• Bulletin of the Korean Chemical Society
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• 제23권4호
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• pp.605-609
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• 2002

A competitive enzyme-linked immunosorbent assay (ELISA) was developed for the quantitative detection of organophosphorus insecticide cyanophos. An analogue (hapten) of cyanophos was synthesized and was coupled to BSA to produce polyclonal antibodi es from rabbits. The antisera were screened against another hapten coupled to ovalbumin (OVA). Using the sera of highest specificity, an antigen-coated ELISA was developed, which showed an I50 of 310 ng/mL with the detection limit of 20 ng/mL. The antibodies showed negligible cross-reactivities with other organophosphorus pesticides except for parathion-methyl, which makes the assay suitable for the selective detection of cyanophos.

• Smart Structures and Systems
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• 제22권6호
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• pp.711-725
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• 2018

Most of the practical engineering structures exhibit nonlinearity due to nonlinear dynamic characteristics of structural joints, nonlinear boundary conditions and nonlinear material properties. Hence, it is highly desirable to detect and characterize the nonlinearity present in the system in order to assess the true behaviour of the structural system. Further, these identified nonlinear features can be effectively used for damage diagnosis during structural health monitoring. In this paper, we focus on the detection of the nonlinearity present in the system by confining our discussion to only a few selective time-frequency analysis and multivariate analysis based techniques. Both damage induced nonlinearity and inherent structural nonlinearity in healthy systems are considered. The strengths and weakness of various techniques for nonlinear detection are investigated through numerically simulated two different classes of nonlinear problems. These numerical results are complemented with the experimental data to demonstrate its suitability to the practical problems.

• Bulletin of the Korean Chemical Society
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• 제26권5호
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• pp.781-785
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• 2005

A fast and reliable method for the selective separation and preconcentration of $Cu^{2+}$ ions using homogeneous liquid-liquid extraction was developed. A new $\alpha$-dioxime derivative (2H-1,4-benzothioazine-2,3(4H)dionedioxime, Dioxime I) was synthesized and investigated as a suitable selective complexing ligand for $Cu^{2+}$ ions. Zonyl FSA (FSA) was applied as a phase-separator agent under the slightly acidic pH conditions. Under the optimal experimental conditions ([FSA] = 3.2% w/v, [THF] = 19.5% v/v, [Dioxime I] = 1.9 ${\times}\;10^{-3}$ M, and pH = 4.7), 10 ${\mu}g\;of\;Cu^{2+}$ in 5.2 mL aqueous phase could be extracted quantitatively into 80 $\mu$L of the sedimented phase. The maximum concentration factor was 65-fold. The limit of detection of the proposed method was 0.005 ng $mL^{-1}$. The reproducibility of the proposed method, on the 10 replicate measurements, was 1.3%. The influence of the pH, type and volume of the water-miscible organic solvent, concentration of FSA, concentration of the complexing ligand and the effect of different diverse ions on the extraction and determination of $Cu^{2+}$ ions were investigated. The proposed method was applied to the extraction and determination of $Cu^{2+}$ ion in different synthetic and natural water samples.

• Bulletin of the Korean Chemical Society
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• 제31권2호
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• pp.401-405
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• 2010

The Schiff base 1,2-bis(E-2-hydroxy benzylidene amino)anthracene-9,10-dione has been synthesized and explored as ionophore for preparing PVC-based membrane sensors selective to the copper ($Cu^{2+}$) ion. Potentiometric investigations indicate high affinity of these receptors for copper ion. The best performance was shown by the membrane of composition (w/w) of ionophore: 1 mg, PVC: 33 mg, DOP: 66 mg and KTpClPB as additive were added 50 mol % relative to the ionophore in 1 ml THF. The proposed sensor's detection limit is $2.8{\times}10^{-7}$ M over pH 5 at room temperature (Nernstian slope 31.76 mV/dec.) with a response time of 15 seconds and showed good selectivity to copper ion over a number of interfering cations.

• ETRI Journal
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• 제37권1호
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• pp.66-76
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• 2015

In this work, we propose an efficient selective retransmission method for multiple-input and multiple-output (MIMO) wireless systems under orthogonal frequency-division multiplexing (OFDM) signaling. A typical received OFDM frame may have some symbols in error, which results in a retransmission of the entire frame. Such a retransmission is often unnecessary, and to avoid this, we propose a method to selectively retransmit symbols that correspond to poor-quality subcarriers. We use the condition numbers of the subcarrier channel matrices of the MIMO-OFDM system as a quality measure. The proposed scheme is embedded in the modulation layer and is independent of conventional hybrid automatic repeat request (HARQ) methods. The receiver integrates the original OFDM and the punctured retransmitted OFDM signals for more reliable detection. The targeted retransmission results in fewer negative acknowledgements from conventional HARQ algorithms, which results in increasing bandwidth and power efficiency. We investigate the efficacy of the proposed method for optimal and suboptimal receivers. The simulation results demonstrate the efficacy of the proposed method on throughput for MIMO-OFDM systems.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제9권2호
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• pp.583-599
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• 2015

