• Journal of Photoscience
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• 제8권3_4호
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• pp.99-104
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• 2001

Studies have been conducted to explore single electron transfer (SET) promoted photocyclization reactions of ($\omega$-phthalimidoalkylthio)acetic acids (alkyl=ethyl, n-propyl, n-butyl, n -hexyl and n-nonyl). Photocyclizations occur in methanol in modest yields to produce cyclized products in which phthalimide carbonyl carbon is bonded to the carbon of side chain in place of the carboxylic group. The initially formed cyclized products undergo efficient water eliminations to produce enthiol ethers in secondary ground state reactions.

• Journal of Photoscience
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• 제8권1호
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• pp.9-12
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• 2001

The photoisomerization behavior of benzylideneacetophenones, known as chalcones, was studied. We synthesized the chalcone derivatives that have ether groups at 4 and 4＇ positions. Due to the electron donating ability of the ether oxygen, the bond order of the single bond between two phenyl ring of the chalcone strengthened, which eventually increased the rotational barrier of the single bond. The rotational barrier of the single bond is about 20-22 kcal/mole. Thermal recovery of this process took about 1 min. The UV-visible spectra of these chromophores exhibit two characteristic absorption peaks at 276 nm and 340 nm. The relative intensity of the peaks varies depending on the alkyl chain length of the substituent. Photo-irradiation with the 365 nm light monotonously decreases the 340 nm peak. However, the photo-irradiation with 254 nm light induce two competing processes and produced rather complicated absorption profile.

• Management Science and Financial Engineering
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• 제18권2호
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• pp.23-27
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• 2012

The problem of jointly determining a robust optimal bundle of price and order quantity for a retailer in a single-retailer, single supplier, single-product supply chain is considered. Demand is modeled as a decreasing power function of product price, and unit purchasing cost is modeled as a decreasing power function of order quantity and demand. Parameters defining the two power functions are uncertain but their possible values are characterized by ellipsoids. We extend a previous study in two ways; the purchasing cost function is generalized to take into account the economies of scale realized by higher product demand in addition to larger order quantity, and an exact transformation into an equivalent convex optimization program is developed instead of a geometric programming approximation scheme proposed in the previous study.

• 산업경영시스템학회지
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• 제26권3호
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• pp.50-57
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• 2003

In this paper, we consider an integrated inventory system where a single supplier purchases and processes raw materials in order to deliver finished goods to a single buyer for effective implementation of Just-In-Time purchasing. An integrated JIT lot-splitting model of facilitating multiple shipments in small lots is developed in a JIT purchasing environment. Also, an iterative solution procedure is developed to find the order quantity for the finished goods and raw materials, and the number of shipments between buyer and supplier. We show by example that the integrated policy adopted by both buyer and supplier in a cooperative manner can provide them a greater economic benefit than seeking the local optimal inventory policy independently.

• Industrial Engineering and Management Systems
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• 제13권3호
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• pp.304-318
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• 2014

It is necessary for a retailer to improve responsiveness to uncertain customer demand in product sales. In order to solve this problem, this paper discusses an optimal operation for a 2-stage-ordering-production system consisting of a retailer and a manufacturer. First, based on the demand information estimated at first order time $t_1$, the retailer determines the optimal initial order quantity $Q^*_1$, the optimal advertising cost $a^*_1$ and the optimal retail price $p^*_1$ of a single product at $t_1$, and then the manufacturer produces $Q^*_1$. Next, the retailer updates the demand information at second order time $t_2$. If the retailer finds that $Q^*_1$ dissatisfies the demand indicated by the demand information updated at $t_2$, the retailer determines the optimal second order quantity $Q^*_2$ under $Q^*_1$ and adjusts optimally the advertising cost and the retail price to $a^*_2$ and $p^*_2$ at $t_2$. Here, decision-making approaches for two situations are made-a decentralized supply chain (DSC) whose objective is to maximize the retailer's profit and an integrated supply chain (ISC) whose objective is to maximize the whole system's profit. In the numerical analysis, the results of the optimal decisions under DSC are compared with those under ISC. In addition, supply chain coordination is discussed to adjust the unit wholesale price at each order time as Nash Bargaining solutions.

• 한국멀티미디어학회논문지
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• 제12권9호
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• pp.1273-1287
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• 2009

Chain-based protocol방법 중의 하나인 PEGASIS는 모든 노드들의 공평한 에너지 소모를 유도 할 수 있지만 BS(Base station)로부터 멀리 떨어진 노드들 중에서 HEAD가 선택될 경우에는 데이터 전송 시에 심각한 에너지 소모와 불필요한 노드들 간의 데이터 이동이 발생하게 된다. 본 논문에서는 이러한 문제점을 해결하기 위해 PEGASIS의 greedy알고리즘을 응용하고, BS를 기준으로 주변 node들과의 거리를 비교하여 에너지 소모를 줄일 수 있는 프로토콜인 DERP(Distance-based Energy efficient routing protocol)을 제안한다. DERP의 기법은 예비헤드(P-HD)노드를 선택하여 보다 효율적인 클러스터 구조를 생성할 수 있는 방법이다. 아울러 더 큰 센서 필드에서의 확장을 위해서 PEGASIS와 제안방법에서 기본이 되는 single-hop 기반의 통신을 HEAD와 BS와의 거리에 따른 relay노드를 선택함으로서 multi-hop 기반의 통신으로 변환하여 에너지 소모를 줄일 수 있는 방법을 추가하였다. DERP의 시뮬레이션 결과 값으로 에너지 효율은 기존의 PEGASIS방법에 비해 최고 80%정도까지의 에너지 효율이 있는 것으로 나타났으며, 데이터 전송 지연 역시 감소하는 것으로 확인 되었다.

