• Title/Summary/Keyword: salt transport

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Theoretical Analysis of Soil Desalination Characteristics for Underdrain System at Reclaimed Tidal Land (간척지 흙의 암거 설치조건에 따른 제염 특성의 이론적 해석)

  • Kim, Hyuntai;Seo, Donguk;Yoo, Chanho;Kim, Seogyeol
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.3
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    • pp.87-92
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    • 2015
  • Cultivation on reclaimed tidal land is often difficult in the problem such as high salinity of soil, bad drainage because of high level of groundwater. Many researches have been made efforts to solve these problems, but effect of improvement is low and practicality is insufficient. In this study, through numerical analysis of the transport properties of salt and water, we suggested underground drainage of the reclaimed land and the desalination promotion methods in the soil. The results of characteristic of desalination and seepage analysis of underdrain show that underdrain is able to increase twice of the underground seepage amount when installing perforated pipe with horizontal filter (width 50cm) more than installing only the perforated pipe. For soil which coefficient of permeability is below $1{\times}10^{-4}cm/s$ that desalination with pond water is not possible, a method to increase the permeability of the soil is necessary. Therefore, it was concluded that application of underdrain using perforated pipe with horizontal filter would be low-cost and practical.

Characteristics of Air Pollutants at Three Background Sites in Korea in the Winter of 1996/1997 (1996/1997년 겨울 우리나라 배경측정소에서의 대기오염 물질 특성)

  • 김용표
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.4
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    • pp.415-420
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    • 2000
  • The daily mean concentrations of PM2.5 mass ionic species carbonaceous species and HNO3, HCl, and NH3 were analyzed at three background sites in Korea : Kangwha, Kosan, and Dongbaik during two intensive field studies between December 1996 and January 1997, Four-day backward trajectory analysis was also carried out. The mean concentrations of anthropogenic species were higher at Kangwha and Dongbaik than Kosan. At these two sites themean concentrations of nitrate and ammonium/ammonia were higher than those of Kosan. It was suggested that these two sites be considered as the background sites of the Seoul Metropolitan Area and Pusan respectively. Major chemical components in fine particles were sulfate organic carbon nitrate and ammonium for all the sites. More than 90% of sulfate were non-sea-salt(nss) sulfates and most of the nss sulfate in PM2.5 might be present as ammonium sulfates at all sites. Most of air parcels arriving a Kangwha and Dongbaik were from the northern China. At Kosan during the measurement period half of air parcels were from the northern China and the other half from the southern China. At Kosan the concentrations of anthropogenic air pollutants originated from the southern China were higher than those typically observed from the northern China.

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Measurement Study at Kosan, Cheju Island during March-April, 1994: (I) Transport of Ambient Aerosol (고산에서의 1994년 3월 - 4월 측정연구: (I) 입자상 오염물질의 이동)

  • 김용표;박세옥;김진영;심상규;문길주;이호근;장광미;박경윤;강창희
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.1
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    • pp.79-90
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    • 1996
  • Total suspended particles were measured at Kosan, Cheju Island, Korea during the period of March 11 .sim. April 19, 1994. Concentrations of non-sea salt(nss) ions were higher than those measured at clean marine areas in Japan and other background marine areas in the world. Especially, nss sulfate concentration is compatable to thoes measured at Seoul. It is suggested that most nss sulfate concentration is originated from anthropogenic sources. Nss sulfate concentration shows strong correlation with ammonium and nss potassium concentrations while shows no a pparent correlation with nitrate and nss calcium concentrations. Nss calcium concentrations shows strong correlation with nss potassium and mss magnesium concentrations. It is deduced that nss potassium has two origins, one anthropogenic, the other crustal. Backward trajectory analysis results show the trajectories of air parcel during the measurement period were mostly originated from China. It is shown that cases of high nss sulfate with high nss calcium can occur when an air parcel originated from arid and semi-arid regions of morthwestern China or Mongolia passes through northeastern China.

