• 한국전기화학회:학술대회논문집
• /
• 2004.04a
• /
• pp.60-60
• /
• 2004

• Journal of the Korean Ceramic Society
• /
• v.37 no.5
• /
• pp.466-472
• /
• 2000

As cathode materials of LiMn2O4-based lithium-ion secondary batteries, Li(Mn1-$\delta$M$\delta$)2O4 (M=Ni and Co, $\delta$=0, 0.05, 0.1 and 0.2) materials which Co and Ni are substituted for Mn, were syntehsized by the solid state reaction at 80$0^{\circ}C$ for 48 hours. No second phases were formed in Li(Mn1-$\delta$M$\delta$)2O4 system with substitution of Co. However, substitution of Ni caued to form a second phase of NiO when its composition exceeded over 0.2 of $\delta$ in Li(Mn1-$\delta$M$\delta$)2O4. As the results of charging-discharging test, the maximum capacity of Li(Mn1-$\delta$M$\delta$)2O4 appeared in $\delta$=0.1 for both Co and Ni. Also, Li(Mn1-$\delta$M$\delta$)2O4 electrode showed higher capacity and better cycle performance than LiMn2O4.

• Journal of Powder Materials
• /
• v.29 no.3
• /
• pp.252-261
• /
• 2022

Cobalt is a vital metal in the modern society because of its applications in lithium-ion batteries, super alloys, hard metals, and catalysts. Further, cobalt is a representative rare metal and is the 30th most abundant element in the Earth's crust. This study reviews the current status of cobalt extraction and recycling processes, along with the trends in its production amount and use. Although cobalt occurs in a wide range of minerals, such as oxides and sulfides of copper and nickel ores, the amounts of cobalt in the minerals are too low to be extracted economically. The Democratic Republic of Congo (DRC) leads cobalt mining, and accounts for 68.9 % of the global cobalt reserves (142,000 tons in 2020). Cobalt is mainly extracted from copper-cobalt and nickel-cobalt concentrates and is occasionally extracted directly from the ore itself by hydro-, pyro-, and electro-metallurgical processes. These smelting methods are essential for developing new recycling processes to extract cobalt from secondary resources. Cobalt is mainly recycled from lithium-ion batteries, spent catalysts, and cobalt alloys. The recycling methods for cobalt also depend on the type of secondary cobalt resource. Major recycling methods from secondary resources are applied in pyro- and hydrometallurgical processes.

• Journal of Surface Science and Engineering
• /
• v.55 no.1
• /
• pp.32-37
• /
• 2022

In a carbon-zero social atmospher, research is underway to reduce the use of fossil fuels. Interest in cleaner energy sources and their storage system is growing, and among them, research on effective energy storage is being actively conducted. Energy storage system(ESS) can be divided into secondary batteries, fuel cells, and capacitors, and the superiority of energy density of secondary batteries has a dominent influence on the ESS market. However, as problems with secondary batteries, charge/discharge speed, safety, and deterioration of electrodes are being highlighted. In this study, an electrode for supercapacitor with superior charge/discharge speed and specific capacitance is manufactured. The manufactured spinel nickel cobalt electrodes had specific capacitances of 1018.8 F/g, 690.8 F/g, and 475.1 F/g at 1 A/g in 1 M KOH electrolyte, and shows a performance retention rate of 77.48%, 63.30%, and 58.16% after 2000cycles at 7 A/g.

• Korean Chemical Engineering Research
• /
• v.61 no.3
• /
• pp.348-355
• /
• 2023

Magnesium secondary batteries are attracting much attention due to their potential to replace conventionally used lithium ion batteries. Magnesium secondary battery cathode material Mo₆S₈ were synthesized by molten salt synthesis method and PVC as a carbon materials were added to improve electrochemical properties. Crystal structure, size and surface of the synthesized anode materials were measured through XRD and SEM. Charge-discharge profiles and rate capabilities were measured by battery test system. 2.81 wt% PVC coated sample showed the best rate capabilities of 85.8 mAh/g at 0.125 C-rate, 69.2 mAh/g at 0.5 C-rate, and 60.5 mAh/g at 1 C-rate.

