MPa at 7 days, was met for all applied compaction methods and aggregate sizes, except for the case of self-compaction. Infiltration rate became increased as the size of aggregate increased. The measured continuous porosities varied with the different compaction methods but the variation was not significant. When GGBS was incorporated, the strength requirement was successfully satisfied and the resistance to freezing-thawing was also superior to the required limit. CONCLUSIONS: The infiltration rate increased as the maximum size of aggregate increased but considering construct ability and supply of course aggregate, its size is recommended to be 25mm. With the suggested mix proportions, the developed pervious concrete is expected to successfully meet requirements for strength, drainage and durability for cement treated base or subbase course of an airport pavement.

An Experimental Study on the mechanical and Shrinkage Properties of Concrete Using High Fineness Fly ash (고분말도 플라이애쉬를 사용한 콘크리트의 역학 및 수축특성에 관한 실험적 연구)

  • Lee, Ji-Hwan;Bae, Pil-Sik;Kim, Sung-Soo;Kim, Jae-Hwan;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.725-728
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    • 2008
  • This study was to establish 3 levels of high fineness fly ash like 4000, 6000, and 8000 class and 30% replacement ratio in order to analyze mechanics and shrinkage properties of concrete by using high fineness fly ash. Furthermore, this study was to make a plan in two levels of water-binder ratio like 40% and 50%. In addition, as a result of measurement by the establishment of combined condition of ternary system as 20% replacement ratio level of three sorts of ground granulated blast furnace slag, there was a tendency to be equal or higher to the plain concrete as the fineness of fly ash increased in strength property. Simultaneously, this study had a tendency in the relationship between the compressive strength and elastic modulus that the more the fineness of fly ash, the more the elastic modulus increased a little. In addition, this study had a tendency that the more elastic modulus moved to the long-term aged one, the more it increased definitely. The effect on the fineness of fly ash remained at a low level in the drying shrinkage. This study has shown that the more the fineness increased, the more the elastic modulus decreased.

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A Study of 240MPa Ultra High Strength Concrete Properties Using High Flow Cement (하이플로 시멘트를 이용한 240MPa 초고강도 콘크리트 물성에 관한 연구)

  • Kim, Kang-Min;Yoo, Seung-Yeup;Song, Yong-Soon;Koo, Ja-Sul;Kang, Suck-Hwa;Jeon, Hyun-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.365-368
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    • 2008
  • This research is related to 240MPa ultra-high strength concrete(UHSC) with extremely loss W/B ratio. For this development, High flow cement is mainly used which has a short reaction rate due to the high blaine and high early strength, which can make greater fluidity in case of very low W/C ratio. It made the best mixture using the mineral admixtures silica fume, slag powder and special admixture. For dispersibility and homogeneity of cement binder, cement of premix type is produced using omni-mixer. Moreover, it ensures the fluidity of ultra-high strength concrete(UHSC). For having a good fire performance, we made an experiment special coarse aggregate. As a result, we got 180MPa in case of water curing, 200MPa in case of steam curing and uniform UHSC of 240MPa in case of a special curing method.

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Characteristics of Diffusion Coefficient of High Performance Concrete using GGBFS for Road Structures by Accelerating Test Method (슬래그 미분말 혼입률에 따른 도로구조물용 고성능 콘크리트의 압축강도 및 촉진 염소이온 확산 특성)

  • Han, Seong-Woo;Kim, Hong-Sam;Lee, Chan-Young;Cheong, Hai-Moon;Ahn, Tae-Song
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.885-888
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    • 2008
  • In recent years, the terminology "High-Performance Concrete(HPC)" has been introduced into the construction industry. Most high-performance concretes have a high cementitious content and a low water-cementitious material ratio. The proportions of the individual constituents vary depending on local preferences and local materials. Therefore, many trial batches are usually necessary before a successful mix is developed. The objective of this experiments is to investigate the fundamental properties of high performance concrete based binary cimentitious materials such as ordinary portland cement and ground granulated blast furnace slag. The results from the study will be utilized as the basic data and guideline in making standard mixproportions and the manufacture, construction work and quality control of HPC

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Zero-Crack Construction on the Fundamental Mass Concrete Using Double Bubble Sheets and Applying Low Heat Mixture (저발열 배합 및 이중버블시트에 의한 기초 매트 매스 콘크리트의 무균열 시공)

  • Park, Yong-Kyu;Song, Sung-Bin;Baek, Byung-Hoon;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.5-8
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    • 2006
  • This study investigates the field application, Songdo the # 1st WORLD, on zero-crack construction of the fundamental mass concrete using double bubble sheets and applying low heat mixture. Experimental results of hydration heat analysis showed that crack modulus of concrete incorporating 20% of blast furnace slag cement was 1.0 in 120 hours, representing 50% probability of crack occurrence, thus requiring additional measures. As for a curing method, a specimen insulating two layers of vinyl chloride+double bubble sheets exhibited only $16.5^{\circ}C$ difference between upper and lower sections, and it also showed favorable workability as well as competitive economic side. Therefore it was determined to use it for curing method in this field. For the curing results of practical field, using 2 layers of vinyl chloride+double bubble sheets and applying low heat mixture on the fundamental mass concrete in 3A residential building exhibited less than only $15^{\circ}C$ difference between surface and center section of that in 5 days elapse and less than $20^{\circ}C$ in 9 days. This means that the crack by hydration heat was prevented, and other fields structures also resisted the plastic shrinkage by insulating the vinyl, sinking crack by second temping, even drying shrinkage by the mixture of low unit water. Therefore the crack on the placement has not been found so far, since the construction was started before 6 month.

