• Title/Summary/Keyword: second phases

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A study on the activation characteristics of multi-phase Zr-based hydrogen storage alloy for Ni-MH rechargeable battery (Ni-MH 2차전지용 다상의 Zr계 수소저장합금 전극의 활성화 특성에 관한 연구)

  • Lee, Ho;Jang, Kuk-Jin;Lee, Jai-Young
    • Journal of Hydrogen and New Energy
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    • v.8 no.4
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    • pp.161-171
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    • 1997
  • $AB_2$ type Zr-based Laves phase alloys have been studied for potential application as negative electrode in Ni/MH batteries. However, They have a serious disadvantage of poor activation behavior in KOH solution. In this work, a new method of alloy design method was tried for improving Zr-based alloy activation. this method has focused on phase controlling to make multi-phase microstructure. In the case of multi-phase Zr-V-Mn-Ni shows good performance in activation, but activation mechanism has not been known. So, we were in search of elucidating this mechanism, Using morphological and electrochemical analysis, we could find that surface morphology and electocatalytic activity of the alloy change during immersion in KOH solution. V-rich second phases are selectively corroded and dissolved and then become Ni-rich phases. Resulting from these surface reaction in KOH solution, self-hydrogen charging occurs through Ni-rich phase. However, the alloy has poor cyclic durability because of such a corrosion mechanism. Therefore, finally we developed durable alloys by substitution of other alloying element.

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Effect of pre-annealing conditions on critical current density of Bi-2223 tapes

  • Ha, Dong-Woo;Yang, Joo-Saeng;Ha, Hong-Soo;Oh, Sang-Soo;Lee, Dong-Hoon;Hwang, Sun-Yuk;Park, Jung-Gyu;Kwon, Young-Kil
    • Progress in Superconductivity and Cryogenics
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    • v.5 no.1
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    • pp.31-34
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    • 2003
  • Bi-2223 superconducting wires with 55 filaments were fabricated by stacking, drawing process with different heat-treatment histories. Two kinds of powders were prepared. One was pre-annealed at 760-820 $^{\circ}C$ and low oxygen partial pressure, and the other was only calcined state. Before rolling process, round wires were pre-annealed at 760 -820 $^{\circ}C$ and in a low oxygen partial pressure. We confirmed that pre-annealing step was to transform Bi-2212 orthorhombic structure from Bi-2212 tetragonal structure and to reduce the formation of second phases at superconducting wire. However Bi-2223 phases were formed at higher pre-annealing temperature. Bi-2223 conductor was needed frequently annealing at low temperature because pre-annealing at precursor powder brought about decrease in workability. We could achieve highest Je of 6500 A/$\textrm{cm}^2$ at the tape using Bi-2212 orthorhombic phase by introduced slightly overheating at the 1st sintering process.

Superconducting properties of Bi-2223 tapes with various pre-annealing conditions (전열처리 조건에 따른 Bi-2223 초전도 선재에서의 특성 변화)

  • 하동우;하홍수;오상수;이동훈;윤진국;양주생;최정규;권영길
    • Progress in Superconductivity
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    • v.4 no.2
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    • pp.176-179
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    • 2003
  • A lot of efforts have been focused on the optimization of PIT parameters for Bi-2223/Ag wire. Bi-2223 superconducting wires with 55 filaments were fabricated by stacking, drawing process. Before rolling process, round wires were pre -annealed at 760 - 820 $^{\circ}C$ and low oxygen partial pressure. We confirmed that pre-annealing step was to transform Bi-2212 orthorhombic structure from Bi-2212 tetragonal structure and to reduce the formation of second phases. However Bi-2223 phases also were formed at higher than 76$0^{\circ}C$ of pre-annealing temperature. The engineering critical current densities (Je) of Bi-22231Ag tapes were sintered at low oxygen partial pressure were higher than t hat of the wires sintered at air. We could achieve 6500 A/${cm}^2$ of Je for the tape that was initially kept at slightly higher temperature than that of normal heat treatment.

