• Title/Summary/Keyword: sandy silt

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Analysis of heavy metals from soils with magnetite immobilized functional groups (기능성기가 결합된 자성체를 이용한 토양의 중금속 분석)

  • Hyungsuk So;Nah, In-Wook;Hwang, Kyung-Yub
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.156-156
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    • 2003
  • 유럽의 여러나라들의 경우 토양내 중금속의 허용치는 그 사용 목적에 따라 다르게 책정되고 있으며 1999년에 제정된 독일의 새로운 토양보전법에서도 토양의 사용목적별로 중금속 허용치를 달리 정하고 있다. 여기서 중금속 농도를 측정하기 위한 방법으로는 DIN(독일 공업규격)에서 정하고 있는 증류수추출법과 왕수추출법이 채택되고 있다. 그러나 이 2가지 방법들은 토양의 중금속분석에서 가장 큰 factor로 작용하는 것이 pH인데 반하여 pH가 7인 증류수와 pH가 0인 왕수를 사용함으로써 실제환경에 적용하기에는 많은 무리수를 내포하고 있으며 차츰 적당치 못한 것으로 판명되고 있다. 실질적인 중금속의 유해성 여부는 토양에서의 그 중금속의 용해도와 유동성으로 결정되는데 강한 산성비가 내린다고 가정하였을 때 비의 pH가 약 4 정도이고 이 경우 식물 뿌리 부분의 pH는 5 정도가 되므로 pH를 기준으로 할 때 잠재적으로 유동가능한 중금속을 분석하는 데에는 pH 4.5 에서 EDTA 추출이 가장 적당하고 또한 이를 토대로 토양내 중금속 허용치를 정하는 것이 합리적이라고 하겠다. 그러나 EDTA는 pH 4에서 부분적으로 Proton과 결합되어 Metal Chelate로의 능력을 잃게 되고 또한 식물 뿌리의 중금속 흡착을 Simulation할 수 없어 불리한 점이 있다. 또한 EDTA는 분해기간이 길고 인체에 해롭다는 것이 알려지고 있어 점점 사용이 어려워지고 있다. 본 연구에서는 토양에 함유된 유동가능한 중금속농도분석을 보다 적절히 하기 위한 방법으로 EDTA와 같이 Carboxyl기가 결합된 고분자 자성체를 이용해 토양의 중금속을 분석하는 것을 제안하였고 분석을 위한 중금속 추출 시 토양시료와 증류수 그리고 고분자 자성체만을 사용하여 근본적으로 토양에서 유동 가능성이 있는 중금속만을 추출하였다. 분석실험은 토양의 Cd2+ 와 Pb2+를 대상으로 행하여졌으며, 여러 토양에서 추출 분석한 결과를 EDTA분석결과와 비교하였다. 실험결과, 중금속은 매우 신속하게 고분자 자성체와 결합하였고, 그 후 자성체를 외부 자장으로 모은 후 산으로 용해시키고, 결합된 중금속은 Graphite furnace AAS로 분석함으로써 빠르고 효율적으로 분석실험을 수행할 수 있음을 알 수 있었다. 한편, 실험에서 나타난 수치들을 비교 검토한 결과 토양 분석시 sandy soil에서는 자성체를 이용한 분석이 EDTA에 의한 방법보다 더 높은 추출도를 보인 반면, silt 함량이 많은 토양의 경우에서 EDTA분석에서 더 높은 중금속 추출도를 보였다.

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Analysis of Soil Moisture Changes in Reclaimed Tideland Using Van Genuchten Model (Van Genuchten 모델을 활용한 간척지의 토양수분변화 분석)

  • Ko, Dae-Hee;Son, Jae-Gwon;Lee, Gi-Sung;Kim, Jeong-Kyun;Song, Jae-Do;Park, Young-Jun
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.4
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    • pp.53-61
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    • 2020
  • The laboratory model test was conducted by dividing domestic reclaimed tideland into Sandy Loam (SL) and Silt Clay Loam (SiCL) to estimate soil moisture change and water supply according to soil characteristic when establishing irrigation plan for reclaimed tideland upland crop. In addition, the applicability of each scenario was verified using Van Genuchten model, which is the most widely used mathematical model for analyzing soil moisture characteristics of reclaimed tideland uplands crops. The required water supply according to the target soil moisture tension by reclaimed tideland is as follow. In the case of SL, soil depths of 0~10 cm, 10~20 cm were analyzed as 19 mm, 35 mm to reach the field capacity, and SiCL, 33 mm, 63 mm. The required water supply of SiCL was higher than that of SL. The study compared the simulation results from the scenarios of Van Genuchen model and the measured results from the laboratory model test based on according to the reclaimed tidelands. In the case of parameter, θs, θr, α, η were analyzed 0.55, 0.18, 0.064, 1.74 in SL and 0.46, 0.22, 0.105, 1.92 in SiCL. In terms of soil characteristics, SL with better water permeability was found to have higher applicability than SiCL. By Soil depth, applicability was found in 0~10 cm directly affected by water supply.

