• 분석과학
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• 제12권4호
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• pp.341-345
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• 1999

The separation and determination of inorganic cations by a capillary zone electrophoresis was studied. Cations were separated by the capillary column and detected by indirect UV method. The running buffer of 0.03 M creatinine and 0.02 M-hydroxy isobutylic acid solution (pH 4.8) was used to improve the mobility of ions in the column. A potential of 18 kV was applied at anode. A complete separation of cations ranged within 15 min and detection limits were between 0.1 and 1.0 ppm. The applicability of the method for real samples was demonstrated.

• 한국산업융합학회 논문집
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• 제19권4호
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• pp.176-184
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• 2016

Electrochemical ion exchange method is expected to be one of the most acceptable techniques for the separation of radioactive cations from nuclear wastewater. In this study a thin film of hexacyanoferrate on nickel surface was derivatized chemically in an aqueous potassium-ferricyanide solution. Electrochemical redox behavior of the nickel hexacyanoferrate(NiHCNFe) film electrode was investigated with the use of cyclic voltammetry potentiostated from -100 to 800 mV versus SCE. The electro-reduction characteristics of the NiHCNFe film were examined in the cobalt solutions. The NiHCNFe ion exchanger was more useful at lower concentration, lower temperature, and pH7 of the cobalt solution. The capacity loss of NiHCNFe was 0.018%/cycle that was less than the average loss of 2~3%/cycle of the convective organic exchanger. The 45~55% of the initial cobalt ions was electro-deposited on the NiHCNFe by using continuous recirculating reactor system. As a result, it was found that the electroactive NiHCNFe films showed better performance than the organic resins for the separation of cobalt ion from the aqueous solutions.

• 대한화학회지
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• 제5권1호
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• pp.56-59
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• 1961

Ion exchange procedure was studied for the separation of thorium from the acidic solution obtained by means of decomposition of monazite with alkali solution. Present cation exchange method consists of adsorption of cations from the sample solution (ca. 0.6N HCl acidic) onto Amberlite IR-120 resin, elution of all of the rare earth cations with 700 ml. of 2N Hydrochloric acid, and recovery of the thorium by elution with 200ml. of 6N sulfaric acid. Thorium recovery by the ion-exchange method mentioned above, was quantitative, and it is concluded that this ion-exchange method may be used not only for industrial separation of thorium from rare earths but also for quantitative determination of thorium with relative error, ${\pm}1.0.$.

• Bulletin of the Korean Chemical Society
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• 제24권9호
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• pp.1324-1328
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• 2003

The simultaneous determination of anions ($SO_4 ^{2-},\;Cl^-,\;and\;NO_3^-$) and cations ($Na^+,\;NH^{4+},\;K^+,\;Mg^{2+},\;and\;Ca^{2+}$) in natural water obtained by Nakdong River waters system in Korea were performed by ion-exclusion/cationexchange chromatography with conductimetric detection. The stationary phase was a polymethacrylate-based weakly acidic cation-exchange resin column in the $H^+$-form and a weak-acid eluent. When using only a 1.4 mM sulfosalicylic acid/6 mM 18-crown-6 ether as an eluent, good resolution of both anions and cations, minimum time required for the separation, and satisfactory detection sensitivity were obtained in a reasonable time. The method was successfully applied to the simultaneous determination of anions and cations in natural waters.

• 전기화학회지
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• 제15권4호
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• pp.256-263
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• 2012

본 연구에서는 전기화학적 이온교환체 중의 하나인 nickel hexacyanoferrate($KNiFe(CN)_6$) 막 전극을 사용하여 세슘 양이온을 분리하는 실험을 수행하였다. 1.0M $NaNO_3$와 1.0M $CsNO_3$의 단일성분계 및 이성분계 수용액에서 순환전위곡선을 측정하여 전극전위, 전류, 전기량의 변화 거동을 조사하였으며, 실험 전과 후에 $KNiFe(CN)_6$ 막의 구조 형태와 원자조성의 변화를 각각 SEM과 EDS 분석을 통하여 조사하였다. 또한 나트륨과 세슘 용액에서 교대로 이온교환 반응을 수행하여 측정한 순환전위곡선과 원자조성으로부터 $KNiFe(CN)_6$의 이온 선택성을 조사하였다. 본 연구의 실험 결과에 의하면, 전기를 인가한 $KNiFe(CN)_6$ 이온교환체는 화학적 유 무기물 이온교환체에 비해 약 40배 이상의 우수한 내구성을 가짐을 알 수 있었다. 또한 $KNiFe(CN)_6$ 이온교환체는 나트륨보다 세슘에 대해 보다 높은 선택도를 가짐을 확인할 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제34권11호
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• pp.3362-3366
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• 2013

