• Title/Summary/Keyword: separation of mixture

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Separation of Hydrogen-Nitrogen Gas Mixture by PTMSP/PDMS-PEI Composite Membrane

  • Lee, Hyun-Kyung;Kang, Tae-Beom
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.148-151
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    • 2004
  • The development of the gas separation processes using polymeric membranes has attracted a great deal of interest during the last two decades. Membrane in this application has to offer an excellent thermal stability, chemical/solvent resistance, and mechanical strength under operating conditions.(omitted)

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Separation of 20(R&S) Prosapogenin Isomers of Ginsenoside-$Rg_2$ and -$Rg_3$ from Ginseng Saponins by Reversed-Phase High Performance Liquid Chromatography (인삼 사포닌에서 Ginsenoside-$Rg_2$와 -$Rg_3$의 이성질체인 20(R&S) Prosapogenin들의 역상 고속 액체 크로마토그래피에 의한 분리)

  • Jeong, Seung-Il;Kim, Cheon-Suk;Lee, Yong-Gu;Lee, Ho-Sup;Kim, Il-Kwang
    • Analytical Science and Technology
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    • v.11 no.5
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    • pp.404-408
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    • 1998
  • Using a reversed-phase high performance liquid chromatography, the separation of 20(S)-, 20(R)-prosapogenin stereo-isomers of ginsenoside-$Rg_2$ and of ginsenoside-$Rg_3$ in ginseng saponins has been carried out with binary solvent system. The optimum conditions for the isomer separation are as following: Nova-$Pak^{(R)}C_{18}$ (Waters, $3.9{\times}150mm$) column, $CH_3CN/CH_3CN$ (100:8, v/v) binary solvent system and the flow rate was 1.7 mL/min. The stereoisomers were separated with change of the mixture ratio of the solvent system, the solvent elution by gradient program, and then detected at 203 nm of UV detector. The simultaneous separation of mixture that were the $Rg_2$, $Rg_3$ isomers was easily performed in nonpolar solvent for $Rg_2$, polar solvent for $Rg_3$ at the same optimum conditions.

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Investigation of Cryogenic Breakthrough Curve Measurement System at 77 K for Hydrogen Isotopologue Separation (수소 동위원소 분리를 위한 77 K 극저온 파과 곡선 측정 시스템 제작)

  • Kim, Suhwan;Oh, Hyunchul
    • Korean Journal of Materials Research
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    • v.32 no.1
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    • pp.36-43
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    • 2022
  • Breakthrough analysis has widely been explored for the dynamic separation of gaseous mixtures in porous materials. In general, breakthrough experiments measure the components of a flowing gas when a gaseous mixture is injected into a column filled with an adsorbent material. In this paper, we report on the design and fabrication of a breakthrough curve measurement device to study the dynamic adsorptive separation of hydrogen isotopologues in porous materials. Using the designed system, an experiment was conducted involving a 1:1 mixture of hydrogen and deuterium passed through a column filled with zeolite 13X (1 g). At room temperature, both hydrogen and deuterium were adsorbed in negligible amounts; however, at a temperature of 77 K, deuterium was preferentially adsorbed over hydrogen. The selectivity was different from that in the existing literature due to the different sample shapes, measurement methods, and column structures, but was at a similar level to that of cryogenic distillation (1.5).

Dehydration of Alcohol Solutions Through Crosslinked Chitosan Composite Membranes III. Effects of Substrate, Neutralization and Active Layer Thickness on Pervaporation of Water/Ethanol Mixture (가교키토산 복합막을 통한 알콜수용액의 탈수 III. 화학가교시 지지체, 중화에 의한 효과와 이온가교시 활성층두께 변화에 의한 효과)

  • 이영무;남상용;유제강;류경옥
    • Membrane Journal
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    • v.6 no.4
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    • pp.250-257
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    • 1996
  • Surface crosslinked chitosan composite membranes were prepared with glutaraldehyde and surfuric acid. Effects of neutralization for complex between chitosan and acetic acid and of water permeability for substrate membranes on pervaporation performance were investigated. For ionically crosskinked membranes, effect of active layer thickness on separation factor of water/ethanol mixture was studied. With increasing the water permeability of the substrate, the membrane showed an increased separation factor, while it maintained a constant permeate flux. Neutralized chitosan composite membranes revealed a decreased separation factor and a constant permeate flux. When the thickness of the active layer increased, an optimum crosslinking time to achieve higher separation factor shifted to a prolonged times.

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Separation and Purification of 2,6-dimethylnaphthalene in the Light Cycle Oil(I) -Concentration of a mixture of dimethylnaphthalene isomers in the light cycle oil- (접촉분해경유에 함유된 2,6-dimethylnaphthalene의 분리, 정제(I) -접촉분해경유에 함유된 dimethylnaphthalene이성체 혼합물의 농축-)

  • Kim, Su-Jin;Kim, Sang-Chai;Kawasaki, Junjiro
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.162-170
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    • 1996
  • Light cycle Oil(LCO) contains 2,6-dimethylnaphthalene (2,6-DMNA) which is used as the basic material for high performance engineering plastics and liquid crystal polymer. This study was experimentally investigated to concentrate a mixture of dimethylnaphthalene(DMNA) isomers in the LCO by extraction-distillation combination as a pretreatment for separation and purification of 2,6-DMNA in the LCO. Furthermore, concentration of a mixture of DMNA isomers in the LCO compared between distillation and extraction-distillation combination. The recovery of aromatics in the LCO was performed by batch cocurrent multistage extraction with dimethylsulfoxide and water mixture as solvent. The concentration of naphthalene group(carbon number 10-12) in the extracted mixture is higher than that in the LCO. The yield for naphthalene group increased with decreasing carbon number. The yield for a mixture of DMNA isomers obtained in 5 equilibrium extration runs was about 65%. the separation of individual components with extractedmixture was tested by batch distillation. Futhermore, for recovery of a mixture of DMNA isomers of high concentration, distillate containing DMNA was distilled. As a result, a mixture of DMNA isomers with high concentration such as 60wt% was recovered. The extraction-distillation combination was more effective than the distillation to concentration a mixture of DMNA isomer in the LCO.