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Characterization of Kinetics of Urea Hydrolysis in A Newly Reclaimed Tidal Soils

  • Kim, Hye-Jin;Park, Mi-Suk;Woo, Hyun-Nyung;Kim, Gi-Rim;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.1
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    • pp.84-90
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    • 2011
  • It is imperative to study the hydrolysis of urea in high saline-sodic condition of a newly reclaimed tidal land in order to overcome the problems associated with use of urea fertilizer. The methodology adopted in this study tried to get a convenient way of estimating rate for N transformation needed in N fate and transport studies by reviewing pH and salt contents which can affect the microbial activity which is closely related to the rate of urea hydrolysis. The hydrolysis of urea over time follows first-order kinetics and soil urease activity in reclaimed soils will be represented by Michaelis-Menten-type kinetics. However, high pH and less microorganisms may delay the hydrolysis of urea due to decrease in urease activity with increasing pH. Therefore, the rate of urea hydrolysis should adopt $V_{max}$ referring enzyme activity ($E_0$) accounting for urease concentration which is indicative for urea hydrolysis, especially in a high saline and sodic soils.

An integrated studies for salt-water intrusion in Yeonggwang-gun, Korea

  • Hwang Seho;Chi Sejung;Lee Won-suk;Shin Jehyun;Park Inhwa;Huh Dae-Gee;Lee Sang-kyu
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.455-458
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    • 2003
  • A combination of drilling, hydrogeochemical survey, geophysical survey and the numerical modelling for the flow and transport of groundwater was performed to evaluate the seawater intrusion in Baeksu-eup, Yeonggwang-gun, Korea. The survey area extends to over 24 $km^2$. Twelve wells were also drilled for the collection of geologic, geochemical, hydrologic, and geophysical logging data to delineate the degree and vertical extent of seawater intrusion. To evaluate and map the salinity in a coastal aquifer, geophysical data and hydrogeochemical results were used. Layer parameters derived from VES data, various in situ physical properties from geophysical well loggings, and the estimated equivalent NaCl concentration were used as the useful input parameters for the numerical simulation with density-dependent flow. Our multidisciplinary approach for evaluating the seawater intrusion can be considered as a valuable attempt to enhancing the utilization of various data and the reliability of numerical ground modelling.

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Trace Metals in Airborne Particulates Collected at Cheju Island, Korea (제주도 대기 분진 중 미량금속의 농도 특성)

  • 최만식;박은주
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.6
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    • pp.727-738
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    • 1999
  • Total 76 aerosol samples were collected at Sungsan in Cheju Inland by high volume air sample for 1 year, from May 1995 to April 1996, and were analyzed for major elements(Na, Mg, Ca, Al, Fe) and trace elements(Mn, Co, Ni, Zn, Cd, Pb, U) by ICP/AES and ICP/MS. This study aims to determine the concentrations of trace metals and their seasonal variations in the atmosphere of Cheju Island, where is the remote area from pollution sources and also is the midway of transport of Asian continental materials into the western North Pacific. The concentrations of Na and Mg contributed by sea-salt aerosols were similar to those in the western part of Cheju island(Kosan) and in the western coast of Korea(Mallipo). They showed the highest value in summer and the lowest in spring and winter. Crustal metals(Al, Fe, Ca, Mn, Co, U) were 2~3 times lower than those of Mallipo. These metals showed the lowest values in summer and the highest in spring. Pollution-derived metals (Zn, Cd and Pb) were 2~4 times lower than those in Malipo. Some elemental ratios in aerosols grouped by three wind directions(north-northwest, east, and south-southwest) such as Fe/Al and Pb/Zn are presented as useful tracers indicating source areas, and their differentiation may be explained by geology and fuel types of source areas.

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Electrochemical properties of metal salts polymer electrolyte for DSSC (금속염을 이용한 염료감응 태양전지의 고체전해질의 전기화학적 특성)

  • Zhao, Xing Guan;Jin, En Mei;Gu, Hal-Bon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.55.1-55.1
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    • 2011
  • Dye-sensitized solar cell(DSSC) have been considered one of the promising alternatives to conventional solar cells, because of their low cost, easy fabrication and relatively high energy conversion efficiency. However, although the cell offers reasonable efficiency at least 11%, the use of a liquid electrolyte placed technological challenges for achieving the desired durability and operational stability of the cell. In order to prevent or reduce electrolyte leakage considerable efforts have been made, such as p-type semiconductor or organic hole-transport material that better mechanical properties and simple fabrication processes. In this work, we synthesized solid-state electrolyte containing LiI and KI metal salt with starting materials of poly ethylene oxide to substitute liquid electrolyte enhance the ionic conductivity and solar conversion efficiency. Li+ leads to faster diffusion and higher efficiency and K+ leading to higher ionic conductivity. The efficiency of poly ethylene oxide/LiI system electrolyte is 1.47% and poly ethylene oxide/potassium electrolyte is 1.21%. An efficiency of 3.24% is achieved using solid-state electrolyte containing LiI and KI concentrations. The increased solar conversion efficiency is attributed to decreased crystallinity in the polymer that leads to enhanced charge transfer.