Threshold Subsoil Bulk Density for Optimal Soil Physical Quality in Upland: Inferred Through Parameter Interactions and Crop Growth Inhibition

  • Cho, Hee-Rae;Han, Kyung-Hwa;Zhang, Yong-Seon;Jung, Kang-Ho;Sonn, Yeon-Kyu;Kim, Myeong-Sook;Choi, Seyeong
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.548-554
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    • 2016
  • Optimal range of soil physical quality to enhance crop productivity or to improve environmental health is still in dispute for the upland soil. We hypothesized that the optimal range might be established by comparing soil physical parameters and their interactions inhibiting crop growth. The parameter identifying optimal range covered favorable conditions of aeration, permeability and root extension. To establish soil physical standard two experiments were conducted as follows; 1) investigating interactions of bulk density and aeration porosity in the laboratory test and 2) determining effects of soil compaction and deep & conventional tillage on physical properties and crop growth in the field test. The crops were Perilla frutescens, Zea mays L., Solanum tuberosum L. and Secale cereael. The saturated hydraulic conductivity, bulk density from the root depth, root growth and stem length were obtained. Higher bulk density showed lower aeration porosity and hydraulic conductivity, and finer texture had lower threshold bulk density at 10% aeration bulk density. Reduced crop growth by subsoil compaction was higher in silt clay loam compared to other textures. Loam soil had better physical improvement in deep rotary tillage plot. Combined with results of the present studies, the soil physical quality was possibly assessed by bulk density index. Threshold subsoil bulk density as the upper value were $1.55Mg\;m^{-3}$ in sandy loam, $1.50Mg\;m^{-3}$ in loam and $1.45Mg\;m^{-3}$ in silty clay loam for optimal soil physical quality in upland.

Assessment of Heavy Metal Concentrations in Greenhouse Soils of Gyeongnam Province

  • Son, Daniel;Cho, Hyeon-Ji;Heo, Jae-Young;Lee, Byeong-Jeong;Hong, Kwang-Pyo;Lee, Young Han
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.5
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    • pp.383-390
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    • 2017
  • Heavy metal contamination of soil might be a cause of serious concern due to the potential health impacts of consuming contaminated products. In this study, the total content of heavy metals (Cd, Cr, Cu, Ni, Pb, Zn, As, and Hg) in soils was analyzed, and the difference of heavy metal contents depending on crops, soil characteristics, and topography was compared in 169 greenhouse soils obtained from Gyeongnam Province. The concentrations of the heavy metals were $0.25mg\;kg^{-1}$ (ranged 0.01~0.44) for Cd, $28.94(0.53{\sim}72.63)mg\;kg^{-1}$ for Cr, $26.03(0.5{\sim}166.13)mg\;kg^{-1}$ for Cu, $14.91(1.27{\sim}33.22)mg\;kg^{-1}$ for Ni, $15.76(0.43{\sim}57.1)mg\;kg^{-1}$ for Pb, $119.72(6.33{\sim}239.39)mg\;kg^{-1}$ for Zn, $2.54(0.01{\sim}23.57)mg\;kg^{-1}$ for As, and $0.049(0.012{\sim}0.253)mg\;kg^{-1}$ for Hg in topsoils. The concentrations of Pb and As in topsoil were highest in green pepper and those of Cd, Cr, and Ni were highest in melon. In addition, the concentrations of Cr and Ni were highest in diluvial terrace compared with the other topographies. Higher concentrations of Cd, Cr, and Ni were found in silty clay loam and silt loam soils than sandy loam and loam soils.

