• Bulletin of the Korean Chemical Society
• /
• v.17 no.7
• /
• pp.607-612
• /
• 1996

A series of new NLO-active poly(4-nitrophenylallylamine) derivatives was synthesized by the nucleophilic substitution reaction of several substituted 4-nitrohalobenzenes and poly(allylamine hydrochloride). All polymers obtained were amorphous and their glass transition temperatures (Tg) were observed around 148-160 ℃. For each of these polymers, their specific Tg values were dependent on characteristic electronic structures. UV-visible absorption spectra showed maximum absorption intensity at 355-393 nm for π-π* transition of alkylaminonitrophenyl groups. The χ(2)value of poly(4-nitrophenylallylamine), as determined by the second harmonic generation at 1064 nm, for a thin polymer film poled at an elevated temperature, was 1.4x10-8esu. The third-order NLO properties of poly(4-nitrophenylallylamine) derivatives were evaluated through measurement of degenerate four-wave mixing technique and χ(3) coefficient in the range of 2.7~3.2x10-12 esu at 602 nm was found with 400 fs laser pulses.

• Proceedings of the Korean Magnestics Society Conference
• /
• 2008.06a
• /
• pp.101-101
• /
• 2008

• Proceedings of the Optical Society of Korea Conference
• /
• 2003.07a
• /
• pp.168-169
• /
• 2003

We have determined the orientational distribution functions (OBFs) at both air and substrate isotropic interfaces of a chiral chitosan bio-polymer film by the measurements of surface second-harmonic generation (SHG). It was shown that the simultaneous SHG analysis of both interfaces, based on the macroscopic and microscopic relations, provides all the informations on the nonlinear optical (NLO) activity. (omitted)

• Korean Journal of Optics and Photonics
• /
• v.16 no.5
• /
• pp.456-461
• /
• 2005

We numerically investigate the characteristic of single Nd:YAG rod laser with the convex-plane resonator configuration in order to get the best condition for high efficient intra-cavity second harmonic generation(SHG). The beam quality is analyzed with ABCD matrixes including the thermal lensing characteristic of Nd:YAG rod. The analysis is focused on stability, M2, beam waist and mode-volume of laser beam inside the resonator. The best conditions for SHG is obtained when a laser rod is set near the curved laser mirror.

• Nuclear Engineering and Technology
• /
• v.51 no.3
• /
• pp.867-876
• /
• 2019

Second harmonic generation using nonlinear ultrasonic waves have been shown to be an early indicator of possible fatigue damage in nuclear power plant components. This technique relies on measuring amplitudes, making it highly susceptible to variations in transducer coupling and instrumentation. This paper proposes an experimental procedure for in-situ surface wave nonlinear ultrasound measurements on specimen with permanently mounted transducers under high cycle fatigue loading without interrupting the experiment. It allows continuous monitoring and minimizes variation due to transducer coupling. Moreover, relations describing the effects of the measurement system nonlinearity including the effects of the material transfer function on the measured nonlinearity parameter are derived. An in-situ high cycle fatigue test was conducted using two 304 stainless steel specimens with two different excitation frequencies. A comprehensive analysis of the nonlinear sources, which result in variations in the measured nonlinearity parameters, was performed and the effects of the system nonlinearities are explained and identified. In both specimens, monotonic trend was observed in nonlinear parameter when the value of fundamental amplitude was not changing.

• Korean Journal of Optics and Photonics
• /
• v.7 no.3
• /
• pp.251-259
• /
• 1996

Two-Photon Fluorescence (TPF) experiment measures temporal width of an amplified short laser pulse which has passed through a four-pass Nd: glass amplifier, after selecting a single pulse from pulse train Q-switched and mode-locked(QSML) in Nd:YLF master oscillator. Determination of pulsewidth and pulseshape was also made with detection of autocorrelation trace of CW mode-locked pulse train by using noncollinear type I Second Harmonic Generation (SHG) method. The observed TPF track showed various patterns, depending on pulse-selecting position in QSML pulse train. That is, autocorrelation of a pulse extracted at front of the train displayed smooth pulse shape, while one from the trailing part of the train created many sharp spikes and substructure in the pulse. By TPF method, pulsewidth was measured to be 44.4 ps with contrast ratio of 2.86 which enabled us to find out energy fraction of a pulse to total energy, (sum of pulse and background); we obtain the value of 0.62. Pulsewidth of 46.6ps was also acquired in another SHG experiment with the help of only mode-locked pulse train. On the other hand, we confirmed that shape of the pulse is close to $sech^2$ one as a result of fitting the SHG autocorrelation signal with various functions. With simulation using this $sech^2$ type of pulse, pulsewidth reduction of the beam, having passed through four-pass amplifier, was also verified.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.8 no.3
• /
• pp.181-188
• /
• 2010

