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Process Technology of the Direct Separation and Recovery of Iron and Zinc Metals Contained in High Temperature EAF Exhaust Gas

  • Furukawa, Takeshi;Sasamoto, Hirohiko;Isozaki, Shinichi;Tanno, Fumio
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.393-397
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    • 2001
  • The innovatory process, that is the direct separation and recovery of the iron and zinc metals contained in the high temperature exhaust gas generated from the electric arc furnace fer the inn scrap melting and/or the dust treatment, has been proposed. This proposed process consists of the moving coke bed filter that is directly connected to the electric furnace, and the following heavy metal condenser. The exhaust gas passes through the filter and the condenser right after exhausting from the electric furnace. The moving coke bed filter is being controlled at about 1000℃ and collects iron and slag components contained in the high temperature exhaust gas. Heavy metals such as zinc and lead pass through the filter as vapor. Based on the thermodynamic considerations, the iron oxide and the zinc oxide are reduced in the filter. The solution loss reaction rate is comparatively low at about 1000℃ in the coke bed filter by the analysis using the mathematical simulation model. The heavy metal condenser is installed in the position after the coke bed filter, and rapidly cools the gas from about 1000℃ to 450℃ by a full of the cooling medium like the solid ceramic ball in addition to the cooling from the wall. The zinc and lead vapor condense and separate f개m the gas in a liquid state. The investigation of the characteristics of the exhaust gas of the commercial electric arc furnace, the fundamental experiments of the laboratory scale and the bench scale ensured the formation of this proposed process. A small-scale pilot plant examination is carrying out at present to confirm the formation of the process. It is certain that the dust generation of the electric arc furnace is extremely decreased, and it can save the energy consumption of usual dust treatment processes by the realization of this process.

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Application for Uni-materialization and Life Cycle Assessment of the Vehicle Undercover (자동차 언더커버의 유니소재화 적용 및 전과정평가)

  • Yun, Hyeri;Park, Yoosung;Yu, MiJin;Bae, Hana;Lee, Hanwoong
    • Clean Technology
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    • v.23 no.3
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    • pp.256-269
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    • 2017
  • In response to national and international regulations for resource circulation and to reduce greenhouse gas emissions, the automotive industry has tried to reuse scrap parts and defective products produced in the disposal or production stages as recycled resources. Attempts have been made to reach the target recycling rate by reducing the number of material types required for each part. Moreover, in order to achieve greenhouse gas reduction targets while maintaining the performance of existing products, lighter components are being developed. Existing products were 100% incinerated at the disposal stage, but the uni-materialized products were improved to be possible that it could be recycled 90% through scraps and the defective product in the pre-production and production stage. It also appears that the fuel efficiency improves through 56% lightweight compared to the existing product. In this paper, a preliminary assessment is conducted on the applicability of uni-materialized product development of car parts. The environmental impact values of existing products and developed prototypes are compared and analyzed through life cycle assessment.

Fabrication and Properties of Natural Fiber-Reinforced Waste Wool/Polypropylene Composites (NFRP) (천연섬유강화 폐양모/폴리프로필렌 복합재료(NFRP)의 제조 및 특성)

  • Kim, Ki Hyun;Cho, Donghwan;Kim, Jong Hyun
    • Journal of Adhesion and Interface
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    • v.9 no.2
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    • pp.16-23
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    • 2008
  • In this study, novel waste wool/polypropylene NFRPs (natural fiber reinforced polymer composites), which are constituted with waste wool discarded as industrial scrap during manufacturing processes of woven fabrics and general purpose thermoplastic polypropylene (PP), were fabricated by means of compressionmolding and their mechanical and thermal properties were characterized. The mechanical properties of PP resin were significantly improved by an introduction of waste wool to PP. In particular, as the loading of waste wool was 50 vol% in the NFRP, the flexural strength of the NFRP was increased about 20%, the flexural modulus about 143%, the tensile strength about 76%, and the tensile modulus about 90% in comparison with each of PP control. In addition, the maximum value of the heat deflection temperature (HDT) obtained with the NFRP was $138^{\circ}C$ at a 50 vol% loading of waste wool. This is $21^{\circ}C$ higher than the HDT of PP control. The result here suggests that waste wool be a potential candidate for a reinforcing material of thermoplastic matrix resins.

