• Title/Summary/Keyword: sea-salt

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Source Identification of Ambient PM-10 Using the PMF Model (PMF 모델을 이용한 대기 중 PM-10 오염원의 확인)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.701-717
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    • 2003
  • The objective of this study was to extensively estimate the air quality trends of the study area by surveying con-centration trends in months or seasons, after analyzing the mass concentration of PM-10 samples and the inorganic lements, ion, and total carbon in PM-10. Also, the study introduced to apply the PMF (Positive Matrix Factoriza-tion) model that is useful when absence of the source profile. Thus the model was thought to be suitable in Korea that often has few information about pollution sources. After obtaining results from the PMF modeling, the existing sources at the study area were qualitatively identified The PM-10 particles collected on quartz fiber filters by a PM-10 high-vol air sampler for 3 years (Mar. 1999∼Dec.2001) in Kyung Hee University. The 25 chemical species (Al, Mn, Ti, V, Cr, Fe, Ni, Cu, Zn, As, Se, Cd, Ba, Ce, Pb, Si, N $a^{#}$, N $H_4$$^{+}$, $K^{+}$, $Mg^{2+}$, $Ca^{2+}$, C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, TC) were analyzed by ICP-AES, IC, and EA after executing proper pre - treatments of each sample filter. The PMF model was intensively applied to estimate the quantitative contribution of air pollution sources based on the chemical information (128 samples and 25 chemical species). Through a case study of the PMF modeling for the PM-10 aerosols. the total of 11 factors were determined. The multiple linear regression analysis between the observed PM-10 mass concentration and the estimated G matrix had been performed following the FPEAK test. Finally the regression analysis provided source profiles (scaled F matrix). So, 11 sources were qualitatively identified, such as secondary aerosol related source, soil related source, waste incineration source, field burning source, fossil fuel combustion source, industry related source, motor vehicle source, oil/coal combustion source, non-ferrous metal source, and aged sea- salt source, respectively.ively.y.

Characteristics of Metallic and Ionic Concentrations in PM10 and PM2.5 in Busan (부산지역 PM10과 PM2.5 중의 금속 농도와 이온농도 특성)

  • Jeon, Byung-Il;Hwang, Yong-Sik
    • Journal of Environmental Science International
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    • v.23 no.5
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    • pp.819-827
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    • 2014
  • This study analyzes the chemical composition of metallic elements and water-soluble ions in $PM_{10}$ and $PM_{2.5}$. $PM_{10}$ and $PM_{2.5}$ concentrations in Busan during 2010-2012 were $97.2{\pm}67.5$ and $67.5{\pm}32.8{\mu}g/m^3$, respectively, and the mean $PM_{2.5}/PM_{10}$ concentration ratio was 0.73. The contribution rate of water-soluble ions to $PM_{10}$ ranged from 29.0% to 58.6%(a mean of 38.6%) and that to $PM_{2.5}$ ranged from 33.9% to 58.4%(a mean of 43.1%). The contribution rate of sea salt to $PM_{10}$ was 13.9% for 2011 and 9.7% for 2012, while that to $PM_{2.5}$ was 17.4% for 2011 and 10.1% for 2012. $PM_{10}$ concentration during Asian dust events was $334.3{\mu}g/m^3$ and $113.3{\mu}g/m^3$ during non-Asian dust events, and the $PM_{10}$ concentration ratio of Asian Dust/Non Asian dust was 2.95. On the other hand, the $PM_{2.5}$ concentration in Asian dust was $157.4{\mu}g/m^3$ and $83.2{\mu}g/m^3$ in Non Asian dust, and the $PM_{2.5}$ concentration ratio of Asian Dust/Non Asian dust was 1.89, which was lower than that of $PM_{10}$.