We apply the Bayesian matching pursuit (BMP) algorithm to the estimation of time-frequency selective channels in orthogonal frequency division multiplexing (OFDM) systems. By exploiting prior statistics and sparse characteristics of propagation channels, the Bayesian method provides a more accurate and efficient detection of the channel status information (CSI) than do conventional sparse channel estimation methods that are based on compressive sensing (CS) technologies. Using a reasonable approximation of the system model and a skillfully designed pilot arrangement, the proposed estimation scheme is able to address the Doppler-induced inter-carrier interference (ICI) with a relatively low complexity. Moreover, to further reduce the computational cost of the channel estimation, we make some modifications to the BMP algorithm. The modified algorithm can make good use of the group-sparse structure of doubly selective channels and thus reconstruct the CSI more efficiently than does the original BMP algorithm, which treats the sparse signals in the conventional manner and ignores the specific structure of their sparsity patterns. Numerical results demonstrate that the proposed Bayesian estimation has a good performance over rapidly time-varying channels.

• 한국전자통신학회논문지
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• 제10권1호
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• pp.1-6
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• 2015

최근 원음 반주기에 대한 관심이 증가됨에 따라 고가의 스튜디오 직접 녹음 방법 대신 보다 저렴한 방법을 시도하고 있다. 그 구체적인 방법으로는 가수의 음악 앨범에서 가수의 목소리만 제거하여 원음 반주 음원을 만드는 것이다. 본 논문에서는 스테레오로 녹음된 반주음악에서 보컬을 분리하는 시스템을 제안한다. 제안하는 시스템은 두 단계로 구성된다. 첫 단계는 보컬을 검출하는 단계이다. 이 단계에서는 MFCC를 가지고 SVM 방법을 이용하여 입력 신호를 보컬 부분과 비보컬 부분으로 분리한다. 두 번째 단계에서는 보컬 부분에 대해 각 주파수 빈별로 선택적 주파수 차감을 수행한다. 제안하는 방법으로 보컬을 제거한 음악에 대한 청취실험에서 상대적으로 높은 만족도를 보여준다.

• Bulletin of the Korean Chemical Society
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• 제32권4호
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• pp.1215-1220
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• 2011

An electrochemically-modified electrode [P(EDOP-SWNTs)/GCE] was prepared by electropolymerization of 3,4-ethylenedioxy pyrrole (EDOP) single-walled carbon nanotubes (SWNTs) on the surface of a glassy carbon electrode (GCE) and characterized by SEM, CV, and DPV. This modified electrode was employed as an electrochemical biosensor for the selective determination of serotonin concentrations at pH 7.4 and exhibited a typical enhanced effect on the current response of serotonin with a lower oxidation overpotential. The linear response was in the range of $1.0{\times}10^{-7}$ to $1.0{\times}10^{-5}$ M, with a correlation coefficient of 0.998 on the anodic current. The lower detection limit was calculated as 5.0 nM. Due to the relatively low currents and difference of potentials in the electrochemical responses of uric acid (UA), ascorbic acid (AA), and dopamine (DA), the modified electrode was a useful and effective sensing device for the selective and sensitive serotonin determination in the presence of UA, AA, and DA.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2466-2470
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• 2007

A new highly salicylate-selective PVC membrane electrode based on tripodal tris-thiourea derivatives, L1 and L2, as neutral carriers is described. The electrodes display an excellent potentiometric response to salicylate ions and an anti-Hofmeister selectivity sequence in the following order: Salicylate? > ClO4 ? > Benzoate? > I? >NO3? > NO2? > Maleate? > Acetate? > Lactate? > Fumarate?. It also exhibited a near-Nernstian potential in a linear range of 5.0 × 10?5 - 1.0 × 10?1 M with a detection limit of 9.0 × 10?5 mol/L and a slope of ?59.9 mV/decade at a pH of 7.0 in a saline buffer solution at 25 oC. The stability constant (log KS) of the anionsionophore complex was also determined at 25 oC by a conductometric titration in DMSO solution.

• Bulletin of the Korean Chemical Society
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• 제26권1호
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• pp.57-62
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• 2005

The potentiometric responses for various anions are investigated with membrane electrode (membrane 1) based on 1,3-diethyl-1,3-dihydroxy-1,3-bis(2-dimethylaminomethyl ferrocenyl) disiloxane. The nitrate ion-selective electrode based on compound 1 gave a good Nernstian response of 58.18 mV per decade for nitrate with the detection limit of −e5.66 of log [NO3−e]. Compound 1 has all those functional groups and the other two compounds have less functional group of ferrocenyl or ferrocenyl and hydroxide, respectively. Even though, potentiometric response to anions was excellent at pH 5, the selectivity pattern for all three membrane electrode based on series of disiloxane is almost like Hofmeister sequence at pH 5. However, the membrane electrode 1-3 exhibited very different response to anions at pH 7. In this pH, NH2 is not protonated and ionophore may act as neutral carrier. Hydrogen bond may enhance the responsibility to hydrogen acceptors and intramolecular electro-active site may increase the permeability of analyte to ionophore in membrane.