• 제목/요약/키워드: shift factor

검색결과 556건 처리시간 0.022초

A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction III. Modification of $Mo/γ-Al_2O_3$ Catalyst with Iron Group Metals

  • 박진남;김재현;이호인
    • Bulletin of the Korean Chemical Society
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    • 제21권12호
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    • pp.1233-1238
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    • 2000
  • $Mo/{\gamma}-Al_2O_3catalysts$ modified with Fe, Co, and Ni were prepared by impregnation method and catalytic activity for water gas shift reaction was examined. The optimum amount of Mo loaded for the reaction was 10 wt% $MoO_3$ to ${\gamma}-Al_2O_3.$ The catalytic activity of $MoO_3/{\gamma}-Al_2O_3was$ increased by modifying with Fe, Co, and Ni in the order of Co${\thickapprox}$ Ni > Fe. The optimum amounts of Co and Ni added were 3 wt% based on CoO and NiO to 10 wt% $MoO_3/{\gamma}-Al_2O_3$, restectively. The TPR (temperature-programmed reduction) analysis revealed that the addition of Co and Ni enganced the reducibility of the catalysts. The results of both catalytic activity and TPR experiments strongly suggest that the redox property of the catalyst is an important factor in water gas shift reaction on the sulfided Mo catalysts, which could be an evidence of oxy-sulfide redox mechanism.

Interdiffusion at Interfaces of polymers with Similar Physical Properties

  • 김운천;이창준;심훈구;박형숙
    • Bulletin of the Korean Chemical Society
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    • 제21권6호
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    • pp.577-582
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    • 2000
  • Interdiffusion process at interfaces of chemically identical polymers (e.g., deuterated-nondeuterated pairs) with different molecular weights or polymers with similar physical properties, is studied here by varying the diffusion time. Considering the vacancy flux ($J_v$) and adopting the Cahn-Hilliard interracial energy in describing this system, we can see that the variation of the interfacial composition profile with time is asymetric and the interface moves towards the polymer with the lower molecular weight as interdiffusion progresses. Furthermore, interface shift $\Delta\chi$, which characterizes the interdiffusion between polymers, agrees well with the behaviors of the existing experimental data. We can also obtain the interface shift factor C, which can be converted into values of $D_s$ (self-diffusion coefficient of the smaller molecules), from the slopes of the linear fits to the data of the interface shift.

리트벨트 해석법을 이용한 $Y_1Ba_2Cu_3O_x$ 고온 초전도체의 구조분석 (The structure analysis of $Y_1Ba_2Cu_3O_x$ high Tc superconductor based on rietveld method)

  • 채기병;소대화
    • E2M - 전기 전자와 첨단 소재
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    • 제8권6호
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    • pp.780-786
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    • 1995
  • For the execution of RIETAN program adopting Rietveld Analysis Method, the sample superconductor is made according to the solid state synthesis method at 920.deg. C for 24hrs, and was examined for the optimization of parameters needed to analyze Rietveld method with the input of the measured pattern data after measuring the pattern resulted from the X-ray diffraction. It was proven that the lattice constant of the superconductor which was consisted of Pmmm orthorhombic crystal structure in the analyzed space group correspond to the presented theoretical lattice constant a=3.8887(8).angs., b=3.8238(4).angs., c=11.7079.angs.. Therefore, it was examined and confin-ned that the R factor, which was compensated after analyzing the structure of superconductor resulted from this experimented data with the computer simulation, was refined to $R_{wp}$=8.83[%], $R_{P}$=6.47[%], $R_{I}$=10.08[%], $R_{F}$=7.19[%], $R_{E}$=3.76[%]. On the basis of these experimental data, the significant parameter such as the scale factor(S) and the zero point shift(Z) and FWHM value(U,V,W) were optimized as follows; S=2.0827E-3, Z=0.2146, U=4.2761E-2, V=1.7983E-2, and W=2.6768E-2.2.2.2.2.2.

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쌀 전분 젤의 creep 특성 (Compressive Creep Behavior of Rice Starch Gels)

