• Title/Summary/Keyword: sc-$CO_2$

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Analysis of inter-disciplinarity on renewable energy research (지식흐름 관점에서 신.생에너지연구의 학제간 다양성 분석 -태양전지 연구를 중심으로-)

  • Kim, Minji;Park, Junggyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.141-141
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    • 2010
  • 과학기술은 기술영역간의 관계를 통해 고유한 연구영역을 그리며 발달하며, 이는 학제의 다양성을 바탕으로 기존 기술들이 독특한 결합과정의 형성을 의미한다. 기술의 결합과정은 지식의 결합과정 관점으로 이해할 수 있다. 본 연구에서는 기존의 에너지산업과 다른 특성을 갖는 신 재생에너지의 기술발전경로를 '지식흐름'의 관점에서 탐색하여 신 재생에너지 연구의 학제 구조 및 다양성을 살펴보고자 한다. 계량서지학적 분석은 데이터 수집의 간편성 및 초기 연구결과물 분석에 적용할 수 있다는 장점에 의해 여러 분야에서 폭넓게 응용되어 왔다. 특히, A.L Porter(1984)에 의해 'citation'을 이용한 학제간관계 측정에 적용하여 계량서지학적 방법을 바탕으로 지식흐름을 관찰하는데 선구적인 방법을 제시하였다. 또한 Tijsen(1992)은 동시분류분석방법을 적용하여 네덜란드 에너지 연구분야의 학제구조를 분석하였고, Kajikawa(2007)은 에너지분야의 신기술인 태양전지와 연료전지에 한정하여 인용네트워크 분석을 수행하여 연구발전의 경향을 알아보았다. 이에 본 연구에서는 계량 서지학적 방법의 하나인 co-classification 방법론을 적용하여 태양광 분야 중 태양전지에 초점을 맞추어 학제 간 다양성 분석 연구를 수행 하였다. 태양광은 신 재생에너지 중 전후방연관 파급효과가 가장 큰 분야이며, 반도체 기반기술을 바탕으로 그 기술을 전개할 수 있기에 국내 산업과의 연관도가 높은 산업이다. 태양전지의 연구 동향 파악 및 고유의 연구영역을 도출을 분석하기 위한 기본 자료는 ISI의 'Web of Science'를 기반하여 수집하였다. 또한 태양광 연구의 연구구조 파악을 위하여 계량서지학분석의 하나인 'co-classification' 방법론을 추가적으로 적용하여 학제간의 분석을 수행하였다. 분석결과 1979-2009년까지의 태양전지 연구 논문 2,602개를 바탕으로 동시에 2개 이상의 SC를 포함한 논문은 총 논문의 51.8%이며, 출현한 SC는 65개로 분석되었다. 이 중 2개 이상의 SC가 동시에 출연한 횟수는 증가하는 경향을 가짐을 알 수 있었다. 이는 과학기술의 발전이 기술의 결합과정 또는 지식의 결합과정 관점으로 이해할 수 있음을 확인할 수 있었다.

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Safety assessment of Generation III nuclear power plant buildings subjected to commercial aircraft crash Part I: FE model establishment and validations

  • Liu, X.;Wu, H.;Qu, Y.G.;Xu, Z.Y.;Sheng, J.H.;Fang, Q.
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.381-396
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    • 2020
  • Investigations of the commercial aircraft impact effect on nuclear island infrastructures have been drawing extensive attention, and this paper aims to perform the safety assessment of Generation III nuclear power plant (NPP) buildings subjected to typical commercial aircrafts crash. At present Part I, finite element (FE) models establishment and validations for both the aircrafts and NPP buildings are performed. (i) Airbus A320 and A380 aircrafts are selected as the representative medium and large commercial aircrafts, and the corresponding fine FE models including the skin, beam, fuel and etc. are established. By comparing the numerically derived impact force time-histories with the existing published literatures, the rationality of aircrafts models is verified. (ii) Fine FE model of the Chinese Zhejiang Sanao NPP buildings is established, including the detailed structures and reinforcing arrangement of both the containment and auxiliary buildings. (iii) By numerically reproducing the existing 1/7.5 scaled aircraft model impact tests on steel plate reinforced concrete (SC) panels and assessing the impact process and velocity time-history of aircraft model, as well as the damage and the maximum deflection of SC panels, the applicability of the existing three concrete constitutive models (i.e., K&C, Winfrith and CSC) are evaluated and the superiority of Winfrith model for SC panels under deformable missile impact is verified. The present work can provide beneficial reference for the integral aircraft crash analyses and structural damage assessment in the following two parts of this paper.

