• 한국환경과학회지
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• 제5권2호
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• pp.195-201
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• 1996

This study was conducted for the efficient utilization of a scoria, which is abundantly found in Cheju island, as adsorbent and the scoria was examined for its performance in clarification of adsorption of heavy metal ions. The order in heavy metal ions adsorbed on scoria was; Pb+>Cd^{2+}$>Cu^{2+}$>Ag^+$>Co^{2+}$>Zn^{2+}$>Cr^{3+}$>Cr^{6+}$. This tendency was relatively consistent with the decreasing order of radius of hydrated metal ion. Also, the smaller scoria size and the larger amounts of scoria showed higher removal efficiency for heavy metal ions. The same scoria size showed more effective removal efficiency for heavy metal ions at lower initial concentration than at higher initial concentration. The adsorption abilities of original scoria and chemically treated scoria were compared. Adsorption isotherm of scoria was generally obeyed to Freundlich formula than langmuir formula and Freundlich constant, than was obtained in the range of 0.2~0.4.

• 한국축산시설환경학회지
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• 제11권2호
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• pp.77-88
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• 2005

Scoria의 입자도를 달리하여 양돈사료내 첨가급여시 돼지의 성장효과, 사료이용성, 도체 특성 그리고 분중의 주요 오염물질인 질소와 인의 함량에 미치는 영향을 비교하기 위하여 시 험을 실시하였다. 대조구(기초사료)와 대조구 사료의 $3\%$ 수준을 500, 1,000, 1,700 ${\mu}m$로 제조된 scoria로 대체하여 배합된 사료로 나누어 급여한 처리 등 모두 4처리를 두어 143일간 사양시험을 실시하였는데 각 처리당 3반복(반복당 male 4, 거세돈 3두)으로 총 84두의 이유자돈을 완전임의 배치하였다. 시험종료 후 전두수를 축협공판장(등급판정소)에서 돼지등급판정 기준에 의해 도체등급을 조사하였고, 육색은 Chromameter를 사용하였으며, 분중의 질소와 인의 함량은 A.O.A.C 분석법 (1990)에 따라 분석하였다. 이러한 방법에 의해 얻어진 결과를 요약하면 다음과 같다. 1. 자돈기에는 scoria 첨가구 모두가 대조구에 비해 증체량이 낮았고, 사료요구율은 높았으며 육성기에는 scoria 입자도 $1,700\;{\mu}m$ 급여구가 증체량 및 사료효율이 가장 높았고, 비육기에서는 $1,000\;{\mu}m$ 입자도 첨가구가 일당증체량이 높고 사료요구율이 낮아지는 경향을 보였다. 그러나 전기간($0{\sim}143$일) 동안을 비교하면 scoria 입자도 $1,000\;{\mu}m$가 증체량 및 사료효율면에서 $1,700\;{\mu}m$ 보다 유리하였다. 2. 도체중은 모든 scoria 첨가구가 유의적 (P<0.05)으로 높았으나, scoria 입자도간 차이는 없었다. 그리고 등지방두께는 처리간 차이가 없었고, 도체등급에서 A+B 등급인 상등급 출현율은 대조구에 비해 scoria 첨가구가 월등히 증가하였으며, scoria 입자도간에는 $500\;{\mu}m$가 A등급 출현율이 가장 높았다. 3. 돼지고기의 육색은 명도(L값)의 경우는 대조구가 약간 높았으나 $1,000\;{\mu}m$ 및 $1,700\;{\mu}m$ 입자도와는 유의적인 차이가 없었으며, 적색도(a값)는 scoria 입자도 $1,000\;{\mu}m$ 급여구에서 가장 높게 나타났고, 황색도(b값)에서는 처리간 차이가 없었다. 4. 분중의 총질소 함량은 육성기에서 scoria 입자도 $1,000\;{\mu}m$ 급여구가, 비육기에서는 scoria 입자도 $1,700\;{\mu}m$ 급여가 가장 감소효과가 컸고, 인의 함량은 자돈기에서 scoria 입자도간 차이는 없었으나, 육성기와 비육기에는 각각 $1,700\;{\mu}m,\;1,000{\mu}m$의 scoria 입자도에서 배설량 감소효과가 낮았다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2002년도 추계학술발표회
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• pp.302-305
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• 2002