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Synthesis and Characteristics of Blue Ceramic Pigments Using Electric Arc Furnace Dust (제강분진을 활용한 고온발색 청색무기안료 합성 및 특성에 관한 연구)

  • Son, Bo-Ram;Kim, Jin-Ho;Han, Kyu-Sung;Cho, Woo-Suk;Hwang, Kwang-Taek
    • Journal of the Korean Ceramic Society
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    • v.51 no.3
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    • pp.184-189
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    • 2014
  • Electric arc furnace dust (EAFD) is a solid waste generated by the steel-scrap recycling process. It mainly consists of zinc oxides (ZnO), alumina ($Al_2O_3$), iron oxides ($Fe_2O_3$), and silica ($SiO_2$). Here we report the preparation and characterization of blue ceramic pigments using EAFD powder as a starting material. $(Zn(EAFD),Co)Al_2O_4$ blue ceramic pigment was prepared by the solid-state reaction method. The color characteristics of the pigment obtained were compared with those of pure $CoAl_2O_4$. The new pigment was characterized using XRD, CIE-$L^*a^*b^*$ color-measurements, SEM, and EDX. The XRD analysis revealed that the $(Zn(EAFD),Co)Al_2O_4$ pigment was composed of mainly the spinel phase of $(Zn,Co)Al_2O_4$. The $Zn(EAFD)_{0.25}Co_{0.75}Al_2O_4$ pigments showed a vivid blue color with a $b^*$ value of -28.64 and a good glaze stability with a transparent glaze.

Evaluating Cultured Sea Mussels Mytilus edulis Extractions Methods and Extract Quality Characteristics (진주담치(Mytilus edulis) 추출물의 제조 및 품질특성)

  • Kim, Seon-Geun;Cho, Jun-Hyun;Hwang, Young-Sook;Lee, In-Seok;Oh, Kwang-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.50 no.6
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    • pp.650-655
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    • 2017
  • Extraction methods for cultured sea mussels Mytilus edulis and the quality characteristics of resulting extracts were investigated. The crude protein, carbohydrate and volatile basic nitrogen content of raw sea mussels was 15.2%, 1.9%, and 11.2 mg/100 g, respectively. Extracts were prepared using three different methods: hot-water extract (WE), scrap enzymatic hydrolysate extraction (SE), and complex extraction (CE). The respective extracts contained 5.5%, 8.6%, and 6.6% crude protein; 281.7, 366.0, and 343.0 mg/100 g amino nitrogen,: and 2.0%, 1.1% and 1.8% salinity. Their extraction yields were 689, 323, and 1,012 mL/kg. The CE method was superior to the traditional WE method in terms of extraction yield, amino-nitrogen content, and organoleptic qualities, but not odor. Active taste components were evaluated and the total free amino acid content of the WE and CE methods was 5,667.0 and 7,006.3 mg/100 g, respectively. The concentrations of major components (for WE and CE methods, respectively) were as follows: glutamic acid (1,244.0 and 955.4 mg/100 g), taurine (987.9 and 746.8 mg/100 g), glycine (721.2 and 847.0 mg/100 g), alanine (341.9 and 423.8 mg/100 g), arginine (265.5 and 376.5 mg/100 g), lysine (199.8 and 270.4 mg/100 g), and proline (253.9 and 220.3 mg/100 g). In conclusion, these results demonstrate that there is potential for using the CE method to expand the commercial utilization of sea mussels as a flavoring substance resource.

The Study for the CMP Automation with Nova Measurement System (NOVA System을 이용한 CMP Automation에 관한 연구)

  • Kim, Sang-Yong;Chung, Hun-Sang;Park, Min-Woo;Kim, Chang-Il;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.176-180
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    • 2001
  • There are several factors causing re-work in CMP process such as improper polish time calculation by operator. removal rate decline of the polisher, unstable in-suit pad conditioning, slurry supply module problem and wafer carrier rotation inconsistancy. And conclusively those fundimental reason for the re-work rate increasement is mainly from the cycle time delay between wafer polish and post measurement. Therefore, Wafer thickness measurement in wet condition could be able to remove those improper process conditions which may happen during the process in comparison with the conventional dried wafer measurement system and it can be able to reduce the CMP process cycle time. CMP scrap reduction by overpolish, re-work rate reduction, thickness control efficiency also can be easily achieved. CMP Equipment manufacturer also trying to develop integrated system which has multi-head & platen, cleaner, pre & post thickness measure and even control the polish time from the calculated removal rate of each polishing head by software. CMP re-work problem such as over & under polish by target thickness may result in the cycle time delay. By reducing those inefficient factors during the process and establish of the automatic process control, CLC system need to be adopted to maximize the process performance. Wafer to Wafer Polish Time Feed Back Control by measuring the wafer right after the polish shorten the polish time calculation for the next wafer and it lead to the perfact Post CMP target thickness control capability. By Monitoring all of the processed the wafer, CMP process will also be stabilize itself.

