• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.519-523
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• 2013

When atomic layer deposition (ALD) is performed on a porous material by using an organometallic precursor, minimum exposure time of the precursor for complete coverage becomes much longer since the ALD is limited by Knudsen diffusion in the pores. In the previous report by Min et al. (Ref. 23), shrinking core model (SCM) was proposed to predict the minimum exposure time of diethylzinc for ZnO ALD on a porous cylindrical alumina monolith. According to the SCM, the minimum exposure time of the precursor is influenced by volumetric density of adsorption sites, effective diffusion coefficient, precursor concentration in gas phase and size of the porous monolith. Here we modify the SCM in order to consider undesirable adsorption of byproduct molecules. $TiO_2$ ALD was performed on the cylindrical alumina monolith by using titanium tetrachloride ($TiCl_4$) and water. We observed that the byproduct (i.e., HCl) of $TiO_2$ ALD can chemically adsorb on adsorption sites, unlike the behavior of the byproduct (i.e., ethane) of ZnO ALD. Consequently, the minimum exposure time of $TiCl_4$ (~16 min) was significantly much shorter than that (~71 min) of DEZ. The predicted minimum exposure time by the modified SCM well agrees with the observed time. In addition, the modified SCM gives an effective diffusion coefficient of $TiCl_4$ of ${\sim}1.78{\times}10^{-2}\;cm^2/s$ in the porous alumina monolith.

• Journal of the Korean Chemical Society
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• v.47 no.1
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• pp.59-66
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• 2003

The comb-type grafted polymer hydrogels, which composed of N-isopropylacrylamide monomer and oligo(N-isopropylacrylamide-co-tert-butylacrylamide) [oligo(NIPAAm-co-t-BAM)], were synthesized by redox polymerization in 5~10% methanol aqueous solution using ammonium peroxodisulfate (APS) at 4 oC for 24h. The lower critical solution temperatures (LCSTs) of the comb-type grafted hydrogels were decreased with increase of t-BAM content in the grafted copolymer. We observed the effect of crosslinker and concentration of oligo(NIPAAm-co-t-BAM) on the shrinking/swelling ratio of hydrogels. Changes of shrinking/swelling ratio were decreased with increase of concentration of crosslinker. The increase of grafted oligo(NIPAAm-co-t-BAM) in the hydrogel shows an fast changes of shrinking/ swelling rate. The comb-type grafted hydrogels are expected to be valuable for the sensing materials of time-temperature labels(TTLs).

• Journal of IKEEE
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• v.23 no.2
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• pp.681-686
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• 2019

This paper proposes a CMOS temperature sensor using inverter delay chains of the same size based on the pulse shrinking method. A temperature-pulse converter (TPC) uses two different temperature delay lines with inverter chains to generate a pulse in proportion to temperature, and a time-digital converter (TDC) shrinks the pulse using inverter chains of the same size to convert pulse width into a digital value to be insensitive to process changes. The chip was implemented with a $0.49{\mu}m{\times}0.23{\mu}m$ area using a $0.35{\mu}m$ CMOS process with a supply voltage of 3.3V. The measurement results show a resolution of $0.24^{\circ}C/bit$ for 9-bit data for a temperature sensor range of $0^{\circ}C$ to $100^{\circ}C$.

• Journal of People, Plants, and Environment
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• v.23 no.4
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• pp.387-398
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• 2020

Background and objective: Land vacancy is a persistent issue in most urban areas in the United States, yet few case studies have examined how vacant lots are used and the functions they serve in local communities. The purposes of this study were to provide a new revitalization planning and design proposal for the Durant-Tuuri-Mott (DTM) target area in the shrinking city of Flint, MI, USA, and to assess the final planning and design guideline through an analysis of vacant land redevelopment alternatives. Methods: For developing a revitalization planning and design guideline, this study developed several design modules with three main design themes. Then, landscape performance of the final design proposals was analyzed by three development scenarios, based on implementation level: 100%, 75%, and 50%. These development scenarios were based on the local context and different implementation budgets needed to adopt the proposed design modules. To generate a comprehensive development plan by optimizing design module allocation in the study area, this research employed a system-oriented approach, analyzing the existing cultural, natural, and built environments. A community participant process was adopted to collect stakeholders' opinions on future development. Results: By utilizing landscape performance metrics to quantify the environmental, social, and economic benefits, this study developed optimized development scenarios and a master plan for the reuse and redevelopment of existing vacant lots across DTM neighborhoods and analyzed the benefits of each. Conclusion: This research offers a flexible design method for balancing objectives in vacant land redevelopment that can be applied in other shrinking cities.

