• KEPCO Journal on Electric Power and Energy
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• v.2 no.1
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• pp.127-131
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• 2016

Polymer electrolyte membrane for unitized regenerative fuel cells requires high proton conductivity, high dimensional stability, low permeability, and low cost. However, DuPont's Nafion which is a commercial polymer electrolyte membrane has high permeability, high cost, and decreasing proton conductivity and dimensional stability over $80^{\circ}C$. To address these problems, sulfonated poly ether ether ketone (sPEEK) which is a low cost hydrocarbon polymer is selected as matrix polymer for the preparation of polymer electrolyte membrane. In addition, composite membrane with improved proton conductivity and dimensional stability is prepared by introducing sulfonated graphene oxide (sGO). The fundamental properties of polymer electrolyte membranes are analyzed by investigating membrane's water content, dimensional stability, proton conductivity, and morphology. The cell test is conducted to consider the possibility of application of sPEEK/sGO composite membrane for an unitized regenerative fuel cell.

• Composites Research
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• v.12 no.4
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• pp.8-16
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• 1999

In this study, when the applied directions of tensile loading is changed fatigue damage of quasi-isotropic composite laminates was discussed. Low cycle fatigue tests of $[0/-60/+60]_s$ laminates and $[+30/-30/90]_s$ laminates were carried out. Material systems used were AS4/Epoxy and AS4/PEEK. The fatigue damage of $[+30/-30/90]_s$ laminates differed from that of $[0/-60/+60]_s$ laminates. The position of delamination generated at AS4/Epoxy and AS4/PEEK $[+30/-30/90]_s$ laminates appeared differently according to the kind of matrix. Critical values of strain energy release rate were obtained by using the strain measured at the initiation of delamination. The experimental results agreed well with the results obtained by the proposed method for determining strain energy release rate.

• International Journal of Ocean System Engineering
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• v.3 no.3
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• pp.147-151
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• 2013

This study was to correctly estimate the friction and wear behavior of carbon fiber and PEEK sheet composites, and the validity of using them as alternatives to the metal-based materials used for artificial hip joints. Moreover, this work evaluated the friction coefficient according to the fiber ply orientation, along with the fractured surfaces of the carbon/PEEK composites. The unidirectional composites had higher friction coefficients than those multidirectional composites. This was caused by the debonding between the carbon fiber and the PEEK sheet, which was proportional to the contact area between the sliding surface and the carbon fiber. The friction test results showed that there was no significant differences in relation to the fiber ply orientation. However, in a case where the speed was 2.5 m/s, the friction coefficient was relatively large for configuration I. The friction surface of the specimen was analyzed using an electron microscope. In all cases, the debonding of the fiber and PEEK could be confirmed.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.4 s.175
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• pp.1055-1064
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• 2000

First, various specimen geometries, namely, coupon type, waisted type and dog-bone type, were examined to determine appropriate fatigue specimen of thermoplastic composite material AS4/PEEK and the n, fatigue strength of smooth and notched specimens of AS4/PEEK [-45/0/+45/90]2s was investigated. Fatigue tests were performed under load controlled condition at a stress ratio of 0. 1 at a frequency of 5Hz. Stiffness degradation of specimens with fatigue cycling was monitored using an automated unloading compliance technique. The waisted type specimen is found appropriate for smooth fatigue specimen geometry of AS4/PEEK. As for the effect of stress concentration, it is found that fatigue strength is higher for a 2mm-diameter hole notched specimen than a 5mm-diameter one. Fatigue notch factor decreases with the increase of fatigue life. These results are far different from the trend of fatigue strength of metallic materials. The stiffness variation of smooth specimen was only 4% at maximum until final fracture. On the other hand, the stiffness of hole notched specimen was reduced by 45% at maximum. Notched fatigue strength was compared between thermoplastic composite AS4/PEEK and thermosetting composite Graphite/Epoxy. In long-life fatigue (>104), the AS4/PEEK composite shows superior fatigue strength, but in short-life fatigue, the fatigue strength of the Graphite/Epoxy composite is nearly equal or somewhat higher than that of the AS4/PEEK composite.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.4
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• pp.396-403
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• 2004

The dielectric properties of Y-ray irradiated and thermally aged polyetheretherketone (PEEK) have been investigated. Results of the temperature dependency of dielectric properties indicated that the glass transition temperature of aged PEEK increased as radiative and thermal ageing. The frequency dependency of dielectric properties implied that the magnitude of radiation and thermal induced dipoles, ions increased as radiative and thermal ageing. The values of relaxation intensity calculated using Cole-Cole's circular arc can be useful for evaluation of degradation level of PEEK.