Scoria is a bomb-sized, generally vesicular pyroclast that is red or black in color and light in weight. In this study, scoria from Cheju was examined for the use as a sorbent. It is composed of plagioclase, olivine, hornblende, pyroxene, and glass, with an average composition of 49.84% SiO$_2$, 14.07% A1$_2$O$_3$, End 9.14% Fe$_2$O$_3$. Studies on kinetic isotherm sorption of Zn(II) onto scoria under various parameters such as initial zinc concentration, particle size, and adsorbent/adsorbate ratio were carried out using an agitated batch. The results suggest that the smaller scoria size and the larger adsorbent/adsorbate ratio produce the higher degree of Zn(II) removal. More effective removal also appears at lower initial Zn concentration. The sorption behavior of Zn(II) onto scoria seems to be mainly controlled by cation exchange. Studies on equilibrium isotherm sorption of other heavy metals (Pb, Cu, Cd) onto scoria were also conducted and compared with those onto powdered activated carbon (PAC) and non-organic matter scoria (NOS), The results suggest that the Cheju scoria has the slightly higher sorption capability than PAC and NOS, and the order of the effective sorption onto scoria and PAC is Pb > Cu > Zn > Cd. The monometal sorption onto scoria is more stronger than the competitive sorption.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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• pp.334-336
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• 2003

Recently, considerable researches have been focused to find out inexpensive sorbents. for removal of heavy metals in aquatic environments. In particular, various natural materials including geologic media have been attractive. In order to evaluate the applicability of the scoria taken from the Jeju island, Korea, to remove Zn(II) from aqueous solutions, the kinetic sorption experiments were performed in this study. The batch-type kinetic sorption tests were carried out under different conditions, such as different initial Zn(II) concentration, particle size of the scoria, and sorbate/sorbent ratio. The results indicated that the removal of Zn(II) by scoria increased with decreases in initial Zn(II) concentration, particle size of the scoria, and sorbate/sorbent ratio. However, the sorption capacity of the scoria decreased with increasing amount of the scoria. The sorption behavior of Zn(II) onto scoria seemed to be mainly controlled by cation exchange.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 추계 학술발표회
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• pp.1630-1637
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• 2008

Jeju-do is a island formed by the volcanic activity and has more than 360 volcanic cones distributed widely along the long axis of the elliptically shaped island. The volcanic cones consist mainly of scoria, so called "Song-I" in the local dialect. In this study the chemical and soil mechanical properties of scoria being very different from those of the inland were investigated with the various tests. In the sieve-passing test the particle size of scoria had more than 10 of uniformity coefficient and gradation coefficient of 1 ~ 3, showing relatively homogenous distribution. Based on the uniformity classification, scoria was assorted into GW. In the large scale direct shear tested for measuring the mechanical strength of scoria the internal friction angle of red scoria was $37^{\circ}$ and that of black scoria was $36^{\circ}$. This indicated that there was no difference in the mechanical strength between two types of scoria. On the other hand, red and black scoria had $1.24{\times}10^{-3}$ to $3.55{\times}10^{-2}$ cm/sec of k values for the static water level permeability, thus being classified into a coarse or fine sand as compared with that representing the saturated soil. They also had 1.411 to $1.477\;g/cm^3$ of notably low $r_{dmax}$ values for the compaction test as compared with common soil, which was considered to be due to their low specific gravity and high porosity. In conclusion, the soil mechanic properties of scoria obtained from this study are thought to be very helpful for reducing lots of trial and error happening in the civil engineering construction.

• 한국양식학회지
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• 제21권3호
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• pp.133-138
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• 2008

돌돔 Oplegnathus fasciatus과 넙치 Pralichthys olivaceus를 대상으로 사료 내 송이(Scoria)의 첨가에 따른 사육효과 및 단백질 소화율을 알아보기 위해 2가지 실험이 수행되었다. 돌돔(초기평균무게: 7.6 g)을 대상으로 한 1차 사양실험에서는 사료 내 송이함량을 0%(Con), 1%와 2%를 첨가하여 3반복으로 수행하였다. 9주간의 성장실험 결과, 송이 2%를 첨가한 실험구에서 대조구와 비교해 유의적인 차이가 없었으나 송이 1%를 첨가한 실험구에서 대조구와 비교해 유의적으로 낮은 값을 나타내었다. 단백질 소화율 측정 결과에서는 45.0%(Con), 60.6%(송이 1%), 64.0%(송이 2%)로 송이가 첨가된 실험구에서 대조구에 비해 유의적으로 높은 단백질 소화율을 나타내었다. 넙치를 대상으로 한 2차 실험은 1차 사양실험에서 확인되어진 증가된 단백질 소화율을 증명하기 위해 실시되었다. 실험사료는 송이 0%(Con), 1%, 2%, 3%, 4%로 조성되었다. 2차 실험의 단백질 소화율 결과에서는 사료 내 송이를 1%(56.7%), 2%(65.5%), 3%(52.8%) 첨가한 실험구에서 대조구(43.5%)에 비해 유의적으로 높은 값이 보였다. 반면 송이 4%를 첨가한 실험구에서는 단백질 소화율의 값이 41.4%로 대조구와 유의적인 차이를 보이지 않았다. 1 2차 사양실험의 결과를 종합하여 볼 때 해산어 배합사료 내 송이의 첨가는 사료 내 단백질 소화율을 증진시킬 수 있을 것으로 보여지며, 그 첨가함량은 $2{\sim}3%$ 내외가 될 것으로 판단된다.