• PNF and Movement
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• 제15권3호
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• pp.237-246
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• 2017

Purpose: The purpose of this study was to investigate the effects of forward-and-backward shift trunk exercise using a proprioceptive neuromuscular facilitation (PNF) diagonal pattern in a closed kinematic chain exercise on the upper limb function and activity of daily living (ADL) in a stroke patient. Methods: One subject participated in this study. The study used a reversal A-B-A' design, where A and A' were the baseline period (no intervention), and B was the intervention period. The intervention was a forward-and-backward trunk shift exercise, using a PNF diagonal pattern on both a stand-on-hand position and a quadruped position of closed kinematic chain exercises, for 20 min per day for 2 weeks. The range of motion (ROM) of the shoulder joint was measured and a Fugl-Meyer assessment of upper extremity (FMA-UE) and a functional independence measure (FIM) were performed to measure upper limb function and activity of daily living (ADL). Results: ROMs of shoulder joint (flexion, extension, abduction, and external rotation) increased in the intervention phase. The FMA-UE score increased (from 28 to 36) in the intervention phase. The FIM score increased (from 20 to 25) in the intervention phase. These increases were maintained after intervention (Baseline II). Conclusion: These results suggest that forward-and-backward shift trunk exercises using a PNF diagonal pattern in a closed kinematic chain exercise have a positive effect on stroke patients' upper limb function and ADL ability.

• 자원환경지질
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• 제33권4호
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• pp.249-260
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• 2000

한국 남부에서 섭입 해구의 방향과 나란히 쌍으로 발달한 화산대가 발견된다. 경상분지와 영동-광주 함몰대의 화산암류는 거의 나란한 양상을 보이며, 이들은 각각 동일한 섭입 체계에 따르는 첫 번째 화산대, 두 번째 화산대이다. 경상분지와 영동-광주 함몰대 화산암류의 불호정성 원소 함량은 호를 가로지르는 변화를 뚜렷하게 보인다. 즉, 첫 번째 화산대 (경상분지 및 남해안 도서지역)용암들의 불호정성 원소 함량은 두 번째 화산대 (영동-광주 함몰대)에 비해 더욱 결핍되며 두 번째 화산대에서 더욱 증가하는 경향을 보인다. 이와 같이 호를 가로지르는 변화를 보이는 것은, 탈수과정 동안 유체상과 공존하는 고체상의 차이에 기인한 것으로 보인다. 두 번째 화산대의 불호정성 원소의 함량, Zr/Y 비, Rb/K 비는 첫 번째 화산대에 비해 더 깊은 깊이에서 더 적은 정도의 부분 용융, 그리고 용융 과정에서의 잔류 석류석에 기인할 것이다.

• Journal of Communications and Networks
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• 제17권2호
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• pp.184-197
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• 2015

This paper builds on a recent method, chain routing with even energy consumption (CREEC), for designing a wireless sensor network with chain topology and for scheduling the communication to ensure even average energy consumption in the network. In here a new suboptimal design is proposed and compared with the CREEC design. The chain topology in CREEC is reconfigured after each group of n converge-casts with the goal of making the energy consumption along the new paths between the nodes in the chain as even as possible. The new method described in this paper designs a single near-optimal Hamiltonian circuit, used to obtain multiple chains having only the terminal nodes different at different converge-casts. The advantage of the new scheme is that for the whole life of the network most of the communication takes place between same pairs of nodes, therefore keeping topology reconfigurations at a minimum. The optimal scheduling of the communication between the network and base station in order to maximize network lifetime, given the chosen minimum length circuit, becomes a simple linear programming problem which needs to be solved only once, at the initialization stage. The maximum lifetime obtained when using any combination of chains is shown to be upper bounded by the solution of a suitable linear programming problem. The upper bounds show that the proposed method provides near-optimal solutions for several wireless sensor network parameter sets.

• 한국정보통신학회논문지
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• 제14권5호
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• pp.1049-1056
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• 2010

최근 RFID 시스템의 채택이 다양한 분야에서 빠르게 진행되고 있다. 그러나 RFID 시스템의 대중화를 위해서는 RFID 태그의 정보를 무단으로 획득함으로써 발생할 수 있는 프라이버시 침해 문제를 해결해야 한다. 이 문제를 해결하기 위해서 기존 연구들 중에서 가장 안전한 M. Ohkubo 등의 Hash-Chain 기법이 있다. 그러나 이 기법은 태그를 판별할 때 엄청난 태그 수의 증가로 인해 막대한 계산 능력을 요구하는 문제점이 있다. 따라서 본 논문에서는 프라이버시 보호 기법의 필수 보안 요건 3가지를 모두 만족하면서 태그 판별 시간을 감소할 수 있는 SP분할 알고리즘을 제안한다. 그리고 제안한 알고리즘을 적용하여 각 노드에 분할된 데이터 중에서 최초의 키를 찾는 시간 기준으로 구현한다. 구현 결과 Hash-Chain 길이 1000으로 고정된 상태에서 SP들의 총수를 1000, 2000, 3000, 4000으로 증가하고 노드 수를 1, 2, 3, 4로 확장하면서 SP들의 총수, 노드 수에 따른 태그 판별 시간을 단일 노드와 비교하면 노드 수가 2개일 때 40%, 노드 수가 3개일 때 56%, 노드 수가 4개일 때 71%로 성능이 향상 되었다.