A Study on Mitigation of Rail Corrosion using Sacrificial Anode Cathodic Protection Method (희생양극법을 이용한 레일부식 저감 방안에 관한 연구)

  • Choi, Jung-Youl;Kim, Jun-Hyung;Lee, Kyu-Yong;Kim, Young-Ki;Park, Jong-Yoon;Song, Bong-Hwan;Seol, Jin-Woong
    • Journal of the Korean Society of Safety
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    • v.32 no.6
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    • pp.54-60
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    • 2017
  • A railway rail will be corroded by the repetitive sea wind and fog in the splash and tidal zone such as Youngjong grand bridge. And these rusts of rail could be increased by increasing service period, and it frequently occurred the safety accidents or disorders in electrical problem. In this study, the sacrificial anode cathodic protection method was proposed as a measures for reducing the corrosion of the railway rails in the oceanic climate conditions. As the results of immersion test using the salt water during four months, the sacrificial anode cathodic protection method using the aluminum anode(Al-anode) was evaluated that a distinct effect on corrosion reduction in the rails. Therefore the sacrificial anode cathodic protection method was experimentally proven that a disorders in aspects electric and signal of railway operation condition such as direct fixation track system in Youngjong grand bridge could be prevented by reducing rust falling from the rail. In addition, the installation conditions of the anodes directly affect the transmission range of corrosion potential, the sectional loss of anode, and the corrosion reduction effect. Therefore, to expect the corrosion reduction effect of rails under the oceanic climate conditions for railway track, it was important to adopted the appropriate spacing of anode installation by considering the actual field conditions.

Comparison of Source Apportionment of PM2.5 Using PMF2 and EPA PMF Version 2

  • Hwang, In-Jo;Hopke, Philip K.
    • Asian Journal of Atmospheric Environment
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    • v.5 no.2
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    • pp.86-96
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    • 2011
  • The positive matrix factorization (PMF2) and multilinear engine (ME2) models have been shown to be powerful environmental analysis techniques and have been successfully applied to the assessment of ambient particulate matter (PM) source contributions. Because these models are difficult to apply practically, the US EPA developed a more user-friendly version of the PMF. The initial version of the EPA PMF model does not provide any rotational capabilities; for this reason, the model was upgraded to include rotational functions in the EPA PMF ver. 2.0. In this study, PMF and EPA PMF modeling identified ten particulate matter sources including secondary sulfate I, vehicle gasoline, secondary sulfate II, secondary nitrate, secondary sulfate III, incinerators, aged sea salt, airborne soil particles, oil combustion, and diesel emissions. All of the source profiles determined by the two models showed excellent agreement. The calculated average concentrations of $PM_{2.5}$ were consistent between the PMF2 and EPA PMF ($17.94{\pm}0.30{\mu}g/m^3$ and $17.94{\pm}0.30\;{\mu}g/m^3$, respectively). Also, each set of estimated source contributions of the PMF2 and EPA PMF showed good agreement. The results from the new EPA PMF version applying rotational functions were consistent with those of PMF2. Therefore, the updated version of EPA PMF with rotational capabilities will provide more reasonable solutions compared with those of PMF2 and can be more widely applied to air quality management.

Internal Mixing of Pollutants for Submicron Particles Observed during Springtime in Japan

  • Matsumoto, Jun;Narukawa, Masahiro;Takahashi, Kenshi;Matsumi, Yutaka;Yabushita, Akihiro;Shimizu, Atsushi;Matsui, Ichiro;Sugimoto, Nobuo
    • Asian Journal of Atmospheric Environment
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    • v.3 no.1
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    • pp.27-41
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    • 2009
  • Internally mixed states of submicron particles during transport from the Asian continent to the Pacific Ocean were analyzed using a single-particle time-offlight mass spectrometer. The observation was conducted at Tsukuba in Japan in the spring of 2005 in order to investigate springtime transport of particles from the continent. The sum of ion intensities of sulfate (${HSO_4}^-$) detected in particles originating from the continental air masses counted for 75% of that in all particles during the observation. By analyzing correlations among compounds, origins and internally mixed states of compounds were estimated. It was found that nitrate was mixed with sulfate-rich particles as the air mass approached Japan. It was confirmed that Asian mineral dust particles played significant roles for transport of continental sulfate to Japan. As a result of analysis on internal mixing of chlorine and nitrate, it was implied that the chlorine loss in fine sea salt particles had already proceeded at Tsukuba. It was characteristic that fluoride ions were significantly detected, coal combustion in the Asian Continent can be an important source of fluorides detected in Japan through the westward transportation of fine particles including fluorides.

