• Journal of Korean Society of Environmental Engineers
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• v.37 no.6
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• pp.340-348
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• 2015

Removal efficiency of PCBs in contaminated marine sediments treated by Fenton-like oxidation combined with surfactant was investigated in this research in order to achieve remediation of PCBs. A washing treatment using various concentrations of hydrogen peroxide (1% and 15%) and surfactants (Triton X-100, Tween 60 and Tween 80) was evaluated at various conditions in laboratory scale experiments. The mean removal efficiencies of tPCBs varied from 24.1 to 46.7% in the sediments for 1 hour duration of the treatments. The concentration of tPCBs in contaminated marine sediments after the simultaneous treatment with hydrogen peroxide and surfactant satisfied the domestic environmental standards for the beneficial use of sediments. When suitable surfactant was used for Fenton-like oxidation, the removal efficiency of tPCBs at low concentration of hydrogen peroxide was similar to that at high hydrogen peroxide concentration. Thus the efficient removal of PCBs in contaminated marine sediments could be achieved through treatment with Fenton-like oxidation combined with surfactant washing.

• Earthquakes and Structures
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• v.18 no.5
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• pp.649-665
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• 2020

One of the most important issues in structural systems is evaluation of the margin of safety in low and mid-rise buildings against the progressive collapse mechanism due to the earthquake loads. In this paper, modeling of collapse propagation in structural elements of RC frame buildings is evaluated by tracing down the collapse points in beam and column structural elements, one after another, under earthquake loads and the influence of column removal is investigated on how the collapse expansion in beam and column structural members. For this reason, progressive collapse phenomenon is studied in 3-story and 5-story intermediate moment resisting frame buildings due to the corner and edge column removal in presence of the earthquake loads. In this way, distribution and propagation of the collapse in progressive collapse mechanism is studied, from the first element of the structure to the collapse of a large part of the building with investigating and comparing the results of nonlinear time history analyses (NLTHA) in presence of two-component accelograms proposed by FEMA_P695. Evaluation of the results, including the statistical survey of the number and sequence of the collapsed points in process of the collapse distribution in structural system, show that the progressive collapse distribution are special and similar in low-rise and mid-rise RC buildings due to the simultaneous effects of the column removal and the earthquake loads and various patterns of the progressive collapse distribution are proposed and presented to predict the collapse propagation in structural elements of similar buildings. So, the results of collapse distribution patterns and comparing the values of collapse can be utilized to provide practical methods in codes and guidelines to enhance the structural resistance against the progressive collapse mechanism and eventually, the value of damage can be controlled and minimized in similar buildings.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.6
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• pp.791-799
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• 2005

The phased isolation intra-clarifier ditch system used in this study is a simplified novel process enhancing simultaneous removal of biological nitrogen and phosphorus in municipal wastewater in terms of elimination of additional pre-anaerobic reactor, external clarifier, recycle of sludge, and nitrified effluent recirculation by employing intrachannel clarifier. Laboratory-scale phased isolation ditch system was used to assess the treatability on municipal wastewater. When the system was operated at the HRTs of 6~12hours, SRTs of 9~31days, and cycle times of 2~8hours, the system showed removals of BOD, TN, and TP as high as 88~97%, 70~84%, and 65~90%, respectively. The rainfall in Korea is generally concentrated in summer because of site-specific characteristics. Especially, the wet season has set in on June to August. In combined sewers, seasonal variations are primarily a function of the amount of stormwater that enters the system. In order to investigate the effect of hydraulic shock loading on system performance, the laboratory-scale system was operated at an HRT of 6hours (two times of influent flowrate) during two cycles (8hours). The system performance slightly decreased by increasing of influent flowrate and decreasing of system HRT. Nitrification efficiency and TN removal were slightly decreased by increasing of influent flowrate (decreasing of system HRT), whereas, the denitrification was not affected by hydraulic shock loading. However, the higher system performance could be achieved again after four cycles. Thus, the phased isolation technology for enhanced biological nutrient removal in medium- and small-scale wastewater treatment plants suffering fluctuation of influent quality and flowrate.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.5
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• pp.512-522
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• 2008

