• Title/Summary/Keyword: selectivity

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Effects of Reaction Conditions on Cobalt-Catalyzed Fischer-Tropsch Synthesis: Interactions between Operating Factors

  • Ajamein, Hossein;Sarkari, Majid;Fazlollahi, Farhad;Atashi, Hossein
    • Journal of the Korean Chemical Society
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    • v.55 no.5
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    • pp.824-829
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    • 2011
  • In Fischer-Tropsch Synthesis, because of few reactants ($H_2$, CO), scarce operating parameters affected on efficiency especially the selectivity of products. In this research, effect of operating parameters on the selectivity of Co-Mn-$TiO_2$ Fischer-Tropsch synthesis catalyst were studied by design of experimental procedure and Taguchi method. According to this research, interactions between operating factors have a crucial effect on light products selectivity. Among these interactions, (temperature${\times}$feed ratio) has the main influence on light hydrocarbons selectivity. It was concluded that temperature and feed ratio ($H_2$/CO) were the most integral operating parameters for much greater selectivity of light hydrocarbons.

Nitrate reduction by iron supported bimetallic catalyst in low and high nitrogen regimes

  • Hamid, Shanawar;Lee, Woojin
    • Advances in environmental research
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    • v.4 no.4
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    • pp.263-271
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    • 2015
  • In this study, the effect of initial nitrate loading on nitrate removal and byproduct selectivity was evaluated in a continuous system. Nitrate removal decreased from 100% to 25% with the increase in nitrate loading from 10 to $300mg/L\;NO_3-N$. Ammonium selectivity decreased and nitrite selectivity increased, while nitrogen selectivity showed a peak shape in the same range of nitrate loading. The nitrate removal was enhanced at low catalyst to nitrate ratios and 100% nitrate removal was achieved at catalyst to nitrate ratio of ${\geq}33mg\;catalyst/mg\;NO_3-N$. Maximum nitrogen selectivity (47%) was observed at $66mg\;catalyst/mg\;NO_3-N$, showing that continuous Cu-Pd-NZVI system has a maximum removal capacity of 37 mg $NO_3{^-}-N/g_{catalyst}/h$. The results from this study emphasize that nitrate reduction in a bimetallic catalytic system could be sensitive to changes in optimized regimes.

Spatial Selectivity Estimation for Intersection region Information Using Cumulative Density Histogram

  • Kim byung Cheol;Moon Kyung Do;Ryu Keun Ho
    • Proceedings of the KSRS Conference
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    • 2004.10a
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    • pp.721-725
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    • 2004
  • Multiple-count problem is occurred when rectangle objects span across several buckets. The Cumulative Density (CD) histogram is a technique which solves multiple-count problem by keeping four sub-histograms corresponding to the four points of rectangle. Although it provides exact results with constant response time, there is still a considerable issue. Since it is based on a query window which aligns with a given grid, a number of errors may be occurred when it is applied to real applications. In this paper, we proposed selectivity estimation techniques using the generalized cumulative density histogram based on two probabilistic models: (1) probabilistic model which considers the query window area ratio, (2) probabilistic model which considers intersection area between a given grid and objects. In order to evaluate the proposed methods, we experimented with real dataset and experimental results showed that the proposed technique was superior to the existing selectivity estimation techniques. The proposed techniques can be used to accurately quantify the selectivity of the spatial range query on rectangle objects.

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A Compressed Histogram Technique for Spatial Selectivity Estimation (공간 선택률 추정을 위한 압축 히스토그램 기법)

  • Chung, Jae-Du;Chi, Jeong-Hee;Ryu, Keun-Ho
    • 한국공간정보시스템학회:학술대회논문집
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    • 2004.12a
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    • pp.69-74
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    • 2004
  • Selectivity estimation for spatial query is very important process in finding the most efficient execution plan. Many works have been performed to estimate accurately selectivity. Although they deal with some problems such as false-count, multi-count, they require a large amount of memory to retain accurate selectivity, so they can not get good results in little memory environments such as mobile-based small database. In order to solve this problem, we propose a new technique called MW histogram which is able to compress summary data and get reasonable results. It also has a flexible structure to react dynamic update. The experimental results showed that the MW histogram has lower relative error than MinSkew histogram and gets a good selectivity in little memory.

