• Title/Summary/Keyword: sharp temperature change

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High Temperature Oxidation Behavior of Plasma Sprayed $ZrO_2$ Having Functionally Gradient Thermal Barrier Coating

  • Park, Cha-Hwan;Lee, Won-Jae;Cho, Kyung-Mox;Park, Ik-Min
    • Corrosion Science and Technology
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    • v.2 no.3
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    • pp.155-160
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    • 2003
  • Plasma spraying technique was used to fabricate functionally graded coating (FGC) of NiCrAIY/YSZ 8wt%$Y_2O_3-ZrO_2$ on a Co-base superalloy (HAYNES 188) substrate. Six layers were coated on the substrate for building up compositionally graded architecture. Conventional thermal barrier coating (TBC) of NiCrAIY/SZ with sharp interface was also fabricated. As-coated FGC and TBC samples were exposed at the temperature of $1100^{\circ}C$ for 10, 50, 100 hours in air. Microstructural change of thermally exposed samples was examined. Pores and microcracks were formed in YSZ layer due to evolution of thermal internal stress at high temperature. The amount of pores and microcracks in YSZ layer were increased with increasing exposure time at high temperature. High temperature oxidation of coatings occurred mainly at the NiCrAIY/YSZ interface. In comparison with the case of TBC. the increased area of the NiCrAIY/YSZ interface in FGC is likely to attribute to forming the higher amount of oxides.

Growth of Clostridium thermobutyricum: a Cellulolytic Thermophile

  • Kuk, Seung-Uk;Hong, Seung-Suh
    • Journal of Microbiology and Biotechnology
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    • v.2 no.4
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    • pp.293-296
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    • 1992
  • Increased concentrations of yeast extract led to increased growth yields and faster growth rates of the newly isolated Clostridium thermobutyricum. This species produced butyrate as its main fermentation product from glucose as well as from yeast extract. In the presence of peptone or tyrptone and during growth on agar, up to 70% of the cells sporulated. Growth yields were 30 and 55 g per mole glucose in the presence of 0.05 and 2.0% yeast extract, respectively. The Arrhenius graph was biphasic, exhibiting an intermediary plateau around $38^{\circ}C$ with a concomitant change in the Arrhenius energy. The optimum temperature was $55^{\circ}C$. An unusually sharp decline in the growth rate occurred above $59^{\circ}C$ .

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Characteristics of Visible Laser Diode and Its Injection-Locking (가시광 다이오드 레이저의 스펙트럼 및 주입-잠금 특성분석)

  • 남병호;박기수;권진혁
    • Korean Journal of Optics and Photonics
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    • v.5 no.2
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    • pp.278-285
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    • 1994
  • We investigated the spectral characteristics for temperature and driving current change in visible laser diode. As a result of spectrum analysis, the ratio of frequency change for temperature and driving current change were about $33 GHz/^{\circ}C$, 6.6 GHz/mA in the region which was not mode hopping range. Compared to the sharp mode hopping in the near IR single mode AlGaAs lasers, the visible laser diode showed relatively broad multimode operation in the mode hopping region. We performed the experiment of injection-locking characteristics analysis for visible laser diode. Locking half bandwidth(LHBW) was measured 0~5.0 GHz for $0~25\muW$ input power and it was dependent on the input power. Also, LHBW for polarization angle was dependent on the difference of polarization angle between master laser and slave laser. The phase change of injection-locked output beam of the slave laser diode as a function of the drive current was measured in the interferometer which was composed of master laser and slave laser. The ratio of phase change with the slope of 5.0~1.3 rad/mA was obtained within injection-locking range for the change of $2~25\muW$ input power. power.

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Temperature Variations of Air Pocket in Type-3 Composite Vessel during Ambient Hydraulic Cycling Test (상온 수압반복시험 시 Type 3 복합재용기 내 공기층의 온도변화)

  • Cho, Sung-min;Kim, Kwang Seok;Kim, Chang Jong;Lyu, Geun-jun;Lee, Yeon-jae;Jo, Yun Seong;Lyu, Sung-Ki
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.14 no.5
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    • pp.120-125
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    • 2015
  • This research aims to increase the reliability and reproducibility of the ambient cycling test by properly making corrections to the test procedure. The vessel (106 L) is initially filled with 70 L of water and horizontally placed on a balance. The pressure range inside the vessel varies from 2.5 to 25.9 MPa at the frequency of 6 cycles per minute. After reviewing the results, there was a temperature difference of approximately $10^{\circ}C$ between the air pocket and the water, and the upper part of the liner faced a repeated temperature change of $40^{\circ}C$. It is possible for the aluminum liner of the composite vessel to be damaged by such a sharp change in temperature. Additionally, as a result, no pass having anything to do with the purpose of the test would occur. Therefore, it is suggested that the air pocket be completely removed.

