• Corrosion Science and Technology
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• v.14 no.5
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• pp.207-212
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• 2015

The purpose of this research was to synthesize fluorine modified waterborne polyurethane dispersion (F-WPU) by soap-free (internal emulsifier) emulsion polymerization techniques, to prepare coating solution based on fluorine modified waterborne polyurethane dispersion (F-WPU) and to compare the chemical and thermo-mechanical properties on the electrogalvanized steel sheet. Environmentally friendly F-WPU was prepared with a fluorinated polyol containing 60 wt% of fluorine. There are various ways of combining a wide variety of fluorinated polyols and diisocyanate to exhibit novel properties of waterborne polyurethane dispersion. Components of coating solution were largely divided into 4 kinds i.e., F-WPU, acrylic emulsion, silane coupling agent, and colloidal silicate. F-WPU coating solution on the electro-galvanized steel sheet showed excellent properties of corrosion resistance, alkali resistance and heat resistance, as compared to other coating solutions using a general waterborne resin. The F-WPU coating solution's reliable effects are possibly due to the fluorine atoms incorporated even in a small amount of F-WPU.

• Journal of the korean academy of Pediatric Dentistry
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• v.35 no.2
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• pp.195-204
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• 2008

Orthodontic brackets often need to be bonded to porcelain such as porcelain fused to metal crowns and porcelain jacket crowns. The purpose of this study was to evaluate the clinical usability of direct bonding system on porcelain teeth by measuring shear bond strength according to various conditions and observing adhesive failure patterns. The specimens, 20 maxillary premolars and 80 porcelain teeth that were produced by duplication of the labial surface of a maxillary first premolar were used and randomly divided into four groups of twenty teeth each. The 5 different preparation procedures tested: (1) application of 37% phosphoric acid on natural teeth, (2) sandblasting on porcelain surfaces, (3) sandblasting and application of 9.6% hydrofluoric acid on porcelain surfaces, (4) sandblasting and application of silane on porcelain surface, (5) sandblasting and application of 9.6% hydrofluoric acid and silane on porcelain surfaces. The metal brackets were bonded with Transbond $XT^{(R)}$ bonding material. The shear bond strength was tested by the micro universal testing machine(Kyung-Sung, Korea) and the amount of residual adhesive on the tooth surface after debonding was examined by stereoscope and assessed with an adhesive remnant index. The results of this study suggest that the direct bonding system on porcelain teeth with sandblasting, HF and porcelain primer is clinically useful.

• Journal of the Korea Concrete Institute
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• v.27 no.1
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• pp.21-28
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• 2015

Recent studies on concrete floating structure development focused on connection system of concrete modules. Precast concrete modules are designed to be attached by prestressing in the water, exposing the structure to the loads from water and making the construction difficult. Therefore, a development of bond material became a key issue in successful connection of floating concrete modules. In this study, micro-silica mixed aqua epoxy (MSAE) is developed for the task. Existing primer aqua epoxy, originally used as a bond material for the retrofit of concrete structures using fiber reinforced polymers, is evaluated to find the optimum micro-silica added mix proportion. Micro-silica of 0~4 volume % was mixed in standard mixture of aqua epoxy. Then, the material property tests were performed to study the effect of micro-silica in aqua epoxy by controlling the epoxy silane proportion by 0, ${\pm}5$, ${\pm}10%$. The optimum mix design of MSAE was derived based on the test results. The MSAE was used to connect concrete module specimens with the epoxy thickness variation of 5, 10, and 20mm. Then, 3-point loading test was performed to verify the bond capacity of MSAE. The results show that MSAE improves the bond capacity of concrete module.