Change of Heavy Metals and Sediment Facies in Surface Sediments of the Shihwa Lake (시화호 표층퇴적물의 중금속 및 퇴적상 변화)

  • 최만식;천종화;우한준;이희일
    • Journal of Environmental Science International
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    • v.8 no.5
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    • pp.593-600
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    • 1999
  • In order to determine the changes of sediment facies and metal levels in surface sediments after the construction of Shiwha Lake, surface sediments were sampled at 8 sites located on the main channel monthly from June, 1995 to August, 1996 and analysed for 12 metals (Al, Fe, Mn, V, Cr, Co, Ni, Cu, Zn, Cd, As and Pb) by ICP/AES and ICP/MS. Two groups of sampling sites(the inner lake with 3 sites and the outer lake with 5 sites) are subdivided by the surface morphology ; the inner lake is a shallow channel area with a gentle slope, while the outer lake is relatively deep and wide channel with a steep slope which has many small distributaries. After the construction of dam, fine terrestrial materials were deposited near the outer lake, which resulted in the change of major sediment facies from sandy silt to mud. With the deposition of fine sediments in the outer lake, anoxic water column induced the formation of sulfide compounds with Cu, Cd, Zn and part of Pb. Metal (Cr, Ni, Cu, Zn and Cd) contents in sediments increased up to twice within 2 years after the construction of dam. This is due to the direct input of industrial and municipal wastes into the lake and the accumulation of metals within the lake. In addition, frequent resuspension of contaminated sediments in a shallow part of the lake may make metal-enriched materials transport near the outer lake with fine terrestrial materials. As the enrichment of Cu, Zn, Cd and part of Pb in the Shiwha Lake may be related to the formation of unstable sulfide compounds by sulfate reduction in anoxic water or sediment column, the effect of mixing with open coastal seawater is discussed.

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Sedimentary Characteristics in the Tidal Flat of Janghwa-ri, Kangwha Island, Eastern Yellow Sea (강화도 장화리 조간대의 퇴적 특성)

  • Oh, Jae-Kyoung;Do, Jong-Dae;Jo, Yong-Gu
    • Journal of the Korean earth science society
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    • v.27 no.3
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    • pp.328-340
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    • 2006
  • In Janghwa-ri of Kanghwa Island morphological changes in four transects, 112 surface, and 2 core sediments were analyzed to understand the seasonal variation of the muddy tidal-flat environment. Sedimentary of facies can be classified into four facies; sand, muddy sand, sandy mud, and silt. During winter, the coarse-grained sediment facies expanded seaward. In the subsurface part of the core sediments, poorly sorted silty sediments dominate the area. According to the Pb-210 isotope analysis, accumulation rates of the tidal flat in Jangwha-ri appear to be $5{\sim}19mm/yr$. In the study area, the result is suggestive of a rapid change in depositional environments in recent years.

Development and Evaluation of a Dust Generator Using Soil Samples (토양 분진발생장치의 개발과 평가)

  • Lee, Ji-Yeon;Lee, Ki-Young
    • Journal of Environmental Health Sciences
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    • v.36 no.5
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    • pp.383-390
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    • 2010
  • Exposure to fugitive dust can contribute to several respiratory health problems, and proper sampling of fugitive dust is necessary to assess exposure. However, field sampling of soil dust encounters problems from spatial and temporal differences in soil properties, field operations, and meteorological conditions. To minimize these problems, we designed a dust generator that simulates dust generation from soil. The dust generator consisted of a rotating chamber where soil samples were loaded and tumbled, and a settling chamber, where airborne soil dust samples were collected. As standard operating conditions, we decided on 2 g soil mass, 10 min sampling time, and 20 rpm rotating speed, with a flow rate of 30 l/min, based on three common soil textures of loam, sandy loam and silt loam. To evaluate optimal operating conditions, we used mixtures of Joomoonjin silica sand and clay. Although the average $PM_{10}$ concentration of Joomoonjin silica sand was low, dust concentrations were increased by an increased content of clay. The dust concentrations were consistent across repeated experiments, and showed similar concentration profiles during the sampling time with mixtures of clay and sand (coefficient of variation was $13.6{\pm}w;7.1%$). The results demonstrated that these standard operating conditions were suitable for the dust generator, which can be used to investigate variations in soil properties that affect dust production and potential potency of fugitive dust exposure.