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The Assessment on the Sound Quality of Reduced Frequency Selectivity of Hearing Impaired People (난청인의 주파수 선택도 둔화현상이 음질에 미치는 영향 평가)

  • An, Hong-Sub;Park, Gyu-Seok;Jeon, Yu-Yong;Song, Young-Rok;Lee, Sang-Min
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.6
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    • pp.1196-1203
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    • 2011
  • The reduced frequency selectivity is a typical phenomenon of sensorineural hearing loss. In this paper, we compared two modeling methods for reduced frequency selectivity of hearing impaired people. The two models of reduced frequency selectivity were made using LPC(linear prediction coding) algorithm and bandwidth control algorithm based on ERB(equivalent rectangular bandwidth) of auditory filter, respectively. To compare the effectiveness of two models, we compared the result of PESQ (perceptual evaluation of speech quality) and LLR(log likelihood ratio) using 36 Korean words of two syllables. To verify the effect on noise condition, we mixed white and babble noise with 0dB and -3dB SNR to speech words. As the result, it is confirmed that the PESQ score of bandwidth control algorithm is higher than the score of LPC algorithm, on the other hands, and the LLR score of LPC algorithm is lower than the score of bandwidth control algorithm. It means that both non-linearity and widen auditory filter characteristics caused by reduced frequency selectivity could be more reflected in bandwidth control algorithm than in LPC algorithm.

Study on the size selectivity of a gillnet for Pacific herring (Clupea pallasii) in the eastern sea of Korea (동해안 청어 (Clupea pallasii) 자망의 망목선택성에 관한 연구)

  • An, Heui-Chun;Bae, Jae-Hyun;Kim, Seonghun
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.49 no.4
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    • pp.360-367
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    • 2013
  • The mesh selectivity of the gillnet for Pacific herring (Clupea pallasii) was examined in field experiments with four different mesh sizes (63, 69, 75 and 81mm) from June to July, 2013 in the coastal areas of Imwon in Gangwon province. The fishing performance tests were conducted with a commercial Pacific herring gillnet and a biodegradable gillnet for Pacific herring together selectivity tests. The filed tests were carried out the total 11 times. The master curve of selectivity was estimated by the extended Kitahara's method. In the results, the catch number of Pacific herring was 9,409 (2,203kg) and occupied 84.2% in total catches weight. The optimal mesh size for 50% retention on first maturity size (female, 250mm) of Pacific herring was estimated as 64.5mm by master selectivity curves. The fishing performance of the biodegradable gillnet was showed to be equivalent with commercial gill for Pacific herring.

Characteristics of Cation Selectivity for Equilibrium and Column Cation Exchanges (평형 및 칼럼교환에서 양이온 선택도 특성)

  • 이석중;이인형
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.2
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    • pp.156-159
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    • 2002
  • Ion exchange is the most reliable process to remove the ionic impurities and the economic operation. ion exchange is widely used in water and wastewater treatment, especially softening and demineralization. ion selectivity depends on the hydrated radius, charge of ions and concentration. The objective of this study was to determine the selectivity order of cations with equilibrium and column ion exchanges and to investigate the effect of the background anion on selectivity. Cation selectivity increases with decreasing concentration and increasing charge ( $H^+$ < $K^+$ << $Cu^{2+}$ < $Co^{2+}$ < TEX>$Ca^{2+}$ << $Ce^{3+}$)in equilibrium and column cation adsorptions.

