• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.63-70
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• 2000

In 1925, H.J. Joosten was the first in the world to use chemical injection grouts composed of sodium silicate and calcium chloride. This unique development prompted the introduction of other chemical grouting techniques. Among these chemical grouting techniques, sodium silicate based grout has been the most widely used in the world, but it has not been generally considered to be a permanent material. Therefore, studies to improve the weak points of sodium silicate based grout have been conducted, and new applications of grout were recently developed. We also developed the micro fine hybrid silicate grout of suspention type which properties are sepecialized as the high strength and durability, according to the reactant of special sodium silicate grout and the high strength hardener. As the results of this study we could derive the 2 times over high strength of Micro fine hybrid Silicate grouting method(MS method) more than that of the ordinary sodium silicate grout. And also we could confirm that the alkali leakage of micro fine hybrid silicate grout is less than that of ordinary sodium silicate grout. So we could get the high strength and durability of hybrid silicate grout are superior to those of ordinary sodium silicate grout.

• Macromolecular Research
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• v.8 no.2
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• pp.95-101
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• 2000

Clay/poly(styrene-co-acrylonitrile) copolymer (SAN) hybrids have been prepared by simple meltmixing of two components, SAN and organophilic clays with a twin screw extruder. Effects of intercalant on the dispersibility of silicate layers in clay-dispersed nanocomposite were studied by using five different organophilic clays modified with the intercalants of different chemical structures and different fractions of intercalant. The dispersibility of 10-$\AA$-thick silicate layers of clay in the hybrid was investigated by using an X-ray diffractometer and a transmission electron microscope. It was found that if the fraction of intercalant in the organophilic clay becomes too high, SAN is difficult to intercalate into the inter-gallery of silicate layers in the hybrid prepared at 180$\^{C}$, and thus the hybrid shows poor dispersibility of silicate layers. The flexural modulus of the hybrid increases as the dispersibility of silicate layers in the hybrid increases.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.147-147
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• 2010

An electrolyte membranes for high temperature/low humidity is a demand for the proton exchange membrane fuel cells (PEMFCs). In this work, we prepared hybrid membranes, which have novel glass content in the hydrophilic and hydrophobic part of sulfonated poly(arylene ether sulfone) (SPAES) by in-situ sol-gel synthesis of various functional silane. The effect of silicate from functional silane content on the proton conductivity, water uptake of the hybrid membranes under high temperature and low humidity was quantitatively identified. The silicate content contributed to the enhancement of not only proton conductivity, but also water retention ability for PEMFCs operation.

• Macromolecular Research
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• v.8 no.3
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• pp.120-124
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• 2000

Clay-dispersed nanocomposites have been prepared by simple melt-mixing of two components, styrenic polymers with different content of functional groups and two different organophilic clays (Cloisite(R) 25A and Cloisite(R)30A) with a twin screw extruder. Dispersibility of 10-$\AA$-thick silicate layers of clay in the hybrid was investigated by using an X-ray diffraction method and a transmission electron microscope. It was found that if the interaction force between intercalant and matrix polymer is attractive, the matrix polymer intercalates more rapidly into the gallery of silicate layers. The faster intercalation of matrix polymer leads to the better dispersibility of silicate layers in the matrix polymer.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.190-190
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• 2006

The approach used in present work allows achieving highly exfoliated state of layered silicate s through confinement of the charged nanobeads within the gallery of swollen pristine clay. The latter is principally promoted by ion exchange that involves polar functional groups on the surface of nanobeads and sodium cation in the interlayer gallery of layered silicates. Surface functionality of the nanobeads plays crucial role in establishment of strong interactions with silicate surface, and eventually, dispersion of individual silicate nanoplatelets.