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Mechanical Properties and Flexural Behavior of Recycled PET Fiber Reinforced Eco-Friendly Hwang-toh Concrete (재생 PET 섬유로 보강된 친환경 황토 콘크리트의 역학적 특성과 휨 거동)

  • Kim, Sung-Bae;Yi, Na-Hyun;Kim, Hyun-Young;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.3
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    • pp.152-159
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    • 2010
  • Recently, the public interest in eco-friendly material and structure has been increasing and many Hwang-toh researches are being actively performed. Hwang-toh is one of the traditional environment friendly construction materials used as a construction and plastering material. Hwang-toh has many advantages as construction material due to its high heat storage capacity, auto-purification, antibiotic ability, and infrared ray emission characteristics. But, currently it has not been developed into construction material and used in modern construction due to its low strength and dry shrinkage cracking prone characteristics. According to the recent researches and study results, Hwang-toh can be used as a natural pozzolanic material like fly-ash or pozzolan. In this study, mechanical properties and structural flexure behavior experiments of slag, recycled PET fiber, and Hwang-toh added concrete are carried out. The test results showed that drying shrinkage of concrete mixed with Hwang-toh has lower compressive strength and elastic modulus than those of control cement concrete specimen, but it has the similar flexural behavior in reinforced concrete beams.

Effect of GGBS and fly ash on mechanical strength of self-compacting concrete containing glass fibers

  • Kumar, Ashish;Singh, Abhinav;Bhutani, Kapil
    • Advances in concrete construction
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    • v.12 no.5
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    • pp.429-437
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    • 2021
  • In the era of building engineering the intensification of Self Compacting Concrete (SCC) is world-shattering magnetism. It has lot of rewards over ordinary concrete i.e., enrichment in production, cutback in manpower, brilliant retort to load and vibration along with improved durability. In the present study, the mechanical strength of CM-2 (SCC containing 10% of rice husk ash (RHA) as cement replacement and 600 grams of glass fibers per cubic meter) was investigated at various dosages of cement replacement by fly ash (FA) and GGBS. A total of 17 SCC mixtures including two control SCC mixtures (CM-1 and CM-2) were developed for investigating fresh and hardened properties in which, ten ternary cementitious blends of SCC by blending OPC+RHA+FA, OPC+RHA+GGBS and five quaternary cementitious blends (OPC+RHA+FA+GGBS) at different replacement dosages of FA and GGBS were developed with reference to CM-2. For constant water-cement ratio (0.42) and dosage of SP (2.5%), the addition of glass fibers (600 grams/m3) in CM-1 i.e., CM-2 shows lower workability but higher mechanical strength. While fly ash based ternary blends (OPC+RHA+FA) show better workability but lower mechanical strength as FA content increases in comparison to GGBS based ternary blends (OPC+RHA+GGBS) on increasing GGBS content. The pattern for mixtures appeared to exhibit higher workablity as that of the concentration of FA+GGBS rises in quaternary blends (OPC+RHA+FA+GGBS). A decrease in compressive strength at 7-days was noticed with an increase in the percentage of FA and GGBS as cement replacement in ternary and quaternary blended mixtures with respect to CM-2. The highest 28-days compressive strength (41.92 MPa) was observed for mix QM-3 and the lowest (33.18 MPa) for mix QM-5.

Experimental Study on the Time-dependent Property of Chloride Diffusivity of Concrete (콘크리트의 염소이온 확산계수의 시간의존성에 대한 실험적 고찰)

  • Choi, Doo Sun;Choi, Jae Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.4A
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    • pp.365-371
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    • 2009
  • It is time-consuming to estimate chloride diffusivity of concrete by concentration difference test. For the reason chloride diffusivity of concrete is mainly tested by electrically accelerated method, which is accelerating the movement of chloride ion by potential difference. In this study, portland cement concrete and concrete containing with ground granulated blast-furnace slag (40 and 60% of cement by weight) with water-cementitious material ratio 40, 45, 50 and 60% were manufactured. To compare with chloride diffusivity calculated from the electrically accelerated test and immersed test in artifical seawater, chloride diffusivity tests were conducted. From the results of regression analysis, regression equation between accelerated chloride diffusivity and immersed chloride diffusivity was linear function. And the determinant coefficient was 0.96 for linear equation.