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Test Run of the Pilot Plant for Recycling of the Waste Aluminum Dross (알루미늄 페드로스 재활용 파일롯트플랜트 시운전 결과)

  • Park, Hyung-Kyu;Lee, Hoo-In;Choi, Young-Yoon
    • Resources Recycling
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    • v.14 no.4 s.66
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    • pp.41-46
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    • 2005
  • Waste aluminum dross is a major waste in the aluminum scrap smelters and its major components are alumina and metallic aluminum. In this study, waste aluminum dross was leached with sodium hydroxide solution to extract the remained aluminum into the solution, and aluminum hydroxide was recovered from the leached solution. The dross residue generated at the leaching step was recycled into alumina base ceramic materials through a series of treatments such as washing, drying and roasting. Also, a pilot plant was constructed and tested to demonstrate the developed technology. Four tons of waste aluminum dross could be processed per day. From the test run of the pilot plant, it was confirmed that the developed technology could be applied to commercialization.

Analysis and Separation of Constituent Materials of Old Car by Shredding Process (폐자동차 파쇄를 통한 주요구성물질의 분리 및 분석평가)

  • Lee Hwa-Young;Oh Jong-Kee;Kim Sung-Gyu
    • Resources Recycling
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    • v.11 no.4
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    • pp.11-16
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    • 2002
  • Analysis and separation of constituent materials of old car have been performed by using the industrial shredding line. For this aim, three old cars made by domestic automobile manufacturers, Sonata II, Sephia and Prince were chosen and delivered in pressed form without engine, tires and doors, etc. Shredding line was substantially composed of pre- and main-shredder. cyclone, magnetic separation, eddy current separation and man-power separation. From the separation of shredder products, iron scrap was observed to be the major material of old car accounting for 60.1 % of total weight and non-ferrous metals involving Al, Cu and Zn, etc. were about 2%. Light fluff, about 90% of total fluff product, was comprised with plastic, fiber and sponge, etc. and the fraction of 5 cm undersize in light fluff was 70.5%. In case of heavy fluff, however. rubber and plastic were found to be the major constituent materials of it. Among the constituent materials of fluff, plastic showed the highest calorific value, more than 10,000 cal/gr and leather and rubber showed relatively high chlorine content, 10.3 and 2.55 wt%, respectively.

Electrochemical Corrosion Characteristics of the Iron-based Damping Alloy (철기제진합금의 전기화학적 부식특성)

  • Shim, Hyun Yee;Jee, Choong Soo;Lee, Jin Hyung;Lee, Kyu Hwan;Shin, Myung Chul
    • Analytical Science and Technology
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    • v.8 no.1
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    • pp.85-90
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    • 1995
  • Corrosion characteristics of 4 kinds of the Fe-Al damping alloys has been studied in the 3.5% NaCl solution and compared with a cold rolled mild steel and pure Ti, No passivation, besides Ti, was observed in the Fe-Al damping alloys and a cold rolled mild steel. Corrosion rate was decreased with lower carbon concentration. In the case of Mn addition for improving damping capacity, corrosion rate was decreased in scrap iron but was not decreased in electrolytic iron. It has been shown that corrosion rate of Fe-Al damping alloys lays between that of the pure Ti and that of a cold rolled mild steel.

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The Study on Domestic Fashion Information Service Industry for Systematization of Fashion Trend Information Planning Process (패션정보기획의 체계화를 위한 국내 패션정보산업의 고찰)

  • Choi, Mi-Young;Son, Mi-Young
    • Fashion & Textile Research Journal
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    • v.10 no.6
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    • pp.926-935
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    • 2008
  • The field of textile and fashion is regard to be sensitive to trend, however, the professional fashion information planning company for trend forecasting has not settled down in Korea. This study was designed to propose systemizing for fashion trend information planning in domestic fashion information service market. The empirical research was conducted by analysing in-depth interview data and news-scrap contents about each fashion information planning company. The result are as follows; First, fashion information service showed a little difference according to the type of fashion information companies, but they provided not only general fashion trends but also external market environmental information, survey-based consumer information and various segmented market research reports including academic information. Second, the fashion information planning process is largely divided into 3 stages; trend analysis, trend forecasting, trend application. The trend application step is the stage which connects the fashion information service industry to the fashion business. Thirdly, as a result of the competitive power evaluation for fashion information planning, the domestic fashion information planning companies came to reveal the fact that the possibility of carrying out and information analysis power were weak, however, how to present trend information had a relatively competitive. Consequently, this study is expected to play a role in understanding the importance of fashion trend information, and further ahead it would be helpful to organize the curriculum of fashion information planning subject in order to educate the future fashion executives.