• 제목/요약/키워드: shear flow dispersion

검색결과 45건 처리시간 0.035초

Structure Analyses of Rubber/Filler System under Shear Flow by Using Time Resolved USAXS Method

  • Nishitsuji, Shotaro;Takenaka, Mikihito;Amino, Naoya;Ishikawa, Yasuhiro
    • Elastomers and Composites
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    • 제54권2호
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    • pp.156-160
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    • 2019
  • The changes in the dispersion of carbon black in liquid polyisoprene under shear flow with time have been investigated by time-resolved ultra small-angle X-ray scattering (USAXS) method. The analyses of USAXS profile immediately after the start of shear flow clarified that the aggregates of carbon black with a mean radius of gyration of 14 nm and surface fractal dimension of 2.5 form the fractal network structure with mass-fractal dimension of 2.9. After the application of the shear flow, the scattering intensity increases with time at the observed whole entire q region, and then the a shoulder appears at $q=0.005nm^{-1}$, indicating that the agglomerate is broken and becomes smaller by shear flow. The analysis by the Unified Guinier/Power-law approach yielded several characteristic parameters, such as the sizes of aggregate and agglomerate, mass-fractal dimension of agglomerate, and surface fractal dimension of the primary particle. While the mean radius of gyration of the agglomerate decreases with time, the mean radius of gyration of the aggregate, mass fractal dimension, and surface fractal dimension don't change with time, indicating that the aggregates peel off the surface of the agglomerate.

Sodium bis-(2-ethylhexyl)sulfosuccinate-water 미셀의 틱소트로 피와 다일레턴시 유동단위에 대한 비뉴톤 유동메카니즘 (Non-Newtonian Flow Mechanism for Thixotropic and Dilatant Flow Units of Sodium bis-(2-ethylhexyl)sulfosuccinate-water Micelles)

  • 김남정
    • 한국응용과학기술학회지
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    • 제33권3호
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    • pp.540-548
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    • 2016
  • sodium bis-(2-ethylhexyl)sulfosuccinate-water 라멜라 액정의 비뉴톤 유동곡선을 cone-plate 레오메타를 사용하여 여러 농도와 온도 조건에서 얻었다. 이러한 비뉴톤 유동곡선을 비뉴톤 유동식에 적용하여 유동파라메타를 구하였다. 특별히 주목할 점은 액정시료의 전단속도에 대한 전단응력은 증가와 감소에서 틱소트로피와 다일레턴시 현상을 보여 hysteresis loop를 나타내고 있다는 점이다. sodium bis-(2-ethylhexyl)sulfosuccinate-water 라멜라 액정은 작은 전단속도에서는 약한 젤 현상을 보이지만 응력이 한계 응력 이상에서는 비 선형 점탄성 성질을 나타낸다. 전단속도 감소에서 분산계는 전단속도가 증가할 때 측정된 값 보다는 큰 구조변화와 전단응력을 유지하고 있다.

Numerical and wind tunnel simulation of pollutant dispersion in the near wake of buildings

  • Wang, X.;McNamara, K.F.
    • Wind and Structures
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    • 제8권6호
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    • pp.427-442
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    • 2005
  • Numerical and wind tunnel simulations of pollutant dispersion around rectangular obstacles with five aspect ratios have been conducted in order to identify the effects of flow patterns induced by buildings on plume dispersion in the near wake of buildings. An emission from a low source located upwind of obstacles was used in this simulation. The local flow patterns and concentrations around a cubical obstacle were initially investigated using three RANS turbulence models, (the standard $k-{\varepsilon}$, Shear Stress Transport (SST), Reynolds-Stress RSM turbulence model) and also using Large-eddy simulation (LES). The computed concentrations were compared with those measured in the wind tunnel. Among the three turbulence models, the SST model offered the best performance and thus was used in further investigations. The results show, for normal aspect ratios of width to height, that concentrations in the near wake are appreciably affected because of plume capture by the horseshoe vortex and convection by the vertical vortex pairs. These effects are less important for high aspect ratios. Vertical vortex pairs present a strong ability to exchange mass vertically and acts efficiently to reduce ground-level concentrations in the near wake.

A CFD Study of Near-field Odor Dispersion around a Cubic Building from Rooftop Emissions

  • Jeong, Sang Jin
    • Asian Journal of Atmospheric Environment
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    • 제11권3호
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    • pp.153-164
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    • 2017
  • Odor dispersion around a cubic building from rooftop odor emissions was investigated using computational fluid dynamics (CFD). The Shear Stress Transport (here after SST) $k-{\omega}$ model in FLUENT CFD code was used to simulate the flow and odor dispersion around a cubic building. The CFD simulations were performed for three different configurations of cubic buildings comprised of one building, two buildings or three buildings. Five test emission rates were assumed as 1000 OU/s, 2000 OU/s, 3000 OU/s, 4000 OU/s and 5000 OU/s, respectively. Experimental data from wind tunnels obtained by previous studies are used to validate the numerical result of an isolated cubic building. The simulated flow and concentration results of neutral stability condition were compared with the wind tunnel experiments. The profile of streamline velocity and concentration simulation results show a reasonable level of agreement with wind tunnel data. In case of a two-building configuration, the result of emission rate 1000 OU/s illustrates the same plume behavior as a one-building configuration. However, the plume tends to the cover rooftop surface and windward facet of a downstream building as the emission rate increases. In case of a three-building configuration, low emission rates (<4000 OU/s) form a similar plume zone to that of a two-building configuration. However, the addition of a third building, with an emission rate of 5000 OU/s, creates a much greater odorous plume zone on the surface of second building in comparison with a two-building configuration.

