• Title/Summary/Keyword: shear flow dispersion

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Experimental Study on the Reological Properties of Carbon Nano Materials as Cement Composites (탄소계 나노소재를 적용한 시멘트 페이스트 복합체의 유변학적 특성에 대한 연구)

  • Kim, Won-Woo;Moon, Jae-Heum;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.227-234
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    • 2022
  • In this study, the rheological properties of cement paste composites applied with carbon-based nano-materials were experimental analyzed. Flow table and rheological properties, compressive strength were measured in the cement paste using graphene oxide asqueous solution and carbon nanotube aqueous solution. When carbon nano-materials was mixed in an aqueous solution, flow decreased and plastic viscosity and shear stress were increased. In particular, graphene oxide rapidly increased the plastic viscosity and shear stress. In the case of carbon nanotube aqueous solution, when less than 0.2 % was mixed, the increase rate was low compared to graphene oxide. This is because the specific surface area of graphene, which is in the form of a plate, is large. The compressive strength showed a small amount in strength increase when graphene mix, and CNT had a strength about 112 % of OPC. Carbon-based nanomaterials, is considered that CNT are suitable more to be used construction materials. However, extra studies on the surfactant to be used for mixing proportion and dispersion will be needed.

Effect of Nanotube Length on Rheological Characteristics of Polystyrene/Multi-walled Carbon Nanotube Nanocomposites Prepared by Latex Technology (라텍스 기법으로 제조한 폴리스티렌/다중벽 탄소나노튜브 나노복합재료의 나노튜브 길이가 유변학적 특성에 미치는 영향)

  • Woo, Dong-Kyun;Noh, Won-Jin;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.34 no.6
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    • pp.534-539
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    • 2010
  • Polystyrene (PS)/multi-walled carbon nanotube (MWCNT) nanocomposites were prepared via latex technology and the effect of nanotube length on rheological properties were investigated. Monodisperse PS particle was synthesized by the emulsifier-free emulsion polymerization and two types of MWCNTs were used after surface modification to improve dispersion state and to remove impurities. Final nanocomposites were prepared by the freeze-drying process after dispersing the PS particles and the surface-modified MWCNTs in a ultrasonic bath. The effects of MWCNT content and nanotube length on rheological properties were evaluated by imposing the small-amplitude oscillatory shear flow. The PS/MWCNT nanocomposites showed that rheological properties were enhanced as the amount and length of MWCNT increased. It is speculated that the rheological characteristics of nanocomposites change from liquid-like to solid-like as the MWCNT amount increases, and the critical concentration to achieve network structure decreases as the nanotube length increases.

Swelling and Pasting Properties of Non-Waxy Rice Flour/Food Gum Systems

  • Song, Ji-Young;An, Young-Hyun;Kim, Jae-Suk;Choi, Jung-Do;Kim, Young-Chang;Shin, Mal-Shick
    • Food Science and Biotechnology
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    • v.15 no.2
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    • pp.207-213
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    • 2006
  • The effects of gellan gum (from S. paucimobilis), EPS-CB (exopolysaccharide from S. chungbukensis), and a series of commercial gums (arabic gum, xanthan gum, guar gum, deacyl gellan gum), on the swelling, rheological, and pasting properties of non-waxy rice flour dispersions were investigated. The swelling properties of rice flours in gellan or guar gum dispersion after heating were found to have increased with increasing gum concentrations, but the swelling properties of rice flour/other gum systems decreased with increasing concentrations. The rice flour/gum mixtures showed high shear-thinning flow behavior (n=0.14-0.32), and consistency index (K) was higher in guar gum than other gum dispersions. The initial pasting temperatures and peak times increased along with increasing gum concentration. The peak viscosity of rice flour increased in guar gum and deacyl gellan dispersions, and the breakdown and setback viscosity of the rice flour paste was lowest in the xanthan gum system, but remained higher than those of the control. The apparent viscosities of the rice flour/gellan gum mixture pastes were the highest among the tested combinations.

Analysis of Shear Flow Dispersion Using Sequential Mixing Model (순차혼합모형에 의한 전단류 분산 해석)