Ammonia is a major compound of odor in livestock house. To enhance the performance of ammonia oxidation (decomposition). the gas-liquid, two phase photocatalytic oxidation system was designed and prepared in this study. Commercial P-25 as $TiO_2$ catalyst was used for ammonia decomposition. V/P-25 catalyst prepared by sol gel method was also used for the removal of by-producted $NO_x$ in $NH_3$ oxidation reaction. When $TiO_2$ was used as a photocatalyst, the conversion to $N_2$ in ammonia decomposition reached above 90% until 200hr (The air flow rate of 4L/min with the ammonia concentration up to 25ppm.). However, considerable amounts of NO and $NO_2$ were formed as a result of $NH_3$ oxidation (as a by-product). Therefore, we added Vanadia impregnated $TiO_2$(P-25) catalyst for the removal of $NO_x$ at the end of reaction trail. The results of a pilot-scale operation were successful to achieve the simultaneous removal of $NH_3\;and\;NO_x$ about 81 and 87%, respectively.

• Journal of Environmental Science International
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• v.14 no.7
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• pp.675-681
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• 2005

A laboratory experiment was performed to investigate phosphorus and nitrogen removal from synthetic wastewater by intermittently aerated activated sludge process packed with aluminum and silver plate. Three continuous experi­mental processes, i. e. an intermittently aerated activated sludge process(Run A), an intermittently aerated activated sludge process with an aluminum and silver plate packed into the reactor(Run B), and a reactor post stage(Run C) were compared. In the batch experiments, the phosphorus removal time in the reactor packed with aluminum and silver plate simultaneously was faster than that of the reactor packed with only an aluminum plate. More phos­phorus was removed with an increase of NaCl concentration. The pitting corrosion of aluminum does not affect the performance of the biological treatment. The total nitrogen removal efficiency in Run B was $57\%\;and\;43.6\%$ at the HRT of 12 and 6 hours respectively. The effluent $PO_{4-}P$ concentration as low as 1.0 mg/L could be ob­tainable through the continuous experiment in Run B at HRT of 6 hours.

• Earthquakes and Structures
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• v.18 no.6
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• pp.691-707
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• 2020

One of the most important issues in structural systems is evaluation of the margin of safety in low and mid-rise buildings against the progressive collapse mechanism due to the earthquake loads. In this paper, modeling of collapse propagation in structural elements of RC frame buildings is evaluated by tracing down the collapse points in beam and column structural elements, one after another, under earthquake loads and the influence of column removal is investigated on how the collapse expansion in beam and column structural members. For this reason, progressive collapse phenomenon is studied in 3-story and 5-story intermediate moment resisting frame buildings due to the corner and edge column removal in presence of the earthquake loads. In this way, distribution and propagation of the collapse in progressive collapse mechanism is studied, from the first element of the structure to the collapse of a large part of the building with investigating and comparing the results of nonlinear time history analyses (NLTHA) in presence of two-component accelograms proposed by FEMA_P695. Evaluation of the results, including the statistical survey of the number and sequence of the collapsed points in process of the collapse distribution in structural system, show that the progressive collapse distribution are special and similar in low-rise and mid-rise RC buildings due to the simultaneous effects of the column removal and the earthquake loads and various patterns of the progressive collapse distribution are proposed and presented to predict the collapse propagation in structural elements of similar buildings. So, the results of collapse distribution patterns and comparing the values of collapse can be utilized to provide practical methods in codes and guidelines to enhance the structural resistance against the progressive collapse mechanism and eventually, the value of damage can be controlled and minimized in similar buildings.