A Policy Suggestion for the Adaptation of Climate Change in Korea (우리나라의 기후변화 대응방안에 관한 정책 제언)

  • Shin, Im Chul;Kim, Yeongsin
    • Atmosphere
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    • v.19 no.1
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    • pp.53-66
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    • 2009
  • The purpose of this study is to describe the roles of carbon dioxide in the climate change, and carbon dioxide reduction policies in some countries. In addition, ways to cope with climate change in Korea are also discussed. Currently, global temperatures are rising due to the carbon dioxide produced by human beings. Global temperatures will rise approximately $6^{\circ}C$ until 2100 if we emit carbon dioxide at a present rate. Temperature rise will affect the terrestrial and oceanic resources, and ultimately influence the socio-economic structures including political stability. Most of the carbon dioxide comes from fossil fuels. Therefore, it is urgent to reduce the use of energy, which comes from fossil fuels. Solving the climate change due to the increases in carbon dioxide is a global problem. Korea should participate in the international community and cooperate with each other in order to reduce the carbon dioxide concentration. No policy was announced for the reduction of carbon dioxide so far. Korea should make a policy for the reduction of carbon dioxide in a specific year compared to that of certain standard year such as 1990 or 2005. Making policy should be based on the scientific result of the amount of carbon dioxide emitted and absorbed. Germanwatch announced the Climate Change Performance Index (CCPI) in order to evaluate an effort to reduce the carbon dioxide for 56 countries which emits 90 % of global carbon dioxide. Ranking for Korea is 51 among 56 countries. This clearly indicates that the appropriate carbon dioxide reduction has not been exercised yet in Korea. Researchers have a moral responsibility to provide updated new ideas and knowledges regarding climate change. Politicians should have a sharp insight to judge the ideas provided by researchers. People need an ethics to reduce the carbon dioxide in every day's life. Scientific research should not be influenced by stress caused by external budget and negative impact of capitalism. Science should be based on the pure curiosity.

Thermotropic Liquid Crystalline Behavior of [4-{4'-(Nitrophenylazo)phenoxycarbonyl}]alkanoated Celluloses ([4-{4'-(니트로페닐아조)펜옥시카보닐}]알카노화 셀룰로오스들의 열방성 액정 거동)

  • Jeong, Seung-Yong;Ma, Yung-Dae
    • Polymer(Korea)
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    • v.33 no.1
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    • pp.58-66
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    • 2009
  • The thermotropic liquid crystalline behavior of the homologous series of cellulose tri[4-{4'-(nitrophenylazo) phenoxycarbonyl}] alkanoates (NACEn, n=2$\sim$8, 10, the number of methylene units in the spacer) have been investigated. All of the homologoues formed monotropic nematic phases. The isotropic-nematic transition temperature ($T_{iN}$) decreased when n is increased up to 7, but it became almost constant when n is more than 7. The plot of transition entropy at $T_{iN}$ against n had a sharp negative inflection at n=7. The sharp change at n=7 may be attributed to the difference in arrangement of the side groups. The melting temperature ($T_m$) and associated entropy change at $T_m$, in contrast with $T_{iN}$ and associated entropy change at $T_{iN}$, exhibited a distinct odd-even effect, suggesting that the average shape of the side chains in the crystalline phase is different from that in the nematic phase. The thermal stability and degree of order of the nematic phase observed for NACEn were significantly different from those reported for the homologous series of side-chain and combined type liquid crystal polymers bearing azobenzene or biphenyl units in the side chains. The results were discussed in terms of the differences in the chemical structure, the flexibility of the main chain, the mode of chemical linkage of the side group with the main chain, and the number of the mesogenic units per repeating unit.

