• Title/Summary/Keyword: selective protection

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A Simple, Efficient, Catalyst-Free and Solvent-Less Microwave-Assisted Process for N-Cbz Protection of Several Amines

  • Aouf, Zineb;Mansouri, Rachida;Lakrout, Salah;Berredjem, Malika;Aouf, Nour-Eddine
    • Journal of the Korean Chemical Society
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    • v.61 no.4
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    • pp.151-156
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    • 2017
  • A simple, green and chemo-selective method for the N-benzyloxycarbonylation of amines, ${\beta}$-amino alcohols, ${\alpha}$-amino esters and sulfonamides has been developed under microwave irradiation. Good to excellent yields of the N-benzyloxycarbamates compounds were obtained in short times without any side products.

Transient Protection of Intramolecular Hydrogen Bonding: A Simple but Elegant Approach for Functional Imaging

  • Kim, Jong-Man;Min, Sung-Jun;Park, Bum-Jun;Lee, Jae-Hyung;Ahn, Kwang-Duk
    • Macromolecular Research
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    • v.12 no.5
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    • pp.493-500
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    • 2004
  • We have developed a novel method for patterning functional images in thin polymer films. The key materials we utilized for the imaging were dihydroxyanthraquinones protected with acid-labile tert-butoxycarbonyl (t-Boc) blocking groups. Among the tested compounds, 1,4-dihydroxyanthraquinone (quinizarin; 1) underwent the most drastic change in terms of its color and fluorescence upon protection. We prepared the t-Boc-protected quinizarin and polymers bearing the protected quinizarins as pendent groups. To investigate the possibility of a single-component imaging system, we synthesized a styrenic monomer 14 incorporating protected quinizarin and a maleimide derivative 15 bearing a photoacid generating group and subjected them to polymerization. Selective removal of the protecting groups of the quinizarin moieties in the exposed area using photolithographic techniques allowed regeneration of quinizarin and patterned fluorescence images in the polymer films.

Efficient Protection of Alcohols with Carboxylic Acids Using a Variety of Heteropolyoxometallates as Catalysts, Studying Effective Reaction Parameters

  • Tayebee, Reza;Cheravi, Fatemeh
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.2899-2904
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    • 2009
  • Esterification is an important class of reactions in the preparation of perfumery and flavor chemicals, wherein homogeneous, solid acidic, and superacidic catalysts are normally used. Now, an efficient and selective protocol for protection of various functionalized alcohols employing carboxylic acids as protecting agents is realized through the catalytic mediation of simple heteropolyoxometallates. In this methodology, water is the only by-product and notably the aspect of effluent treatments does not arise. The advantages include the operational simplicity, recycle ability of the catalyst and mild reaction conditions. The present catalytic system may be a potential candidate not only for laboratory practice but also for commercial applications and offers an environmentally safer alternative to the existing processes.

Integrated Protection Method for DC Railway Systems (통합형 직류철도 보호계전 방식)

  • Kang, Sang-Hee;Choi, Chang-Young;Lee, Won-Seok;Jung, Ho-Sung
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.2
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    • pp.285-292
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    • 2011
  • DC traction power system is operated ungrounded so that minimize the stray current. Because the stray current is still present, a rail potential is increased. The ground faults in the DC railway systems are usually detected by a potential relay(64P). Moreover, if the rail potential goes high in the ordinary operating state because of the traction load, the potential relay would be maloperated. A presented protective relaying algorithm that can identify exactly the faulted region and can distinguish a ground fault from the potential rising of the rail is presented in this paper. This paper presents simulation technique that is very similar to the real operation situation using PSCAD/EMTDC.

Seed and Root Rots of Ginseng (Panax quinquefolius L) Caused by Cylindrocarpon destructans and Fusarium spp.

  • Reeleder, R.D.;Roy, R.;Capell, B.
    • Journal of Ginseng Research
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    • v.26 no.3
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    • pp.151-158
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    • 2002
  • Ginseng (Panax quinquefolius L.) has become one of the most valuable herb crops grown in North America. However, traditional cropping practices are favourable to disease and significant losses due to root disease are common, despite frequent use of fungicides. Seedlots are often contaminated with pathogens, however, little is known about the causes of seed decay and the role of seed pathogens as incitants of root rots. It was shown that both Fusarium spp. and Cylindrocarpon destructans were able to rot seeds and that C. destructans was more virulent than Fusarium spp. on seedling roots. A modified rose bengal agar MRBA) medium (1 g KH$_2$PO$_4$; 0.5 g MgSO$_4$; 50 mg rose bengal; 10 g dextrose; 5 g Bacto peptone; 15 g Bacto agar; 30 mg streptomycin sulfate; 250 mg ampicillin; 10 mg rifampicin; 500mg pentachloronitrobenzene; 500 mg dicloran; and 1 L distilled water) was superior to potato dextrose agar in detecting C. destuctans in diseased roots. Isolation of C. destructans from diseased seedlings arising from seeds sown in replant soil supported the hypothesis that this pathogen is a cause of ginseng replant failure in North America.