Size Distribution Characteristics of Particulate Mass and Ion Components at Gosan, Korea from 2002 to 2003

  • Han J.S.;Moon K.J.;Lee S.J.;Kim J.E.;Kim Y.J.
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.E1
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    • pp.23-35
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    • 2005
  • Size distribution of particulate water-soluble ion components was measured at Gosan, Korea using a micro-orifice uniform deposit impactor (MOUDI). Sulfate, ammonium, and nitrate showed peaks in three size ranges; Sulfate and ammonium were of dominant species measured in the fine mode ($D_{p} < 1.8 {\mu}m$). One peak was observed in the condensation mode ($0.218\sim0.532{\mu}m$), and the other peak was obtained in the droplet mode ($0.532\sim1.8{\mu}m$). Considering the fact that the equivalent ratios of ammonium to sulfate ranged from 0.5 to 1.0 in these size ranges, it is inferred that they formed sufficiently neutralized compounds such as ($NH_{4})_{2}SO_{4} and (NH_{4})_{3}H(SO_{4})_{2}$ during the long-range transport of anthropogenic pollutants. On the other hand, nitrate was distributed mainly in the coarse mode ($3.1\sim6.2{\mu}m$) combined with soil and sea salt. Two sets of MOUDI samples were collected in each season. One sample was collected when the concentrations of criteria air pollutants were relatively high, but the other represented relatively clean air quality. The concentrations of sulfate and ammonium particles in droplet mode were the highest in winter and the lowest in summer. When the air quality was bad, the increase of nitrate was observed in the condensation mode ($0.218\sim0.282{\mu}m$). It thus suggests that the nitrate particles were produced through gas phase reaction of nitric acid with ammonia. Chloride depletion was remarkably high in summer due to the high temperature and relative humidity.

Effects of the Brackish Water Desalination System on Soil Environment and Growth in Squash Greenhouse Cultivation Area (시설재배지에서 기수담수화시스템 적용에 따른 토양 환경 및 애호박의 생육 영향 분석)

  • Kim, Soo-Jin;Bae, Seung-jong;Jeong, Han-Suk;Kim, Hak-Kwan;Park, Seung-Woo
    • Journal of The Korean Society of Agricultural Engineers
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    • v.60 no.3
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    • pp.113-121
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    • 2018
  • The objectives of the research were 1) to develop the low-cost and high efficient desalination system to treat brackish water having high salt contents for irrigation at greenhouses near coast, and 2) to monitor and assess the effects of the brackish water desalination system on soil environment and growth in squash greenhouse cultivation area. The monitoring site was one of the squash greenhouse cultivation farm at Choengam-ri, Jinsang-myun, Gwangyang-si, Jeonnam-Do Monitoring results for groundwater irrigation water quality, and salinity showed a remarkable difference between control and treatment group. The salinity of soil at treatment group was less than at control group. While, the system made possible to increase the squash quantity from 4.7 ea to 6.3 ea at each and the average weight of the harvested squash was increased from 277.2 g to 295.1 g. The applied brackish water desalination system may be appled to reclaim sea or brackish irrigated area as alternative water resources, although long-term monitoring is needed to get more representative results at different level of salinity.

Influence of freeze-dried acid whey addition on biogenic amines formation in a beef and deer dry fermented sausages without added nitrite

  • Kononiuk, Anna D.;Karwowska, Malgorzata
    • Asian-Australasian Journal of Animal Sciences
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    • v.33 no.2
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    • pp.332-338
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    • 2020
  • Objective: Aim of this study was to evaluate the influence of freeze-dried acid whey addition and the use a game meat (fallow deer) on a microbial content and the biogenic amines formation in dry fermented sausages. Methods: The experiment involved dry fermented sausages made in two variants from beef and from fallow deer. Each variant was divided into five groups: control (with a curing mixture), reference (with a sea salt), sample with a liquid acid whey and two samples with the addition of reconstituted freeze-dried acid whey in different concentrations. Changes in lactic acid bacteria (LAB), Enterobacteriaceae content and biogenic amines content were determined. Results: The microbial content changes suggest that addition of acid whey slightly affected LAB content in comparison with the control and reference sample, but the addition of freezedried acid whey resulted in a reduction of Enterobacteriaceae content in the sausages from fallow deer or a similar level in the beef sausages compared with the control and reference sample. Both changes in LAB and Enterobacteriaceae content were more evident in case of sausages made from fallow deer. Addition of acid whey (liquid and a higher amount of freezedried) and use of fallow deer meat to produce the sausages resulted in a significant reduction of total biogenic amines content. Conclusion: The addition of acid whey (liquid and higher amount of freeze-dried) resulted in a significant reduction of total biogenic amines content in dry fermented sausages made from fallow deer meat.

