• Title/Summary/Keyword: secondary compound

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Experimental performance investigation of compound parabolic cavity receiver having single absorber tube

  • Omar Al-Nabhani;Saud Al-Kalbani;Azzam Al-Alawi;Afzal Husain
    • Advances in Energy Research
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    • v.8 no.3
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    • pp.155-163
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    • 2022
  • The current study presents experimental research on a parabolic trough collector with tube and cavity receivers. The primary concentrating parabolic reflector is designed for an aperture area of 2×2 m2 with mirror-polished stainless steel sheet reflectors. The cavity receiver consists of a compound parabolic secondary reflector and a copper tube. Both the conventional tube receiver and the cavity receiver tube are coated with black powder. The experiments are carried out to compare the efficiency of the cavity receiver with the tube receiver for fluid temperature rise, thermal efficiency, and overall losses. The experiments showed significantly higher fluid temperature rise and overall efficiency and lower thermal losses for the cavity receiver compared to the tube receiver within the parameters explored in this study.

Ruthenium Complex Catalyzed Syntehesis of Diamino Compounds from ${\alpha},{\omega}$-Diols and Secondary Amines

  • Keun-Tae Huh;Sang Chul Shim;Chll Hoon Doh
    • Bulletin of the Korean Chemical Society
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    • v.11 no.1
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    • pp.45-49
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    • 1990
  • ${\alpha},{\omega}$-Diols react with secondary amines in the presence of a catalytic amount of ruthenium catalyst at $180^{\circ}C$ to give diamino compounds in good to excellent yields. The yield of diamino compound was affected by the molar ratio of ${\alpha},{\omega}$-diol to secondary amine. The reaction is affected by the nature of the phosphorus ligands employed and the effectiveness of the added ligand is completely different depending on the chain length of the ${\alpha},{\omega}$-diol. The reaction between ethylene glycol and primary amine in the presence of a catalytic amount of ruthenium catalyst gave 1,4-disubstituted piperazine.

A Volatile Organic Compound Sensor Using Porous Co3O4 Spheres

  • Kim, Tae-Hyung;Yoon, Ji-Wook;Lee, Jong-Heun
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.134-138
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    • 2016
  • Porous $Co_3O_4$ spheres with bimodal pore distribution (size: 2-3 nm and ~ 30 nm) were prepared by ultrasonic spray pyrolysis of aqueous droplets containing Co-acetate and polyethylene glycol (PEG), while dense $Co_3O_4$ secondary particles with monomodal pore distribution (size: 2-3 nm) were prepared from the spray solution without PEG. The formation of mesopores (~ 30 nm) was attributed to the decomposition of PEG. The responses of a porous $Co_3O_4$ sensor to various indoor air pollutants such as 5 ppm $C_2H_5OH$, xylene, toluene, benzene, and HCHO at $200^{\circ}C$ were found to be significantly higher than those of a commercial sensor using $Co_3O_4$ and dense $Co_3O_4$ secondary particles. Enhanced gas response of porous $Co_3O_4$ sensor was attributed to high surface area and the effective diffusion of analyte gas through mesopores (~ 30 nm). Highly sensitive porous $Co_3O_4$ sensor can be used to monitor various indoor air pollutants.

Cytotoxic Effects of Furanosesterterpenes, Cyclitol Derivatives, and Bromotyrosine Derivative Isolated from Marine Sponges