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Evaluation of Feeding a Fibrolytic Enzyme to Lactating Dairy Cows on Their Lactational Performance during Early Lactation

  • Titi, H.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.5
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    • pp.677-684
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    • 2003
  • Twenty eight multiparous lactating cows were utilized in an experiment to evaluate the response to an exogenous fibrolytic enzyme on their lactational performance during early lactation period (in terms of milk production, milk composition, feed intake, milking efficiency, body weight change) and the exact time of this response. Cows were randomized into two groups (14 each) with similar parities and were fed a concentrate ration of barley, ground corn, soybean meal, and wheat bran and roughage ration of alfalfa hay. One of the two groups was supplemented with the fibrolytic enzyme immediately after parturition up to 100 post partum. The experiment was of two phases with 50 days each. The enzyme, which has a cellulase/hemicellulase activity (derived from Trichoderma group), was added to the concentrate part of the ration in a dry powder form. Milk production, 3.5% fat corrected milk, energy corrected milk were higher (p<0.05) for cows fed treated diet. At the same time, No differences were observed in percentages of milk components, feed intake, body weight, body weight change, or rectal temperature for the whole experimental period or during any of the two phases. Efficiency of milk production was higher (p<0.05) for treatment group cows than for that of the control ones. However, efficiency was better during the second phase than during the first phase. Feeding enzyme treated diets to dairy cows improved lactational performance during early 100 day of the lactation period. However, the first 50 days of lactation looked to be the critical.

Architectural Theories and Planning Concepts of Korean Residence, Soengyo-jang (전통주택(傳統住宅) 선교장(船橋莊)의 건축이론(建築理論)과 계획개념(計劃槪念) 연구 - 집합론적(集合論的) 해석(解釋)을 중심으로 -)

  • Kim, Bong-Ryol
    • Journal of architectural history
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    • v.7 no.1 s.14
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    • pp.31-48
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    • 1998
  • Soengyo-jang has some characteristics as the most great house, the special functions, and the non-regional type of house form. And it has constructed continuously for two centuries by many owners in the different generations, It needs a special research method ; which are consist of a) comprehension of background information from documents and oral instructed materials, b) pursuit of design process through the building survey, and c) theoretical interpretation about 'collectivism'. From the results of this research, it is revealed that the architectural purpose of this house was constructing 'a great manor'. At first phase, it had been a single ordinary house, at second, it had expanded to a complex including many housing clusters, and finally became to expand its dwelling territory into whole village. Its expansion was progressed by the four collecting phases of which were building, building cluster, group of clusters, and topological setting. Main design elements operated in each of collecting phases ; they were partial element of , exterior spaces of , a linear building of , and a pavilion of . The last two elements were also powerful datum.

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Heterogeneity-aware Energy-efficient Clustering (HEC) Technique for WSNs

  • Sharma, Sukhwinder;Bansal, Rakesh Kumar;Bansal, Savina
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.11 no.4
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    • pp.1866-1888
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    • 2017
  • Efficient energy consumption in WSN is one of the key design issues for improving network stability period. In this paper, we propose a new Heterogeneity-aware Energy-efficient Clustering (HEC) technique which considers two types of heterogeneity - network lifetime and of sensor nodes. Selection of cluster head nodes is done based on the three network lifetime phases: only advanced nodes are allowed to become cluster heads in the initial phase; in the second active phase all nodes are allowed to participate in cluster head selection process with equal probability, and in the last dying out phase, clustering is relaxed by allowing direct transmission. Simulation-based performance analysis of the proposed technique as compared to other relevant techniques shows that HEC achieves longer stable region, improved throughput, and better energy dissipation owing to judicious consumption of additional energy of advanced nodes. On an average, the improvement observed for stability period over LEACH, SEP, FAIR and HEC- with SEP protocols is around 65%, 30%, 15% and 17% respectively. Further, the scalability of proposed technique is tested by varying the field size and number of sensing nodes. The results obtained are found to be quite optimistic. The impact of energy heterogeneity has also been assessed and it is found to improve the stability period though only upto a certain extent.