Novel Detection Protocol for Erwinia amylovora in Orchard Soil after Removal of Infected Trees

  • Sujin Song;Byeori Kim;Kwang-Pyo Kim;Eunjung Roh
    • The Plant Pathology Journal
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    • v.40 no.3
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    • pp.282-289
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    • 2024
  • Fire blight is a bacterial disease caused by Erwinia amylovora. In Korea, fire blight was first reported in 2015 in an orchard. If the infection is confirmed, all trees in the orchard must be removed and the orchard must remain closed for 3 years. Since 2020, if the number of trees infected with fire blight is less than 5% of the total trees in the orchard, only the infected tree and adjacent trees are removed in Korea. Three years after removal, the trees can be replanted after confirming that the orchard soil is free from E. amylovora. In this study, a protocol was established for detecting E. amylovora in soil via selective enrichment, using tryptic soy broth with 0.05% bile salts and 50 ㎍/ml cycloheximide, and real-time polymerase chain reaction. This protocol resulted in a 1,000-times improved detection limit for E. amylovora in soil samples compared to that in unenriched samples. Soil monitoring was performed for orchards where fire blight-infected trees had been removed 3-27 months prior; the selected orchards were monitored every 3 months. Monitoring confirmed that E. amylovora was not present in the soil at any site in any of the orchards. A new detection protocol facilitates the monitoring of E. amylovora in soil and could help permit the replanting of trees in orchards. Also monitoring results provide evidence that trees can be planted earlier.

A Study on the Development and Application of Digital Protective Relay for DC Feeding System of Light Rail Transit System (경전철 직류급전계통을 위한 디지털 보호제어장치의 개발 및 적용에 관한 연구)

  • Baek, Byung-San;Kim, Jae-Chul
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.2
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    • pp.77-86
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    • 2005
  • The DC protection and control device for the feeding system of a Light Rail Transit(LRT) system is developed. For the development, the short circuit characteristics in the system are analyzed. As a result a protection algorithm for the DC fault selective relay (50F) is newly proposed, and principles of the DC fault selective relay, Line Test Device (LTD), DC Over Current Relay (DC OCR) are introduced From the development, the specifications and codes used to be unclear have become clarified and summarized. Moreover, the methods to examine the protective characteristics and Electromagnetic Compatibility (EMC) are established Finally, the performance and the effectiveness of the developed protective relay have been verified with the test based on IEC. For the reliability of the system, the relay has been installed and is being operated at the test track of the LRT system at Gyeong-San.

The Effects of Advanced Reburning with SNCR on NOx and CO Reduction (무촉매 환원법이 적용된 응용 재연소 방법에 의한 NOx와 CO의 저감 효과)

  • Lee Chang-Yeop;Kim Dong-Min;Baek Seung-Wook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.8 s.251
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    • pp.788-795
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    • 2006
  • From the view of the environmental protection against the use of fossil fuels, the great of efforts have been exerted to find an effective method which is not only pollutant reduction but also high thermal efficiency. Reburning is a useful technology in reducing nitric oxide through injection of a secondary hydrocarbon fuel. In this paper, an experimental study has been conducted to evaluate the hybrid effects of reburning and selective non-catalytic reaction (SNCR) on $NO_x/CO$ reduction from oxygen-enriched LPG flame. Experiments were performed in flames stabilized by a co-flow swirl burner, which was mounted at the bottom of the furnace. Tests were conducted using LPG gas as main fuel and also as reburn fuel. The paper reported data on flue gas emissions, temperature distribution in furnace and various heat fluxes at the wall for a wide range of experimental conditions. Overall temperature in the furnace, heat fluxes to the wall and $NO_x$ generation were observed to increase by oxygen-enriched combustion, but due to its hybrid effects of reburning and SNCR, $NOx/CO$ concentration in the downstream has considerably decreased.

A simple route for synthesis of SnO2 from copper alloy dross

  • Lee, Jung-Il;Lee, Bo Seul;Lee, Ji Young;Shin, Ji Young;Kim, Tae Wan;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.2
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    • pp.84-87
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    • 2014
  • Separation/recovery of valuable metals such as zinc, nickel or tin from copper alloy dross has recently attracted from the viewpoints of environmental protection and resource recycling. In this study, preliminary investigation on separation of tin (Sn) from copper alloy dross using selective dissolution method was performed. The tin in the copper alloy dross did not dissolve in an aqueous nitric acid solution which could allow the concentration/separation of tin from the copper alloy dross. Precipitation of tin as $H_2SnO_3$ (meta stannic acid)occurred in the solution and transformed to tin dioxide ($SnO_2$) after drying process. The dried sample was heat-treated at low temperature and its crystal structure, surface morphology and chemical composition were investigated.

Protection of Windows Media Video Providing Selective Encryption (선택적 암호화가 가능한 윈도우 미디어 보호 방법)

  • Park, Ji-Hyun;Ryou, Jae-Cheol
    • The KIPS Transactions:PartB
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    • v.16B no.2
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    • pp.101-108
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    • 2009
  • As content serviced for IP set-top boxes is streamed over IP network, the existing hacking tools for IP network can be used to capture the streamed content. Until recently, most of the content serviced on IP set-top boxes has been MPEG-2 TS. However, this content will be gradually moved to WMV, MPEG-4 or H.264 because of the relatively low compression efficiency and overhead of the TS packet. In this paper, we propose a DRM scheme other than WMRM for streamed WMV content. Our approach is to design a DRM scheme independent to the existing WMV streaming system. We also design this scheme in order to provide the feature for controlling the DRM processing time considering device performance. We verified it through the experiment.