  • Sohn, Jae-Hak;Oh, Hyun-Cheol;Jung, Jee-H.;Bae, Song-Ja
    • Preventive Nutrition and Food Science
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    • v.10 no.3
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    • pp.257-261
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    • 2005
  • Marine sponges are known to produce a number of cytotoxic secondary metabolites. In the course of searching for cytotoxic metabolites from marine organisms, we have evaluated cytotoxic activities of six marine secondary metabolites isolated from various sponges. The cytotoxic compounds 1-6 were isolated by the application of various chromatographic methods, including column chromatography and HPLC. The molecular structures were mostly determined using mass spectrometry (MS) and Nuclear Magnetic Resonance (NMR) Spectroscopy. Furanosestererpenes (compounds 1-3) from Psammocinia sp., cyclitol derivatives (compounds 4 and 5) from Sarcotragus sp., and bromotyrosine-type compound (6) from an association of two sponges Jaspis wondoensis and Poecillastra wondoensis were evaluated for their cytotoxic activity against three cancer cell lines; Hep G2, HeLa, and MCF-7. All tested compounds exhibited cyctoxicity at concentrations ranging from $5\;\mug/mL\;to\;25\;\mug/mL.$ Particularly, among the tested compounds, compound 6 showed the highest potency displaying at least $80\%$ of cytotoxicity at $5\;\mug/mL$ level against all three cancer cell lines.

Kinetic Study on the Oxidation Reaction of Alcohols by Cr(VI)-Quinoline Compound (크롬(VI)-퀴놀린 화합물에 의한 알코올류의 산화반응에 대한 반응속도론적 연구)

  • Park, Young-Cho;Kim, Soo-Jong
    • Journal of Convergence for Information Technology
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    • v.11 no.9
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    • pp.109-114
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    • 2021
  • Cr(VI)-quinoline compound[(C9H7NH)2Cr2O7] was synthesized by the reaction between of quinoline and chromium(VI) trioxide, and structure was FT-IR, elemental analysis. The oxidation ability of benzyl alcohol greatly depends upon the dielectric constant of the used organic solvent, where carbon tetrachloride was worst and N,N'-dimethylformamide was best solvent. Noticeably, in N,N'-dimethylformamide solvent, Cr(VI)-quinoline compound oxidized substituted benzyl alcohols. The Hammett reaction constant(ρ)=-0.69(303K). As a resuit, Cr(VI)-quinoline compound was found as efficicent oxidizing agent that converted benzyl alcohol, allyl alcohol, primary alcohol and secondary alcohols to the corresponding aldehydes or ketones. Cr(VI)-quinoline compound was selective oxidizing agent of benzyl alcohol, allyl alcohol and primary alcohol in the presence of secondary alcohol ones.

Production and Characteristics of Antidandruffy Compound from Chrysanthemum zawadskii (구절초(Chrysanthemum zawadskii)로부터 비듬균에 대한 항균물질의 생산 및 특성)

  • Lee, Sung-Hyun;Lee, Jong-Soo
    • Microbiology and Biotechnology Letters
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    • v.35 no.3
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    • pp.220-225
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    • 2007
  • In order to develop a potent antidandruffy agent from medicinal plants, various extracts of medicinal plants and herbs were prepared and investigated its antifungal activity against Malassezia furfur. Among 85 kinds of the secondary screened medicinal plants and herbs, water extract of Chrysanthemum zawadskii had the highest antifungal activity against dandruffy-producing Malassezia furfur. The antifungal compound was also maximally extracted when the powder of Chrysanthemum zawadskii was treated with water at $50^{\circ}C$ for 6 hours. The antifungal compound from Chrysanthemum zawadskii was partially purified by silica gel column chromatography and the partial purified compound was soluble at $70^{\circ}C$ for 20 min and pH $3.0{\sim}9.0$.

Performance Analysis of CPV Modules for Optimizing Secondary Optical Elements (CPV모듈의 2차 광학계 특성에 따른 성능분석)