  • Seo, Il-Won;Son, Eun-Woo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.991-995
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    • 2005
  • 본 연구에서는 1차원 이송-분산 과정을 연구하고 전단류 흐름 및 분산거동에 있어 Taylor 이론의 핵심이라 할 수 있는 '종방향 이송과 횡방향 확산의 균형'을 기본 개념으로 하여, 이송과 확산을 분리하여 이 두 과정이 순차적으로 발생한다는 가정에 의거한 순차혼합모형을 제시하였다. 본 모형에서는 가상의 하천을 여러 개의 행과 종방향 거리를 길이가 일정한 구획으로 나누어 연속적인 분산과정을 이산적인 형태로 나타낼 수 있게 하고, 횡방향 유속분포에 따라 각 행에 각기 다른 유속을 할당한다. 오염물질은 하폭방향 선오염원으로 원점에 순간주입되며, 주어진 혼합시간 $t_m$ 동안 각 행의 오염물질들이 각자에 할당된 유속을 따라 진행하고 진행이 끝난 후 횡방향 확산이 순간적으로 이루어진다. 횡방향 확산은 횡방향으로 완전하게 일어남을 가정하여, 횡방향 확산이 끝나면 각 열에서의 농도 평균값이 할당된다. 이러한 혼합시간 $t_m$ 동안의 순차적인 이송-확산 과정이 반복되면서 오염물질의 분산이 일어나며, 농도 분포 그래프를 그릴 수 있게 된다. 순차혼합모형을 가상의 직선하천에 적용하여 종분산계수를 유도하였는데, 본 연구에서 유도된 종분산계순식은 Fischer.가 제안한 식과 유사한 형태로 나타남을 알 수 있었다. 본 모형에서 계산된 농도분포 곡선을 해석해와 비교한 결과,두 곡선이 적절히 일치함을 확인할 수 있었으며 해석해와의 비교를 통해 종분산계수 K가 혼합시간 $t_m$과 선형관계임을 확인할 수 있었다. 수심대하폭비에 따라 각기 다른 유속분포에 적용하여 종분산계수 K가 유속편차강도의 제곱에 비례관계에 있음이 밝힐 수 있었다. 수압은 $4.69kg/cm^2$으로 나타났다. 밸브 개폐도가 $100\%$일 때가 밸브를 $60\%$$80\%$ 개폐시켰을 때보다 $0.3kg/cm^2,\;0.29kg/cm^2$ 낮게 나타나 밸브를 전체 개방 했을 때 관로내의 수압이 상수설계기준에 적합한 수압을 유지함을 알 수 있다. 상수관로 설계 기준에서는 관로내 수압을 $1.5\~4.0kg/cm^2$으로 나타내고 있는데 $6kg/cm^2$보다 과수압을 나타내는 경우가 $100\%$로 밸브를 개방하였을 때보다 $60\%,\;80\%$ 개방하였을 때가 더 빈번히 발생하고 있으므로 대상지역의 밸브 개폐는 $100\%$ 개방하는 것이 선계기준에 적합한 것으로 나타났다. 밸브 개폐에 따른 수압 변화를 모의한 결과 밸브 개폐도를 적절히 유지하여 필요수량의 확보 및 누수방지대책에 활용할 수 있을 것으로 판단된다.8R(mm)(r^2=0.84)$로 지수적으로 증가하는 경향을 나타내었다. 유거수량은 토성별로 양토를 1.0으로 기준할 때 사양토가 0.86으로 가장 작았고, 식양토 1.09, 식토 1.15로 평가되어 침투수에 비해 토성별 차이가 크게 나타났다. 이는 토성이 세립질일 수록 유거수의 저항이 작기 때문으로 생각된다. 경사에 따라서는 경사도가 증가할수록 증가하였으며 $10\% 경사일 때를 기준으로 $Ro(mm)=Ro_{10}{\times}0.797{\times}e^{-0.021s(\%)}$

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Numerical Hydrodynamic Modeling Incorporating the Flow through Permeable Sea-Wall (투수성 호안의 해수유통을 고려한 유동 수치모델링)

  • Bang, Ki-Young;Park, Sung Jin;Kim, Sun Ou;Cho, Chang Woo;Kim, Tae In;Song, Yong Sik;Woo, Seung-Buhm
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.25 no.2
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    • pp.63-75
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    • 2013
  • The Inner Port Phase 2 area of the Pyeongtaek-Dangjin Port is enclosed by a total of three permeable sea-walls, and the disposal site to the east of the Inner Port Phase 2 is also enclosed by two permeable sea-walls. The maximum tidal range measured in the Inner Port Phase 2 and in the disposal site in May 2010 is 4.70 and 2.32 m, respectively. It reaches up to 54 and 27%, respectively of 8.74 m measured simultaneously in the exterior. Regression formulas between the difference of hydraulic head and the rate of interior water volume change, are induced. A three-dimensional numerical hydrodynamic model for the Asan Bay is constructed incorporating a module to compute water discharge through the permeable sea-walls at each computation time step by employing the formulas. Hydrodynamics for the period from 13th to 27th May, 2010 is simulated by driving forces of real-time reconstructed tide with major five constituents($M_2$, $S_2$, $K_1$, $O_1$ and $N_2$) and freshwater discharges from Asan, Sapkyo, Namyang and Seokmoon Sea dikes. The skill scores of modeled mean high waters, mean sea levels and mean low waters are excellent to be 96 to 100% in the interior of permeable sea-walls. Compared with the results of simulation to obstruct the flow through the permeable sea-walls, the maximum current speed increases by 0.05 to 0.10 m/s along the main channel and by 0.1 to 0.2 m/s locally in the exterior of the Outer Sea-wall of Inner Port. The maximum bottom shear stress is also intensified by 0.1 to 0.4 $N/m^2$ in the main channel and by more than 0.4 $N/m^2$ locally around the arched Outer Sea-wall. The module developed to compute the flow through impermeable seawalls can be practically applied to simulate and predict the advection and dispersion of materials, the erosion or deposion of sediments, and the local scouring around coastal structures where large-scale permeable sea-walls are maintained.