  • 홍석인;김영숙;최동원;변유량
    • 한국식품과학회지
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    • 제24권2호
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    • pp.165-170
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    • 1992
  • 호화된 쌀 전분 젤의 creep 거동을 농도($30{\sim}45%$)와 온도($20{\sim}85^{\circ}C$)를 달리하여 측정하였으며 전분 젤의 점탄성에 미치는 온도와 농도의 영향은 shift factor($a_{T},\;a_{C}$)를 이용하여 분석하였다. Compression creep test의 결과 쌀 전분 젤은 순간변형 부분, 지연탄성 부분 및 유동부분으로 구성된 6-element의 역학적 모델로 해석할 수 있었으며 점탄성 거동은 순간변형 부분이 주체를 이루었다. 전분 농도가 $30{\sim}45%$로 증가함에 따라 creep compliance는 감소하였고 농도 증가는 주로 순간변형 부분에 영향을 미쳤다. 각 농도에서의 total compliance는 shift factor($a_{C}$)를 이용하여 일정한 기준농도(38%)로 변환시켜 농도불변 곡선으로 정확히 나타낼 수 있었다. 온도를 $20{\sim}85^{\circ}C$로 조절하여 얻은 creep compliance는 온도의 증가에 따라 증가하여 젤의 조직이 점점 연화되었다. $20^{\circ}C$를 기준온도로 shift factor($a_{T}$)에 의해 각 온토에서의 단편적 total compliance 곡선을 log(t)에 대해 수평이동시키면 전반적으로 부드럽게 연결되는 master curve를 얻을 수 있었으므로 시간-온도 환산법칙이 잘 성립되었다. 수정된 WLF식을 이용하여 $a_{T}$의 온도 의존성을 분석한 결과 전분 젤의 활성화에너지는 일정하지 않고 온도의 증가에 따라 감소하였으며, 공유결합에 의해 망상구조를 이루는 다른 젤들에 비해 그 값이 상대적으로 작았다.

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Efficient Design and Performance Analysis of a Hardware Right-shift Binary Modular Inversion Algorithm in GF(p)

  • Choi, Piljoo;Lee, Mun-Kyu;Kong, Jeong-Taek;Kim, Dong Kyue
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제17권3호
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    • pp.425-437
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    • 2017
  • For efficient hardware (HW) implementation of elliptic curve cryptography (ECC), various sub-modules for the underlying finite field operations should be implemented efficiently. Among these sub-modules, modular inversion (MI) requires the most computation; therefore, its performance might be a dominant factor of the overall performance of an ECC module. To determine the most efficient MI algorithm for an HW ECC module, we implement various classes of MI algorithms and analyze their performance. In contrast to the common belief in previous research, our results show that the right-shift binary inversion (RS) algorithm performs well when implemented in hardware. In addition, we present optimization methods to reduce the area overhead and improve the speed of the RS algorithm. By applying these methods, we propose a new RS-variant that is both fast and compact. The proposed MI module is more than twice as fast as the other two classes of MI: shifting Euclidean (SE) and left-shift binary inversion (LS) algorithms. It consumes only 15% more area and even 5% less area than SE and LS, respectively. Finally, we show that how our new method can be applied to optimize an HW ECC module.

일개 화장품 제조업체 근로자의 소음 인식도와 청력역치 조사에 관한 연구 (A study on recognition of noise and hearing threshold among workers in a cosmetics manufacturing factory)

  • 어원석;함완식;김현욱
    • 한국산업보건학회지
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    • 제21권3호
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    • pp.162-167
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    • 2011
  • To identify the relationship between types of job classification (typical and atypical) and the levels of recognition of noise and the hearing threshold shift, a total of 457 workers in a cosmetic company were studied utilizing a questionnaire and the audiometric hearing test. The results were analyzed by factor analysis, t-test, and general linear model, as appropriate. The results showed that atypical workers had higher level of noise recognition but had lower levels of hearing ability, noise exposure, and the knowledge on hearing loss prevention, compared with those of typical workers. The high noise level group of typical workers showed higher threshold shift levels than that of atypical workers. Significant differences were found at 4 kHz for both ears and in right ear only for hearing threshold shift after adjusting age.

직접대역확산방식 기술조사 및 분석 (Technical Survey and Analysis of DSSS)

  • 임유철;마근수;김명환;이재득
    • 항공우주기술
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    • 제10권1호
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    • pp.45-53
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    • 2011
  • 본 연구는 직접대역확산방식(DSSS)에 대한 기술검토 자료로서 현재까지 직접대역확산방식이 적용되고 있는 통신시스템들을 알아보고 각각의 주파수, 코드길이, 확산이득, 데이터 전송속도 등의 대역확산 규격에 대하여 소개한다. 또한 발사체에 직접대역확산방식을 적용하기 위해 고려되어야 하는 사항에 대하여 알아보고 특히 도플러천이(Doppler Shift)가 직접대역확산방식의 동기획득에 미치는 영향에 대하여 기존에 연구된 사례들을 조사하고 정리하였다. 도플러천이에 대한 영향을 다루는 이유는 발사체와 같이 빠르게 이동하는 시스템에 있어서 도플러천이는 DSSS시스템의 코드추적에 주요오차요인으로 작용한다. 따라서 시스템에 적용을 위해서는 이에 대한 검토가 필요하다.