Development of Dry Paddy Seeder of Strip Tillage (부분경운 건답직파기 개발)

  • 박석호;이동현;김학진;이채식;곽태용;조성찬
    • Journal of Biosystems Engineering
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    • v.27 no.1
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    • pp.25-32
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    • 2002
  • This study was conducted to develop a dry paddy seeder of strip tillage. The prototype is 8 rows drill seeder, which is composed of a strip tillage, sowing and fertilizing device, and pressing wheels to do the strip tillage, sowing, fertilizing, and draining ditch, simultaneously. The performances of prototype was evaluated through the investigation of fuel consumption, tillage torque, ratio of soil breaking, and economical efficiency and the results were compared with these of a dry paddy seeder that needs whole tillage. According to the USDA textural classification, the experiment field was composed of sandy loam which consisted of 56.8 of sand, 30.2 of silt and 13.0 % of clay, respectively. Its hardness ranged from 952 to 1,673 kPa depending on the soil depth, and its soil moisture content was 24.9%(d. b.) Fuel consumption of the prototype was 5,015g/hr at 2,000 rpm of engine, which was consequently 64% smaller than that of the conventional dry paddy seeder. For the tillage torque, it ranged from 132 to 206N$.$m depending on the tillage pitch, which was 10∼30% smaller than that of the conventional dry paddy seeder. The ratio of soil braking of the prototype was 87∼98%, whereas that of the conventional dry paddy seeder was 80∼97%. The working performance of the prototype was surveyed to be 3.8hours/ha, which was about 5 times higher than that of the conventional dry paddy seeder. The cost reduction of 26.3% was obtained by using the prototype.

A Study on the Evaluation of Dynamic Behavior and Liquefaction Cau8ed by Earthquake of Sea Dike Structures on the Ground (방조제 축조 예정지반의 지진에 의한 액상화 거동 평가)

  • 도덕현;장병욱;고재만
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.35 no.2
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    • pp.43-56
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    • 1993
  • The laboratory tests are performed on how the liquefaction potential of the sea dike structures on the saturated sand or silty sand seabed could be affected due to earthquake before and after construction results are given as follows ; 1. Earthquake damages to sea dike structures consist of lateral deformation, settlement, minor abnormality of the structures and differential settlement of embankments, etc. It is known that severe disasters due to this type of damages are not much documented. Because of its high relative cost of the preventive measures against this type of damages, the designing engineer has much freedom for the play of judgement and ingenuity in the selection of the construction methods, that is, by comparing the cost of the preventive design cost at a design stage to reconstruction cost after minor failure. 2. The factors controlling the liquefaction potential of the hydraulic fill structure are magnitude of earthquake(max. surface velocity), N-value(relative density), gradation, consistency(plastic limit), classification of soil(G & vs), ground water level, compaction method, volumetric shear stress and strain, effective confining stress, and primary consolidation. 3. The probability of liquefaction can be evaluated by the simple method based on SPT and CPT test results or the precise method based on laboratory test results. For sandy or silty sand seabed of the concerned area of this study, it is said that evaluation of liquefaction potential can be done by the one-dimensional analysis using some geotechnical parameters of soil such as Ip, Υt' gradation, N-value, OCR and classification of soils. 4. Based on above mentioned analysis, safety factor of liquefaction potential on the sea bed at the given site is Fs =0.84 when M = 5.23 or amax= 0.12g. With sea dike structures H = 42.5m and 35.5m on the same site Fs= 3.M~2.08 and Fs = 1.74~1.31 are obtained, respectively. local liquefaction can be expected at the toe of the sea dike constructed with hydraulic fill because of lack of constrained effective stress of the area.

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Physico-Chemical Properties on the Management groups of Upland Soils in Korea (밭유형(類型)에 따른 토양(土壤)의 이화학적(理化學的) 특성(特性))

  • Rim, Sang-Kyu;Hur, Bong-Koo;Jung, Sug-Jae;Hyeon, Geun-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.1
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    • pp.67-71
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    • 1997
  • To grasp the physico-chemical properties on the management groups of upland soil, the data obtained from the detailed soil survey which conducted from 1964 to 1979 by Agricultural sciences Institute, were analyzed and classified. The clay content in A horizon soil was low in sandy textured and well adapted types and high in heavy clayey type, and that in B horizon was lowest in volcanic ash type and highest in heavy clayey type. High organic matter content was found in the volcanic ash and plateau type. The correlations among soil physico-chemical properties were significant. Especially canon exchange capacity of B horizon soil was highly correlated with the content of available water, clay, silt and organic matter positively.

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