  • Park, Jeom-Ju;Jeong, Byeong-Ho;Park, Ju-Hoon;Lee, Kang-Yeon;Kim, Hyo-Jin
    • Journal of the Korean Solar Energy Society
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    • v.40 no.5
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    • pp.23-34
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    • 2020
  • Concentrator photovoltaic (CPV) system consists of high-quality complex optical elements, mechanical devices, and electronics components and can have the advantages of high integration and high-efficiency energy sources. III-V compound semiconductor cells have proven performance based on high reliability in the aerospace field, but have characteristics that require absolute support of the balance of systems (BOS) such as solar position trackers, receivers with heat sinks, and housing instruments. To determine the optimum parameters of secondary optical elements (SOEs) design for CPV systems, we designed three types of CPV modules, classified as non-SOEs type, reflective mirror type, and CPC lens type. We measured the I-V and P-V characteristics of the prototype CPV modules with the angle of inclination varying from 0° to 12° and with a 500-magnification Fresnel lens. The experimental results assumed misalignment of the solar position tracker or module design of pinpoint accuracy. As a result, at the 0° tilt angle, the CPC lens produced lower power due to the quartz transmittance ratio compared to that by other SOEs. However, for tilt angles greater than 3°, the CPC lens type module achieved high efficiency and stability. This study is expected to help design high-performance CPV systems.

Variation in the Pattern of Isoperoxidase Bands in the Four Parts of Lespedeza cyrtobotrya Miq. (참싸리 부위별(部位別) 과산화(過酸化) 동위효소형(同位酵素型)의 변이(變異))

  • Han, Young Chang
    • Journal of Korean Society of Forest Science
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    • v.30 no.1
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    • pp.42-49
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    • 1976
  • In order to study the variations of isoperoxidases of four parts of L. cyrtobotrya, leaves, secondary phloem, fibrous root, ovary were collected on september 29, 1975, respectively from 12 individuals which were planted in the compound of Institute of Forest Genetics, suwon, Korea. No variation of isoperoxidases appeared among the same parts which were collected from the same individual. There was a great variation in the pattern of isoperoxidase band among the 12 individuals in leaves, secondary phloem, fibrous root, and ovary. Regarding to the common occurrence band, the number was 7 in the leaves, secondary phloem, and fibrous root, while 35 bands were appeared in the ovary part. These was a great variation of occurrence band in four parts of Lespedeza. But the number of band in the parts of the Lespedeza was 4.50-5.16 on average, on the other hand there was no significant difference. No variation was observed in the activity of isoperoxidase in leaves. On the other hand, there was small varation in the secondary phloem, fibrous root and ovary.

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Control of Anthracnose and Gray Mold in Pepper Plants Using Culture Extract of White-Rot Fungus and Active Compound Schizostatin

  • Dutta, Swarnalee;Woo, E-Eum;Yu, Sang-Mi;Nagendran, Rajalingam;Yun, Bong-Sik;Lee, Yong Hoon
    • Mycobiology
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    • v.47 no.1
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    • pp.87-96
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    • 2019
  • Fungi produce various secondary metabolites that have beneficial and harmful effects on other organisms. Those bioactive metabolites have been explored as potential medicinal and antimicrobial resources. However, the activities of the culture filtrate (CF) and metabolites of whiterot fungus (Schizophyllum commune) have been underexplored. In this study, we assayed the antimicrobial activities of CF obtained from white-rot fungus against various plant pathogens and evaluated its efficacy for controlling anthracnose and gray mold in pepper plants. The CF inhibited the mycelial growth of various fungal plant pathogens, but not of bacterial pathogens. Diluted concentrations of CF significantly suppressed the severity of anthracnose and gray mold in pepper fruits. Furthermore, the incidence of anthracnose in field conditions was reduced by treatment with a 12.5% dilution of CF. The active compound responsible for the antifungal and disease control activity was identified and verified as schizostatin. Our results indicate that the CF of white-rot fungus can be used as an eco-friendly natural product against fungal plant pathogens. Moreover, the compound, schizostatin could be used as a biochemical resource or precursor for development as a pesticide. To the best of our knowledge, this is the first report on the control of plant diseases using CF and active compound from white-rot fungus. We discussed the controversial antagonistic activity of schizostatin and believe that the CF of white-rot fungus or its active compound, schizostatin, could be used as a biochemical pesticide against fungal diseases such as anthracnose and gray mold in many vegetables.