Expression and Purification of a Recombinant scFv towards the Exotoxin of the Pathogen, Burkholderia pseudomallei

  • Lim, Kue-Peng;Li, Hong-Bin;Sheila Nathan
    • Journal of Microbiology
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    • v.42 no.2
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    • pp.126-132
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    • 2004
  • A single chain variable fragment (scFv) specific towards B. pseudomallei exotoxin had previously been generated from an existing hybridoma cell line (6E6AF83B) and cloned into the phage display vector pComb3H. In this study, the scFv was subcloned into the pComb3X vector to facilitate the detection and purification of expressed antibodies. Detection was facilitated by the presence of a hemagglutinin (HA) tag, and purification was facilitated by the presence of a histidine tag. The culture was grown at 30$^{\circ}C$ until log phase was achieved and then induced with 1 mM IPTG in the absence of any additional carbon source. Induction was continued at 30$^{\circ}C$ for five h. The scFv was discerned by dual processes-direct enzyme-linked immunosorbent assays (ELISA), and Western blotting. When compared to E. coli strains ER2537 and HB2151, scFv expression was observed to be highest in the E. coli strain Topl0F'. The expressed scFv protein was purified via nickel-mediated affinity chromatography and results indicated that two proteins a 52 kDa protein, and a 30 kDa protein were co-purified. These antibodies, when blotted against immobilized exotoxin, exhibited significant specificity towards the exotoxin, com-pared to other B. pseudomallei antigens. Thus, these antibodies should serve as suitable reagents for future affinity purification of the exotoxin.

Preparation and Adsorption Properties of PA6/PSMA-OA Molecularly Imprinted Composite Membranes in Supercritical CO2

  • Zhang, Qing;Zhang, Xingyuan;Zhang, Wencheng;Pan, Jian;Liu, Ling;Zhang, Haitao;Zhao, Dong;Li, Zhi
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3348-3354
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    • 2011
  • Oleanolic acid (OA) as template molecule, polyamide-6 (PA6) as basement membrane and poly(styrene-comaleic acid) (PSMA) were used to prepare PA6/PSMA-OA molecularly imprinted composite membranes by phase inversion method in supercritical $CO_2$ ($ScCO_2$). The template molecule (OA), [poly(styrene-co-maleic anhydride) (PSMAH), PSMA, molecularly imprinted membranes (MIMs) imprinting OA and MIMs after elution were all characterized by Fourier transform infrared spectroscopy (FTIR). The conditions that were the mass ratio between PSMA and OA from 3:1 to 8:1, temperature of $ScCO_2$ from $35^{\circ}C$ to $50^{\circ}C$ and pressure of $ScCO_2$ 12 MPa to 17 MPa were studied. It was obtained the largest adsorption rate and purity of OA after adsorption of the resultant MIMs, 50.41% and 96.15% respectively. After using PA6 film and non-woven fabrics as basement membrane respectively, it was found that smaller aperture of PA6 was used as basement membrane, a higher adsorption rate and a higher purity of OA after adsorption of the MIMs were obtained, and so were the stability and reproducibility of the resultant MIMs. After template molecules being removed, the MIMs had effective selectivity hydrogen bonding to separately bind in the binary components to the template molecules-oleanolic acid.