• Journal of the Korean GEO-environmental Society
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• v.2 no.1
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• pp.67-79
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• 2001

The objective of this study is to determine the engineering properties of micro fine hybrid silicate grout materials that were developed recently. In this study, MSG-N type was mainly used as grout materials, and the chemical components, grain size distribution, mineral characteristics were analyzed. Moreover, the properties of active silica and ordinary portland cement acting as coagulating agent were analyzed and compared with each other. To determine the engineering properties, the bleeding test, viscosity test, coagulation test, examination with naked eye, photographing by using SEM, uniaxial compression test and in-situ application test for reclaimed ground were carried out. A series of test results showed that the strength of micro fine hybrid silicate grout materials was about twice that of ordinary sodium silicate grout materials, and alkali leakage decreased dramatically when MSG method was utilized. Especially, based on the evaluation of the application of the MSG method to field, this method would be very effective in reducing coefficient of permeability due to its excelent permeability.

• Polymer(Korea)
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• v.31 no.2
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• pp.141-147
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• 2007

Dental properties of polymer composite loaded with hybrid filler of barium silicate (BaSi) and hydroxyapatite, which is a principal component of human bone material, were investigated. A visible light system was utilized to activate the acrylic resin matrix of the composite. Based on the experimental results, it was found that mechanical strength of the composite was consistently increased with an increase of BaSi content in the hybrid filler. And those value rose above the dental specification enough to apply for dental materials. However, abrasion resistance was slightly decreased with increasing BaSi content in the filler. Depth of cure value was 6 to 9 mm applicable for dental restoration irrelevant to hybrid filler composition. On the other hand, there was no strict trend between filler composition and polymerization shrinkage as well as degree of conversion.

• Journal of the Korean Society of Safety
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• v.21 no.1 s.73
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• pp.79-85
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• 2006

Olefinic compatibilized blend(R-PP/R-PE)/layered silicate composites have been prepared by melt intercalation technique directed from $Na^{+}$ montmorillonite(MMT) or organophilic montmorillonites while using magnesium hydroxide as flame retardant. Morphology and flammability properties were characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM), thermogravimetry analysis(TGA), limiting oxygen index(LOI), UL94 test. It is found that the compatibilized blend/layered silicate(Cloisite 20A) nanocomposites have a mixed immiscible-intercalated structure and there is better intercalation when a compatibilizer is combined with the polymer and layered silicate to be melt blended. A very large increase in the LOI value was observed with hybrid filler addition and further enhancement in thermal stability and compatibility of blend was obtained for the compatibilized blend containing small amount of layered silicate.

• 한국문화재보존과학회:학술대회논문집
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• 2007.05a
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• pp.67-68
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• 2007

Tetraethyl orthosilicate (TEOS)로 형성된 gel의 film 형성 특성을 증가시키기 위하여 (3-glycidyloxypropyl)trimethoxysilane (GPTMS)와 1,2-bis(triethoxysilyl)ethane (BTEOS)를 추가한 유기-무기 복합 용액을 제조하였다. 화강암과 사암에 적용한 후, 접촉 각 및 고형화 시간, silicate의 함유량, 수분 흡수율 및 석재에 적용되었을 때의 공극률 변화를 측정하여 silicate를 기본으로 하는 복합제의 특성을 분석하였다.

• Journal of the Korea Concrete Institute
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• v.18 no.4 s.94
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• pp.553-558
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• 2006

In this study, fluorine-silicate hybrid type crack reducing agent(FS) consisted of fluorine and silicate compounds applied to concrete mix(specification : 25-30-18) between 0.5% and 2.0% at intervals of 0.5% based on cement weight. Experiments for material properties of concrete such as slump, air content and bleeding with elapsed time were performed. Experiment and elucidation for shrinkage crack resistance as well as adiabatic hydration temperature were also carried out. It was appeared that FS addition contributed to lower bleeding and hydration temperature without disturbance of fresh properties of concrete such as slump and air content compared to non-added concrete. Especially, shrinkage crack resistance of concrete resulted from plastic and drying shrinkage could be effectively reduced by the addition of FS ranging from 1.0% to 1.5%.