• 자원리싸이클링
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• 제31권5호
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• pp.20-25
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• 2022

본 연구에서는 방사성 폐액내 포함된 방사성 핵종인 세슘-137(Cs-137) 및 스트론튬-90(Sr-90)의 친환경적인 제염을 위해 미세조류의 적용 가능성을 평가하였다. Cs-137 및 Sr-90이 각각 함유된 일원계 표준 방사성 용액과 3차 증류수를 희석하여 1.5 Bq/mL Cs-137, 1.0 Bq/mL Sr-90 농도로 제조한 뒤 실험에 사용하였다. 미세조류는 2종을 사용했으며, Sr-90 제염에는 Chlorella Vulgaris를 사용하였고, Cs-137 제염에는 Hematococcus pluvialis를 사용하여 실험을 수행하였다. 실험 방법은 2주 간 배양된 미세조류를 반투과막이 부착된 병에 투입한 뒤, 미세조류가 투입된 병을 제조된 방사성 용액에 투입하여, 반투과막을 통해 미세조류와 방사성 용액이 48 시간 동안 반응하도록 하였다. 각 시료에 대한 방사능 농도 분석은 γ선 동위원소인 Cs-137은 감마선 핵종 분석기를 사용하였고, β선 동위원소인 Sr-90은 액체섬광계수기(LSC: Liquid Scintillation Count)를 사용하였다. 실험 결과, Cs-137은 약 88.0 %, Sr-90은 약 89.7 % 제염이 가능함을 확인하였으며, Sr-90은 2단 제염 방법에 의해 최종적으로 약 98.6 % 제염이 가능하였다.

• 농업과학연구
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• 제7권2호
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• pp.109-118
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• 1980

Slump시험(試驗)보다는 조작(操作)이 간편(簡便)한 유통(流動) Table을 사용(使用)하여 화강암질풍화토(花崗岩質風化土)의 유동한계(流動限界)를 측정(測定)하는 방법(方法)을 시험(試驗)하여 다음과 같은 결론(結論)을 얻었다. 1) 화강암질풍화토(花崗岩質風化土)의 유동한계(流動限界)는 입도분포(粒度分布), 퐁화도(風化度) 및 유색광물함량(有色鑛物含量)에 영향(影響)되므로 유동(流動) Table에 의한 유동한계시험법(流動限界試驗法)을 제정(制定)할 때는 최대입경(最大粒徑)이 규정(規定)되어야 할 것으로 생각된다. 2) 유동(流動) Table의 낙하회수(落下回數)를 10회(回)로 하여 유동고(流動高)와 유동폭(流動幅)이 1cm일 때의 함수비(含水比)의 평균치(平均値)를 유동한계(流動限界)로 택(擇)하면 Slump시험(試驗)에서 구(求)한 유동한계(流動限界)보다 약간 작은 값으로 되며 대략(大略) 10%오차한계선내(誤差限界線內)에 속(屬)했다. 3) 유동폭(流動幅)과 함수비(含水比) 및 유동고(流動高)와 함수비(含水比)의 관계곡선(關係曲線)은 유사(類似)한 변화(變化)를 나타내고 반대수용선(半對數用線)에 도시(圖示)하면 액성한계시험(液性限界試驗)에서와 같이 직선관계(直線關係)를 나타냈다. 4) Slump시험(試驗)에 비(比)하여 조작(操作)이 간편(簡便)하고 개인적(個人的)인 오차(誤差)가 작으며 유동폭(流動福)과 유동고(流動高)를 동시측정(同時測定)하여 시험오차(試驗誤差)가 작은 것으로 공학적(工學的) 성질(性質)을 판단(判斷)하는 자료(資料)로 사용(使用)될 수 있는 것으로 생각된다.