• Bulletin of the Korean Mathematical Society
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• v.38 no.1
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• pp.65-69
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• 2001

For any closed subspace X of $\ell_p, \; 1<\kappa<\infty$, K(X) is proximinal in L(X), and if X is a Banach space with an unconditional shrinking basis, then K(X, c$_0$) is proximinal in L(X,$ \ell_\infty$).

• Resources Recycling
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• v.23 no.6
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• pp.47-53
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• 2014

Effective treatment and energy conversion technologies are necessary due to the ban of the dumping of organic waste including the sewage sludge. In this study, the kinetics of pyrolysis and combustion were derived in a TGA and thermobalance reactor, which is essential for thermal conversion of sewage sludge to energy. Three steps are shown for the pyrolysis in TGA and the different pre-exponential factors and activation energies are derived depending on the temperature range. Three models of gassolid reaction were applied to the reaction kinetics analysis for the combustion of sewage sludge char and shrinking core model was an appropriated model. Apparent activation energy and pre-exponential factor were evaluated and the effect of oxygen partial pressure was examined.

• Proceedings of the KSME Conference
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• 2007.05a
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• pp.1481-1486
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• 2007

Frictional laws are criticized with emphasis on their application to bulk metal forming simulation in this paper. Coulomb frictional law and constant shear frictional law are investigated in detail in terms of their effect on metal forming process. A friction sensitive bulk metal forming process, a long-pipe simultaneously shrinking and expanding process, is introduced and the problems of the constant shear frictional law are revealed comparing the predictions obtained by the Coulomb frictional law and the constant shear frictional law with the experiments. It is shown that the constant shear frictional law is improper in the case that the normal stress varies very much from position to position and that the normal stress is low compared with flow stress of the adjacent material. It is also shown that the Coulomb frictional constant is more or less affected by the normal stress.

• Journal of the Korean Society of Combustion
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• v.13 no.4
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• pp.26-36
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• 2008

Experimental study is conducted to identify the existence of a shrinking flame disk and to clarify its flame characteristics through the inspection of critical mole fraction at flame extinction and edge flame oscillation at low strain rate flames. Experiments are made as varying global strain rate, velocity ratio, and burner distance. The transition from a shrinking flame disk to a flame hole is verified through gradient measurements of maximum flame temperature. The evidence of edge flame oscillation in flame disk is also provided through numerical simulation in microgravity. It is found at low strain rate flame disks in normal gravity that buoyancy effects are importantly contributing to lateral heat loss to burner rim, and is proven through critical mole fraction at flame extinction, edge flame oscillation, and measurements of flame temperature gradient along flame disk surface.

• Journal of the Korean Society of Combustion
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• v.15 no.1
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• pp.22-29
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• 2010

In this study, carbon conversion was measured using an electronic mass balance. In a lab scale furnace, each coal sample was pyrolyzed in a nitrogen environment and became coal char, which was then gasified with steam under isothermal conditions. The reactivity of coal char was investigated at various temperatures and steam concentrations. The VRM(volume reaction model), SCM(shrinking core model), and RPM(random pore model) were used to interpret experimental data. For each model the activation energy(Ea), pre-exponential factor (A), and reaction order(n) of the coal char-steam reaction were determined by applying the Arrhenius equation into the data obtained with thermo-gravimetric analysis(TGA). According to this study, it was found that experimental data agreed better with the VRM and SCM for 1,000 and $1,100^{\circ}C$, and the RPM for 1,200 and $1,300^{\circ}C$. The reactivity of chars increased with the increase of gasification temperature. The structure parameter(${\psi}$) of the surface area for the RPM was obtained.

• Korean Chemical Engineering Research
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• v.48 no.1
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• pp.16-19
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• 2010

Devolatilization characteristics of municipal wood waste were measured by using an isothermal thermogravimetric analyzer(TGA) and discussed. Volatile matter was mainly released at temperatures between $250^{\circ}C$ and $350^{\circ}C$. The volatile content increased with an increase of temperature but levelled off at temperatures ${\geq}527^{\circ}C$. The rate of devolatilization could be expressed by a shrinking particle model which was ruled by the reaction rate. The activation energy ranged from 13.1 to 18.5 kJ/g mol.