A simple and quick separation technique for selenite in natural water was developed using $TiO_2$@$SiO_2/Fe_3O_4$ nanoparticles. For the synthesis of nanoparticles, a polymer-assisted sol-gel method using hydroxypropyl cellulose (HPC) was developed to control particle dispersion in the synthetic procedure. In addition, titanium butoxide (TBT) precursor, instead of the typical titanium tetra isopropoxide, was used for the formation of the $TiO_2$ shell. The synthesized nanoparticles were used to separate selenite ($Se^{4+}$) in the presence of $Se^{6+}$ or selenium anions for the photocatalytic reduction to $Se^0$ atom on the $TiO_2$ shell, followed by magnetic separation using $Fe_3O_4$ nanoparticles. The reduction efficiency of the photocatalytic reaction was 81.4% at a UV power of 6W for 3 h with a dark adsorption of 17.5% to the nanoparticles, as determined by inductively coupled plasma-mass spectrometry (ICP-MS). The developed separation method can be used for the speciation and preconcentration of selenium cations in environmental and biological analysis.

• 대한화학회지
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• 제38권2호
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• pp.129-135
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• 1994

Acyclic polyether dicarboxylic acid는 액체막계에서 금속이온의 운반체로 연구되었다. 수소이온이 이온화될 수 있는 리간드는 금속이온의 이동에 수소이온이 반대방향으로 이동된다. 이와 같은 리간드는 pH를 변화시키면 효과적으로 금속이온을 분리할 수 있고 농축시킬 수도 있다. 금속이온의 이동은 source phase의 염기의 농도와 receiving phase의 산의 농도를 증가시키면 증가된다. Acyclic polyether dicarboxylic acids를 운반체로 사용한 경쟁이동반응에서 칼슘이온을 선택적으로 분리할 가능성이 있다.

• Korean Membrane Journal
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• 제3권1호
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• pp.51-58
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• 2001

The surface of Poly(ether imide) (PEI) membranes has been sulfonated using CIS03H. The resulting membranes were characterized through the analysis of ESCA and contact angle measurements The sulfonated PEI membranes were exposed to gases of $O_2$, $N_2$, and $CO_2$ to measure the permeation rates and ideal separation factors. In addition, the diffusivities and solubilities of individual gases were measured. The diffusivity effect is more dominant than the solubility one on gas transports.

• Bulletin of the Korean Chemical Society
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• 제8권5호
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• pp.366-372
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• 1987

Cryptand[2,2] was grafted to low crosslinked styrene-divinylbenzene copolymer by substitution reaction with chloromethylated styrene-divinylbenzene copolymer. This resin was stable in concentrated acid and base, and showed a good resistance to heat. The pH, time, and concentration dependence of the adsorption of metal ions by this resin were studied. Studies on the chromatographic separation of lanthanides, $Cu^{2+}$ and $UO_2^{2+_2}$ were also carried out with various eluents. These studies demonstrate that this resin has the applicability to the preconcentration and separation of metal ions.

• Membrane and Water Treatment
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• 제8권5호
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• pp.437-448
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• 2017

A high quality Na-X zeolite membrane was synthesized on a seeded ${\alpha}-alumina$ disc by the secondary growth method. Structural characterization was done by X-ray spectroscopy, FT-IR spectroscopy, SEM and AFM imaging. The performance evaluation of the membrane was firstly tested in separation of glucose/water solutions by pervaporation process. There was obtained a separation factor $182.7{\pm}8.8$, while the flux through the membrane was $3.6{\pm}0.3kg\;m^{-2}\;h^{-1}$. The zeolite membrane was then used for desalination of aqueous solutions consisting of $Na^+$, $Ca^{2+}$, $Cs^+$ and $Sr^{2+}$ because of the importance of these ions in water and wastewater treatments. The effects of some parameters such as temperature and solution concentration on the desalination process were studied for investigating of diffusion/adsorption mechanism in membrane separation. Finally, high water fluxes ranged from 2 up to $9kg\;m^{-2}\;h^{-1}$ were obtained and the rejection factors were resulted more than 95% for $Na^+$ and $Ca^{2+}$ and near to 99% for $Cs^+$ and $Sr^{2+}$. Based on the results, fluxes were significantly improved due to convenient passage of water molecules from large pores of NaX, while the fouling was declining dramatically. Based on the results, NaX zeolite can efficiently use for the removal of different cations from wastewaters.