• 환경위생공학
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• 제14권3호
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• pp.130-138
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• 1999

The feasibility of municipal sewage sludge digestion was investigated by using thermophilic anaerobic sequencing batch reactor(ASBR). One-day settle time was enough for the high performance of solid-liquid separation. The conversion of semi-continuous mode to sequencing batch mode is easily achieved without any adverse effects, although the large amount of sludge equal to the volume ratio of 0.3~06 to reactor volume was added in the feed step of the start-up. The ASBRs had higher conversion capability of organics to biogas than the control reactor. Gas yields of the ASBRs were increased by the average of 50% over the control reactor across a range of hydraulic retention time(HRT)s from 10days to 5days. The thermophilic reactors showed higher gas production than mesophilic reactor. Removal efficiencies of organic matter exceeded 80% on the basis of supernatants, except that at the reactor. Solid-liquid separation was essential in the performance of the ASBR, especially, at the lower HFT. The ASBRs were highly efficient in the retention of activated biomass within the reactor. thus compensating for increased equivalent organic loading rate through increased solids retention times followed by the increased solids, while maintaining shorter HRTs.

• 한국대기환경학회지
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• 제23권6호
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• pp.744-751
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• 2007

Wet scrubber is widely used to remove toxic gaseous contaminants in various industries such as semi-conductor industry, display manufacturing industry and so on. In this study, to optimize a packed bed scrubber as one of typical wet scrubber size while keeping its performance, four different packing materials were investigated at different air flow rates, liquid-gas ratios and pH values. Ammonia, hydrochloric acid and hydrofluoric acid were used as test gases to characterize the scrubber performance. Gas removal efficiency increased as the packing size decreased, which resulted in the increase of specific surface area. The increase of air flow rate led to the decrease of gas removal efficiency, while the increase of liquid-gas ratio led to the increase of gas removal efficiency. For the case of $NH_3$ gas, lower pH, and for the cases of HCl and HF, higher pH contributed to higher gas removal efficiency. Gas removal efficiency of a wet scrubber increased in the order of HCl < $NH_3$ < HF according to its water solubility.

• Mass Spectrometry Letters
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• 제2권1호
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• pp.12-15
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• 2011

The Korean government has regulated emission of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in waste water of manufacturing facilities producing chlorinated compounds since 2009. As this regulation is expected to be reinforced in 2013 to 50 pg I-TEQ/L, a large sample volume is required for the analysis of trace amounts of PCDD/Fs in waste water. Liquid-liquid extraction (LLE) is used to extract PCDD/Fs from aqueous samples; however, its low efficiency makes it inadequate for analyzing large sample volumes. Herein, we present a disk-type solid-phase extraction (SPE) method for the analysis of dioxin at a part per quadrillion level in waste water. This SPE system contains airtight glass covers with a decompression pump, which enables continuous semi-automated extraction. Small (0.5 L) and large (7 L) samples were extracted using LLE and SPE methods, respectively. The method detection limits (MDLs) were 0.001.0.25 and 0.015.4.1 pg I-TEQ/L for the SPE and LLE methods, respectively. The concentrations of detected congeners with both methods were similar. However, the concentrations of several congeners that were not detected with the LLE method were quantified using the SPE method.

• 한국초전도ㆍ저온공학회논문지
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• 제14권4호
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• pp.32-35
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• 2012

A high-$T_c$ superconducting (HTS) DC application has advantages such as the ultimately lower loss, more compact dimensions, and large capacity compared to AC application. In order to optimize the insulation design of a HTS DC machines, it is important to understand the high voltage insulation and materials at cryogenic temperature. Polypropylene laminated paper (PPLP) has been widely used as an insulating material for HTS AC machines. However, the fundamental data under DC voltage have not been revealed satisfactorily until now. In this paper, we will discuss mainly on the breakdown and dielectric characteristics of PPLP in liquid nitrogen ($LN_2$). The polarity effects of DC and impulse voltage were studied by using the semi-rod to cylindrical electrode. The volume resistivity of PPLP in $LN_2$ was studied. Also, the space charge distribution at room temperature was studied. However, it is necessary to study this topic at cryogenic temperature in the near future.