Metal surface decontamination characteristics were investigated by using a laser ablation method. A second harmonic generation of a Q-switched Nd:YAG laser with a wave length of 532 nm, a pulse energy of 150 mJ and a pulse width of 5 ns was employed to assess the decontamination performance for metal surfaces contaminated with $CsNO_3$, $Co(NH_4)_2(SO_4)_2$, $Eu_2O_3$ and $CeO_2$. The ablation behavior was investigated for the decontamination variables such as a number of laser shots, laser fluence and an irradiation angle. Their optimum values were found to be 8, 13.3 J/$cm^2$ and $30^{\circ}$, respectively. The decontamination efficiency was different depending on the kinds of the contaminated ions, due to their different melting and boiling points and was in the order: $CsNO_3>Co(NH_4)_2(SO_4)_2>Eu_2O_3>CeO_2$. We also evaluated a correlation between the metal ablation thickness and the number of laser shots for the different laser fluences.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.5
• /
• pp.1443-1454
• /
• 2011

Methods to prepare novel second-order nonlinear optical (2O-NLO) materials composed of all-silica zeolite (silicalite-1) and a series of 2O-NLO molecules having high second order hyperpolarizability constants (${\beta}$ values) are reviewed. These methods include the development of novel methods to incorporate a series of hemicyanine (HC) molecules into the channels of silicaite-1 films in uniform orientations. The first method is to incorporate HC molecules tethered with long alkyl chains (octadecyl or longer) into the silicalite-1 channels with the long alkyl chain side first through the hydrophobic-hydrophobic interaction between the long alky chains and the silicalite-1 channels. The second method is to incorporate the HC molecule tethered with a medium length alkyl chain (nonyl) into the silicalite-1 channels with the medium length alkyl chain side first through hydrophobic-hydrophobic interaction between the medium length alky chain in the photoexcited state and the silicalite-1 channels. The third method is to incorporate the HC molecule tethered with propionic acid into the silicalite-1 channels with the propionic acid side last mediated by a tetrabultylammonium cation ion-paired to the propionate unit. A method to prepare a novel third-order nonlinear optical (3O-NLO) material composed of zeolite-Y and PbS or PbSe quantum dots is also reviewed. This Account thus describes a promising new direction to which the search for highly sensitive 2O-NLO and 3O-NLO materials has to be conducted and a new direction to which zeolite research and applications have to be expanded.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.12 no.4_1
• /
• pp.137-150
• /
• 1992

A complete solution, exact to second-order, for wave motion forced by a hinged-wavemaker of variable-draft is presented. A solution for a piston type wavemaker is also obtained as a special case of a hinged-wavemaker. The laboratory waves generated by a plane wave board are shown to be composed of two components; viz., a Stokes second-order wave and a second-harnomic free wave which travels at a different speed. The amplitude of the second-harmonic free wave is relatively large in shallow water and decreases to less than 10% of the amplitude of the primary wave in deep water. Wavemakers with relatively deeper draft (i.e., hinged near the bottom) generate the free waves of smaller amplitude in shallow and intermediate water depths than the wavemakers with shallow draft. However, the opposite is predicted by theory in deep water.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.17 no.4
• /
• pp.151-155
• /
• 2007

Quasi-phase-matched (QPM) second harmonic generation (SHG) waveguide devices for a green light generation were fabricated by a periodically patterned electrode on the +Z crystal surface and homogeneous LiCl solution using a 5 mol% MgO doped congruent z-cut lithium niobate crystals. Using selective chemical etching, we confirmed the periodic (${\sim}6.8{\mu}m$) domain inverted structure and measured SHG properties of fabricated periodically poled MgO : $LiNbO_3$ ridge-type waveguides.