Cyclic Shift Based Tone Reservation PAPR Reduction Scheme with Embedding Side Information for FBMC-OQAM Systems

  • Shi, Yongpeng;Xia, Yujie;Gao, Ya;Cui, Jianhua
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제15권8호
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    • pp.2879-2899
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    • 2021
  • The tone reservation (TR) scheme is an attractive method to reduce peak-to-average power ratio (PAPR) in the filter bank multicarrier with offset quadrature amplitude modulation (FBMC-OQAM) systems. However, the high PAPR of FBMC signal will severely degrades system performance. To address this issue, a cyclic shift based TR (CS-TR) scheme with embedding side information (SI) is proposed to reduce the PAPR of FBMC signals. At the transmitter, four candidate signals are first generated based on cyclic shift of the output of inverse discrete Fourier transform (IDFT), and the SI of the selected signal with minimum peak power among the four candidate signals is embedded in sparse symbols with quadrature phase-shift keying constellation. Then, the TR weighted by optimal scaling factor is employed to further reduce PAPR of the selected signal. At the receiver, a reliable SI detector is presented by determining the phase rotation of SI embedding symbols, and the transmitted data blocks can be correctly demodulated according to the detected SI. Simulation results show that the proposed scheme significantly outperforms the existing TR schemes in both PAPR reduction and bit error rate (BER) performances. In addition, the proposed scheme with detected SI can achieve the same BER performance compared to the one with perfect SI.

건강증진을 위한 한의학적 방법론 연구 -야간근로와 음허증의 상관관계를 중심으로- (A Study on the Method of Health Promotion in Korean Medicine: Correlation between Night-shift Work and Yin-deficiency)

  • 이상재;박종배;이선동;김광호
    • 동의생리병리학회지
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    • 제18권2호
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    • pp.344-348
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    • 2004
  • This study regarded irregular life styles such as nigh-shifts as contrary to the norm advised in the rules of Yang-saeng to analyze the problems brought about in relation to the concept of 'Yin-deficiency syndrome'. Yin-deficiency survey was given to sales workers on a big shopping mall in Seoul to compare the measurements of daytime workers to those of nigh-shift workers. The measurement of complaining symptoms related to Yin-deficiency of daytime workers and night-shift workers were compared, In comparison of the daytime workers and the night-shift workers, night-shift workers showed higher measurements than the daytime workers in the item of irritable fever on the five Hearts, flushing of the zygomatic region in the afternoon, tidal fever, dizziness, insomnia, yellow and scanty urination, and constipation. Especially tidal fever, insomnia, and constipation showed statistically significant difference. The total of ten items consisting of Yin-deficiency-related symptoms showed statistically significant high score in night-shift workers than the daytime workers. 'Factors for deficiency-type Heat' consisting of irritable fever on the five Hearts, flushing of the zygomatic region in the afternoon, tidal fever, and dried mouth and throat showed statistically significant high score in night-shift workers than the daytime workers. 'Accompanying factors' consisting of night sweats, emaciation, dizziness, insomnia, yellowish and scanty urination, and constipation also showed statistically and significantly high score in night-shift workers than the daytime workers. From the above results that night-shift workers show high degree of Yin-deficiency than daytime workers, and those overworking irregularly also show high degree of Yin-deficiency than those who work for adequate amount of time regularly implies that sitting up at night for work and sleeping at daytime, excessive work, and irregular life styles all function as high-risk factor for Yin-deficiency.

충청남도 5개 군의 GRDP 변화요인 분석 (An Analysis on the Change Factor Based on the Industrial GRDP of 5 Gun in Chungcheongnam-do)

  • 김정태
    • 농촌지도와개발
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    • 제19권4호
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    • pp.1041-1066
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    • 2012
  • 농촌정책의 중요한 과제는 농촌 지역경제 활성화인데, 대다수 연구와 정책은 농업인과 농업을 중심으로 전개되고 있다. 그러나 지역경제 활성화는 지역 내의 다양한 산업이 얽혀 내외부의 변화에 반응하는 것으로 어느 한 부분의 성장만으로 농촌 지역경제 활성화는 달성되기 어렵다. 본 연구는 이러한 문제점을 바탕으로 충청남도 5개 군을 대상으로 농촌지역에서 농업부문의 위치를 살펴보고, 농촌에 위치한 산업별 변화요인을 살펴보았다. 분석결과 5개 군에서 농림어업은 수위산업으로서 역할을 담당하고 있으며, 지역 내부요인인 지역산업효과, 지역경쟁효과가 매우 취약함을 보여 5개 군에서 지역경제 활성화를 위해서는 위와 관련한 요인들의 성장을 위한 노력이 필요한 것으로 분석되었다. 또한 농림어업부분은 지역 외부효과에 의해 영향을 많이 받고 있었으며, 도소매업, 숙박 및 음식점업 등 농촌 지역에 기초수요를 제공하는 산업부문의 감소가 두드러지게 나타나고 있었다. 이러한 연구결과가 농촌지역에 주는 시사점은 다음과 같다. 우선 농림어업 내 생산물의 지역내 소비와 연결시키는 노력을 통해 지역산업과 연결시키는 개선이 필요할 것이며, 농촌지역 주민의 기초서비스를 제공하는 업종의 보호를 위한 정책적 수단마련을 위해 읍면소재지 개발 등의 사업내용에 소상공인 지원을 위한 사업내용의 고려가 필요하다.