• Title/Summary/Keyword: self assembled monolayer

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A comparison of detection capabilities of anti-IgG immobilizedby protein G and NHS (Protein G와 NHS를 이용하여 고정한 anti-IgG의 검출 성능 비교)

  • Sin, Eun-Jung;Sohn, Young-Ho;Sohn, Young-Soo
    • Journal of Sensor Science and Technology
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    • v.19 no.2
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    • pp.142-148
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    • 2010
  • We have compared and investigated the detection capabilities of antibody of immunoglobulin G(anti-IgG) immobilized by protein G and N-hydroxysuccinimide(NHS) at the end of the self-assembled monolayer(SAM). Surface plasmon resonance(SPR) sensor has been utilized to measure the interaction between biomolecules. After formation of the protein G and SAM, anti-IgG, bovine serum albumin(BSA) and IgG has been sequently injected. Through the reponse of the SPR, we can conclude that the protein G immobilized anti-IgG better than the SAM. In addition, IgG detection capability of the anti-IgG immobilized by the protein G showed better performance compared with that immobilized by the SAM.

A SOD-Based Amperometric Biosensor for Superoxide Ion

  • Tian, Yang;Okajima, Takeyoshi;Kitamura, Fusao;Ohsaka, Takeo
    • Journal of the Korean Electrochemical Society
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    • v.5 no.4
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    • pp.212-215
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    • 2002
  • A superoxide dismutase (SOD)-based superoxide ion $(O_2^-)$ sensor was fabricated by immobilizing SOD on a self-assembled monolayer (SAM) of 3-mercaptopropionic acid (MPA) which was prepared on a gold electrode. The SAM of MPA was found to function as an effective promoter for the electrode reaction of SOD. The amperometric response to $(O_2^-)$ was monitored at 300mV and -100mV vs. Ag/ Agel in 5mM phosphate buffer solution containing $KO_2$. The sensor was proved to have a high sensitivity, selectivity and short response time (<5 s) and negligible interference.

All printed organic thin film transistors with high-resolution patterned Ag nanoparticulate electrode using non-relief pattern lithography

  • Eom, You-Hyun;Park, Sung-Kyu;Kim, Yong-Hoon;Kang, Jung-Won;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.568-570
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    • 2009
  • Octadecyltrichlorosilane (OTS) self-assembled monolayer was selectively patterned by deep ultraviolet exposure, resulting in differential surface state, hydrophilic area with OTS hydrophobic surroundings. High-resolution (<10 ${\mu}m$) nanoparticulate Ag electrodes and organic semiconductors were patterned from simple dip-casting and ink-jetting on the pre-patterned hydrophilic surface, forming all solution-processed organic thin film transistors. The devices typically have shown a mobility of 0.065 $cm^2/V{\cdot}s$ and on-off current ratio of $8{\times}10^5$.

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Vertical Alignment Effects of Liquid Crystals by an Octadecyltrichlorosilane Self-Assembled-Monolayer prepared on an Anisotropic $SiO_2$ Surface

  • Seok, Keun-Yeong;Han, Yeon-Jeong;Kim, Hak-Rin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.645-647
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    • 2009
  • We investigated vertical liquid crystal (LC) alignment effects of a self-assembled-monolayer (SAM) prepared on an anisotropic $SiO_2$ surface where the field-induced LC reorientation produced a uniform single domain texture. We compared the results with the homeotropic-to-random planar reorientation results shown in LCs aligned on a SAM surface prepared on an isotropic $SiO_2$ surface.

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An Experimental Study on the Micro-adhesion of Octadecyltrichlorosilane SAM on the Si Surface (OTS SAM의 미소 응착 특성에 관한 실험적 연구)

  • 윤의성;박지현;양승호;한흥구;공호성
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2000.11a
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    • pp.341-346
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    • 2000
  • The effect of OTS(octadecyltrichlorosilane) SAM(self-assembled monolayer) on the micro-adhesion has been studied. OTS SAM was formed on the Si(100) surface and SPM (scanning probe microscope) tips with different radius of curvature were fabricated by a series of masking and etching processes. Pull-off forces of different tips on Si and OTS SAM surfaces were measured by SPM in different relative humidities. The surface of OTS SAM was changed to hydrophobic surface and the micro-adhesion force of OTS SAM was lower than that of pure Si. As the tip radius of curvature and the relative humidity increased. the micro-adhesion force increased. Based on the test results. the main parameter affected to the micro-adhesion was absorbed humidity on the surface.

