• KEPCO Journal on Electric Power and Energy
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• v.5 no.2
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• pp.83-92
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• 2019

Spontaneous combustion propensity of various coals of carbonization grade as a pulverized fuel of coal-fired power plant has been tested from an initial temperature of $25^{\circ}C$ to $600^{\circ}C$ by heating in an oven with air to analyze the self-oxidation starting temperature. These tests produce CPT (Cross Point Temperature), IT (Ignition temperature), and CPS (Cross Point Slope) calculated as the slope of time taken for a rapid exothermic oxidation reaction at CPT base. CPS shows a carbonization rank dependence whereby wood pellet has the highest propensity to spontaneous combustion of $20.995^{\circ}C/min$. A sub-bituminous KIDECO coal shows a CPS value of $15.370^{\circ}C/min$, whereas pet coke has the highest carbonization rank at $2.950^{\circ}C/min$. The nature of this trend is most likely attributable to a concentration of volatile matter and oxygen functional groups of coal surface that governs the available component for oxidation, as well as surface area of fuel char, and constant pressure molar heat.

• Fire Science and Engineering
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• v.26 no.6
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• pp.99-108
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• 2012

These days, spontaneous ignition phenomena by oxidizing heat frequently occur in the circumstances of processing and storing waste tires. Therefore, to examine the phenomena, in this work, this researcher conducted the tests of fires of fragmented waste tires (shredded tire), closely investigated components of the fire residual materials collected in the processing and storing place, and analyzed the temperature of the starting of the ignition, weight loss, and heat of reaction. For the study, this researcher conducted fire tests with fragmented waste tires in the range of 2.5 mm to 15 mm, whose heat could be easily accumulated, and performed heat analysis through DSC and TGA, DTA, DTG, and GC/MS to give scientific probability to the possibility of spontaneous ignition. According to the tests, at the 48-hour storage, rapid increase in temperature ($178^{\circ}C$), Graphite phenomenon, smoking were observed. And the result from the DTA and DTG analysis showed that at $166.15^{\circ}C$, the minimum weight loss occurred. And, the result from the test on the waste tire analysis material 1 (Unburnt) through DSC and TGA analysis revealed that at $180^{\circ}C$ or so, thermal decomposition started. As a result, the starting temperature of ignition was considered to be $160^{\circ}C$ to $180^{\circ}C$. And, at $305^{\circ}C$, 10 % of the initial weight of the material reduced, and at $416.12^{\circ}C$, 50 % of the intial weight of the material decreased. The result from the test on oxidation and self-reaction through GC/MS and DSC analysis presented that oxidized components like 1,3 cyclopentnadiene were detected a lot. But according to the result from the heat analysis test on standard materials and fragmented waste tires, their heat value was lower than the basis value so that self-reaction was not found. Therefore, to prevent spontaneous ignition by oxidizing heat of waste tires, it is necessary to convert the conventional process into Cryogenic Process that has no or few heat accumulation at the time of fragmentation. And the current storing method in which broken and fragmented materials are stored into large burlap bags (500 kg) should be changed to the method in which they are stored into small burlap bags in order to prevent heat accumulation.

• Composites Research
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• v.33 no.5
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• pp.256-261
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• 2020

In this study, the ignition temperature of the Al-Ti-C reaction system, the microstructure and the mechanical properties of the TiC/Mg composite which produced by the self-propagating high-temperature synthesis (SHS) followed by stir casting process were investigated. Mg based composite with uniformly dispersed 0, 10, 20, and 30 vol.% TiC were fabricated, and higher volume fraction of TiC reinforced composite showed superior compressive strength and wear resistance as compared with Mg matrix. It is attributed to the less contamination, defects, impurities in TiC/Mg composite by the in-situ SHS yield effective load transfer from the matrix to the reinforcement.

• Journal of the Korean Ceramic Society
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• v.31 no.3
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• pp.265-274
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• 1994

Intermetallic Ti-Si system ceramics were synthesized from stochiometric mixtures of titanium and silicone powders in vacuum by Self-propagating High-temperature Synthesis(SHS). In each cases of Ti5Si3, Ti5Si4 and TiSi, and TiSi2 synthesis, 20wt% product dilution, direct ignition and SHS chemical furnace method were employed. The combustion modes, which were observed during the synthesis process by using the high speed camera, of Ti5Si3, Ti5Si4, TiSi, and TiSi2 exhibit spin, osciallatory, steady-state, and spin combustion, respectively. With increasing Ti/Si molar ratio an decrease of combustion velocities was found. From the results on the measurement of the flexural strength, the specimen hot pressed at 135$0^{\circ}C$ for 30 min using synthesized Ti5Si4 powders showed the highest flexural strength at 215 MPa.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.35-39
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• 2003