Study on the Whiteness Improvement of Glyoxal Treated Cotton Fabric - Effects of Additives - (글리옥살 처리 면직물의 백도 개선에 대한 연구 - 첨가제의 영향 -)

  • Cho, Hang Sung;Lee, Bum Hoon
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.284-290
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    • 2017
  • The glyoxal has been used as formaldehyde free DP(durable press) agents in wrinkle free treatment for cotton fabrics. However, the yellowing problem is a disadvantage of DP finishing process for cotton fabrics with glyoxal. In order to improve the whiteness, it was investigated that the effect of coreactant and treatment method with various whitening additives such as STB(sodium tetraborate, $Na_2B_4O_7$), SPB(sodium perborate, $NaBO_3$), SC(sodium chlorite, $NaClO_2$) and SPC(sodium percarbonate, $Na_2CO_3{\cdot}1.5$ $H_2O_2$). The increasing the concentration of whitening additives(STB, SPB, SC and SPC), the whiteness and the strength retention ratio of cotton fabrics were increased but the wrinkle recovery angles were decreased in one bath method. It was not suitable to improve whiteness because the whiteness value is about 60. In the case of SC used two bath method, the whiteness is near 70, which is similar to untreated fabrics, without decreasing of WRA and strength.

Determination of Tributyl Phosphate Degradation Products by Ion Chromatography (이온크로마토그래피에 의한 Tributyl Phosphate(TBP) 분해산물의 정량)

  • Han, Sun Ho;Lee, Hyo Jin;Yang, Han Beom;Park, Yang Soon;Joe, Kih Soo
    • Analytical Science and Technology
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    • v.15 no.4
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    • pp.329-334
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    • 2002
  • Tributyl phosphate(TBP) is used in solvent extraction process for radioactive waste. This compound may be degraded to dibutyl phosphate($DBP^-$), monobutyl phosphate($MBP^{2-}$) and ${PO_4}^{3-}$ by radioactive material. Amount of $DBP^-$ and $MBP^{2-}$ in TBP must be monitored because they production of these compounds means degradation of which leads to a decrease in the extraction yield. Retention behavior for $DBP^-$, $MBP^{2-}$, $F^-$, $Cl^-$, ${NO_2}^-$, ${NO_3}^-$, ${SO_4}^{2-}$ and ${PO_4}^{3-}$ are studied with AS4A-SC(Dionex) analytical column and $Na_2CO_3$/NaOH eluent by Ion chromatography. Optimum condition for these anions is 2 mM $Na_2CO_3$/1 mM NaOH eluent. All anions by this condition is well separated within 15min. Dynamic range is $10{\mu}g/mL$ - $100{\mu}g/mL$ for DBP and $5{\mu}g/mL$ - $50{\mu}g/mL$ for $MBP^{2-}$, respectively. The Detection limit for AS4A-SC are $1{\mu}g/mL$ for $DBP^-$ and $0.5{\mu}g/mL$ for $MBP^{2-}$ in this system with a $25{\mu}L$ sample loop.

Extraction of Impregnated Metals from Charcoal Active Carbon with Supercritical Carbon Dioxide (초임계 이산화탄소에 의한 금속 담지 활성탄으로부터 담지금속의 추출)

  • Lee, Jong-Chol;Ryu, Sam-Gon
    • Journal of the Korea Institute of Military Science and Technology
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    • v.11 no.5
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    • pp.99-106
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    • 2008
  • Metal ions such as Cu and Cr were extracted from the Cu, Cr and Ag impregnated active carbon by contacting the solid surfaces with supercritical carbon dioxide(Sc-$CO_2$) containing chelating agents. About 10g of the active carbon sample were loaded in a vertical tube extractor contacting with $CO_2$ flowing from the bottom of the tube for 6hrs. The ligands used were acetyl acetone(AA) and Cyanex-302(C-302). Water and methanol were used as entrainers to study the effect of co-solvent to $CO_2$. Experimental results showed that C-302 was more effective than AA in removing Cu with the maximum extraction of 42.0wt%, while 57.6wt% of Cr was extracted with AA from the sample.