• Korean Chemical Engineering Research
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• v.55 no.3
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• pp.296-301
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• 2017

Recently, there are many efforts focused on development of more economical non-fluorinated membranes for PEMFCs (Proton Exchange Membrane Fuel Cells). In this study, sulfonated poly (ether ether ketone) (sPEEK) membrane reinforced with poly imide was made to enhance of membrane durability. In order to test durability of single (un-reinforced) membrane and reinforced membrane MEA (Membrane and Electrode Assembly), degradation accelerated stress test was used. Before and after degradation, I-V polarization curve, hydrogen crossover current, electrochemical surface area, membrane resistance and charge transfer resistance were measured. As a result of experiments, hydrogen crossover current of reinforced MEA was lower than that of single MEA, therefor durability of reinforced MEA was higher than that of single MEA. There was not especially short phenomena in reinforced MEA after degradation accelerated stress test.

• Journal of the Korean Society of Safety
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• v.13 no.4
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• pp.41-48
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• 1998

In this paper, an investigation was performed on the dynamic interlaminar fracture toughness of CFRP(carbon fiber reinforcement plastics) composite laminates. Composite laminates used in this experimentation are CF/EPOXY and CF/PEEK laminated plates. In the experiments, Split Hopkinson's Bar(SHPE) test was applied to dynamic and notched flexure test. The mode Ⅱ fracture toughness of each unidirectional CFRP was estimated by the analyzed deflection of the specimen and J-integral with the measured impulsive load and reactions at the supported points. As an experimental result, the vibration amplitude of CF/PEEK laminates appear more than that of CF/EPOXY laminates for the J-integral and displacement velocity at a measuring point. Also, it is thought that the dynamic fracture toughness of two kind specimens(CFRP/EPOXY and CF/PEEK) with the in crease of displacement velocity becomes a little greater at a measuring point within the range of measurement.

• The Journal of Advanced Prosthodontics
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• v.12 no.5
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• pp.307-315
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• 2020

PURPOSE. The purpose of this study was to evaluate the occurrence of displacement while tightening the screw of scan bodies, which were compared according to the material type. MATERIALS AND METHODS. Three types of scan bodies whose base regions were made up of polyether ether ketone (PEEK) material [Straumann Group, Dentium Group, and Myfit (PEEK) Group] and another scan body whose base region was made up of titanium material [Myfit (Metal) Group] were used (15 per group). The reference model was fabricated by aligning the scan body library on the central axis of the implant, and moving this position by the resin model. The screws of the scan bodies were tightened to the implant fixture with torques of 5 Ncm, 10 Ncm, and a hand tightening torque. After the application of the torque, the scan bodies were scanned using a laboratory scanner. To evaluate the vertical, horizontal, and 3-dimensional (3D) displacements, a 3D inspection software program was used. To examine the difference among groups, one-way analysis of variance and Tukey's HSD post hoc test were used (α=.05). RESULTS. There were significant differences in 3D, vertical, and horizontal displacements among the different types of scan bodies (P<.001). There was a significantly lower displacement in the Straumann group than in the Myfit (PEEK) and Dentium groups (P<.05). CONCLUSION. The horizontal displacement in all groups was less than 10 ㎛. With the hand tightening torque, a high vertical displacement of over 100 ㎛ occurred in PEEK scan bodies (Myfit and Dentium). Therefore, it is recommended to apply a tightening torque of 5 Ncm instead of a hand tightening torque.

• Journal of the Korean Society of Propulsion Engineers
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• v.5 no.2
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• pp.59-64
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• 2001

The purpose of this work is to investigate the static strength, the stress distribution, and the failure process of quasi-isotropic composite laminates made of two different matrices when loading directions are changed. We carried out static tests of $[0/-60/+60]_s$ and $[+30/-30/90]_s$ laminates. Two types of matrices used are AS4/epoxy and AS4/PEEK. The damage mechanisms of the quasi-isotropic laminate, $[0/-60/+60]_s$, strongly depend on the load direction applied to the laminate.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.8 no.2
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• pp.80-85
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• 1999

The purpose of this work is to investigate fatigue damage of quasi-isotropic laminates under tensile loading in different directions. Low cycle fatigue tests of [0/-60/+60]a laminates and [+30/-30/90]s lamina tes were carried out. Material systems used are AS4/Epoxy and AS4/PEEK. The fatigue damage of [+30/-30/90]s is very different from that of [0/-60/+60]s. The position of delamination generated at AS4/Epoxy and AS$/PEEK laminates were differentiated by the matrix difference that is, we suppose, the value of both GIcr(critical energy release rate of mode-I) and GIIIcr(critical energy release rate of mode-III) difference.