Ag Pastes의 분산 특성 및 스크린 인쇄된 OTFTs용 전극 물성 (Dispersion Characteristics of Ag Pastes and Properties of Screen-printed Source-drain Electrodes for OTFTs)

  • 이미영;남수용
    • 한국전기전자재료학회논문지
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    • 제21권9호
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    • pp.835-843
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    • 2008
  • We have fabricated the source-drain electrodes for OTFTs by screen printing method and manufactured Ag pastes as conductive paste. To obtain excellent conductivity and screen-printability of Ag pastes, the dispersion characteristics of Ag pastes prepared from two types of acryl resins with different molecular structures and Ag powder treated with caprylic acid, triethanol amine and dodecane thiol as surfactant respectively were investigated. The Ag pastes containing Ag powder treated with dodecane thiol having thiol as anchor group or AA4123 with carboxyl group(COOH) of hydrophilic group as binder resin exhibited excellent dispersity. But, Ag pastes(CA-41, TA-41, DT-41) prepared from AA4123 fabricated the insulating layer since the strong interaction between surface of Ag powder and carboxyl group(COOH) of AA4123 interfered with the formation of conduction path among Ag powders. The viscosity behavior of Ag pastes exhibited shear-thinning flow in the high shear rate range and the pastes with bad dispersion characteristic demonstrated higher shear-thinning index than those with good dispersity due to the weak flocculated network structure. The output curve of OTFT device with a channel length of 107 ${\mu}m$ using screen-printed S-D electrodes from DT-30 showed good saturation behavior and no significant contact resistance. And this device exhibited a saturation mobility of $4.0{\times}10^{-3}$ $cm^2/Vs$, on/off current ratio of about $10^5$ and a threshold voltage of about 0.7 V.

국내산 조전분 호화액의 유동특성 (Rheological Properties of Gelatinized Millet Starch Dispersions)

  • 김남수;남영중
    • 한국식품과학회지
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    • 제21권6호
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    • pp.742-748
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    • 1989
  • 국내산 메조 및 차조의 호화전분액의 농도와 온도에 따른 유동특성을 구명하였다. 메조 및 차조의 호화전분액은 의가고성 유체의 성질을 보여주었으며, 각각의 호화전분액 농도에서 일정 전단속도에 대한 전단응력의 크기는 메조전분보다 차조전분이 높았다. 메조와 차조의 호화전분액의 유동특성은 지수법칙에 잘 적용되었으며 이 때 유동지수 n값은 1% 호화전분액에 있어 메조전분의 경우 0.96, 차조전분의 경우 0.74이나, 5% 호화전분액에 있어서는 메조전분의 경우 0.35, 차조전분의 경우 0.24로 농도증가에 따라 의가소성이 증대되었다. 점조도지수 K값의 경우 농도의존성이 보다 현저하였다. 조전분 호화액은 일정농도 이상에서 항복응력을 보이며, 이 때 농도와 항복응력의 평방근 사이에는 직선관계가 있었고 항복응력이 영이되는 호화전분액 농도는 메조전분의 경우 2.19%, 차조전분의 경우 1.69%로 예측되었다. 3% 조전분 호화액에 대하여 온도에 따른 유동특성을 분석시 일정 전단속도에 대한 전단 응력의 크기는 온도가 낮아짐에 따라 증가하였으며, 특히 $20^{\circ}C$의 측정온도에서 이런 현상이 현저하였다. 이때, 측정온도가 높아지면 유동지수 n값은 증가하고 점조도지수 K값은 감소하였는데 이는 메조 및 차조전분에 공통적인 현상이었다. 점조도지수 K값과 온도와의 관계는 아레니우스 식에 잘 적용되었으며, 3% 호화전분액의 경우 활성화에너지는 메조전분의 경우 2.89kcal/mol, 차조전분의 경우 3.18kca1/mo1이었다.

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Rheological characteristics of non-spherical graphite suspensions

  • Mustafa, Hiromoto Usui;Ishizuki, Masanari;Shinge, Ibuki;Suzuki, Hiroshi
    • Korea-Australia Rheology Journal
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    • 제15권1호
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    • pp.19-25
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    • 2003
  • Since the microstructure of functional thin films depends on the dispersion characteristics of dense slurry, it is important to control the agglomerative nature of slurries under processing. The present authors have been discussing the model prediction of agglomerative nature and local rate of agglomeration in dense suspensions. The experiments have been peformed under shear flow using the nearly spherical and oblate type graphite particles. In this study, the experiment has been conducted using water and glycerol as dispersion media. Stress control type rheometer was used to measure the slurry rheology. Local agglomeration of graphite particles has been predicted by using Usui's model. The experimental results show that both the shape and slurry processing method affect on the local dispersion condition. The agglomeration formed by oblate type graphite particles seems to be more difficult to break up than that of spherical particles.

Electrical and Rheological Behavior of the Anhydrous ER Fluids Based on Chitosan Derivatives as the Dispersion Phases

  • Choi Ung-su;Sung Bo-hyun
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2004년도 학술대회지
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    • pp.323-329
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    • 2004
  • The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphate suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18 ,1.41 and 1.67 powers of the electric field. On the basis of the experimental results, the newly synthesized chitosan derivative suspensions found to be an ER fluid.

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Electrical and Rheological Behavior of the Angydrous ER Fluids Based on Chitosan Derviatives as the Dispersion Phases

  • 최웅수
    • KSTLE International Journal
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    • 제5권2호
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    • pp.49-51
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    • 2004
  • The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphated suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18, 1.41 and 1.67 powers of the electric field. On athe basis of the experimental results, the newly synthesized chitosan dervative suspensions found to be an ER fluid.