• Fire Science and Engineering
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• v.18 no.3
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• pp.9-17
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• 2004

The values of physical properties of the inert gases of Ar, $N_2$, $CO_2$ were calculated by the empirical equations. The regression coefficients were obtained by the experimental data and the resulting calculated values. For the empirical equation with a lower regression coefficient, a new correlation was suggested. At an atmosphere pressure, the empirical equation was confirmed by the experimental values for the viscosity, density, saturated pressure, and surface tension of Ar, $N_2$, $CO_2$. The correlation coefficients of the empirical equations proposed in this work was higher than 0.99.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.11a
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• pp.35-38
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• 2005

The effect of reduction and re-oxidation firing on the PTCR properties of Sm-doped Barium Titanate ceramics was investigated for the application of multilayered PTC thermistor. The lattice parameter a, c decreases monotonically with increasing oxygen concentration in the reoxidation atmosphere, which seems to be related with the electrostatic Coulomb interaction between oxygen vancancy and nearest other atoms. With increasing oxygen concentration, the resistivity at room temperature and the magnitude of resistivity jump as a function of temperature increased in the region of oxygen concentration of 0 $\sim$ 10%. However, the resistivity at room temperature and the magnitude of resistivity jump is nearly constant and saturated in the region of oxygen concentration of 10 $\sim$ 20%. These phenomena is considered to be related with the variation of oxygen and barium-vancany concentration near the grain boundary.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.6
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• pp.681-687
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• 2008

It is well known that the water infiltration rate depends on soil properties such as soil water content, water head, capillary suction, density, hydraulic conductivity, and porosity. However, most of proposed infiltration models assume that the air phase is continuous and in equilibrium with the atmosphere or air compression and air entrapment on infiltration was not considered. This study presents experimental results on unsaturated water infiltration to relate air entrapment and hydraulic conductivity function based on soil air properties. The objectives of this study were to measure change of soil air pressure ahead of wetting front under air drain and air confined condition to find the confined air effect on infiltration rate, to reduce the entrapped air volume related with soil air pressure to increase the soil permeability, and to make a basis of infiltration process model for the purpose of improvement of infiltration rate in the homogeneous soil column. The results of the work show that soil air pressure increases according to increasement of the saturated soil depth rather than the wetting front depth during infiltration process.

• Elastomers and Composites
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• v.50 no.2
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• pp.126-131
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• 2015

$C_{60}$ nanowhiskers were synthesized from $C_{60}$ by liquid-liquid interfacial precipitation (LLIP) using $C_{60}$-saturated toluene and isopropyl alcohol. The $WO_3$ nanoparticles were synthesized by adding $3.8{\times}10^{-4}$ mole amount of ammonium metatungstate hydrate ($H_{26}N_6O_{40}W_{12}{\cdot}H_2O$) to 500 ml of distilled water, and the resulting solution was heated on a hot plate for 4 h. The $C_{60}$ nanowhiskers/$WO_3$ nanocomposites were prepared with $C_{60}$ nanowhiskers and $WO_3$ nanoparticles in an electric furnace at $700^{\circ}C$ in an argon gas atmosphere for 2 h. The $C_{60}$ nanowhiskers/$WO_3$ nanocomposites were characterized by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. UV-vis spectroscopy was used to evaluate the performance of the $C_{60}$ nanowhiskers/$WO_3$ nanocomposites as a photocatalyst in the degradation of organic dyes, such as methylene blue (MB) and brilliant green (BG) under ultraviolet light (254 nm).

• Proceedings of the KIEE Conference
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• 1994.07b
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• pp.1333-1335
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• 1994

The nitrification of pure iron powders is found to occur even at room temperature by high energy ball milling in $NH_3$ gas atmosphere. The powders of metastable iron nitrides ($0<at.%N{\le}23.3$) thus produced are identified as the super-saturated bee structure for the N content below 14.9 at.%N and the high temperature phase of the hcp structure above 19.4 at.%N. The atomic volume of Fe in the bcc phase is found to be smaller than that of the N-martensite reported in the literature. Magnetization at room temperature gradually decreases with increasing the N concentration in contrast to the enhancement reported for the bet nitrides. Neutron diffraction experiment also provide detailed information about the local structure surrounding the nitrogen atom. The coordination number of Fe atom around a nitrogen atom for the iron nitride containing 9.5 at.%N turns out to be 3.9 atoms.

• Journal of the Korean institute of surface engineering
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• v.30 no.5
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• pp.333-346
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• 1997

Plasma spray processes for functional coatings of tubular SOFC ( Soild oxide Fuel Cell).consisting of air electrode, oxide electrolyte, an fuel electrode, are optimized by fully saturated fractional factorial testing. Material and electric characteristics of each coating are analtsed by the implementation of SEM and optical microscope for evaluating microstructure and porosity, X-ray diffraction method for investigating compositional change between raw powder and sprayed coating, and Van der Pauw method for measuring electrical conductivity. LSM ($La_{0.65}Sr_{0.35}MnO_3$air electrode and Ni-YSL fuel electrode coatings have porosities of around 23~30% sufficient for effective fuel and oxidant gas supply to electrochemical reaction interfaces and electrical conductivities of around 90 S/cm and 1000 S/cm, respectively, enough for acting as current collecting electrodes. YSZ($ZrO_2-8mol%Y_2O_3$) electrolyte film has a high ionic conductivities of 0.05~0.07 S/cm at $1000^{\circ}C$ in air atmosphere, but appears to be somewhat too porous to reduce the thickness. for enhancing the cell efficiency. A unit tubular SOFC has beem fabricated by the optimized plasma spray processes for each functional coating and the cell. Its electrochemical chracteristics are investigated by measuring voltage-current and power density with variation of operationg temperature, radio of fuel to air gas flowrates, and total gas flowrate of reactants.