Variation of Supersonic Aircraft Skin Temperature under Different Mach number and Structure (비행마하수와 형상에 따른 초음속 항공기 표면온도 변화)

  • Cha, Jong Hyun;Kim, Taehwan;Bae, Ji-Yeul;Kim, Taeil;Jung, Daeyoon;Cho, Hyung Hee
    • Journal of the Korea Institute of Military Science and Technology
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    • v.17 no.4
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    • pp.463-470
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    • 2014
  • Stealth technology of combat aircraft is most significant capability in recent air battlefield. As the detector of IR missiles is being developed, IR stealth capability which is evaluated by IR signature level become more important than it was in previous generation. Among IR signature of aircraft from various sources, aerodynamic heating dominates in long-wavelength IR spectrum of $8{\sim}12{\mu}m$. Skin temperature change by aerodynamic heating which is derived by effects of Mach number and structure. The 4th and 5th generation aircraft are selected for calculation of the skin temperature, and its height and velocity in numerical conditions are 10,000 m and Ma 0.9~1.9 respectively. Aircraft skin temperature is calculated by computing convection of fluid and conduction, convection and radiation of surface. As the aircraft accelerates to higher Mach number, maximum skin temperature increases more rapidly than average temperature and temperature distribution changes in more sharp, interactive ways. The 4th generation aircraft whose shape is more complex than that of the 5th generation aircraft have complicated temperature distribution. On the other hand, the 5th generation aircraft whose shape is relatively simple shows plain temperature distribution and lower skin temperature in terms of both average and maximum value.

Effects of Al and Ti Additons on Microstructure in Fe-xCrAlloy for Electrical Resistance Wire. (전기저항선용 Fe-xCr합금의 미세조직에 미치는 Al 및 Ti첨가의 영향)

  • 최수정;박수동;이희웅;김봉서
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.108-110
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    • 2000
  • The aim of this paper is to investigate the effect of Al and Ti on microstructure of Fe-Cr-Al alloy systems for applying electrical resistance wires of electrical furnace. From the preliminary study, the amount of recovered addition elements increased in the case of both vacuum and Ar-atmosphere melting than that in the case of air-atmosphere melting. Also, optimum Cr content for good performance at high temperature was approximately 24wt% from the observation of microstucture. The precipitates of Fe-Cr, Al-Cr and Al phases were observed, adding Al and Ti. Especially, Sharp rectangular shapes of precipitates were observed with increasing amount of Ti.

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ANNEALING BEHAVIOR OF FeN THIN FILMS

  • Park, S.;Choi, Y.;Jo, S.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.636-640
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    • 1995
  • FeN thin films were deposited on glass by RF diode reactive sputtering. The films were annealed in the air and in vacuum. The film annealed in the air showed sharp decrease of saturation magnetization and change of easy axis direction to hard axis direction and vice versa after $300^{\circ}C$ anneal. The coercivity decreased down to 0.5 Oe after $400^{\circ}C$ anneal. After $450^{\circ}C$ anneal, the film showed ${\varepsilon}-Fe_{2-3}N$ phase. The films annealed in vacuum showed coercivity increase after $300^{\circ}C$ anneal for the film deposited with initial substrate temperature of $35^{\circ}C$ and after $400^{\circ}C$ anneal for the film deposited with initial substrate temperatue of $170^{\circ}C$. These films showed $Fe_{16}N_{2}$ X-ray peaks after $450^{\circ}C$ anneal.

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[ $^1H$ ] Nuclear Magnetic Resonance Study of Ferroelectric $(NH_4)_3H(SO_4)_2$

  • Choi, S.H.;Han, K.S.;Kwon, S.K.;Nam, S.K.;Choi, H.H.;Lee, Moo-Hee;Lim, Ae-Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.11 no.2
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    • pp.64-72
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    • 2007
  • [ $^1H$ ] nuclear magnetic resonance (NMR) experiments have been performed at 30 - 300 K and 7 T to investigate dynamics of hydrogen bond network in the single crystal $(NH_4)_3H(SO_4)_2$. The two proton sites, ammonium proton and hydrogen-bond proton, are identified from the $^1H$ NMR MAS spectrum at 340 K. As temperature decreases, the $^1H$ NMR spectrum shifts to the higher frequency side with a larger linewidth. The spectrum at 65 K shows a distinctive change in line shape toward the ferroelectric transition at 63 K. The measured values of $T_1$ for ammonium and hydrogen-bond protons are similar in the whole range of temperature. $T_1$ of $^1H$ NMR shows a gradual decrease down to 120 K and starts to steeply increase below 100 K. Then $T_1$ shows abrupt decrease below 70 K with a sharp minimum at 63 K, where the ferroelectric transition occurs. This temperature dependence of spectrum and $T_1$ clearly prove that the large change in the dynamics of hydrogen bond network is associated with the ferroelectric phase transition at 63 K.

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