• Applied Chemistry for Engineering
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• v.28 no.6
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• pp.607-618
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• 2017

Harmful air pollutants are exhausted from the various industrial facilities including the coal-fired thermal power plants and these substances affects on the human health as well as the nature environment. In particular, nitrogen oxides ($NO_x$) and sulfur dioxide ($SO_2$) are known to be causative substances to form fine particles ($PM_{2.5}$), which are also deleterious to human health. The integrated system composed of selective catalytic reduction (SCR) and wet flue gas desulfurization (WFGD) have been widely applied in order to control $NO_x$ and $SO_2$ emissions, resulting in high investment and operational costs, maintenance problems, and technical limitations. Recently, new technologies for the simultaneous removal of $NO_x$ and $SO_2$ from the flue gas, such as absorption, advanced oxidation processes (AOPs), non-thermal plasma (NTP), and electron beam (EB), are investigated in order to replace current integrated systems. The proposed technologies are based on the oxidation of $NO_x$ and $SO_2$ to $HNO_3$ and $H_2SO_4$ by using strong aqueous oxidants or oxidative radicals, the absorption of $HNO_3$ and $H_2SO_4$ into water at the gas-liquid interface, and the neutralization with additive reagents. In this paper, we summarize the technical improvements of each simultaneous abatement processes and the future prospect of technologies for demonstrating large-scaled applications.

• Particle and aerosol research
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• v.15 no.1
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• pp.1-13
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• 2019

Current desulfurization and denitrification technologies have reached a considerable level in terms of reduction efficiency. However, when compared with the simultaneous reduction technology, the individual reduction technologies have issues such as economic disadvantages due to the difficulty to scale-up apparatus, secondary pollution from wastewater/waste during the treatment process, requirement of large facilities for post-treatment, and increased installation costs. Therefore, it is necessary to enable practical application of simultaneous SOx and NOx treatment technologies to remove two or more contaminants in one process. The present study analyzes a technology capable of maintaining simultaneous treatment of SOx and NOx even at low temperatures due to the electrochemically generated strong oxidation of the wet-pulse complex system. This system also reduces unreacted residual gas and secondary products through the wet scrubbing process. It addresses common problems of the existing fuel gas treatment methods such as SDR, SCR, and activated carbon adsorption (i.e., low treatment efficiency, expensive maintenance cost, large installation area, and energy loss). Experiments were performed with varying variables such as pulse voltage, reaction temperature, chemicals and additives ratios, liquid/gas ratio, structure of the aeration cleaning nozzle, and gas inlet concentration. The performance of individual and complex processes using the wet-pulse discharge reaction were analyzed and compared.

• Journal of Soil and Groundwater Environment
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• v.13 no.3
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• pp.52-58
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• 2008

Mn-impregnated activated carbon (Mn-AC) prepared at different conditions was applied in the treatment of synthetic wastewater containing both organic and inorganic contaminants. Phenol and As(III) was used as the representative organic and inorganic contaminants, respectively. After evaluation of the physicochemical characteristic and stability of Mn-AC, oxidation of As(III) as well as adsorption of phenol by activated carbon(AC) and Mn-AC were investigated in a batch reactor. To investigate the stability of Mn-AC, dissolution of Mn from each Mn-AC was measured pH ranging from 2 to 4. Although Mn-AC was unstable at a strong acidic condition, the dissoluted Mn was below 3 ppm at pH 4. XRD analysis of Mn-AC indicated that the mineral type of the impregnated manganese was $Mn_2O_3$. From the simultaneous treatment of As(III) and phenol by AC and Mn-AC, As(III) oxidation by Mn-AC was greater than that by AC at lower pH, while the reverse order was observed at higher pH. After impregnation of Mn onto AC, 13% decrease of the surface area was observed, causing 8% reduction of phenol removal. Considering removal properties of As(III) and phenol, Mn-AC could be applied in the simultaneous treatment of wastewater contaminated with multi-contaminants.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.2 no.2
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• pp.115-121
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• 1998

Train of chemical and biological processes was investigated to treat leachate from industrial waste landfill. Organics and nitrogen concentrations of landfill leachate studied in this research were high and their BOD/COD ratio was 0.3. Biological process should be combined with chemical process for optimum treatment of leachate. PAC(Polyaluminium chloride) was the best coagulant among three chemicals tested, and the optimum condition of PAC coagulation was pH 6 and 1,250 mg/L of dosage. When SBR was operated for simultaneous removal of organics and nitrogen, removal efficiency of COD and T-N reached over $82\%,\;71\%,$ respectively and time distribution of 2/4/2/1 was most effective for one cycle of anoxic/aerobic/anoxic/aerobic.