• Design & Manufacturing
• /
• v.16 no.4
• /
• pp.34-39
• /
• 2022

Sustained economic development around the world is accelerating resource depletion. Research and development of secondary batteries that can replace them is also being actively conducted. Secondary batteries are emerging as a key technology for carbon neutrality. The core of an electric vehicle is the battery (secondary battery). Therefore, in this study, the temperature change by the heat source of the hammer and the rotational speed (rpm) of the abrasive disc of the Classifier Separator Mill (CSM) was repeatedly calculated and analyzed using the heat flow simulation STAR-CCM+. As the rotational speed (rpm) of the abrasive disk increases, the convergence condition of the iteration increases. Under the condition that the inlet speed of the Classifier Separator Mill (CSM) and the heat source value of the disc hammer are the same, the disc rotation speed (rpm) and the hammer temperature are inversely proportional. As the rotational speed (rpm) of the disc increases, the hammer temperature decreases. However, since the wear rate of the secondary battery material increases due to the strong impact of the crushing rotational force, it is determined that an appropriate rpm setting is necessary. In CSM (Classifier Separator Mill), it is judged that the flow rate difference is not significantly different in the direction of the pressure outlet (Outlet 1) right above the classifier wheel with the fastest flow rate. Because the disc and hammer attachment technology is adhesive, the attachment point may deform when the temperature of the hammer rises. Therefore, it is considered necessary to develop high-performance adhesives and other adhesive technologies.

• Journal of the Korean Electrochemical Society
• /
• v.9 no.4
• /
• pp.158-169
• /
• 2006

The present article is concerned with the overview of the chemically/surface modified cubic spinel $LiMn_2O_4$ as a cathode electrode far lithium ion secondary batteries. Firstly, this article presented a comprehensive survey of the cubic spinel structure and its correlated electrochemical behaviour of $LiMn_2O_4$. Subsequently, the various kinds of the chemically/surface modified $LiMn_2O_4$ and their electrochemical characteristics were discussed in detail. Finally, this article reviewed our recent research works published on the mechanism of lithium transport through the chemically/surface modified $Li_{1-\delta}Mn_2O_4$ electrode from the kinetic view point by the analyses of the experimental potentiostatic current transients and ac-impedance spectra.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1996.11a
• /
• pp.373-377
• /
• 1996

Carbon materials have become a major interestings of research directed toward the development for anode of lithium batteries of enhanced cell capacity. The purpose of this study is to research and develop poly(p-phenylene)(PPP)-based carbon as a anode of lithium secondary batteries. We have synthesized PPP from benzen by chemical reaction. And then disordered carbon materials were obtained by heat-treating PPP in a nitrogen atmosphere at 40$0^{\circ}C$ to 100$0^{\circ}C$ for 1 hour. The carbon prepared by heat treatment showed a broad x-ray diffraction peak around 2$\theta$=23$^{\circ}$. Electrodes were charged and discharged at a current density of 0.1㎃/$\textrm{cm}^2$. Excellent reversible capacity of 275㎃h/g and 97% of charge/discharge efficiency were observed heat treated PPP-based carbon a $700^{\circ}C$.

• The Transactions of the Korean Institute of Power Electronics
• /
• v.27 no.3
• /
• pp.265-274
• /
• 2022

This paper proposes a machine learning-based screening algorithm to build the retired battery pack of the energy storage system. The proposed algorithm creates the dataset of various performance parameters of the retired battery, and this dataset is preprocessed through a principal component analysis to reduce the overfitting problem. The retried batteries with a large deviation are excluded in the dataset through a density-based spatial clustering of applications with noise, and the K-means clustering method is formulated to select the group of the retired batteries to satisfy the deviation requirement conditions. The performance of the proposed algorithm is verified based on NASA and Oxford datasets.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.17 no.3
• /
• pp.378-386
• /
• 2014

In this paper, safety evaluation method simulating battlefield environment was studied to verify military operability of commercial lithium secondary battery. Based on the MIL-STD-2105D and STANAG standards, safety tests of lithium secondary battery module were conducted, such as bullet impact, fragment impact, fast cook-off and slow cook-off. All results satisfied the safety evaluation criteria, founded on military standard. It suggests that the lithium secondary module has high potential to be applied in a military power source. The safety evaluation methods developed in this paper can be valuable to propose the new military standards for commercial lithium secondary batteries.