• 대한의생명과학회지
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• 제24권4호
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• pp.329-333
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• 2018

The purpose of this study is to investigate the anti-inflammation effect of the mixture, consisting of a series of different ratio of Ecklonia cava extract and scoria. Also, to make more functional scoria powder into cosmetic material, studies on the toxicity by cell viability assay. Scoria is found in large amounts in Jeju Island, as an adsorbent of heavy metal ions ($Ni_2{^+}$, $Zn_2{^+}$, and $Cr_3{^+}$) in an aspect of its efficient utilization. Marine plants such as Ecklonia cava contain high amounts of polyphenolic antioxidants. The purpose of this study was to examine the anti-oxidative and anti-inflammation effects of combination of mixture of Eckloina cava extrat and scoria with optimal ratio. Therefore, this study suggested that combination of mixture of Eckloina cava extrat and scoria and its attenuated the oxidative and inflammatory reactions.

• 공업화학
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• 제34권1호
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• pp.86-93
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• 2023

In this study, we investigated the various adsorption factors influencing the adsorption of heavy metal ions based on the study of the composition and physicochemical properties of scoria dispersed throughout Jeju Island. Analysis of the distribution characteristics of scoria samples collected from five areas of Jeju showed that reddish-brown-colored scoria were predominant. Analysis of scoria collected from Jeju Island showed that its mineral components are ordered as follows: SiO₂ > Al₂O₃ > Fe₂O₃ > CaO and MgO. The experimental data did not show a linear relationship in the pseudo-first-order adsorption kinetics. In contrast, a pseudo-second-order model yielded a positive linear relationship, and this model was subsequently used. It could be concluded based on an intraparticle diffusion model indicating linear relationships that the capture of metal ions on scoria is dominated by the primary adsorption step.

• 대한의생명과학회지
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• 제23권4호
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• pp.355-361
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• 2017

In this study, antioxidant and anti-inflammatory of fermented Houttuynia cordata Thunb and scoria mixture extract were investigated in vitro. Radical-scavenging activities of the ethanol extracts were examined by using ${\alpha},{\alpha}$-diphenyl-${\beta}$-picrylhydrazyl (DPPH) and 2,2-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid (ABTS)) radicals assay. Consequently, we confirmed that fermented Houttuynia cordata Thunb and scoria mixture extract dependent removed DPPH and ABTS radical. Also, to confirm anti-inflammatory activity of ethanol extract, we treated fermented Houttuynia cordata Thunb and scoria mixture extract on BV-2 cell with LPS. The result showed that fermented Houttuynia cordata Thunb and scoria mixture extract concentration-dependent inhibited NO production. Therefore, fermented Houttuynia cordata Thunb and scoria mixture extract showed inhibition radical oxygen activities and inflammatory and have available for a pharmacological composition on neuritis-protection and treatment.

• 한국환경과학회지
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• 제32권8호
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• pp.563-572
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• 2023

Scoria from Jeju-island (Jeju scoria) was converted into zeolitic material (Z-SA) via zeolitification using the fusion/hydrothermal method. Jeju scoria could be synthesized into Z-SA to from a surface covered with Na-A zeolite crystals, which was confirmed through an analysis of X-ray diffraction peak patterns and scanning electron microscopy images. Jeju scoria and Z-SA were employed as adsorbents to evaluate the adsorption rate and adsorption capacities for Cu²⁺ and Zn²⁺ ions. The adsorption rates and isothermal adsorption capacities could be well fitted by the pseudo-quadratic adsorption kinetics and Langmuir adsorption isotherm, respectively. The maximum adsorption capacities (q_m) of Z-SA for Cu²⁺ and Zn²⁺ ions were found to be 163.36 mg/g and 120.51 mg/g, respectively, using the Langmuir adsorption isotherm. When Z-SA is synthesized from Jeju scoria via zeolitification using the fusion/hydrothermal method, Z-SA exhibits an adsorption capacity that is more than approximately 100 times the value exhibited by Jeju scoria. As a result, the synthesized Z-SA was regarded as an effective, economic adsorbent.