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An Experimental Study on the Nano-adhesion of Octadecyltrichlorosilane SAM on the Si Surface (OTS SAM의 미소 응착 특성에 관한 실험적 연구)

  • 윤의성;박지현;양승호;한흥구;공호성
    • Tribology and Lubricants
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    • v.17 no.4
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    • pp.276-282
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    • 2001
  • Nano adhesion between SPM (scanning probe microscope) tips and 075 (octadecyltrichlorosilane) SAM (self-assembled monolayer) was experimentally studied. Tests were performed to measure the nano adhesion and friction in both AFM(atomic force microscope) and LFM(lateral force microscope) modes in various conditions of relative humidity. OTS SAM was formed on Si-wafer (100) surfaces, and Si$_3$N$_4$ tips of different radius of curvature were used. When the surface was hydrophobic, the adhesion and friction forces were found lower than those of bare Si-wafer. Results also showed that micro-adhesion force increased as the relative humidity and the tip radius of curvature increased. The main parameter for affecting the micro-adhesion was found absorbed humidity on the contact surface. These results were discussed with the JKR model and a capillary force caused by absorbed water.

Study on the Mophology Observation and Electrical Properties of Dipyridinium Organic Monolayer Using STM (STM을 이용한 Dipyridinium 유기 단분자막의 모폴로지 관찰 및 전기적 특성 연구)

  • Lee Nam-Suk;Shin Hoon-Kyu;Kwon Young-Soo
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.2
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    • pp.51-54
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    • 2005
  • In this work, the attempt has been made to investigate the morphology of self-assembled dipyridinium dithioacetate on Au(111) substrate by Scanning Tunneling Microscopy(STM). Also, we measured electrical properties(I-V) using Scanning Tunneling Spectroscopy(STS). Sample used in this experiment is dipyridinium dithioacetate, which contains thiol functional group, this structure that can be self-assembled easily to Au(111) substrate. The self-assembly procedure was used for two different concentrations, 0.5 mM/ml and 1 mM/ml. Dilute density of sample by 0.5 mM/ml, 1 mM/ml and observed dipyridinium dithioacetate's image by STM after self-assembled on Au(111) substrate. The structure of STM tip-SAMs-Au(111) substrate has been used measurement for electrical properties(I-V) using STS. The current-voltage(I-V) measurement result, observed negative differential resistance(NDR) properties.

Electrochemical Properties of Viologen Self-Assembly Monolayer Using QCM (수정진동자를 이용한 Viologen Self-Assembly 단분자막의 전기화학적 특성)

  • Ock, J.Y.;Song, S.H.;Shin, H.K.;Park, J.C.;Chang, J.S.;Chang, S.M.;Kwon, Y.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.403-406
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    • 2002
  • Molecular self-assembled of surfactant viologen are of recent interest because they can from functional electroeds as well as micellar assemblies. which can be profitably utilized for display devices. photoelectrochemical studies and electrocatalysis as electron acceptor or electron mediator[1-3]. Fromherz et al studied the se1f-assembly of thiol and disulfide derivatives of viologens bearing long n-alkyl chains on Au electrode surface[4]. In this study, the electrochemical behavior of self-assembled viologen monolayer has been investigated with QCM, which has been known as nano-gram order mass detector. The self-assembly process of viologen was monitored using resonant frequency$({\Delta}F)$ and resonant resistance(R). The redox process of viologen was observed with resonant frequency$({\Delta}F)$.

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Determining the Self-Assembly and Redox Process of a Viologen Monolayer by Electrochemical Quartz Crystal Microbalance (수정진동자를 이용한 Viologen 단분자막의 자기조립화와 산화,환원 반응 측정)

  • Ock, J.Y.;Song, S.H.;Shin, H.K.;Chang, J.S.;Chang, S.M.;Kwon, Y.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.23-27
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    • 2003
  • Molecular self-assembled of surfactant viologen are of recent interest because they can from functional electrodes as well as micellar assemblies, which can be profitably utilized for display devices, photoelectrochemical studies and electrocatalysis as electron acceptor or electron mediator. Fromherz et al studied the self-assembly of thiol and disulfide derivatives of viologens bearing long n-alkyl chains on Au electrode surface. The electrochemical behavior of self-assembled viologen monolayer has been investigated with QCM, which has been known as nano-gram order mass detector. The self-assembly process of viologen was monitored using resonant frequency$({\Delta}F)$ and resonant resistance(R). The redox process of viologen was observed with resonant frequency $({\Delta}F)$.

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