Identifying Ambient PM2.5 Sources and Estimating their Contributions by Using PMF : Separation of Gasoline and Diesel Automobile Sources by Analyzing ECs and OCs (PMF 모델을 이용한 미세분진의 오염원 확인과 기여도 추정 : 탄소성분을 이용한 휘발유 및 경유차량 오염원의 분리)

  • Lee, Hyung-Woo;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.1
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    • pp.75-89
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    • 2009
  • The purpose of this study was to identify $PM_{2.5}$ sources and to estimate their contributions to the border of Yongin-Suwon area, based on the analysis of the $PM_{2.5}$ mass concentration and the associated inorganic elements, ions and carbon components. The contribution of $PM_{2.5}$ sources were estimated by using a positive matrix factorization (PMF) model to identify air emission sources. For this study, $PM_{2.5}$ samples were collected from May, 2007 to April, 2008. The inorganic elements were analyzed by an ICP-AES. The ionic components in $PM_{2.5}$ were analyzed by an Ie. The carbon components were also analyzed by DRI/OGC analyzer. After performing PMF modeling, a total of 12 sources were identified and their contributions were quantitatively estimated. The contributions from each emission source were as follows: 11.3% from oil combustion source, 3.4% from bus/highway source, 5.8% from diesel vehicle source, 4.7% from gasoline vehicle source, 8.8% from biomass burning source, 15.1 % from secondary sulfate, 5.2% from secondary nitrate source, 13.4% from industrial related source, 4.1% from Cl-rich source, 19.6% from soil related source, 1.0% from aged sea salt, and 7.4% from coal combustion source, respectively. This study provides basic information on the major sources affecting air quality, and then it will help to effectively control $PM_{2.5}$ in this study area.

Corrosion Protection Method of Reinforcing Steel in Concrete by Using Corrosion Inhibitors

  • Bae Su-Ho;Chung Young-Soo;Kim Dae-Ho
    • KCI Concrete Journal
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    • v.14 no.4
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    • pp.145-150
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    • 2002
  • Reinforced concrete is inherently a durable composite material. When properly designed for the environment to be exposed and carefully constructed, reinforced concrete is capable of giving maintenance-free performance. However, unintentionally using improper materials such as non-washed sea sand having much salt together with poor controlled quality, or the concrete are placed in highly severe environment such as marine atmosphere, the corrosion of reinforcing steel in concrete becomes one of the most significant concerns of concrete. The purpose of this experimental research is to evaluate the performance of corrosion inhibitors for normal strength and high strength concrete, and to propose desirable measures for controlling corrosion of reinforcing steel in concrete. Test specimens in normal strength and high strength concrete were made with and without corrosion inhibitors. The accelerated corrosion test for reinforcing steel in concrete was adopted in accordance with JCI-SC3, which required the periodic 20 cycles for 140 days. One cycle includes 3 days for the wetting condition of $65^{\circ}C$ and $90\%$ RH, and 4 days for the drying condition of $15^{\circ}C\;and\;60\%$ RH. It was observed from the test that corrosion inhibitors in normal strength concrete and high strength concrete showed excellent corrosion resistance for reinforcing steel in concrete, but the silica fume in high strength concrete was found to have a negligible corrosion resistance if not used with corrosion inhibitors, since the chloride corrosion threshold limit in concrete containing silica fume without corrosion inhibitor was found to be considerably smaller than that of the case with corrosion inhibitor.

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