• Applied Biological Chemistry
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• 제23권4호
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• pp.206-210
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• 1980

인삼(人蔘)사포닌중 소미량성분인 $ginsenoside-Rf,\;-Rg_2$ 및 $-Rh_1$을 조제용(造製用), 준조제용(準造製用) 및 분석용(分析用) HPLC를 사용(使用)하여 분리(分離)하였다. 본(本) 방법(方法)은 신속하며 이들 소미량 ginsenoside의 분리(分離) 및 동정(同定)에 매우 유효(有效)하였으며 재(再)순환 방식을 사용하여 달성되었다.

• 한국정밀공학회지
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• 제16권9호
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• pp.123-134
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• 1999

A new forming technology has been developed to fabricate near-net shape components by using aluminum alloys with globular microstructure. The estimations of filling characteristic in the forging simulation with arbitrarily shaped dies of SSM are calculated by finite element method with proposed algorithm. The proposed model and various boundary conditions for arbitrarily shaped die are investigated with the coupling calculation between the liquid phase flow and the solid phase deformation. The simulation processes with arbitrarily shaped dies are performed on the isothermal conditions and axisymmetric problems. To analyze the forging process simulation with SSM, new stress-strain relationship for semi-solid behaviour is described, and forging the liquid flow. Furthermore, For the purpose of getting net shape of SSM, it is important to be obtain a solid fraction in forging process with arbitrarily shaped dies. To produce a automotive part which have good mechanical properties, the filling pattern in accordance with die velocity and solid fraction distribution has to be estimated for arbitrarily shaped die.

• 분석과학
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• 제34권1호
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• pp.9-16
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• 2021

In the group of commonly prescribed β-blocker drugs, one of the enantiomers is generally relatively more active than the others. This study aims to develop a technique for the chiral analysis of select β-blockers based on proton nuclear magnetic resonance (1H-NMR) spectrometry. (S)-2-Tert-butyl-2-methyl-1,3-benzodioxole-4-carboxylic acid ((S)-TBMB) was synthesized and utilized as a chiral derivatizing agent. Pure β-blocker enantiomers were isolated from racemates by semi-preparative liquid chromatography prior to derivatization. The reaction time and concentration of (S)-TBMB were controlled to improve the derivatization procedure. No racemization was found during the analysis. High-performance liquid chromatography (HPLC) analysis was also performed for comparative purposes. High agreement between the NMR and HPLC methods was achieved in the determination of (R)-metoprolol in a standard solution of the (S) isomer.

• 폴리머
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• 제31권1호
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• pp.37-46
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• 2007

셀룰로오스 아밀로오스 키토산, 키틴, 알긴산, 풀루란 또는 아밀로펙틴을 6- [4- (4'- (니트로페닐아조)펜옥시)]펜타노일 클로라이드(NA6C)와 반응시켜 전치환 또는 거의 전치환 6- [4- (4'- (니트로페닐아조)펜옥시카보닐)] 펜타노화 다당류 유도체들을 합성함과 동시에 이들의 열방성 액정의 거동들을 검토하였다. NA6C의 경우와 같이, 모든 다당류 유도체들은 단방성 네마틱 상들을 형성하였다. 이러한 사실은 다당류 유도체들의 액정 구조는 다당류 골격에 의해 결정되는 것이 아니고 mesogenic 곁사슬 그룹들에 의해 결정됨을 시사한다. 이것이 셀룰로오스 유도체들을 제외한 다당류 유도체들이 열방성 네마틱 상을 형성한다고 하는 최초의 보고이다. 다당류 유도체들에 있어서 관찰되는 네마틱 상들의 열적 안정성과 질서도는 아조벤젠 그룹들을 유연한 스페이서를 통하여 유연한 혹은 강직한 골격들에 도입시켜 얻은 고분자들에 대해 보고된 결과들과 현저히 다르다. 이들의 결과를 주사슬과 곁사슬의 배열 그리고 주사슬의 유연성의 차이와 관련하에서 검토하였다.