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GENERALIZED GAUSSIAN PRIOR FOR ICA (ICA를 위한 Generalized 가우시안 Prior)

  • 최승진
    • Proceedings of the Korean Information Science Society Conference
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    • 1999.10b
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    • pp.467-469
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    • 1999
  • Independent component analysis (ICA)는 주어진 데이터를 통계적으로 독립인 요소들의 선형 결합으로 표시하는 통계학적 방법이다. ICA의 주요한 적용분야중의 하나는 source들의 선형 mixture로부터 어떠한 서전 정보도 없는 상태에서 원래의 통계학적 독립변수인 source를 복원하는 blind separation이다. ICA와 source separation을 위한 다양한 신경 학습 알고리듬이 제시되어왔다. ICA의 학습 알고리듬에서는 비선형 함수가 중요한 역할을 한다. 이 논문에서는 generalized 가우시안 prior를 도입하여 다양한 확률분포를 갖는 source들의 mixture를 분리하는 효율적인 source separation 알고리즘을 제시한다. 모의실험을 통하여 제안된 방법의 우수성을 살펴본다.

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Blind Source Separation of Instantaneous Mixture of Delayed Sources Using High-Order Taylor Approximation

  • Zhao, Wei;Yuan, Zhigang;Shen, Yuehong;Cao, Yufan;Wei, Yimin;Xu, Pengcheng;Jian, Wei
    • ETRI Journal
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    • v.37 no.4
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    • pp.727-735
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    • 2015
  • This paper deals with the problem of blind source separation (BSS), where observed signals are a mixture of delayed sources. In reference to a previous work, when the delay time is small such that the first-order Taylor approximation holds, delayed observations are transformed into an instantaneous mixture of original sources and their derivatives, for which an extended second-order blind identification (SOBI) approach is used to recover sources. Inspired by the results of this previous work, we propose to generalize its first-order Taylor approximation to suit higher-order approximations in the case of a large delay time based on a similar version of its extended SOBI. Compared to SOBI and its extended version for a first-order Taylor approximation, our method is more efficient in terms of separation quality when the delay time is large. Simulation results verify the performance of our approach under different time delays and signal-to-noise ratio conditions, respectively.

Separation of Single Channel Mixture Using Time-domain Basis Functions

  • Jang, Gil-Jin;Oh, Yung-Hwan
    • The Journal of the Acoustical Society of Korea
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    • v.21 no.4E
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    • pp.146-155
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    • 2002
  • We present a new technique for achieving source separation when given only a single charmel recording. The main idea is based on exploiting the inherent time structure of sound sources by learning a priori sets of time-domain basis functions that encode the sources in a statistically efficient manner. We derive a learning algorithm using a maximum likelihood approach given the observed single charmel data and sets of basis functions. For each time point we infer the source parameters and their contribution factors. This inference is possible due to the prior knowledge of the basis functions and the associated coefficient densities. A flexible model for density estimation allows accurate modeling of the observation, and our experimental results exhibit a high level of separation performance for simulated mixtures as well as real environment recordings employing mixtures of two different sources. We show separation results of two music signals as well as the separation of two voice signals.

Separation of Single Channel Mixture Using Time-domain Basis Functions

  • 장길진;오영환
    • The Journal of the Acoustical Society of Korea
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    • v.21 no.4
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    • pp.146-146
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    • 2002
  • We present a new technique for achieving source separation when given only a single channel recording. The main idea is based on exploiting the inherent time structure of sound sources by learning a priori sets of time-domain basis functions that encode the sources in a statistically efficient manner. We derive a learning algorithm using a maximum likelihood approach given the observed single channel data and sets of basis functions. For each time point we infer the source parameters and their contribution factors. This inference is possible due to the prior knowledge of the basis functions and the associated coefficient densities. A flexible model for density estimation allows accurate modeling of the observation, and our experimental results exhibit a high level of separation performance for simulated mixtures as well as real environment recordings employing mixtures of two different sources. We show separation results of two music signals as well as the separation of two voice signals.

A Study of the Hull Form of Oil Recovery Vessel by Using Magnetic Fluid (자성유체를 이용한 유회수선박의 선형연구)

  • 이귀주;박영식;김경화;노준혁;장희문
    • Journal of Ocean Engineering and Technology
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    • v.15 no.2
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    • pp.1-5
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    • 2001
  • A study on the new active type oil-water separation system including the oil-water separation system of magnetic film was carried out. Separation system is composed of several active types of circulating oil separation steps and one magnetic film separation step at final stage. At the magnetic separation step, ferrofluid easily forms a weak magnetic mixture with oil, which is from the water by magnetic field gradient. The vessel has been designed to run at the maximum speed of 25 knots. And two typical forms of SWATH and Catamaran have been studied as a new type of oil recovery vessel.

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