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Use of Solar Cell and Nanofiltration Membrane for System of Enzymatic $H_2$ Production Through Light-Sensitized Photoanode (광바이오 수소제조 시스템에서의 쏠라셀 및 나노여과 멤브레인 활용)

  • Shim, Eun-Jung;Bae, Sang-Hyun;Yoon, Jae-Kyung;Joo, Hyun-Ku
    • Journal of Hydrogen and New Energy
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    • v.18 no.2
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    • pp.151-156
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    • 2007
  • Solar cell and nanofiltration membrane were utilized in a system of enzymatic hydrogen production through light-sensitized photoanode, which resembles photoelectrochemical(PEC) configuration. Solar cell uses no additional light energy to increase energy for electrons to reduce protons and for holes to oxidize water to oxygen, and nanofiltration membrane replaces a salt bridge successfully with increased ion transport capability. With this system configuration, optimized amount of enzyme(10.98 unit), and an anodized tubular $TiO_2$ electrode($5^{\circ}C$/1 hr in 0.5 wt% HF-$650^{\circ}C$/5 hr) hydrogen evolved at a rate of ca. $43\;{\mu}mol/(cm^2{\times}hr)$ in a cathodic compartment and oxygen generated at a rate of ca. $20\;{\mu}mol/(cm^2{\times}hr)$ in an anodic compartment. The stoichiometric evolution of gases indicated that water was splitted in the system.

A Study on Validation of Variable Aperture Channel Model: Migration Experiments of Conservative Tracer in Parallel and Wedge-Shaped Fracture

  • Keum, D.K.;Hahn, P.S.;Vandergraaf, T.T.
    • Nuclear Engineering and Technology
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    • v.30 no.3
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    • pp.245-261
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    • 1998
  • In order to validate the variable aperture channel model that can deal with the non-uniform How rate in flow domain, migration experiments of conservative tracer were performed in two artificial fractures, a parallel and a wedge-shaped fracture. These different fracture shapes were designed to give different flow pattern. The fractures were made from a transparent acrylic plastic plate and a granite slab with dimensions of 10 $\times$ 61 $\times$ 61 cm. Uranine (Fluorescein sodium salt) was used as a conservative tracer. The volumetric flow rates of uranine feed solution were 30 mL/ hr, giving a mean residence time in the fracture of approximately 24 hours for the parallel fracture and 34 hours for the wedge-shaped fracture. The migration plumes of uranine were photographed to obtain profiles in space and time for movement of a tracer in fractures. The photographed migration plume was greatly affected by the geometric shape of fractures. The variable aperture channel model could have predicted the experimental results for the parallel fracture with a large accuracy. It is expected that the variable aperture channel model would be effective to predict the transport of the contaminant, especially, with the flow rate variation in a fracture.

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ONE-DIMENSIONAL ANALYSIS OF THERMAL STRATIFICATION IN THE AHTR COOLANT POOL

  • Zhao, Haihua;Peterson, Per F.
    • Nuclear Engineering and Technology
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    • v.41 no.7
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    • pp.953-968
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    • 2009
  • It is important to accurately predict the temperature and density distributions in large stratified enclosures both for design optimization and accident analysis. Current reactor system analysis codes only provide lumped-volume based models that can give very approximate results. Previous scaling analysis has shown that stratified mixing processes in large stably stratified enclosures can be described using one-dimensional differential equations, with the vertical transport by jets modeled using integral techniques. This allows very large reductions in computational effort compared to three-dimensional CFD simulation. The BMIX++ (Berkeley mechanistic MIXing code in C++) code was developed to implement such ideas. This paper summarizes major models for the BMIX++ code, presents the two-plume mixing experiment simulation as one validation example, and describes the codes' application to the liquid salt buffer pool system in the AHTR (Advanced High Temperature Reactor) design. Three design options have been simulated and they exhibit significantly different stratification patterns. One of design options shows the mildest thermal stratification and is identified as the best design option. This application shows that the BMIX++ code has capability to provide the reactor designers with insights to understand complex mixing behavior with mechanistic methods. Similar analysis is possible for liquid-metal cooled reactors.