A numerical study is carried out to investigate combustion phenomena in a model SCRamjet engine, which has been experimentally studied at the Australian National University using a T3 free-piston shock tunnel. The Mach number is 3.8, the static pressure 110kPa and the static temperature 1100K in the main air flow. The fuel is hydrogen, which is injected in the cavity. Equivalence ratio is set to either 0.25 or 0.5 to access its effect on the fuel-air mixing combustion phenomena. The results show that the cavity generates several recirculation zones, which increase the fuel-air mixing. Self ignition occurs near the point of fuel injection. The flame is anchored by the cavity and generates the precombustion shock on the step. For a high equivalence ratio, the recirculation zones are bigger and the flame is present throughout the combustor.

• Journal of Electrical Engineering and Technology
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• v.13 no.6
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• pp.2421-2424
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• 2018

A direct measurement of an initiation carrier injection for a low voltage discharge is presented. A self-sustained pulsed discharge is utilized to characterize electrical responses of a glow discharge for varying amounts of injected initiation carriers. It is clearly demonstrated that the initiation carrier injection affects the ignition time and the breakdown voltage of the primary discharge. An abrupt reduction in the breakdown voltage for a $300{\mu}m$ gap pin-plate discharge is observed when a threshold carrier density of $3{\times}10^{11}cm^{-3}$ is injected and the breakdown voltage continues to decrease to 250 V with increasing the initiation carrier injection beyond the threshold density.

• Journal of the Korean Society of Combustion
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• v.7 no.3
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• pp.32-36
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• 2002

A numerical study was carried out to investigate combustion phenomena in a model Scramjet engine, which had been experimentally studied at the University of Tokyo using a high-enthalpy supersonic wind tunnel. The main airflow was Mach number 2.0 and the total temperature of hot flow was 1800K. Equivalence ratio was set to be 0.26 which is higher than that of experiment to investigate the effect of strong precombustion shock. The results showed that self-ignition occurred at the rear bottom wall of the combustor and combined with the shear layer flame between fuel jet and main airflow. Then, precombustion shock was generated at the step location and reversely enhanced the mixing and combustion process behind the shock. Due to the high equivalence ratio, the precombustion shock moved upstream of the step compared with that of experiment.

• Journal of the Korean Society of Combustion
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• v.12 no.1
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• pp.11-20
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• 2007

The supersonic combustion experiments are carried out using T3 free-piston shock tunnel. Different shock tube fill pressures have various inflow conditions. $15^{\circ}$ inclined hydrogen fuel injection is located before the cavity. Oblique shock is generated from the cavity and reflects off the top and bottom wall. For non-reacting flow, fuel makes the shear layer thicker above the cavity therefore, the shock is generated just before the trailing edge. This research has self-ignition in the combustor. For reacting flow, as the equivalence ratio increases, flame starts to generate near the injector or occur in the recirculation zone before the injector. High fuel injection sustains the jet shape in the cross flow and air can mix with fuel along the shear layer. Therefore, two flame layers find above the cavity for high equivalence ratio.

• 한국연소학회:학술대회논문집
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• 2001.06a
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• pp.127-132
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• 2001

A numerical study was carried out to investigate the combustion phenomena in a model Scramjet engine, which had been experimentally studied in the University of Tokyo using a high-enthalpy supersonic wind tunnel. The main airflow was 2.0 in Mach number and the total temperature of hot flow was 1800K. Equivalence ratio was set to be rather higher value of 0.26 than that of experiment to investigate the effect of strong precombustion shock. The results showed that self-ignition occurred at the rear bottom wall of the combustor and combined with the shear layer flame between fuel jet and main airflow. Then, precombustion shock was generated at the step location and reversely enhanced the mixing and combustion process behind the shock. Due to the high equivalence ratio, the precombustion shock moved upstream of the step compared with that of experiment.

• Journal of Korea Foundry Society
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• v.1 no.3
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• pp.19-29
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• 1981

An emphasis has been placed on the importance of selecting a sand for furan sand process, which ie affected by the properties of sand. Investigations have been carried out to use the domestic artificial sands for the furan sand process. For laboratory investigations, the sands have been prepared and tested for chemical analysis, loss on ignition, sieve analysis, AFS grain fineness number, grain shape, PH value, acid demand, surface shape, theoretical surface area, moisture absorption, crushing durability and compressive strength and S. S. I. of molding sands. Most commercial sands have been found to be able to be used. The main requirement of the sands has been shown to be that 3 or 4 screen sands, AFS no.40-70 (or 100), of low acid demand, good surface area and good grain shape require less resin and catalyst to give an adequate strength.