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A Study on the Selectivity of the Trawl Net for the Demersal Fishes in the East China Sea-III (동지나해 저서 어자원에 대한 트롤어구의 어획선택성에 관한 연구-III)

  • Lee, Ju-Hee;Kim, Sam-Gon;Kim, Min-Seok
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.29 no.3
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    • pp.177-182
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    • 1993
  • In order to estimate the mesh selectivity master curves and the optimum mesh size, experiments were made by the cover net method with the cod-ends of the five different the opening mesh sizes(51.2mm, 70.2mm, 77.6mm, 88.0mm and 111.3mm). After that 163 hauling were performed and there by investigated, on the training vessel Saebada in the Southern Korean Sea and East China Sea from June 1991 to August 1992. In this report, the mesh selectivity master curves were fitted by using logistic function(S=1/(1+exp super(-(aR+b))), R=(L-L sub(0))/(M-M sub(0)) and the optimum mesh sizes were estimated from each master curve. In this case, a and b are the selection parameters, M is the mesh size of each experimental cod-end. L is body length, L sub(0) and M sub(0) is the distance from the coordinate origine to intersection of linear regression between 25% and 50% selection length. The results obtained are summarized as follows; 1. Trachurus japonicus: Mesh selectivity master curve parameters: a and b were 2. 25, -4.73 respectively and optimum mesh size was estimated to be 79.3mm. 2. Trichiurus lepturus: Mesh selectivity master curve parameters: a and b were 0.81, -3.17 respectively and optimum mesh size was estimated to be 64.5mm. 3. Photololigo edulis: Mesh selectivity master curve parameters: a and b were 1.30m, -4.10 respectively and optimum mesh size was estimated to be 89.9mm. 4. Todarodes pacificus: Mesh selectivity master curve parameters: a and b were 1. 35, -3.45 respectively and optimum mesh size was estimated to be 89.4mm.

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A Selectivity Estimation Technique for Current Query of Moving Objects (이동객체를 위한 현재 질의 선택율 추정 기법)

  • Chi, Jeong-Hee;Ryu, Keun-Ho;Jeong, Doo-Young
    • Journal of the Korea Society of Computer and Information
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    • v.11 no.1 s.39
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    • pp.87-96
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    • 2006
  • Selectivity estimation is one of the query optimization techniques. It is difficult for the previous selectivity estimation techniques for moving objects to apply the position change of moving objects to synopsis. Therefore, they result in much error when estimating selectivity for queries, because they are based on the extended spatial synopsis which does not consider the property of the moving objects. In order to reduce the estimation error, the existing techniques should often rebuild the synopsis. Consequently problem occurs, that is, the whole database should be read frequently. In this paper, we proposed a moving object histogram method based on quad tree to develop a selectivity estimation technique for moving object queries. We then analyzed the performance of the proposed method through the implementation and evaluation of the proposed method. Our method can be used in various location management systems such as vehicle location tracking systems, location based services, telematics services, emergency rescue service, etc in which the location information of moving objects changes over time.

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Diffusion-Selectivity Analysis of Permanent Gases through Carbon Molecular Sieve Membranes

  • Kang, Jong-Seok;Park, Ho-Bum;Lee, Young-Moo
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.43-53
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    • 2003
  • The selectivity of a gas in the carbon molecular sieve membrane (CMSM) can be expressed as the ratio of the product of the diffusivity and the solubility of two different gases. The diffusivity is also expressed as the product of the entropy and the total energy (kinetic and potential energy) in the nano-sized pore of the membrane. The present study calculates the entropic-energy and selectivity of penetrant gases such as H$_2$, O$_2$, N$_2$, and CO$_2$ from the gas-in-a box theory to physically analyze the diffusivity of penetrant gas in slit-shaped pore of CMSM focusing on the restriction of gas motion based on the size difference between penetrant gas pairs. The contribution of each energy term is converted to entropic term separately. By the conjugated calculation for each entropic-energy, the entropic effects on diffusivity-selectivity for gas pairs such as H$_2$/N$_2$, CO$_2$/N$_2$, and O$_2$/N$_2$ were analyzed within active pore of CMSM. In the activated diffusion domain, the calculated value of entropic-selectivity lies between 9.25 and 111.6 for H$_2$/N$_2$, between 3.36 and 6.0 for CO$_2$/N$_2$, and between 1.25 and 16.94 for O$_2$/N$_2$, respectively. The size decrement of active pore in CMSM had the direct effect on the reduction of translational entropic-energy and the contribution of vibrational entropic-energy for N$_2$, O$_2$, and H$_2$ was almost negligible. However, the vibrational entropic term of CO$_2$ might extravagantly affect on the entropic-selectivity.