• Atmosphere
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• v.33 no.5
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• pp.457-475
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• 2023

Accurately predicting localized heavy rainfall is challenging without high-resolution mesoscale cloud information in the numerical model's initial field, as precipitation intensity and amount vary significantly across regions. In the Korean Peninsula, the radar observation network covers the entire country, providing high-resolution data on hydrometeors which is suitable for data assimilation (DA). During the pre-processing stage, radar reflectivity is classified into hydrometeors (e.g., rain, snow, graupel) using the background temperature field. The mixing ratio of each hydrometeor is converted and inputted into a numerical model. Moreover, assimilating saturated water vapor mixing ratio and decomposing radar radial velocity into a three-dimensional wind vector improves the atmospheric dynamic field. This study presents radar DA experiments using a numerical prediction model to enhance the wind, water vapor, and hydrometeor mixing ratio information. The impact of radar DA on precipitation prediction is analyzed separately for each radar component. Assimilating radial velocity improves the dynamic field, while assimilating hydrometeor mixing ratio reduces the spin-up period in cloud microphysical processes, simulating initial precipitation growth. Assimilating water vapor mixing ratio further captures a moist atmospheric environment, maintaining continuous growth of hydrometeors, resulting in concentrated heavy rainfall. Overall, the radar DA experiment showed a 32.78% improvement in precipitation forecast accuracy compared to experiments without DA across four cases. Further research in related fields is necessary to improve predictions of mesoscale heavy rainfall in South Korea, mitigating its impact on human life and property.

• Analytical Science and Technology
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• v.11 no.1
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• pp.62-72
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• 1998

This study was performed to characterize the trace organic pollutants in the industrial wastewater and to establish the database of the trace organic pollutants. The four manufacturing industries, which are refined petroleum, industrial chemicals, rubber & plastics and fabricated metals, were surveyed. The wastewater and discharging water of these 30 factories are analyzed to characterize the trace organic pollutants. In industrial chemicals, the kinds of products and organic pollutants are very various. Therefore to select the characteristic organic pollutants in this categories are also very difficult. In industrial chemicals, the gas chromatograpic peak patterns of wastewater are represented the various type according to their products, therefore the typical patterns of the characteristic organic pollutants could not be obtained because the kinds of manufactured goods and organic pollutants are very various. In refined petroleum, the effluent is discharged in the distillatory process of atmosphere pressure and contained the saturated hydrocarbons, phenol compounds, benzene compounds and naphtalene compounds. The saturated hydrocarbons peaks from $C_{15}$ to $C_{35}$ are represented the typical oil patterns by the uniform intervals therefore the peak can be easily distinguished. In rubber & plastics, the wastewater is discharged in the washing process which contains the additives. The problem of wastewater is not serious because the manufacturing process is not produced the effluent or the produced cooling water is recycled in that process.

• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.19-26
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• 1986

A titanium oxide thin films were prepared by air oxidation and vapour oxidation and a $TiO_2$ single crystal was reduced by heating in an argon atmosphere. All the electrode characteristics of the Ti$O_{2-x}$, thin films are not different from those of slightly reduced single crystal rutile. In cyclic voltammogram of oxygen containing electrolyte solution at Ti$O_{2-x}$ electrodes, cathodic peaks were observed at between -0.8V and -1.0V vs. SCE. The cathodic current near 0V vs. SCE in saturated solution with nitrogen was observed to be greater than in saturated solution with air. The chronoamperogram was represented by the equation of i = $i_0e^{-kt}$, when the rate constant k was represented by the equation of k =$k_0{[H^+]}^nexp(A{\eta}+E_a/RT)$ The values of activation energy $E_a $were found to be 4.6~4.8kcal/mole in overpotential range of 0.035∼0.145 V and 1.6kcal/mole in overpotential range of 0.2∼0.5V. The values of n and A were found to be 0. 1 and 5.4~5.6/V in range of 0.035~0.145V, and in range of 0.2~0.5V, to be 0.04 and 1.3/V, respectively. This can be interpreted as an totally irreversible reduction of oxygen.

• Atmosphere
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• v.17 no.1
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• pp.109-114
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• 2007

The mist on the inside of an automobile windshield is not only uncomfortable but also very dangerous because it obstructs the driver's vision. However, the removal process of the mist has never been studied in detail. This study performed experiments analyzing the mechanism causes the mist in a car and investigated the appropriate removal process. The experiments were performed on two rainy days, 10 April 2006 and 26 May 2006, with temperature and relative humidity sensors of testo-175-H2 and DICKSON-TK500. We found a passenger increased water vapor by 0.2 g $min^{-1}$ through respiration and thereby relative humidity (RH) from 55% to 67% in 8 minutes. Even though RH was not saturated, misting occurred because the humid air contacted the colder surface of the window. To remove the mist, it is necessary to increase the temperature or inflow drier air in the car. Therefore, we expected that the heater would be more effective than air conditioner for this matter. However, the outcome was the other way around due to the structure of the heating and cooling system in the car. When the air-conditioner was on, colder and drier air was generated and flowed through the so-called evaporator. Droplets were produced in the evaporator due to cooling procedure. When the heater was on, the warm air evaporated the droplets and increased the water content in the air resulting in an increase of relative humidity. Consequently, the air conditioner is more effective than the heater to remove the mist.