Synthesis of Solid Electrolyte Nasicon by Solid State Reaction

  • Kim, Cheol-Jin;Chung, Jun-Ki;Lim, Sung-Ki;Rhee, Meung-Ho
    • The Korean Journal of Ceramics
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    • v.2 no.1
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    • pp.25-32
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    • 1996
  • Solid electroyte nasion was synthesized by the optimized solid state reaction minimizing the volume fraction of secondary $ZrO_2$ and glassy phases. To compensate for the evaporation of Na and P during heat-treatment, excess Na and P were added to the starting composition $Na_{1+x} Zr_2 Si_x P_{d-x} O_{12}$ (x=2.1). Phases pure nasicon comparable in volume fraction to the one obtaied from sol-gel process were synthesized after the reaction at $1100~1150^{\circ}C$,$ P_{O2}>=0.1-0.15 $$ZrO_2$ increased with the heat-treatment time due to the decomposition of nasicon phase and that of glassy phase increased as partial oxygen pressure decreased. The synthesized nasion showed a good electrical conductivity of $-1{\times}10^{-2}({\omega}{\cdot}cm)^{-1}$ at $350^{\circ}C$.

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Characteristics of Vertical Acceleration at Center of Mass of the Body in Normal Gait (정상보행시 체중심의 수직 가속도 특성)

  • Yi, Jin-Bock;Kang, Sung-Jae;Kim, Young-Ho
    • Physical Therapy Korea
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    • v.9 no.3
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    • pp.39-46
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    • 2002
  • In this study, vertical acceleration of center of mass was observed along normal gait phases in 9 healthy male volunteers (aged $25.7{\pm}2.18$). The developed wireless accelerometric device was attached on the intervertebral space between L3 and L4 using a semi-elastic waist belt. A three-dimensional motion analysis system, synchronized with the accelerometry, was used for detecting gait phases. There was no significant correlation between the body weight and the acceleration. The first peak curve covered loading response phase. The second downward peak point was matched accurately with the opposite toe-off. In mid-stance and terminal stance, the acceleration curve highly resembled the vertical ground reaction force curve. There was no significant difference in timing between the final upward peak point and the initial contact. Therefore, the developed accelerometry system would be helpful in determining determine temporal gait pattems in patients with gait disorders.

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A Percolation based M2M Networking Architecture for Data Transmission and Routing

  • Lu, Jihua;An, Jianping;Li, Xiangming;Yang, Jie;Yang, Lei
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.6 no.2
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    • pp.649-663
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    • 2012
  • We propose a percolation based M2M networking architecture and its data transmission method. The proposed network architecture can be server-free and router-free, which allows us to operate routing efficiently with percolations based on six degrees of separation theory in small world network modeling. The data transmission can be divided into two phases: routing and data transmission phases. In the routing phase, probe packets will be transmitted and forwarded in the network thus multiple paths are selected and performed based on the constriction of the maximum hop number. In the second phase, the information will be encoded, say, with the fountain codes, and transmitted using the paths generated in the first phase. In such a way, an efficient routing and data transmission mechanism can be built, which allow us to construct a low-cost, flexible and ubiquitous network. Such a networking architecture and data transmission can be used in many M2M communications, such as the stub network of internet of things, and deep space networking, and so on.

Fabrication of High Strength Mg-Li-Al Alloys by Squeeze Casting Process (용탕단조법에 의한 고강도 Mg-Li-Al합금 제조)

  • Han, Chang-Hwa;Hwang, Yong-Ha;Kim, Yong-Woo;Kim, Do-Hyang;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.17 no.3
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    • pp.267-275
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    • 1997
  • Fabrication of high strength Mg-Li-Al alloys by squeeze casting was established by the stabilization of melt and mold temperatures, applied pressure and the refining method. The entrapment of inclusions during pouring was prevented using 30 ppi alumina foam filter. The as-cast microstructure consists of a mixture of ${\alpha}$ and ${\beta}$ phases including AILi and $MgLi_2$, Al particles, which are distributed in the ${\beta}$ matrix. The grain sizes of gravity and squeeze casting alloys were 288 ${\mu}m$ and 207 ${\mu}m$ respectively. The addition of Al in Mg-Li alloys promoted the formation of second phase particles, which were adjusted to optimize the properties of Mg-Li-Al alloys. The Mg-10wt%Li-5wt%Al alloy after heat treatment at $350^{\circ}C$ for 1 hour showed the maximum hardness value. This is due to the facts that the amounts of ${\alpha}$ and ${\beta}$ phases and their distributions are dependent upon the solution treatment temperature, and that the amounts of AILi and $MgLi_2Al$ particles are dependent upon the Al content.

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