The Fabrication of the Cu(In,Ga)Se2 Absorber Layer Using Binary Precursor Films Deposited by Chemical Vapor Deposition (화학기상증착된 이원계 화합물 프리커서를 이용한 Cu(In,Ga)Se2 흡수층의 제조)

  • Lee, Gyeong A;Kim, A Hyun;Cho, Sung Wook;Lee, Kang-Yong;Jeon, Chan-Wook
    • Current Photovoltaic Research
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    • v.9 no.4
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    • pp.137-144
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    • 2021
  • In this study, the microstructure of the CVD-fabricated Cu(In,Ga)Se2 (CIGSe) absorber layer by simulating the stacking sequence used in a co-evaporation method, and changes solar cell performance were investigated. The absorber layer prepared by stacking CuSe and (In,Ga)Se between InSe is separated into Ga-free CuInSe2 and Ga-rich CIGSe, and transformed to CIGSe by selenization heat treatment with slight improvement in the the solar cell efficiency. However, in CVD, since the supply of liquid Cu-Se is not as active as in the co-evaporation method, the nanoocrystalline layer containing a large amount of Ga remained independently in the absorption layer, which acted as a cause of the loss of JSC and FF. Therefore, by using a precursor structure in which CuGa is sputter-deposited on a single layer of InSe deposited by CVD, performance parameters of VOC, JSC, and FF could be greatly improved.

Continuous Process for the Etching, Rinsing and Drying of MEMS Using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 미세전자기계시스템의 식각, 세정, 건조 연속 공정)

  • Min, Seon Ki;Han, Gap Su;You, Seong-sik
    • Korean Chemical Engineering Research
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    • v.53 no.5
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    • pp.557-564
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    • 2015
  • The previous etching, rinsing and drying processes of wafers for MEMS (microelectromechanical system) using SC-$CO_2$ (supercritical-$CO_2$) consists of two steps. Firstly, MEMS-wafers are etched by organic solvent in a separate etching equipment from the high pressure dryer and then moved to the high pressure dryer to rinse and dry them using SC-$CO_2$. We found that the previous two step process could be applied to etch and dry wafers for MEMS but could not confirm the reproducibility through several experiments. We thought the cause of that was the stiction of structures occurring due to vaporization of the etching solvent during moving MEMS wafer to high pressure dryer after etching it outside. In order to improve the structure stiction problem, we designed a continuous process for etching, rinsing and drying MEMS-wafers using SC-$CO_2$ without moving them. And we also wanted to know relations of states of carbon dioxide (gas, liquid, supercritical fluid) to the structure stiction problem. In the case of using gas carbon dioxide (3 MPa, $25^{\circ}C$) as an etching solvent, we could obtain well-treated MEMS-wafers without stiction and confirm the reproducibility of experimental results. The quantity of rinsing solvent used could be also reduced compared with the previous technology. In the case of using liquid carbon dioxide (3 MPa, $5^{\circ}C$, we could not obtain well-treated MEMS-wafers without stiction due to the phase separation of between liquid carbon dioxide and etching co-solvent(acetone). In the case of using SC-$CO_2$ (7.5 Mpa, $40^{\circ}C$), we had as good results as those of the case using gas-$CO_2$. Besides the processing time was shortened compared with that of the case of using gas-$CO_2$.

Estimation and Feature of Greenhouse Gas Emission in Building Sector by National Energy Statistic (국가 에너지통계에 따른 건물부문 온실가스 배출량 추계 및 특성)

  • Jeong, Young-Sun;Kim, Tae-Hyoung
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.7
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    • pp.187-195
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    • 2019
  • In December 2015, The Paris Agreement was adopted to undertake ambitious efforts to combat climate change. Korean government announced its goal of reducing the country's greenhouse gas emissions by up to 37% below business as usual projections by 2030 in 2015. The purpose of this study was to set up the calculation methodology of GHG emission($CO_{2e}$) in building sector and to estimate the annual GHG emission in building sector based on national energy consumption statistic. The GHG emission from buildings is about 135.8 million ton $CO_{2e}$ as of 2015, taking up about 19.6% of Korea's entire emission and is about 144.7 million ton $CO_{2e}$ in 2017. The GHG emission of building sector is increasing at annual rate of 2.0% from 2001 to 2017. The GHG emission from electricity consumption in buildings is 91.8 million ton $CO_{2e}$ in 2017, is the highest $CO_2$ emission by energy source. The results show that the intensity of GHG emission of residential building sector is $40.6kg-CO_{2e}/m^2{\cdot}yr$ and that of commercial building sector is $68.4kg-CO_{2e}/m^2{\cdot}yr$.